Safety Data Sheet

according to 1907/2006/EC, Article 31

Sodium Hypochlorite 6 %
Issued Date: 23.04.2020

1. Identification of the substance/ preparation & of the company / undertaking

PRODUCT NAME: Sodium Hypochlorite 6%

APPLICATION: Chlorine based Disinfectant & Cleaner

SUPPLIER: S & D Associates

No 36, Old Kesbewa Road,
Raththanapitiya,
Boralesgamuwa.
Tel: + 94 11 4515544
Fax: + 94 11 4515545
admin@sdchemlanka.com

EMERGENCY TELEPHONE : + 94 71 4883939 – Mr. Dayantha De Silva

2. Hazards identification

Causes burns. Contact with acids liberates toxic gas. Toxic to aquatic organisms.

CLASSIFICATION (1999/45/EC): C;R34,R31,R51

3. Composition / information on ingredients

DESCRIPTION: Sodium Hypochlorite Solution

Classification
Name EC No CAS-No Content
(67/548/EEC)
SODIUM HYPOCHLORITE
231-668-3 7681-52-9 6% C;R34, R31 N;R50
SOLUTION % Cl ACTIVE
SODIUM HYDROXIDE 215-185-5 1310-73-2 0-1% C;R35

The full text for all R-phrases are displayed in section 16

4. First aid measures

INHALATION:
Move the exposed person to fresh air at once. Get medical attention if any discomfort continues.
INGESTION:
DO NOT INDUCE VOMITING! Rinse mouth thoroughly. Drink a few glasses of water or milk. Get medical
attention immediately!
SKIN CONTACT:
Wash the skin immediately with soap and water. Get medical attention promptly if symptoms occur after
washing.
EYE CONTACT:
Promptly wash eyes with plenty of water while lifting the eye lids. Get medical attention immediately. Continue
to rinse.

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 Safety Data Sheet
according to 1907/2006/EC, Article 31
Sodium Hypochlorite 6 %
Issued Date: 23.04.2020

5. Fire-fighting measure
EXTINGUISHING MEDIA:
This product is not flammable. Use fire-extinguishing media appropriate for surrounding materials.
SPECIFIC HAZARDS:
When heated and in case of fire, harmful vapors/gases may be formed.
PROTECTIVE MEASURES IN FIRE:
Self contained breathing apparatus and full protective clothing must be worn in case of fire.

6. Accidental release measures

PERSONAL PRECAUTIONS:
Avoid contact with eyes. Avoid contact with skin.
ENVIRONMENTAL PRECAUTIONS:
This product is dangerous for the environment: Spillages or uncontrolled discharges into watercourses must be
immediately alerted to the CEA or other appropriate regulatory body.
SPILL CLEAN UP METHODS:
Small quantities may be flushed to drains with plenty of water. Large Spillages: Pick up with vacuum or
absorbent solid, store in closed container for disposal.

*7. Handling and storage

USAGE PRECAUTIONS:
Avoid contact with skin and eyes. Do not mix with other chemicals.

STORAGE PRECAUTIONS:
Store at moderate temperatures in a dry, well ventilated area. Keep in original container. Store away from
Oxidising material. Avoid alkali, acids, metal salts, and reducing agents. Toxic chlorine gas is released if product is
mixed with acidic materials.

8. Exposure controls/ personal protection

Name Std TWA – 8 hrs STEL – 15 min Notes

SODIUM
WEL 2 mg/m3
HYDROXIDE

WEL = Workplace Exposure Limit.

ENGINEERING MEASURES:
Not relevant.
RESPIRATORY EQUIPMENT:
Respiratory protection not required.
HAND PROTECTION:
Wear protective gloves. (Household rubber gloves.)
EYE PROTECTION:
Eye protection recommended.
OTHER PROTECTION:
Wear appropriate clothing to prevent any possibility of skin contact.

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 Safety Data Sheet
according to 1907/2006/EC, Article 31
Sodium Hypochlorite 6 %
Issued Date: 23.04.2020

9. Physical and chemical properties

APPEARANCE: Liquid
COLOUR : Light Yellow
ODOUR: Slightly Chlorine
SOLUBILITY: Soluble in water
BOILING POINT (°C): 101
RELATIVE DENSITY: 1.080 @ 20 °c
FLASH POINT (°C): Boils without flashing
MELTING POINT (°C): Not determined
pH-VALUE: 11.0-13.0
VISCOSITY: 29.6 – 44.1 cSt

10. Stability and reactivity

STABILITY:
Inadequately vented containers may become pressurized.
CONDITIONS TO AVOID:
Avoid exposure to high temperatures or direct sunlight.
MATERIALS TO AVOID:
Avoid alkalis, acids, metal salts and reducing agents.
HAZARDOUS DECOMPOSITION PRODUCTS:
Toxic chlorine gas is released if product is mixed with acidic materials.

