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Topic 3 - Periodicity: Quick Questions
Topic 3 - Periodicity: Quick Questions
Topic 3 – Periodicity
Quick questions
Page 71
●● ental amalgam releases low levels of mercury vapor that can be absorbed by the lungs; long term,
d
high level absorption has been linked to brain and kidney damage, however, many countries have
not banned the use of these fillings as the evidence is not absolute and irrefutable;
●● c omposite fillings have improved in their strength and durability to the point where they are a
viable alternative to the mercury fillings;
Page 77
a) iodine monobromide, IBr: iodine has 7 valance electrons and will be part of an ABE3 system when
bonding to a bromine atom; it forms a trigonal bipyramidal molecular geometry, with single I—Br
sigma bond; to predict the I—Br bond length, we approximate that the atomic radius of iodine is
greater than 117 pm by less than 17 pm (the difference between Cl and Br), the bond length of
Br—I is approximately 250 pm (using the values on page 77 for the atomic radius of halogens and
figure 4 on page 78 for trends in atomic radii);
b) trichloromethane (chloroform), CHCl3: this is a polar molecule with tetrahedral molecular
geometry; the C-H sigma bond has a bond length of 107 pm as the atomic radius of hydrogen and
carbon are 32 and 75 pm, respectively; with the chlorine being a much larger atom (atomic radius
100 pm), when compared to hydrogen, the bond length of the C-Cl bond is 175 pm;
Page 83
Group 2 elements have a fully-filled s subshell; the addition of an electron into the higher energy p
subshell is not energetically favorable, resulting in the more positive electron affinity;
© Oxford University Press 2014: this may be reproduced for class use solely for the purchaser’s institute 1
© Oxford University Press 2014: this may be reproduced for class use solely for the purchaser’s institute 2
c) the first ionization energy of the alkali metals decreases down the group; this trend is the
result of:
●● atomic radius increasing down the group, making is easier for the valence electrons to
be removed;
●● the shielding effect of the core electrons increasing faster than the increase in the nuclear
charge, weakening the attraction between valence electrons and the nucleus;
d) potassium-39 is made up of 19 protons, 20 neutrons and 19 electrons; the attraction between
the electrons and the nucleus results in an atomic radius of 200 pm; when the atom loses
its one valence electron, the resulting potassium cation has 19 protons and 18 electrons; the
valence electrons are now more strongly held by the nucleus and the resulting ionic radius
(138 pm) is smaller than the atomic radius;
e) alkali metals can react vigorously when in contact with water to form a metal hydroxide;
your hands have moisture on their surface and touching an alkali metal with your bare hands
is hazardous.
© Oxford University Press 2014: this may be reproduced for class use solely for the purchaser’s institute 3