DATOS

LOG
[Hg+2] 0.0001 -4
[HS-] 0.01 -3
[SO4-2] 0.01 -2 (a qu e ous sp e cie s only )
F 96500 [ S O 4 2 ] T O T = 1 0 .0 0 m M [P b4
[ H S ] = 1 0 .0 0 m M [P b2
R 8.314 TOT

2.303 2

25°C T1 298.15

/ V
0 H 2S HS S

S H E
DATOS: MEDUSA

E
Compuesto Log K -1
H2 -3.15
H2S 6.994
Hg 22.301 -2
Hg(HS)2 37.5 0 5 10 15
2 Hg(OH)2 -6.097 pH

3 Hg(OH)3- -21.1
4 HgOH+ -3.4
HgS 26.5 Especie log K
5 HgSO4 1.394 * H2S(a) 6.994
HSO4- 1.98 ** S 2- 12.864
O2 -86.08
O2(g) -83.12
OH- -14
S 2- -12.864
1 Hg(l) 28.854
6 HgS(s) 39.092
S(s) 2.145
REACCIONES BRIN

Sistema Hg-S-H2O
1
2
3
F 96500 T0 25 298.15 4
R 8.314 273.15 5
2.303 6
7
 8

REACC

Sistema
2

(1-6)
 DIAGRAMAS DE POURRBAIX ELA

) (aq u eo u s sp eci es o n ly )
0 mM [P b4 + ] = 0 .1 0 m M [ S O 4 2 ] T O T = 10.00 m M
TOT
mM [P b2 + ] = 0 .1 0 m M
TOT 2

ESHE / V
0 H SO 4 S O 4 2
H 2S HS S 2

-1

-2
0 5 10 15 20 2 4 6 8
pH t = 2 5 C pH

Reacción Especie log K

H(+a) + HS(-a)=H2S *** HSO4(-a) 1.98
H(+a) + S(-2a)=HS(-a)

REACCIONES BRINDADAS POR MEDUSA

ema Hg-S-H2O LOG K

Hg(+2a) + 2e- = Hg(l) 28.854
Hg(+2a) + 2H2O = 2H(+a) + Hg(OH)2 -6.097
Hg(+2a) + 3H2O = 3H(+a) + Hg(OH)3(-a) -21.1
Hg(+2a) + H2O = H(+a) + Hg(OH)(+a) -3.4
Hg(+2a) + SO4(-2a) = HgSO4 1.394
Hg(+2a) + HS(-a) = HgS(s) + H(+a) 39.092
2Hg(+2a) + 2H2O + 2e- = Hg2(OH)2 + 2H(+a) 25.538
 HSO4- + 9H+ 8e- = H2S + 4H2O 38.68

REACCIONES FORMADAS

Sistema Hg-S-H2O LOG K

Hg(+2a) + 2H2O = 2H(+a) + Hg(OH)2 -6.097 L
Hg(OH)2 + H2O = H(+a) + Hg(OH)3(-a) -15.003
Hg(l) + HSO4(-a) + 7H(+a) + 6e- = HgS(s) + 4H2O 41.924 LogK = Log[HgS(s)] + 7pH + 6pe - Log[HSO4
8e- + Hg(OH)2 + SO4(-2a) + 10H(+a) = Hg(s) + 6H2O 46.041 LogK = Log[HgS(s)] + 10pH +8pe - Log[Hg(OH)2] - L
Hg(OH)3(-a) + SO4(-2a) + 11H(+a) + 8e- = HgS(s) + 7H2O 59.064 LogK = Log[HgS(s)] + 8pe + 11pH- Log[(Hg(OH)3)-] - L
SO4(-2a) + Hg(l) + 8H(+a) + 6e- = HgS(s) + 4H2O 9.110 LogK = Log[HgS(s)] + 6pe + 8pH - L
HgS(s) + 2H(+a) + 2e- = H2S(a) + Hg(l) -3.244 LogK = Log[H2S(a)] - Log[HgS(s)]
HgS(s) + H(+a) + 2e- = HS(-a) + Hg(l) -10.238 LogK = Log[HS-] - Log[HgS(s
HgS(s) + 2e- = S(-2a) + Hg(l) -23.102 LogK = Log[S(-2)] - Log[H
Hg(2+) + HSO4(-a) + 7H+ + 8e- = HgS(s) + 4H2O 70.778 LogK = Log[HgS(s)] + 7pH + 8pe - Log[HSO4-] -
 S DE POURRBAIX ELABORADOS CON MEDUSA

y)
00 m M [ H S ] T O T = 10.00 m M

H S O 4 SO 42

2 4 6 8 10 12
pH t = 2 5 C

Reacción
HSO4(-a)=H(+a)+SO4(-2a)

