Version : 1.

2
Date of preparation : 14 January 2018
Previous date : 20 November 2014

SAFETY DATA SHEET

PETROFLO 20Y25
1. Identification
Product identifier PETROFLO 20Y25
Other means of identification None.
Recommended use of the chemical and restrictions on use
Recommended use An oil based antifoulant
Recommended restrictions None known.
Company/undertaking identification
SUEZ Water Technologies & Solutions Singapore Pte. Ltd.
10, Tanjong Penjuru Crescent
608973
Singapore
Tel: (65) 6268 4366

Emergency telephone
+(65)-31581349/800-101-2201 (Singapore)

+1 703-527-3887 (US)

2. Hazards identification
GHS classification
Physical hazards Not classified.
Health hazards Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 1
Sensitization, skin Category 1
Carcinogenicity Category 2
Specific target organ toxicity, single exposure Category 3 narcotic effects
Specific target organ toxicity, repeated Category 1
exposure
Aspiration hazard Category 1
Environmental hazards Hazardous to the aquatic environment, Category 2
long-term hazard
GHS label elements, including precautionary statements
Pictograms

Signal word Danger

Hazard statements
Precautionary statement
Prevention
May be fatal if swallowed and enters airways. Causes skin irritation. May cause an allergic skin
reaction. Causes serious eye damage. May cause drowsiness or dizziness. Suspected of
causing cancer. Causes damage to organs through prolonged or repeated exposure. Toxic to
aquatic life with long lasting effects.
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Wear eye/face protection. Do not breathe mist or vapor. Do not get in eyes, on
skin, or on clothing. Wash thoroughly after handling. Do not eat, drink or smoke when using this
product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be
allowed out of the workplace. Avoid release to the environment. Wear protective gloves/protective
clothing/eye protection/face protection. Avoid breathing dust/fume/gas/mist/vapours/spray.

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SAFETY DATA SHEET

PETROFLO 20Y25
Response IF SWALLOWED: Immediately call a POISON CENTER/doctor. Do NOT induce vomiting. IF ON
SKIN: Wash with plenty of water. IF INHALED: Remove person to fresh air and keep comfortable
for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
Specific treatment (see this label). If skin irritation or rash occurs: Get medical advice/attention.
Take off contaminated clothing and wash it before reuse. Collect spillage. IF SWALLOWED:
Storage Store in accordance with local/regional/national/international regulations. Store in a well-ventilated
place. Keep container tightly closed. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Other hazards which do not None known.
result in classification
Supplemental information None.

3. Composition/information on ingredients
Substance or mixture Mixtures
Composition
Chemical name CAS # Concentration (%)
Solvent naphtha (petroleum),heavy aromatic 64742-94-5 10 - < 20

Distillates (petroleum), hydrotreated light paraffinic 64742-55-8 5 - < 10

Distillates (petroleum), solvent-dewaxed light paraffinic 64742-56-9 5 - < 10

Petroleum distillates,hydrotreated heavy paraffinic 64742-54-7 5 - < 10

1,2,3-trimethylbenzene 526-73-8 1 - < 10

1,2,4-Trimethylbenzene 95-63-6 1 - < 10

Naphthalene 91-20-3 1-<5

4. First-aid measures
Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON
CENTER or doctor/physician if you feel unwell.
Skin contact Remove contaminated clothing immediately and wash skin with soap and water. In case of
eczema or other skin disorders: Seek medical attention and take along these instructions. Wash
contaminated clothing before reuse.
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention immediately.
Ingestion Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn't get into the lungs.
Most important Aspiration may cause pulmonary edema and pneumonitis. May cause drowsiness and dizziness.
symptoms/effects, acute and Headache. Nausea, vomiting. Severe eye irritation. Symptoms may include stinging, tearing,
delayed redness, swelling, and blurred vision. Permanent eye damage including blindness could result.
Skin irritation. May cause redness and pain. May cause an allergic skin reaction. Dermatitis. Rash.
Prolonged exposure may cause chronic effects.
Indication of immediate Provide general supportive measures and treat symptomatically. Keep victim under observation.
medical attention and special Symptoms may be delayed.
treatment needed
General information IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice
(show the label where possible). Ensure that medical personnel are aware of the material(s)
involved, and take precautions to protect themselves. Wash contaminated clothing before reuse.

