ALDEHYDE KETONES AND CARBOXYLIC ACIDS

6) The product(s) obtained via

1) Which of the following will fail to Oxymercuration (HgSO4+H2SO4) of 1-
react with potassium dichromate butyne would be
and dilute sulphuric acid a) CH3CH2COCH3
a) Ethyl alcohol (ethanol) b) CH3CH2CH2CHO
b) Acetaldehyde (ethanal) c) CH3CH2CHO+HCHO
c) Secondary propyl alcohol (2- d) CH3CH2COOH+HCOOH
propanol)
d) Acetone (Propanone) 7) The key step in Cannizzaro's
reaction is the intermolecular shift
2) Acetone and acetaldehyde are of
differentiated by a) Proton
a) NaOH+I2 b) Hydride ion
b) HNO2 c) Hydronium ion
c) I2 d) Hydrogen bond
d) Ag (NH3) +2
8) The most suitable reagent for the
3) Which of the following has the most conversion of RCH 2OH→RCHO is
acidic hydrogen a) KMnO 4
a) 3-hexanone b) K 2Cr 2O 7
b) 2, 5-hexanedione c) CrO 3
c) 2, 3-hexanedione d) PCC (Pyridine chloro chromate)
d) 2, 4-hexanedione
9) Which of the following will not
4) Among the given compounds, the give iodoform test?
most susceptible to nucleophilic a) Isopropyl alcohol
attack at the carbonyl group is b) Ethanol
a) CH 3 COCl c) Ethanal
b) CH 3 CHO d) Benzyl alcohol
c) CH 3 COOCH 3
d) CH 3 COOCOCH 3 10) Composition of Lyndler catalyst
a) HgSO 4+BaSO 4
5) Which of the following will be most b) Pd/H 2+BaSO 4
readily dehydrated in acidic c) SnCl 2+HCl
conditions d) AlCl 3+HCl

11) Reductive Ozonalysis of prop-1-ene

gives
a) CH 3CHO + HCHO
b) CH 3COCH 3 + HCHO
c) CH 3CHO + CH 3COOH
d) CH 3COOH + HCOOH

12) The compound will not give iodoform

test on treatment with alkali and
iodine is
a) Acetone
b) Ethanol
c) Diethyl ketone
d) Isopropyl alcohol

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 ALDEHYDE KETONES AND CARBOXYLIC ACIDS

13) The Cannizzaro’s reaction is not given b) B&C only

by c) A&D only
a) Trimethyl acetaldehyde d) A,B,C,D
b) Acetaldehyde
c) Benzaldehyde 20) Acetaldehyde on treating with
d) Formaldehyde LiAlH 4 gives A. product A on
reacting with PCl 3 gives B. the
14) When acetaldehyde is treating with product A & B are
Fehling’s solution, it gives precipitate a) Ethyl alcohol & Ethyl chloride
of b) Ethyl alcohol & Acetic acid
a) Cu c) Acetic acid and Ethyl alcohol
b) CuO d) None of the above
c) Cu2O
d) Cu+Cu2O+CuO 21) CH 3-CHO + NH 20H  X; The number
of sigma bonds, pi bonds and lone
15) A new C-C bond formation is pair of electrons in compound X are
possible respectively
a) Cannizzaro’s reaction a) 9,1,4
b) Fridel-Crafts reaction b) 11,1,5
c) Clemenson’s reduction c) 9,2,2
d) Rosenmond’s reduction d) 8,1,3

