DATOS

LOG
[Hg+2] 0.01 -2
[HS-] 0.01 -2
[SO4-2] 0.01 -2
F 96500 (aqueous species only)
R 8.314 [ S O 4 2 ] T O T = 1 0 .0 0 m M
2.303 [ H S ] T O T = 1 0 .0 0 m M

25°C T1 298.15 2

/ V
DATOS: MEDUSA 0 H 2S

S H E
Compuesto Log K

E
H2 -3.15 -1
H2S 6.994
Hg 22.301
Hg(HS)2 37.5 -2
2 Hg(OH)2 -6.097 0 5
3 Hg(OH)3- -21.1
4 HgOH+ -3.4
HgS 26.5 Especie log K
5 HgSO4 1.394 * H2S(a) 6.994
HSO4- 1.98 ** S 2- 12.864
O2 -86.08
O2(g) -83.12
OH- -14
S 2- -12.864
1 Hg(l) 28.854
6 HgS(s) 39.092
S(s) 2.145
REACCIONES BRIN

Sistema
1
2
3
4
5
6
 7

REACC

Sistema
2

(1-6)
 DIAGRAMAS DE POURRBAIX ELA

ous species only) (aq ue ou s sp eci es on ly )

2 ] = 1 0 .0 0 m M [P b4 +] = 0 .1 0 m M [ S O 4 2 ] T O T = 10.00 m M
TOT TOT
] = 1 0 .0 0 m M [P b2 +] = 0 .1 0 m M
TOT TOT 2
2

1
1

ESHE / V
/ V

0 H SO 4
0 H 2S HS S 2
S H E
E

-1
-1

-2 -2
0 5 10 15 20 2 4
pH t = 2 5 C

Reacción Especie log K

H(+a) + HS(-a)=H2S *** HSO4(-a) 1.98
H(+a) + S(-2a)=HS(-a)

REACCIONES BRINDADAS POR MEDUSA

Sistema Hg-S-H2O LOG K

Hg(+2a) + 2e- = Hg(l) 28.854
Hg(+2a) + 2H2O = 2H(+a) + Hg(OH)2 -6.097
Hg(+2a) + 3H2O = 3H(+a) + Hg(OH)3(-a) -21.1
Hg(+2a) + H2O = H(+a) + Hg(OH)(+a) -3.4
Hg(+2a) + SO4(-2a) = HgSO4 1.394
Hg(+2a) + HS(-a) = HgS + H(+a) 39.092
 2Hg(+2a) + 2H2O + 2e- = Hg2(OH)2 + 2H(+a) 25.538

REACCIONES FORMADAS

Sistema Hg-S-H2O LOG K

Hg(+2a) + 2H2O = 2H(+a) + Hg(OH)2 -6.097 L
Hg(OH)2 + H2O = H(+a) + Hg(OH)3(-a) -15.003
Hg(l) + HSO4(-a) + 7H(+a) + 6e- = HgS + 4H2O 42.793 LogK = Log[HgS] + 7pH + 8pe - Log[HSO4
8e- + Hg(OH)2 + SO4(-2a) + 10H(+a) = HgS + 6H2O 46.910 LogK = Log[HgS] + 10pH +8pe - Log[Hg(OH)2] - L
Hg(OH)3(-a) + SO4(-2a) + 11H(+a) + 8e- = HgS + 7H2O 59.933 LogK = Log[HgS] + 8pe + 11pH- Log[(Hg(OH)3)-] - L
SO4(-2a) + Hg(l) + 8H(+a) + 6e- = HgS + 4H2O 9.979 LogK = Log[HgS] + 6pe + 8pH - L
HgS + 2H(+a) + 2e- = H2S(a) + Hg(l) -3.244 LogK = 8pe + 11pH- Log[(Hg(OH)3)-] - L
HgS + H(+a) + 2e- = HS(-a) + Hg(l) -10.238 LogK = Log[H2S(a)] - Log[HgS]
HgS + 2e- = S(-2a) + Hg(l) -23.102 LogK = Log[HS-] - Log[HgS
LogK = Log[S(-2)] - Log
S DE POURRBAIX ELABORADOS CON MEDUSA

o us sp ecies on ly )
2 ] = 10.00 m M [ H S ] T O T = 10.00 m M
TOT

1
ESHE / V

0 H SO 4 SO 42

-1

-2
2 4 6 8 10 12
pH t = 2 5 C

Reacción
HSO4(-a)=H(+a)+SO4(-2a)

