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  • Kurva Kalibrasi Larutan Standar C-Organik: 1. Penentuan Linieritas

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    aprilia kurnia putri
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    1. This document describes experiments to determine the linearity, limit of detection, limit of quantification, precision, accuracy, and water content of an analytical method. 2. The method was found to be linear with an R2 value of 0.9983. The limit of detection was determined to be 13.94 mg/L and the limit of quantification was 46.47 mg/L. 3. Precision experiments on samples and spiked samples yielded %RSD values below the acceptable 2/3 Horwitz criterion, indicating the method has good precision. The method accuracy was determined to be 186% based on a recovery experiment.

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    Penentuan C-organik

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    1. This document describes experiments to determine the linearity, limit of detection, limit of quantification, precision, accuracy, and water content of an analytical method. 2. The method was found to be linear with an R2 value of 0.9983. The limit of detection was determined to be 13.94 mg/L and the limit of quantification was 46.47 mg/L. 3. Precision experiments on samples and spiked samples yielded %RSD values below the acceptable 2/3 Horwitz criterion, indicating the method has good precision. The method accuracy was determined to be 186% based on a recovery experiment.

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    30 views4 pages

    Kurva Kalibrasi Larutan Standar C-Organik: 1. Penentuan Linieritas

    Uploaded by

    aprilia kurnia putri
    1. This document describes experiments to determine the linearity, limit of detection, limit of quantification, precision, accuracy, and water content of an analytical method. 2. The method was found to be linear with an R2 value of 0.9983. The limit of detection was determined to be 13.94 mg/L and the limit of quantification was 46.47 mg/L. 3. Precision experiments on samples and spiked samples yielded %RSD values below the acceptable 2/3 Horwitz criterion, indicating the method has good precision. The method accuracy was determined to be 186% based on a recovery experiment.

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    © All Rights Reserved
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    of 4

    1.

    Penentuan Linieritas
    Absorbansi
    Kosentrasi Standar (mg/L) Rata-rata Kurva
    1 2 3
    0 0 0 0 0.000 0.600
    25 0.053 0.054 0.054 0.054
    0.500
    50 0.115 0.116 0.115 0.115 f(x) = 0.00
    100 0.203 0.203 0.203 0.203 0.400 R² = 0.998

    Absorbansi
    150 0.286 0.285 0.285 0.285
    0.300
    200 0.384 0.384 0.384 0.384
    250 0.477 0.477 0.477 0.477 0.200

    0.100
    Slope 0.0019
    Intersep 0.0092 0.000
    0
    R2 0.9983
    r 0.9991

    2. Penentuan LOD dan LOQ


    Kosentrasi Standar (mg/L) Y Yi (Y-Yi)2
    0 0.000 0.0092 8.464E-05
    25 0.054 0.0567 9.20111111E-06
    50 0.115 0.1042 0.00012395111
    100 0.203 0.1992 1.444E-05
    150 0.285 0.2942 7.86177778E-05
    200 0.384 0.3892 2.704E-05
    250 0.477 0.4842 5.184E-05
    Jumlah 0.00038973
    Sy/x 0.00882870319
    LOD 13.9400576669
    LOQ 46.4668588896

    3. Penentuan Presisi
    a. Presisi sampel
    Absorbansi
    Keterangan Rata-rata
    1 2 3 ×
    Sampel 1 0.116 0.116 0.116 0.116 56.210526
    Sampel 2 0.117 0.117 0.117 0.117 56.736842
    Sampel 3 0.112 0.112 0.112 0.112 54.105263
    Jumlah

    C 5.5684211E-05
    Log C -4.2542679333
    CV Horwitz 4.12713396663
    2/3 CV Horwitz 2.75142264442
    b. Presisi spike
    Absorbansi
    Keterangan Rata-rata
    1 2 3 ×
    Spike 1 0.285 0.285 0.285 0.285 145.15789
    Spike 2 0.287 0.287 0.287 0.287 146.21053
    Spike 3 0.304 0.304 0.304 0.304 155.15789
    Jumlah

    4. Penentuan Akurasi
    Vs (mL) Cs (mg/L) V (mL) Cs %Recovery
    0.5 5.000 50 0.05 186.31579

    5. Penentuan Kadar air


    Keterangan Massa (g) Kadar Air (%)
    W0 50.6279
    W1 51.6296 89.70
    W2 51.5264
    Kurva Kalibrasi Larutan Standar C-Organik
    0.600

    0.500
    f(x) = 0.001876040955631 x + 0.009200227531286
    0.400 R² = 0.998316955716764
    Absorbansi

    0.300

    0.200

    0.100

    0.000
    0 50 100 150 200 250 300
    Konsentrasi (mg/L)

    × ̅ (×- × ̅)2 SD %RSD


    0.27700831
    55.68421 1.108033241 1.392501 2.50
    2.493074792
    Jumlah 3.878116343
    × ̅ (×−× ̅ )2 SD %RSD
    13.5734072 150.7731 101.2974 C 0.000149
    148.8421 21377.51801 Log C -3.827274
    24073.9723 CV Horwitz 3.913637
    45465.06371 2/3 CV Hor 2.609091

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