16) Which of the following compound will 22) The first oxidation product of
give yellow precipitate with iodine and secondary alcohol is
alkali? a) Acid
a) 2-hydroxy propane b) Aldehyde
b) Acetophenone c) Ketone
c) Methyl acetate d) Ether
d) Acetamide
23) The increasing order of the rate of HCN
17) which of the following is not addition to compound A-D is
monovalent functional group A) HCHO
a) aldehyde B) CH3COCH3
b) ketonic C) PhCOCH3
c) carboxylic D) PhCOPh
d) hydroxyl a) A<B<C<D
b) D<B<C<A
18) CH3COCl + H2 in presence of lindlar’s c) D<C<B<A
catalyst gives CH3CHO+HCl the above d) C<D<B<A
reaction is known as
a) Aldol condensation 24) Acetic acid in vapour phase has
b) Clemmenson’s reaction molecular weight 120 because
c) Rosenmond’s reaction a) Its molecule gets solidifies
d) Tischenko reaction b) Its molecule gets stabilized by
resonance
19) The reaction in which >C=O group c) It undergo intermolecular H-
changes to >CH2 is bonding
1) Clemmenson’s reaction d) None of the above
2) Wolff-Kishner reduction
3) Aldol condensation 25) The IUPAC name of (CH 3 ) 2CHCOOH
4) Rosenmond’s reaction is
a) A&B only a) 2-propanoic acid

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 ALDEHYDE KETONES AND CARBOXYLIC ACIDS

b) Isobutanoic acid a) Acetic acid

c) 2-methyl propanoic acid b) Propionic acid
d) 2-methyl butanoic acid c) Formic acid
d) Iso-butyric acid
26) The higher boil point of carboxylic
acids are due to 33) Vinegar contain
a) Their dimerization a) 10-20% acetic acid
b) Their trimization b) 10% acetic acid
c) Their ability to form H-bonding c) 7-8% acetic acid
d) Both A and C d) 100% acetic acid

27) Acetic acid is treated with Ca (OH) 2 34) Which of the following doesn’t
and product obtained is subjected contain –COOH group?
to dry distillation. The final product a) Aspirin
is b) Benzoic acid
a) Propanone c) Picric acid
b) Propanal d) All have –COOH groups
c) Ethanal
d) Ethanoic acid 35) Which of the following is not
classified as derivative of
28) Which of the following acid are not Carboxylic acid
capable of giving HVZ reaction? a) Alcohol
a) Propionic acid b) Ester
b) Ethanoic acid c) Acid halide
c) 2-methylpropanoic acid d) Amide
d) 2,2-dimethyl propanoicacid
36) Carboxylic acid are functional
29) Acetic anhydride with Lithium isomer of
aluminium hydride would give a) Esters
a) Acetaldehyde b) Alcohols
b) Ethyl alcohol c) Anhydrides
c) Acetone d) None of the above
d) ethane
37) Propanoic acid on reduction
30) Which one of the following is a) Alcohols
strongest acid b) Esters
a) Cl 3 CCOOH c) Both alcohol and ester
b) Cl 2 CHCOOH d) Acid anhydride
c) ClCH 2COOH
d) CH 3COOH
38) Mercuric chloride is reduced to
31) Addition of HBr to CH 2=CHCOOH mercurous chloride by
a) Formic acid
results in the formation of
a) α-bromo propanoic acid b) Ammonia
b) β-bromo propanoic acid as c) Acetic acid
major product d) Benzaldehyde
c) A and B in equal ratio
d) None of the above 39) The main reason for a fact that
carboxylic acid undergo ionization
32) The reactivity of carboxylic acid is
towards esterification highest in a) Absence of α-H
b) High reactivity of α-H

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 ALDEHYDE KETONES AND CARBOXYLIC ACIDS

c) H-bonding
d) Resonance stabilization of
carboxylate ion

40) Calcium acetate on dry distilled

gives
a) Formaldehyde
b) Acetaldehyde
c) Acetone
d) Acetic anhydride

41) Oxidation of Butan-2-one can be

achieved by
a) Tollen’s reagent
b) Conc. HNO 3
c) Br 2 water
d) Atmospheric oxidation

42) Silver mirror test for

a) Aldehydes
b) Thioalcohols
c) Acids
d) Ethers

43) In Cannizzaro’s reaction

a) Aldehydes are converted into
alcohols
b) Alcohol converted into
aldehyde
c) Aldehyde to ketone
d) Aldehyde is converted into
alcohol and sodium carboxylate

44) Which of the following doesn’t give

brick red ppt with fehling solution
a) Formalin
b) Acetaldehyde
c) D-glucose
d) Acetone

45) At room temperature,

formaldehyde is
a) Gas
b) Liquid
c) Solid
d) None of the above

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