6/19/2021 CN1056907A - A kind of process for brightly plating of zinc for metal wire - Google Patents

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A kind of process for brightly plating of zinc for metal wire

Abstract
CN1056907A
The invention belongs to the technical recipe of metal wire electro-galvanizing, it is characterized in
China
that electroplate liquid formulation is a zinc chloride 180-250 grams per liter, Repone K 180-200
grams per liter, boric acid 25-30 grams per liter, 20 to 30 milliliters/liter of additives that contain
compositions such as card fork acetone, polyoxyethylene nonyl ethers, dye leveller, Sodium Download PDF
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Benzoate, current density is 15 to 30 amperes/square decimeter during plating, and this technology
has the advantages that electroplating time is short, bright dipping is fast, current density is high, the Other languages: Chinese
turbidity temperature is high, the fine and close light of wire rod coating.
Inventor: 张国轩, 尹淑玲, 张士杰, 张学军, 刘汉权

Worldwide applications

1990

CN

Application CN 90110089 events

1990-12-22 Application filed by 石家庄市铁丝厂

1990-12-22 Priority to CN 90110089

1991-12-11 Publication of CN1056907A

1993-09-01 Application granted

1993-09-01 Publication of CN1021978C

Info: Cited by (5), Legal events, Similar documents, Priority and

Related Applications

External links: Espacenet, Global Dossier, Discuss

Claims (1) Hide Dependent

1, a kind of process for brightly plating of zinc for metal wire, used electroplate liquid master salt is that zinc chloride, conducting salt are Repone K, buffer reagent is a boric
acid, also has additive, it is characterized in that:

A, plating solution formula:

Zinc chloride 180 to 250 grams per liters

Repone K 180 to 200 grams per liters

Boric acid 25 to 30 grams per liters

Additive 20-30 milliliter/liter

B, additive formulations:

Card fork acetone 25 to 30 grams per liters

Polyoxyethylene nonyl ethers 10 to 15 grams per liters

Styracin 2-3 grams per liter

Nicotinic acid 4 to 5 grams per liters

Phenylpropyl alcohol triazole 0.4-0.5 grams per liter

Dye leveller 300 grams per liters

Sodium Benzoate 50 grams per liters

C, plating bath pH value 5.5-6.5,

15 to 45 ℃ of d, bath temperatures,

15 to 30 amperes/square decimeter of e, cathode current densities.

Description

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6/19/2021 CN1056907A - A kind of process for brightly plating of zinc for metal wire - Google Patents
The present invention relates to the Metal plating zinc technology, particularly a kind of process for brightly plating of zinc for metal wire.

Pot galvanize and sulfate zinc plating are the galvanized current technology of metal wire material surface, but the former zinc consumption is big, tooling cost is high,
and latter's quality of coating is relatively poor, and luminance is not high enough.The sylvite bright plating zinc technology that developed recently gets up has been used
for the barrel plating and the rack plating of metallic element, the main salt of the used electroplate liquid of this technology is zinc chloride, conducting salt is that
Repone K, buffer reagent are boric acid, main salt concentration is 60 to 70 grams per liters, has the current efficiency height, and sedimentation velocity is very fast, the
coating crystallization is careful, bath element stable, advantages such as environmental pollution is little can significantly improve the visual appearance of institute's
metallizing part, but can not be directly used in the plated metal wire rod.Because the metal wire electro-galvanizing is different from the metallic element electro-
galvanizing: the metallic element electro-galvanizing time is long, and generally more than 10 minutes, and the wire material electroplating time is short, only tens
seconds; Be in the middle of being hung vertically on the cathode bar during metal parts plating, zinc anode also is to hang over the coating bath both sides vertical the
branch, and is laterally to pass from coating bath during the wire rod plating, and zinc anode then is layered at the bottom of the coating bath; Common metal part shape
complexity requires plating bath to have higher dispersive ability and covering power, and the wire rod simple shape, and in coating bath moving linearly, therefore relative
not high to the requirement of the dispersive ability of plating bath and covering power.

Purpose of the present invention is exactly that a kind of electroplate liquid formulation and plating technology that is used for metal wire sylvite bright galvanization will
be provided, to improve the galvanized wire quality.

Task of the present invention is finished as follows, the working concentration of main salt, conducting salt and buffer reagent and coating bath cathode current density
etc. in the promptly preferred plating bath, and provide and make the solution additive that plating time is short, bright dipping is fast, current density is high, the
advantage temperature is high.

The technical process of wire rod sylvite bright galvanization of the present invention is: after Mild Steel Wire annealing, and pickling, cold wash, plating, cold wash,
passivation, cold wash, hot water wash, oven dry, take-up.Its electroplate liquid formulation is:

Zinc chloride 180 to 250 grams per liters

Repone K 180 to 200 grams per liters

Boric acid 25 to 30 grams per liters

20 to 30 milliliters/liter of additives

Its additive formulations is:

Card fork acetone 25-30 grams per liter

Polyoxyethylene nonyl ethers 10 to 15 grams per liters

Styracin 2-3 grams per liter

Nicotinic acid 4-5 grams per liter

Phenylpropyl alcohol triazole 0.4-0.5 grams per liter

Equal seven dose of 300 grams per liter

Sodium Benzoate 50 grams per liters

During plating, every square metre of 15-30 ampere of cathode current density, bath temperature 15-45 ℃, the plating bath pH value is 5.5-6.5.

Adopt technical recipe of the present invention to the metal wire plating, the fine and close light of coating, current efficiency more than 60 percent, can realize ultralow
chromium passivating than the current technology saves energy up to more than 95 percent.Solution additive of the present invention satisfy fully electroplating time
short, go out bright fast, current density is high, the molten some requirement that temperature is high is the additive of a kind of brute force, efficient, wide temperature.