5. Fire-fighting measures
Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from During fire, gases hazardous to health may be formed.
the chemical

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SAFETY DATA SHEET
PETROFLO 20Y25
Fire fighting
equipment/instructions
Special protective equipment
and precautions for firefighters
Specific methods
General fire hazards
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Environmental precautions
Spill cleanup methods
7. Handling and storage
Precautions for safe handling
Conditions for safe storage,
including any incompatibilities
8. Exposure controls/personal protection
Occupational exposure limits
Singapore Permissible Exposure Limit of Toxic Substances by Workplace Safety and Health Regulation
Components
1,2,3-trimethylbenzene
(CAS 526-73-8)
1,2,4-Trimethylbenzene
(CAS 95-63-6)
Distillates (petroleum),
hydrotreated light paraffinic
(CAS 64742-55-8)
Distillates (petroleum),
solvent-dewaxed light
paraffinic (CAS 64742-56-9)
Naphthalene (CAS 91-20-3)
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Move containers from fire area if you can do so without risk.
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Use standard firefighting procedures and consider the hazards of other involved materials.
No unusual fire or explosion hazards noted.
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear
appropriate protective equipment and clothing during clean-up. Do not breathe mist or vapor. Do
not touch damaged containers or spilled material unless wearing appropriate protective clothing.
Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be
contained. For personal protection, see section 8 of the SDS.
Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all
environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into
drains, water courses or onto the ground.
Prevent product from entering drains.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product
recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re-use. Put material in suitable, covered, labeled
containers. For waste disposal, see section 13 of the SDS.
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Do not breathe mist or vapor. Do not get this material in contact with eyes. Avoid
contact with eyes, skin, and clothing. Avoid prolonged exposure. When using, do not eat, drink or
smoke. Should be handled in closed systems, if possible. Provide adequate ventilation. Wear
appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid release
to the environment. Observe good industrial hygiene practices.
Store locked up. Keep container tightly closed. Store away from incompatible materials (see
Section 10 of the SDS).
Type Value Form
TWA 123 mg/m3
25 ppm
TWA 123 mg/m3
25 ppm
STEL 10 mg/m3 Mist.
TWA 5 mg/m3 Mist.
STEL 10 mg/m3 Mist.
TWA 5 mg/m3 Mist.
STEL 79 mg/m3
15 ppm
TWA 52 mg/m3
10 ppm
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SAFETY DATA SHEET

PETROFLO 20Y25

Singapore Permissible Exposure Limit of Toxic Substances by Workplace Safety and Health Regulation
Components Type Value Form
Petroleum STEL 10 mg/m3 Mist.
distillates,hydrotreated
heavy paraffinic (CAS
64742-54-7)
TWA 5 mg/m3 Mist.
Solvent naphtha TWA 1370 mg/m3
(petroleum),heavy aromatic
(CAS 64742-94-5)
300 ppm
Control parameters/Occupational exposure limits
US. ACGIH Threshold Limit Values
Components Type Value Form
1,2,3-trimethylbenzene TWA 25 ppm
(CAS 526-73-8)
1,2,4-Trimethylbenzene TWA 25 ppm
(CAS 95-63-6)
Distillates (petroleum), TWA 5 mg/m3 Inhalable fraction.
hydrotreated light paraffinic
(CAS 64742-55-8)
Distillates (petroleum), TWA 5 mg/m3 Inhalable fraction.
solvent-dewaxed light
paraffinic (CAS 64742-56-9)
Naphthalene (CAS 91-20-3) TWA 10 ppm
Petroleum TWA 5 mg/m3 Inhalable fraction.
distillates,hydrotreated
heavy paraffinic (CAS
64742-54-7)
Solvent naphtha TWA 200 mg/m3 Non-aerosol.
(petroleum),heavy aromatic
(CAS 64742-94-5)
Biological limit values
ACGIH Biological Exposure Indices
Components Value Determinant Specimen Sampling Time
Naphthalene (CAS 91-20-3) 2.5 µg/l 1-Hydroxypyre Urine *
ne, with
hydrolysis
(1-HP)
* - For sampling details, please see the source document.
Exposure guidelines
US ACGIH Threshold Limit Values: Skin designation
Naphthalene (CAS 91-20-3) Can be absorbed through the skin.
Solvent naphtha (petroleum),heavy aromatic (CAS Can be absorbed through the skin.
64742-94-5)
Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
control measures should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level. Provide
eyewash station. Eye wash fountain and emergency showers are recommended.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles) and a face shield.

Skin protection
Hand protection Wear appropriate chemical resistant gloves.
Other Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.