HSO4(-a) + 9H(+a) + 8e-= H2S(a) + 4H2O

 [ S O 4 2 ] T O T = 10.00 m M
[ H S ] T O T = 10.00 m M [H g2+]T OT = 0.10 m M

H g 2+
pe
H g (O H ) 2
ph
LogK = -2pH 1
0 3.0485
H g (O H ) 3 
LogK = -pH 0 15.003
HgS] + 7pH + 8pe - Log[HSO4-] - Log[Hg] LogK = 7pH + 8pe - Log[HSO4-]

ESHE / V
0pH +8pe - Log[Hg(OH)2] - Log[SO4(-2)] LogK = 10pH +8pe - Log[SO4(-2)]
0 H g S (s )
+ 11pH- Log[(Hg(OH)3)-] - Log[SO4(-2)] LogK = 8pe + 11pH- Log[SO4(-2)]
= Log[HgS] + 6pe + 8pH - Log[SO4(-2)] LogK = 6pe + 8pH
+ 11pH- Log[(Hg(OH)3)-] - Log[SO4(-2)] LogK = 8pe + 11pH- Log[SO4(-2)]
ogK = Log[H2S(a)] - Log[HgS] + 2pH + 2pe LogK =2pH + -1
2pe
LogK = Log[HS-] - Log[HgS] + pH + 2pe LogK = pH + 2pe H g (l)

LogK = Log[S(-2)] - Log[HgS] + 2pe LogK =2pe

-2
0 5 10 15 20
pH t= 2
Eh (Volts) S - H2O - System at 25.00 C
2.0

1.5

HSO4(-a) SO4(-2a)
1.0

0.5
S
0.0

-0.5

-1.0 H2S(a)
HS(-a)

-1.5 S(-2a)

H 2 O L i m it s
-2.0
0 2 4 6 8 10 12 14 16 18 20

C:\HSC6\EpH\S25595.iep pH

ELEMENTS Molality Pressure

S 1.000E-02 1.000E+00
[H g2+]T OT = 0.10 m M

H g (O H ) 3 

15 20
t = 2 5 C
 DATOS
LOG
[Hg+2] 0.0001 -4
[HS-] 0.01 -2
[SO4-2] 0.01 -2
F 96500 (aqueous sp ecies only )
R 8.314 [ S O 4 2 ] T O T = 1 0 .0 0 m M
2.303 [ H S ] T O T = 1 0 .0 0 m M

25°C T1 298.15 2

/ V
DATOS: MEDUSA 0 H 2S

S H E
Compuesto Log K

E
H2 -3.15 -1
H2S 6.994
Hg 22.301
Hg(HS)2 37.5 -2
Hg(OH)2 -6.097 0 5
Hg(OH)3- -21.1
HgOH+ -3.4
HgS 26.5 Especie
HgSO4 1.394 1 H2S(a)
HSO4- 1.98 2 S 2-
O2 -86.08
O2(g) -83.12
OH- -14
S 2- -12.864
Hg(l) 28.854
HgS(s) 39.092
S(s) 2.145
HS- -5.903 REA

ECUACIÓN
LOG K NO REDOX
S + 2H+ + 2e- = H2S 4.85 NO REDOX
S + H+ + 2e- = HS- -2.15 NO REDOX
S + 4H2O = SO4 2- + 8H+ + 6e- -35.8 REDOX
S + 4H2O = HSO4- + 7H+ + 6e- -33.83 REDOX
HSO4- + 9H+ 8e- = H2S + 4H2O 38.68 REDOX
SO4 2- + 10H+ + 8e- = H2S + 4H2O 40.66 REDOX
SO4 2- + 9H+ + 8e- = HS- + 4H2O 33.65 REDOX
SO4 2- + 8H+ + 8e- = S2- + 4H2O 20.78 REDOX
REDOX
REDOX
REDOX
 DIAGRAMAS DE POUR

us sp ecies only ) (aq ue o us sp e ci es o n ly )

] = 1 0 .0 0 m M [P b 4 + ] = 0 .1 0 m M [ S O 4 2 ] T O T = 10.00 m M
TOT TOT
= 1 0 .0 0 m M [P b 2 + ] = 0 .1 0 m M
OT TOT 2
2