HSO4(-a) + 9H(+a) + 8e-= H2S(a) + 4H2O

 LogK = -2pH pH=-logK/2
LogK = -pH pH=-logK
S(s)] + 7pH + 6pe - Log[HSO4-] - Log[Hg] LogK = 7pH + 6pe - Log[HSO4-] pe=1/6(logK+log[HSO4-])-7/6pH
0pH +8pe - Log[Hg(OH)2] - Log[SO4(-2)] LogK = 10pH +8pe - Log[SO4(-2)] pe=1/8(logK+log[SO4(-2)])-5/4pH
+ 11pH- Log[(Hg(OH)3)-] - Log[SO4(-2)] LogK = 8pe + 11pH- Log[SO4(-2)] pe=1/8(logK+log[SO4(-2)])-11/8pH
Log[HgS(s)] + 6pe + 8pH - Log[SO4(-2)] LogK = 6pe + 8pH pe=1/6logK-4/3pH
K = Log[H2S(a)] - Log[HgS(s)] + 2pH + 2pe LogK =2pH + 2pe pe=1/2logK-pH
LogK = Log[HS-] - Log[HgS(s)] + pH + 2pe LogK = pH + 2pe pe=1/2logK-1/2pH
LogK = Log[S(-2)] - Log[HgS(s)] + 2pe LogK =2pe pe=1/2logK
+ 7pH + 8pe - Log[HSO4-] - Log[Hg(2+)] LogK = 7pH + 8pe - Log[HSO4-] pe=1/8(logK+log[HSO4-])-7/8pH

[ S O 4 2 ] T O T = 10.
[ H S ] T O T = 10.00

E SHE / V
0

-1

-2
0
Eh (Volts) S - H2O - System at 25.00 C
2.0

1.5

HSO4(-a) SO4(-2a)
1.0

0.5
S
0.0

-0.5

-1.0 H2S(a)
HS(-a)

-1.5 S(-2a)

H 2 O L im it s
-2.0
0 2 4 6 8 10 12 14 16 18 20

C:\HSC6\EpH\S25595.iep pH

ELEMENTS Molality Pressure

S 1.000E-02 1.000E+00
 pe ph n
0 3.0485 0
0 15.003 0
og[HSO4-])-7/6pH 4.881125 8
og[SO4(-2)])-5/4pH 8
og[SO4(-2)])-11/8pH 8
6
2
2
-11.551 0 8
og[HSO4-])-7/8pH

[ S O 4 2 ] T O T = 10.00 m M
[ H S ] T O T = 10.00 m M [H g2+ ]T OT = 0.10 m M

H g 2+
H g (O H ) 2

1 H g (O H ) 3 
E SHE / V

0 H g S (s )

-1
H g (l)

-2
0 5 10 15 20
pH t = 2 5 C
 pE = a + b*pH Eth = a' + b'*pH
25⁰C 25⁰C
a b ph a' b'
0 -1 3.0485
0 -1 15.003
4.9905 -0.875 0.295227 -0.051750
5.505125 -1.25 0.325671 -0.073929
7.133 -1.375 0.421972 -0.081322
1.51833333 -1.33333333 0.089821 -0.105143
-1.622 -1 -0.095954 -0.236572
-5.119 -0.5 -0.302828 -0.118286
-11.551 0 -0.683331 0.000000

25⁰C
redox pH Eth
a 0 5708.72039
b 3.0485 0
c 15.003 0
d 20 0
e 3.0485 0
f 15.003 0
y 20
no redox
b 3.0485 0
u 3.0485 2
e 3.0485 0.000000
v 3.0485 -2
d 20 0.000000
z 20 -2