Below be one embodiment of the present of invention.

Earlier by following formulated solution additive:

Card fork acetone 29 grams per liters

Polyoxyethylene nonyl ethers 12 grams per liters

Styracin 2 grams per liters

Nicotinic acid 4.5 grams per liters

Phenylpropyl alcohol triazole 0.4 grams per liter

HW dye leveller (Shanghai immortality auxiliary reagent factory) 300 grams per liters

Sodium Benzoate 50 grams per liters

Again by following formulated plating bath:

Zinc chloride 250 grams per liters

Repone K 200 grams per liters

Boric acid 27 grams per liters

30 milliliters/liter of additives

In the process of metal plated steel wire, cathode current density is controlled at about 20 amperes every square metre, and bath temperature is not higher than 45 ℃,
and the plating bath pH value is controlled at about 6.

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6/19/2021 CN1056907A - A kind of process for brightly plating of zinc for metal wire - Google Patents
Cited By (5)

Publication number Priority date Publication date Assignee Title

CN100415942C
* 2006-01-12 2008-09-03 上海大学 Production of nanometer crystal zinc plating

CN100519722C
* 2005-06-15 2009-07-29 中国科学院海洋研究所 Cleaning agent with a component of nicotinic acid and application thereof

CN104805477A
* 2015-04-02 2015-07-29 上海应用技术学院 Zinc plating liquid used for forming thick zinc coating as well as preparation
method and application

CN107142501A
* 2017-07-12 2017-09-08 合肥信亚达智能科技有 A kind of environment-friendly galvanizing liquid and preparation method thereof
限公司

CN107400906A
* 2017-07-22 2017-11-28 温州裕辉新材料科技有 High anti-corrosion zinc-plating brightener and preparation method thereof
限公司

Family To Family Citations

* Cited by examiner, † Cited by third party, ‡ Family to family citation

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Priority And Related Applications

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6/19/2021 CN1056907A - A kind of process for brightly plating of zinc for metal wire - Google Patents
Priority Applications (1)

Application Priority date Filing date Title

CN 90110089 1990-12-22 1990-12-22 Process for brightly plating of zinc for metal wire

Applications Claiming Priority (1)

Application Filing date Title

CN 90110089 1990-12-22 Process for brightly plating of zinc for metal wire

Legal Events

Date Code Title Description

1991-11-20 C10 Entry into substantive examination

1991-11-20 SE01 Entry into force of request for substantive examination

1991-12-11 C06 Publication

1991-12-11 PB01 Publication

1993-09-01 C14 Grant of patent or utility model

1993-09-01 GR01 Patent grant

1995-02-01 C19 Lapse of patent right due to non-payment of the annual fee

1995-02-01 CF01 Termination of patent right due to non-payment of annual fee

1995-02-08 C19 Lapse of patent right due to non-payment of the annual fee

1995-02-08 CF01 Termination of patent right due to non-payment of annual fee

Concepts

machine-extracted Download Filter table

Name Image Sections Count Query match

plating title,claims,abstract,description 24 0.000

metal title,claims,abstract,description 16 0.000

metal title,claims,abstract,description 13 0.000

zinc title,claims,description 8 0.000

Zn

zinc title,claims,description 8 0.000

zinc title,claims,description 8 0.000

method title,claims,description 5 0.000

additives claims,abstract,description 11 0.000

potassium chloride claims,abstract,description 9 0.000

Cl- K+

Zinc chloride claims,abstract,description 6 0.000
Zn 2+
Cl- Cl-

acetone claims,abstract,description 6 0.000

https://patents.google.com/patent/CN1056907A/en 4/6
6/19/2021 CN1056907A - A kind of process for brightly plating of zinc for metal wire - Google Patents

boric acid claims,abstract,description 6 0.000

mixtures claims,abstract,description 6 0.000

polyoxyethylene nonyl ethers claims,abstract,description 6 0.000

zinc chloride claims,abstract,description 6 0.000

zinc chloride claims,abstract,description 6 0.000

Boric acid claims,abstract,description 5 0.000
HO OH
B

OH

liquids claims,abstract,description 5 0.000

Sodium benzoate claims,abstract,description 4 0.000
Na+
O

O-

sodium benzoate claims,abstract,description 4 0.000

sodium benzoate claims,abstract,description 4 0.000

acetone claims,abstract 2 0.000

dyes claims,abstract 2 0.000

additive claims,description 8 0.000

salts claims,description 7 0.000

sodium chloride claims,description 7 0.000

nicotinic acid claims,description 5 0.000
N O

OH

chemical reaction reagents claims,description 4 0.000

[(E)-3-phenylprop-2-enyl] (E)-3-phenylprop-2-enoate claims,description 3 0.000
O
O

nicotinic acid claims,description 3 0.000

nicotinic acid claims,description 3 0.000

nicotinic acid claims,description 3 0.000

1,2,3-triazole claims 1 0.000
N

HN
N

3-phenylpropan-1-ol claims 1 0.000

HO

Nicotinic acid claims 1 0.000

boric acid group claims 1 0.000

coating agents abstract,description 9 0.000

https://patents.google.com/patent/CN1056907A/en 5/6
6/19/2021 CN1056907A - A kind of process for brightly plating of zinc for metal wire - Google Patents

coating method abstract,description 9 0.000

engineering processes abstract,description 7 0.000

galvanizing abstract,description 4 0.000

electroplating abstract,description 3 0.000

formulation abstract,description 3 0.000

dipping method abstract,description 2 0.000

turbidity abstract 1 0.000

Show all concepts from the description section

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