1
1

ESHE / V
/ V

0 H SO4
0 H 2S HS S 2
S H E
E

-1
-1

-2 -2
0 5 10 15 20 2
pH t = 2 5 C

log K Reacción Especie

6.994 H(+a) + HS(-a) = H2S 3 HSO4(-a)
-12.864 HS(-a)=H(+a) + S(-2a)

REACCIONES FORMADAS (S-H2O)

Sistema Hg-S-H2O LOG K

1 H2S(a)=H(+a) + HS(-a) -6.994
2 H(+a) + S(-2a)=HS(-a) 12.864
3 HSO4(-a)=H(+a)+SO4(-2a) -1.98
4 H2S(a)+4H2O=HSO4(-a)+9H(+a)+8e- -38.68
(3+4) H2S(a)+4H2O= SO4(-2a)+10H(+a) + 8e- -40.66
(3+4-1) HS(-a) +4H2O= SO4(-2a)+9H(+a) + 8e- -33.67
(3+4-1+2) S(-2a) +4H2O= SO4(-2a)+8H(+a) + 8e- -20.80
S + 2H+ + 2e- = H2S 4.85 Log
S + H+ + 2e- = HS- -2.15 Lo
S + 4H2O = SO4 2- + 8H+ + 6e- -35.8 Log
S + 4H2O = HSO4- + 7H+ + 6e- -33.83 LogK
(3+4-1+2) S(-2a) +4H2O= SO4(-2a)+8H(+a) + 8e- -20.80
DIAGRAMAS DE POURRBAIX ELABORADOS CON MEDUSA

Eh (Volts) S-
aq ue o us sp e ci es o n ly ) 2.0
S O 4 2 ] T O T = 10.00 m M [ H S ] T O T = 10.00 m M
1.5
2
HSO4(-a)
1.0

0.5
1
S
0.0
ESHE / V

0 HSO4 S O 42 -0.5

-1.0 H2S(a)

-1 -1.5

-2.0
0 2 4 6
-2 C:\HSC6\EpH\S25595.iep
2 4 6 8 10 12
ELEMENTS
pH t = 2 5 C S

log K Reacción
-1.98 HSO4(-a)=H(+a)+SO4(-2a)

25
pe ph Eth
LogK = -pH 0 6.994 0 a
LogK = pH 0 12.864 0 b
LogK = -pH 0 1.98 0 c
LogK = - 9pH - 8e- 4.835 0 0.2860276 d
LogK = -10pH - 8pe -3.660 6.994 -0.21651727
LogK = -9pH - 8pe -3.660 6.994 -0.21651727
 LogK = -8pH - 8pe -10.264 12.864 -0.60718009 b
LogK =Log[H2S] + 2pH + 2pe 2.42 0 0.14316169 f
LogK = Log[HS-] + pH + 2pe -4.577 6.994 -0.2707649 c
LogK =Log[SO4=] - 8pH - 6pe -3.692 6.994 -0.21841032 g
LogK =Log[HSO4-] - 7pH - 6pe 2.995 1.98 0.17717738 d
LogK = -8pH - 8pe -17.400 20 -1.02932961 h
i
h (Volts) S - H2O - System at 25.00 C
2.0

1.5

HSO4(-a) SO4(-2a)
1.0

0.5
S
0.0

-0.5

-1.0 H2S(a)
HS(-a)

-1.5 S(-2a)

H 2 O L im it s
-2.0
0 2 4 6 8 10 12 14 16 18 20

C:\HSC6\EpH\S25595.iep pH

ELEMENTS Molality Pressure

S 1.000E-02 1.000E+00

SISTEMA S - H2O A 2
2.0

1.5
HSO4-
25⁰C
pe pH Eth 1.0
5.305 0.000 0.3138
2.995 1.980 0.1772
0.5
-3.660 6.994 -0.2165
2.42 0.000 0.1432 S
Eh (volts)

0.0

-0.5

-1.0
 Eh (volts)
0.0

2.995 1.980 0.1772

-0.5
1.980 2.0000
-3.660 6.994 -0.2165
H2S(a)
6.994 -2.0000 -1.0
HS-
-10.264 12.864 -0.6072
12.864 -2.0000
-1.5
-17.400 20 -1.0293

-2.0
0 2 4 6 8 10 12

pH
SISTEMA S - H2O A 25⁰C

SO4=

bf
cg
dh
ab
bc
d-c
c-d
-0.6072 -1.0293
 cg
dh
ab
bc
d-c
c-d
-0.6072 -1.0293

HS-
S=

8 10 12 14 16 18 20

pH