Professional Documents
Culture Documents
12.07.20 Sr.n-Superchaina Jee Adv 2014 p2 Gta-1 P-II QP
12.07.20 Sr.n-Superchaina Jee Adv 2014 p2 Gta-1 P-II QP
CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 21 – 30) Questions with Single Correct Choice 3 -1 10 30
Questions with Comprehension Type
Sec – II(Q.N : 31 – 36) 3 -1 6 18
(3 Comprehensions – 2 +2+2 = 6Q)
Sec – III(Q.N : 37 – 40) Matrix Matching Type 3 -1 4 12
Total 20 60
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 41 – 50) Questions with Single Correct Choice 3 -1 10 30
Questions with Comprehension Type
Sec – II(Q.N: 51 – 56) 3 -1 6 18
(3 Comprehensions – 2 +2+2 = 6Q)
Sec – III(Q.N : 57 – 60) Matrix Matching Type 3 -1 4 12
Total 20 60
A) f/2 B) 3f/2 C) 2f D) f
2. A body is thrown from the surface of the earth with velocity gRe / 2 , where Re is the
radius of the earth at some angle from the vertical. If the maximum height reached be
the body is Re/4, then the angle of projection with the vertical is
5 5 3
A) sin 1 B) cos 1 C) sin 1 D) 300
4 4 2
3. A uniform magnetic field B and electric field E exist along y and negative z axis
respectively. Under the influence of these fields a charged particle moves along OA un-
deflected. If electric field is switched off, find the pitch of helical trajectory in which the
particle move.
2 mE 4 mE 4 mE 2 mE
A) B) C) D)
qB 2 cot qB 2 tan qB 2 cot qB 2 tan
SR.IIT_N-SC/ N-C Page. No. 3
C) The minimum coefficient of friction between the block and the prism is min cot
D) The minimum coefficient of friction between the block and the prism is min tan
V 2 2V 2
A) B)
R a b a x R a b a x
2 2
V 2
C) D) independent on x
2 R a b a x
2
V 3V V
A) V B) C) D)
5 5 6
8. A radionuclide A1 with decay constant 1 transforms into a radionuclide A2 of decay
constant 2 . Assuming that at the initial moment the preparation contained only the
radionuclide A1, then the time interval after which the activity of the radionuclide A2
reaches its maximum value is
ln 2 / 1 ln 1 / 2 ln 2 / 1 2 1
A) B) C) D)
2 1 2 1 1 12
density 2 .
SECTION - II
(PARAGRAPH TYPE)
This section contains 3 Paragraph of questions. Each paragraph has 2 multiple choice questions based on
a paragraph. Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE IS correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Paragraph for Question Nos. 11 & 12:
In a certain region, electric field E exists along the x-axis which is uniform. Given
BA 2 3 m and BC=4m. Points A, B, and C are in xy plane.
A) 3E B) 4E C) E D) 2E
12. A charged particle q is moved from A to C as shown in path 1. What is the work done
by electric field in this process?