11. Toxicological information

TOXICOLOGICAL INFORMATION:
Refer to section 2.
OTHER HEALTH EFFECTS:
Causes burns.
Contact with acids liberates toxic gas.
Acute toxicity, Serious eye damage/irritation, Respiratory or skin sensitization, CMR effects (carcinogenity,
mutagenicity and toxicity for reproduction), Specific target organ toxicity (single/repeated exposure) and Aspiration
hazard are not classified based on available information.

12. Ecological information

ECOTOXICITY:
Dangerous for the environment: Toxic to aquatic organisms.
LC 50, 96 Hrs, FISH mg/l Sodium Hypochlorite [CAS No. 7681-52-9] 0.03 - 0.2mg/l
BIOACCUMULATION:
The product does not contain any substances expected to be bioaccumulating.
DEGRADABILITY:
This product is chemically degradable.

13. Disposal considerations

DISPOSAL METHODS:
Discharge used solutions to drain. Small amounts (less than 5 Liters) of unwanted product may be flushed with
plenty of water to sewer. Larger volumes must be sent for disposal as special waste. Rinse out empty container with
water and consign to normal waste.

Printed Date : 23.04.2020 3/5

 Safety Data Sheet
according to 1907/2006/EC, Article 31
Sodium Hypochlorite 6 %
Issued Date: 23.04.2020

14. Transport information

PROPER SHIPPING NAME: HYPOCHLORITE SOLUTION

UN NO. ROAD 1791

ADR CLASS Class 8: Corrosive substances.
ADR PACK GROUP II
RID CLASS NO. Class 8: Corrosive substances.
RID PACK GROUP II

UN NO. SEA 1791

IMDG CLASS Class 8: Corrosive substances.
IMDG PACK GR. II
MARINE POLLUTANT Yes.
IMDG CODE 8. Hypochlorites

UN NO. AIR 1791

AIR CLASS Class 8: Corrosive substances.
AIR PACK GR. II

15. Regulatory information

LABELLING:

C
Corrosive

RISK PHRASES:
R34 Causes burns.
R31 Contact with acids liberates toxic gas.
R51 Toxic to aquatic organisms.

SAFETY PHRASES:
S1 - Keep locked up.
S22- Do not breath dust.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S27/28 - After contact with skin, take off immediately all contaminated clothing, and wash immediately with plenty
of water.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S46 - If swallowed, seek medical advice immediately and show this container or label.
S61 - Avoid release to the environment.
S63 - In case of accident by inhalation: remove casualty to fresh air and keep at rest.

ENVIRONMENTAL LISTING:
Hazardous Waste CEA Regulations.
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 Safety Data Sheet
according to 1907/2006/EC, Article 31
Sodium Hypochlorite 6 %
Issued Date: 23.04.2020

EU DIRECTIVES:
1907/2006/EC - REACH
67/548/EEC - Approximation of laws ,regulations & administrative provisions relating to the classification ,
packaging & labeling of dangerous substances.
1999/45/EC - Approximation of laws ,regulations & administrative provisions of the member states relating to
the classification , packaging & labeling of dangerous preparations.
98/24/EC - Protection of health & safety of workers from the risks related to chemical agents & work.

GUIDANCE NOTES
Workplace Exposure Limits EH40. As amended in 2005. Approved guide to the Classification and Labeling of
Substances and Preparations Dangerous for Supply. L100

16. Other information

This information is based on our present knowledge. However , this shall not constitute a guarantee for any specific
product features and shall not establish a legally valid contractual relationship.

RISK PHRASES IN FULL:

R35 Causes severe burns.
R31 Contact with acids liberates toxic gas.
R34 Causes burns.
R35 Causes severe burns.
R50 Very toxic to aquatic organisms.
R51 Toxic to aquatic organisms.

CONTACT : Mr.Dayantha De Silva ( Refer Section 1)

ISSUED DATE : 22.04.2020

Printed Date : 23.04.2020 5/5