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SAFETY DATA SHEET

PETROFLO 20Y25
Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene Observe any medical surveillance requirements. Always observe good personal hygiene
considerations measures, such as washing after handling the material and before eating, drinking, and/or
smoking. Routinely wash work clothing and protective equipment to remove contaminants.
Contaminated work clothing should not be allowed out of the workplace.

9. Physical and chemical properties

Appearance
Physical state Liquid.
Form Not available.
Color Not available.
Odor Not available.
Odor threshold Not available.
pH in aqueous solution 4.9 (50% EXTRACT)
Melting point/freezing point -22 °C
Initial boiling point and boiling 177 °C
range
Flash point 73 °C SETA(CC)
Evaporation rate < 1 (Ether = 1)
Flammability (solid, gas) Not applicable.
Flammability limit - lower (%) Not available.
Flammability limit - upper (%) Not available.
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 4.2 mm Hg
Vapor pressure temp. 22 °C
Vapor density > 1 (Air = 1)
Relative density 0.91
Relative density temperature 21 °C
Solubility(ies)
Solubility (water) 0%
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity 334 cps
Viscosity temperature 21 °C
Other data
Explosive properties Not explosive.
Oxidizing properties Not oxidizing.
Specific gravity 0.912
VOC (Weight %) 35 % (Estimated)

10. Stability and reactivity

Reactivity
Chemical stability
Possibility of hazardous
reactions
Conditions to avoid
The product is stable and non-reactive under normal conditions of use, storage and transport.
Not available.
Hazardous polymerization does not occur.
Not available.

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SAFETY DATA SHEET

PETROFLO 20Y25
Incompatible materials Strong oxidizing agents.
Hazardous decomposition No hazardous decomposition products are known.
products

11. Toxicological information

Information on likely routes of exposure
Inhalation May cause damage to organs through prolonged or repeated exposure by inhalation. May cause
drowsiness and dizziness. Headache. Nausea, vomiting.
Skin contact Causes skin irritation. May cause an allergic skin reaction.
Eye contact Causes serious eye damage.
Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious
chemical pneumonia.

Acute toxicity May be fatal if swallowed and enters airways.

Product Species Test Results
PETROFLO 20Y25 (CAS Mixture)
Acute
Dermal
LD50 Rabbit > 5000 mg/kg, (Calculated according to
GHS additivity formula)
Inhalation
LC50 Rat 9.52 mg/l, 4 Hours, (Calculated according
to GHS additivity formula)
Oral
LD50 Rat > 5000 mg/kg, (Calculated according to
GHS additivity formula)
Components Species Test Results
1,2,3-trimethylbenzene (CAS 526-73-8)
Acute
Oral
LD50 Rat > 5000 mg/kg
1,2,4-Trimethylbenzene (CAS 95-63-6)
Acute
Dermal
LD50 Rabbit > 3160 mg/kg
Inhalation
LC50 Rat 18 mg/L, 4 Hour
Oral
LD50 Rat 5000 mg/kg
Distillates (petroleum), solvent-dewaxed light paraffinic (CAS 64742-56-9)
Acute
Dermal
LD50 Rabbit > 5000 mg/kg
Inhalation
LC50 Rat > 5 mg/l, 4 Hours
Oral
LD50 Rat > 5000 mg/kg
Naphthalene (CAS 91-20-3)
Acute
Dermal
LD50 Rabbit > 16000 mg/kg

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SAFETY DATA SHEET

PETROFLO 20Y25
Components Species Test Results
Oral
LD50 Rat > 2000 mg/kg
Petroleum distillates,hydrotreated heavy paraffinic (CAS 64742-54-7)
Acute
Dermal
LD50 Rabbit > 5000 mg/kg
Inhalation
LC50 Rat > 2.18 mg/l/4h
Oral
LD50 Rat > 5000 mg/kg
Solvent naphtha (petroleum),heavy aromatic (CAS 64742-94-5)
Acute
Dermal
LD50 Rabbit > 3160 mg/kg
Inhalation
LC50 Rat > 5.2 mg/L, 4 Hour
Oral
LD50 Rat 7050 mg/kg
UVCB substance(s) Species Test Results
Hydrocarbons, C10, aromatics, >1% naphthalene (CAS N/A)
Acute
Dermal
LD50 Rabbit > 2000 mg/kg
Inhalation
LC50 Rat > 4688 mg/m3, (Saturated vapor
concentration)
Oral
LD50 Rat > 2000 mg/kg