14. What is the impulse generated in the string during the second collision?
15. The rate at which the current through the inductor increases initially is
A) zero B) 10 A s 1 C) 1 A s 1 D) 5 A s 1
16. The current through the inductor after a long time will be
6
A) zero B) infinite C) A D) 1A
13
Column I Column II
A) i a, c, d ii b iii a, c, d iv b, c B) i a, c, d ii b, c iii a, c iv b, c, d
C) i a, c ii b iii a, c, d iv a, b D) i a, d ii b, c iii a, d iv a, b, c
18. A small object of mass 0.5 kg is attached to an end of a mass less 2 m long rope. It is
rotated under gravity in a vertical circle with the other end of the rope being at the
center of the circle. The motion is started from the lowest point. Match columns I and
II. ( g 10m / s 2 )
If the speed of the object at there will be some point on the circle at
i a which speed of the object is zero but
lowest point is 3.5 ms-1 tension in the rope is not zero
If the speed of the object at There will be some point on the circle at
ii b which tension in the rope is zero but
lowest point is 8 ms-1 speed of the object is not zero
If the maximum tension in The object will not be able to reach the
iii c
the rope is 15N highest point
If the maximum tension in The object will be able to reach the
iv d
therope is 30 N highest point
A) i a, b ii a, c iii c, d iv b, c B) i a, d ii a, c iii c iv b, c
C) i a, c ii b, c iii c iv b, d D) i a, c ii b iii b, c iv a, d
19. In case of mechanical wave a particle oscillates and during oscillation its kinetic energy,
potential energy changes. (Assuming a small length element of string as a particle)
Column I Column II
C) i a, b ii c iii a, d iv c D) i b, c ii a, c iii b iv c, d
Column I Column II
A) a p, b q, c r , d s B) a s, b p, c r , d q
C) a p, b q, c q, d s D) a s, b p, c q, d r
A) B)
C) D)
23. At 25ºC, the free energy of formation of H2O(l) is –56.7 kcal mole–1. The free energy of
ionization of water to H+& OH– is 19.05 kcal mole–1. What is the electrode potential of
the following cell at 25ºC ?
1
2H 2OH
H 2 (g) O 2 (g) H 2 O()
2
A) KClO3
MnO 2
Heat
B) SnCl2 HCl O3
C) FeSO 4 H 2SO 4 O3
D) PbS O3
25. The acetoacetic ester synthesis is useful for preparing methyl ketones. Which of the
following would not be easily prepared by this method?
C) When III is protonated in the presence of a strong acid, protonation occurs at C-2
A) Azulene B) Furan
29. Identify the correct trend given below (atomic number of Ti = 22,Cr = 24 & Mo = 42)
30.
A) B)
C) D)
31. How many moles of sodium propionate should be added by the student to obtain a
buffer solution of p H 5.3 ?
32. What will be the pH, if 0.010 moles of HCl are dissolved in the buffer solution
containing 0.020 mole of propionic acid & 0.015 mole of sodium propionate?
2 2
C) Ag NH 3 2 & Cu NH 3 4 D) Ag NH 3 2 & Ni NH 3 6
SR.IIT_N-SC/ N-C Page. No. 14
CN
A) B
C) CN D) COOH
COOH CHO OH
A) B) C) D)
SECTION - III
(Matching List Type)
This section contains four questions, each having two matching lists (List-1 & List-II). The options for the correct
match are provided as (A), (B),(C) and (D) out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
37. Match the following.
Column-I Column-II
(Fraction of volume occupied by void) (Type of packing)
P 0.32 1 Hexagonal close packing
Q 0.48 2 Cubic dose packing
R 0.26 3 Body centered cubic
S 0.66 4 Simple cubic
5 Diamond cubic
A) P-3; Q-4; R-1,2; S-5 B) P-4; Q-3; R-2; S-5
C) P-1,2; Q-3,4; R-4; S-5 D) P-5; Q-1,2; R-3; S-5
Column-I Column-II
R CN– 3 is a nucleophile
is involved in cyanohydrins
S I– 4
formation
Match Eº of the redox pair in column-I with the values given in column-II and select the
40. Match the reactions given in Column-I with the conditions favour the forward reaction
given in Column-II.
Column-I Column-II
Dissociation of N2O4(g)
Q 2 Decrease in pressure
N2O4(g) + 57.2 KJ 2NO2(g)
Oxidation of NH3(g)
R 3 Decrease in temperature
4NH3(g) + 5O2(g) 4NO(g)+6H2O(g)+90KJ
Oxidation of NO2(g)
S 4 Increase in temperature
NO(g) + O3(g) NO2(g) + O2(g) + 200 KJ
42. Let I n x 2020x 2 2021 x 2 2021x 3 2022 dx (where denotes fractional
n
x 2 x 2 3
t2
2 tan z 1 tan 2 z z 2 tan z
2
t
z 1 tan
2
44. If x e
z
dz and y e
dz then the
2 z sec 2
z
2 z sec 2
z
0 0
inclination of the tangent to the curve at t is
4
3
A) B) C) D)
