Planilha para Calcular um Diagrama T-x-y usando a Lei de Raoult

Espécie 1 é acetonitrila, espécie 2 é nitrometano, como na Fig. 12.12

Coeficientes de Antoine (para T em graus C e P em kPa)

P (kPa) A1 B1 C1 A2 B2 C2 SUM((P-Pspec)2)
70 14.895 3413.1 250.523 14.7513 3331.7 227.6 0.00

x1 x2 T (deg C) P1sat P2sat P (kPa) (P-Pspec)2 y1 y2

0.00 1.00 89.62 129.11 70.00 70.00 0.00 0.00 1.00
Diagr

Temperatura (grau C)
0.02 0.98 89.11 127.19 68.83 70.00 0.00 0.04 0.96
Aceto
0.04 0.96 88.61 125.32 67.70 70.00 0.00 0.07 0.93
0.06 0.94 88.12 123.49 66.59 70.00 0.00 0.11 0.89
95.00
0.08 0.92 87.63 121.70 65.50 70.00 0.00 0.14 0.86
0.10 0.90 87.14 119.96 64.45 70.00 0.00 0.17 0.83
0.12 0.88 86.67 118.25 63.42 70.00 0.00 0.20 0.80 90.00
0.14 0.86 86.19 116.58 62.42 70.00 0.00 0.23 0.77
0.16 0.84 85.73 114.95 61.44 70.00 0.00 0.26 0.74
0.18 0.82 85.27 113.36 60.48 70.00 0.00 0.29 0.71 85.00
0.20 0.80 84.81 111.81 59.55 70.00 0.00 0.32 0.68
0.22 0.78 84.36 110.28 58.64 70.00 0.00 0.35 0.65
0.24 0.76 83.91 108.80 57.75 70.00 0.00 0.37 0.63 80.00

0.26 0.74 83.47 107.34 56.88 70.00 0.00 0.40 0.60

0.28 0.72 83.04 105.92 56.03 70.00 0.00 0.42 0.58
0.30 0.70 82.61 104.53 55.20 70.00 0.00 0.45 0.55 75.00

0.32 0.68 82.18 103.16 54.39 70.00 0.00 0.47 0.53

0.34 0.66 81.76 101.83 53.60 70.00 0.00 0.49 0.51
70.00
0.36 0.64 81.34 100.52 52.83 70.00 0.00 0.52 0.48
0.38 0.62 80.93 99.25 52.07 70.00 0.00 0.54 0.46
0.40 0.60 80.52 98.00 51.34 70.00 0.00 0.56 0.44
65.00
0.42 0.58 80.12 96.77 50.61 70.00 0.00 0.58 0.42 0.00 0
0.44 0.56 79.72 95.57 49.91 70.00 0.00 0.60 0.40
0.46 0.54 79.33 94.40 49.22 70.00 0.00 0.62 0.38
0.48 0.52 78.94 93.25 48.54 70.00 0.00 0.64 0.36
0.50 0.50 78.55 92.12 47.88 70.00 0.00 0.66 0.34
0.52 0.48 78.17 91.02 47.23 70.00 0.00 0.68 0.32
0.54 0.46 77.79 89.93 46.60 70.00 0.00 0.69 0.31
0.56 0.44 77.41 88.87 45.98 70.00 0.00 0.71 0.29
0.58 0.42 77.04 87.83 45.37 70.00 0.00 0.73 0.27
0.60 0.40 76.68 86.81 44.78 70.00 0.00 0.74 0.26
0.62 0.38 76.31 85.81 44.20 70.00 0.00 0.76 0.24
0.64 0.36 75.96 84.83 43.63 70.00 0.00 0.78 0.22
0.66 0.34 75.60 83.87 43.07 70.00 0.00 0.79 0.21
0.68 0.32 75.25 82.93 42.52 70.00 0.00 0.81 0.19
0.70 0.30 74.90 82.01 41.99 70.00 0.00 0.82 0.18
0.72 0.28 74.55 81.10 41.46 70.00 0.00 0.83 0.17
0.74 0.26 74.21 80.21 40.95 70.00 0.00 0.85 0.15
0.76 0.24 73.87 79.33 40.45 70.00 0.00 0.86 0.14
0.78 0.22 73.54 78.48 39.95 70.00 0.00 0.87 0.13
0.80 0.20 73.21 77.63 39.47 70.00 0.00 0.89 0.11
0.82 0.18 72.88 76.81 38.99 70.00 0.00 0.90 0.10
0.84 0.16 72.55 75.99 38.53 70.00 0.00 0.91 0.09
0.86 0.14 72.23 75.20 38.07 70.00 0.00 0.92 0.08
0.88 0.12 71.91 74.42 37.62 70.00 0.00 0.94 0.06
0.90 0.10 71.60 73.65 37.18 70.00 0.00 0.95 0.05
0.92 0.08 71.28 72.89 36.75 70.00 0.00 0.96 0.04
0.94 0.06 70.97 72.15 36.33 70.00 0.00 0.97 0.03
0.96 0.04 70.67 71.42 35.91 70.00 0.00 0.98 0.02
0.98 0.02 70.36 70.70 35.51 70.00 0.00 0.99 0.01
1.00 0.00 70.06 70.00 35.11 70.00 0.00 1.00 0.00
 Para achar a temperatura que dá a pressão especificada em cada
composição, use a função Solver para levar a célula I5 (identificada por
SUM((P-Pspec)2) a um mínimo através da mudança de todas as entradas
de temperatura (células C8 a C58).

Diagrama T-x-y para

Temperatura (grau C)

Acetonitrila(1)/Nitrometano(2), a 70 kPa

95.00

90.00

85.00

80.00

75.00

70.00

65.00
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00

x1 ou y1
Geraldo:
VERIFICAR TERMO
DESTACADO NA CÉLULA
U30