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Article
Vol. 23, No. 1, p. 6986, February 2019
https://doi.org/10.1007/s12303-018-0011-6
pISSN 1226-4806 eISSN 1598-7477 Geosciences Journal

Hydrocarbon migration and accumulation history in deep


reservoirs: a case study of Mesozoic sandstone gas res-
ervoirs in the Kelasu-Yiqikelike structural belt of the
Kuqa Depression, Tarim Basin
Xu Song, Xiuxiang Lü*, Yunqi Shen, and Song Guo
State Key Laboratory of Petroleum Resources and Prospecting, China University of Petroleum, Beijing 102249, China

ABSTRACT: Numerous deep oil and gas reservoirs have recently been discovered in the Kelasu-Yiqikelike structural belt of the Kuqa
Depression in the northern Tarim Basin, north-western China. The sources and accumulation processes of the oil and gas are deter-
mined in this study through a series of biomarker geochemical parameter analyses and fluid inclusion analyses, respectively. The geo-
chemical parameters show that the oil of the Kela 2 gas field originated from the Triassic Huangshanjie (T3h) Formation lacustrine
source rock and that the oil of the Jurassic reservoirs in the Dibei gas field was sourced from Jurassic coal measures, with some con-
tribution from the T3h source rock. Furthermore, the gas in the Kela 2, Keshen and Dibei gas fields was derived from the Jurassic coal
measures. Based on petrographic and fluid inclusion analyses, combined with a reconstruction of the reservoir burial history, timing
estimates and charge models of the hydrocarbon accumulation have been obtained. Two stages of oil charging and one stage of gas
charging were identified in the Kela 2 gas field. The two stages of oil charging occurred in the middle–late Miocene and in the early
Pliocene. The gas charge occurred in the middle–late Pliocene. Additionally, one stage of gas charging occurred in the Keshen gas field
in the late Pliocene to Quaternary. In contrast, two hydrocarbon charging stages were identified in the Dibei gas reservoirs, with the
first occurring in the early Miocene and the second occurring in the Pliocene.
Key words: hydrocarbon charge, hydrocarbon source, fluid inclusion, hydrocarbon accumulation, Kuqa Depression

Manuscript received November 15, 2017; Manuscript accepted March 2, 2018

1. INTRODUCTION The sandstone reservoir in the K1bs Formation is generally


buried more than 5000 m deep in the Keshen gas field, and the
The Kuqa Depression is a superimposed foreland basin in the burial depth of the lower Jurassic sandstone reservoirs is
northern Tarim Basin with an exploration area of ~2.8 × 104 km2 approximately 4000–5000 m in the Dibei gas field. According to
(Shen et al., 2017). After natural gas exploration achieved the Regulation of Petroleum Reserves Estimation (Ministry of
breakthroughs in the Kela 2 and Dina 2 gas fields, a series of deep Land and Resources, 2005), a burial depth from 3500 m to 4500
reservoirs were discovered in the Kelasu-Yiqikelike structural m is defined as a deep layer, and a burial depth exceeding 4500
belt (e.g., the Keshen 1, Keshen 2 and Keshen 5 gas fields). m is defined as an ultra-deep layer. Therefore, these reservoirs in
Mesozoic strata are the main hydrocarbon-bearing layers in the the Kelasu-Yiqikelike structural belt can be defined as deep and
Kelasu-Yiqikelike structural belt of the Kuqa Depression and ultra-deep reservoirs. The oil and gas exploration in China has
include the lower Cretaceous Bashijiqike (K1bs) Formation and started to extend to deep reservoirs, especially in the Tarim Basin.
the lower Jurassic Ahe (J1a) and the Yangxia (J1y) formations. Thus, it is important to understand the hydrocarbon charge and
accumulation history in such deep reservoirs.
*Corresponding author: Several researchers have studied the oil and gas accumulation
Xiuxiang Lü
School of Geosciences, China University of Petroleum, Beijing 102249, processes in the Kuqa Depression. Zhao et al. (2005) believed
China that the formation of the giant gas accumulation in the Kuqa
Tel: +86-010-89733357, E-mail: luxx@cup.edu.cn Depression occurred in the past 5 Ma, and the isotopically heavy
The Association of Korean Geoscience Societies and Springer 2019 gas in the Kela 2 gas field and Kelasu-Yiqikelike structural belt
70 Xu Song, Xiuxiang Lü, Yunqi Shen, and Song Guo