Symptoms
Skin corrosion/irritation
Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitization
Skin sensitization
Germ cell mutagenicity
<NO INDENT>Carcinogenicity
IARC Monographs. Overall Evaluation of Carcinogenicity
Naphthalene (CAS 91-20-3)
Petroleum distillates,hydrotreated heavy paraffinic (CAS 3 Not classifiable as to carcinogenicity to humans.
64742-54-7)
Reproductive toxicity
Specific target organ toxicity -
single exposure
Specific target organ toxicity -
repeated exposure
Aspiration may cause pulmonary edema and pneumonitis. May cause drowsiness and dizziness.
Headache. Nausea, vomiting. Severe eye irritation. Symptoms may include stinging, tearing,
redness, swelling, and blurred vision. Permanent eye damage including blindness could result.
Skin irritation. May cause redness and pain. May cause an allergic skin reaction. Dermatitis.
Rash.
Prolonged skin contact may cause temporary irritation.
Causes serious eye damage.
Not a respiratory sensitizer. This product is not expected to cause respiratory sensitization.
May cause an allergic skin reaction.
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
2B Possibly carcinogenic to humans.
This product is not expected to cause reproductive or developmental effects.
May cause drowsiness and dizziness.
Causes damage to organs through prolonged or repeated exposure.

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PETROFLO 20Y25
Aspiration hazard Not an aspiration hazard.
Chronic effects Causes damage to organs through prolonged or repeated exposure. Prolonged inhalation may be
harmful.

12. Ecological information

Ecotoxicity Toxic to aquatic life with long lasting effects.
Product Species Test Results
PETROFLO 20Y25 (CAS Mixture)
LC50 Fathead Minnow 7.6 mg/L, Acute Toxicity, 96 hour,
(Estimated)
Aquatic
Crustacea LC50 Daphnia magna 23 mg/L, Static Acute Bioassay, 48 hour
Fish LC50 Rainbow Trout 14.3 mg/L, Static Acute Bioassay, 96
hour
Bioaccumulative potential
Octanol/water partition coefficient log Kow
Naphthalene 3.3
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
Environmental fate Toxic to aquatic life with long lasting effects.
Persistence and degradability

13. Disposal considerations

Disposal methods/information Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds,
waterways or ditches with chemical or used container. Dispose of contents/container in
accordance with local/regional/national/international regulations.

14. Transport information

IATA
UN number UN3082
UN proper shipping name Environmentally hazardous substance, liquid, n.o.s. (SOLVENT NAPHTHA, PETROLEUM,
HEAVY AROMATIC, NAPHTHALENE)
Transport hazard class(es)
Class 9
Subsidiary risk -
Packing group III
Environmental hazards Yes
ERG Code 171
Special precautions for user Not available.
IMDG
UN number UN3082
UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (SOLVENT NAPHTHA,
PETROLEUM, HEAVY AROMATIC, NAPHTHALENE), MARINE POLLUTANT
Transport hazard class(es)
Class 9
Subsidiary risk -
Packing group III
Environmental hazards
Marine pollutant Yes
EmS F-A, S-F
Special precautions for user Not available.
Transport in bulk according to Not established.
Annex II of MARPOL 73/78 and
the IBC Code

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SAFETY DATA SHEET

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IATA; IMDG

Marine pollutant

15. Regulatory information

Safety, health and environmental regulations specific for the product in question
Controlled Narcotic Drugs (Misuse of Drugs Act, First Schedule, Part I, II & III)
Not regulated.
Controlled Specified Drugs (Misuse of Drugs Act, Fourth Schedule)
Not regulated.
Prior Informed Consent (PIC) Substances (Environment Protection and Management Act, 2nd Schedule, Part 1, Jul. 1,
2013)
Not regulated.
Chemical Weapons Prohibition (Act)
Not applicable.
Environmental Protection and Management (Hazardous Substances) Regulations
Not applicable.
Environmental Public Health Act
Not applicable.
International regulations
Montreal Protocol
Not applicable.
Stockholm Convention
Not applicable.
Rotterdam Convention
Not applicable.
Kyoto protocol
Not applicable.
Basel Convention
Naphthalene (CAS 91-20-3)
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) Yes
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes

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SAFETY DATA SHEET

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Country(s) or region Inventory name On inventory (yes/no)*

Europe European Inventory of Existing Commercial Chemical Yes
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) Yes
Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory Yes
Philippines Philippine Inventory of Chemicals and Chemical Substances Yes
(PICCS)
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other information

Issued by Not available.
Prepared by Not available.
Disclaimer Not available.
Issue date Nov-20-2014
Revision date 14/01/2018
Revision information This document has undergone significant changes and should be reviewed in its entirety.
* Trademark of SUEZ. May be registered in one or more countries.

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