4 3 2 4
sin 4a cos 2 a 1
1 1
If sin a cos a 2 b 2 c 0 then the value of b2 b3 is equal to
b b
ln c 1 c5 c8 2
A) 5 B) 6 C) 10 D) 12
2
x
10
1 2 x
47. Let f x e and if f ln 2 e
r 10
r
then the value of 2 15 is equal to
A) 4 B) 8 C) 6 D) 9
48. In a ABC Let the value of (a, b, c are the sides of ABC ).
L
a 3 cos 3B 3a 2 b cos A 2B 3ab 2 cos 2A B b3 cos 3A is‘L’, then the value of
c3
A) 2 B) 1 C) 4 D) 8
49. An unbiased dice with numbers {1, 2, 3, 4, 5, 6} on its faces rolled once. An observer A
sees the number shown on the dice and reports it. The probability that A speaks truth is
1 2
and the probability that he lies is . Assume that the number he reports is always
3 3
from the set {1, 2, 3, 4, 5, 6}. If p is the probability that the actual number on the dice is
even given that A reports that the number was 2, then p =
4
dy x 3x 2 x3
dx x 2 1
f 1 f 1
y f x (where f 0 1 ) then
4 e
5 3
A) B) 2 C) 3 D)
2 2
2 5 100
drawn to the graph of the function y f x at x is y x . Then answer the
3 3 27
following questions.
A) 4 B) 6 C) 7 D) 10
d
52. If g is the inverse of ‘f’ then
dx
g x f g x at x = 4 is
1 4 3 1
A) B) C) D)
4 7 4 3
0
1
53.
The value of g tan 22 g
2
3
cot150 g 3
sin180 is equal to
7 9
A) 2 B) 4 C) D)
2 2
1
54. Number of solutions of the equation g x tan cot 1 is
4x
A) 0 B) 1 C) 2 D) 4
1 1 1 1
55. The sum of the series 2
3 4 ..... terms is
a b a b
3 1 1 1
A) B) C) D)
2 2 4 3
n
56. The value of n
n 1
4
ab
1 3 3
A) 1 B) C) D)
2 8 4
SECTION - III
(Matching List Type)
This section contains four questions, each having two matching lists (List-1 & List-II). The options for the correct
match are provided as (A), (B),(C) and (D) out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
57. Let a, b, c are the roots of the equation x 3 3x 2 5x 1 0 . A and B are two matrices
a b c bc a 2 ca b 2 ab c 2
given as A b c a , B ca b 2 ab c 2 bc a 2 . If , , are the roots of the equation
c a b ab c 2 bc a 2 ca b 2
B XI 0 . Where I is the identity matrix of order 3. The match list-I with list-II
Column-I Column-II
P The value of det Adet B is 1 18
Q The value of is 2 182
R The value of B is 3 183
S The value of A is 4 6
5 184
A) P-4; Q-3; R-1; S-2 B) P-3; Q-2; R-4; S-1
y 3
where f (x, y) 3x 2y e x 2y e 2 6
6
x 2
Column-I Column-II
P The value of 2 2 OA OB OC is 1 50
Q The value of OA OB OB OC OC OA is 2 54
R The value of 25 is 3 36
S The value of 18 is 4 52
A) P-1; Q-3; R-4; S-2 B) P-2; Q-4; R-1; S-3
Column-I Column-II
y
If Lim 1
y
then 2 3
P
y
1 1 9
1 x dx
1
3
x 2 sin x!
S Lim & x N is less than or equal to 4 3
x x 1
5 5
A) P- 2,3; Q-3; R-3; S-1,2,3,4,5 B) P-1,2; Q-4; R-1,2; S-1,2
Column-I Column-II
e
2
3
1 e sin x log sin x cos x dx
101
P I2 1
sin1 1 e 2
e 1 e k
101
e
If I1 I2 then k
101 101
log x
I k dx k 0
0
x kx k 2
2
Q 2 1
kI k I 1 & k e then
3
R
0
9f 3 x 2 f 1 x f x dx k
2
3 5
S e 1 4 2
a 1 and is greatest integer function is
2
then the value of 5a
5 9