represents high maturity gas generated since the early Pliocene. inclusion data and basin modelling. By discussing the petroleum
Liang et al. (2002) proposed a two-stage trapping and late gas migration and accumulation history in the region, this study
trapping model for the Kuqa Depression and suggested that the can act as a reference for further hydrocarbon exploration.
oil reservoir formed early, while the gas reservoir formed later.
Therefore, few studies have focused on the quantitative analysis 2. GEOLOGICAL SETTING
of the hydrocarbon charge history of the deep reservoirs in the
Kelasu-Yiqikelike structural belt. 2.1. Tectonic Setting
Regarding the source of the oil and gas in this area, different
researchers have different opinions. Li et al. (2004) reported that The Kuqa Depression is a Mesozoic foreland basin located in
the natural gas of the YN2 gas pool in the Dibei gas field is derived the southern part of the Tianshan orogenic belt. It is bounded by
from lower–middle Jurassic coal-bearing source rocks and the North Tarim Uplift to the south and has an east-west length
represents gas accumulated over a long period of time. Lu et al. of approximately 550 km and a north-south width of 30–80 km.
(2016) believed that the natural gas in the Dibei gas field derived The Kuqa Depression consists of the northern monoclinal zone,
from the Triassic source rock. Thus, a detailed hydrocarbon- Kelasu-Yiqikelike structural belt, Qiulitag structural belt, southern
source correlation is necessary to understand the oil and gas slope region, Wushi sag, Baicheng sag, and Yangxia sag. The
accumulation processes in this region. Kela 2 and Keshen gas fields are located in the middle of the Kelasu
In this paper, we seek to determine the sources of the oil and structural belt. The Dibei tight sandstone gas field is situated in
gas in the deep reservoirs in the Kelasu-Yiqikelike structural belt the middle of the Yiqikelike structural belt (Figs. 1a–c).
using various geochemical data and to reconstruct the hydrocarbon The Kuqa Depression has experienced three evolutionary
charging history of these reservoirs through the integration of fluid stages since the late Palaeozoic: a pre-collisional orogenic stage

Fig. 1. Schematic map of the locations of the main oil and gas accumulations in Kuqa Depression and stratigraphic column of the Mesozoic
and Cenozoic. (a) Location map of the Tarim Basin; (b) location map of the Kuqa Depression; (c) distribution of gas reservoirs in the Kuqa
Depression; (d) generalized Mesozoic–Cenozoic stratigraphy of the Kuqa Depression.

https://doi.org/10.1007/s12303-018-0011-6 http://www.springer.com/journal/12303
Hydrocarbon accumulation history in deep reservoirs of the Kuqa Depression 71

(late Permian to Triassic), an extensional rift basin stage (Jurassic techniques, including the analysis of oil biomarkers, gas chemical
to Paleogene) and an intracontinental orogenic stage (since the and carbon isotope compositions, fluid inclusion petrology and
Neogene) (Graham et al., 1993; Jia, 2012). The intra-continent property measurements, were employed to study these samples.
orogeny stage is a significant period for the formation of the deep For soluble bitumen extraction, three source rock samples
reservoirs in the depression. During the Paleogene to Quaternary, were solvent extracted with approximately 500mL of dichloromethane
the South Tianshan Mountains started to uplift because of the and methanol (93:7 v/v) for 72 h using a Soxhlet apparatus. Then,
remote effects of the Himalayan Orogeny, and propagating the hydrocarbon extracts and 11 oil samples were fractionated
compressional tectonics developed in central Asia because of on a silicon and aluminium column to obtain the aliphatic
the intense intracontinental compression. Thus, a large number hydrocarbon fractions using organic eluents. The molecular
of thrust faults and accompanying fold structures formed in the characteristics were further analysed via the gas chromatography-
Kuqa Depression (Min et al., 2005). mass spectrometry (GC-MS) technique. The GC-MS analysis
was performed with a Thermo DSQII instrument. The oven
2.2. Generalized Elements of Petroleum Systems temperature for the analysis of the saturated fractions was
initially held at 60 °C for 5 min, elevated to 310 °C at 5 °C/min
2.2.1. Source rocks and held at 310 °C for 30 min. Helium was used as the carrier gas.
Two sets of source rocks, Triassic strata and Jurassic strata, The chemical composition of 26 gas samples was analysed
have been identified in the Kuqa Depression. The Triassic includes using an Agilent 7890A gas chromatograph equipped with a flame
the Kelamayi (T2-3k), Huangshanjie (T3h), and Taliqike (T3t) ionization detector and a thermal conductivity detector. The
formations. The Jurassic are the Yangxia (J1y), Kezilenuer (J2kz) oven temperature was initially held at 40 °C for 10 min. elevated
and Qiakemake (J2q) formations (Fig. 1d). Among these source to 180 °C at the rate of 10 °C/min, then held at the maximum
rock units, the T2-3k, T3h and J2q formations are lacustrine oil- temperature for 30 min.
prone source rocks, while the T3t, J1y and J2kz formations are The carbon isotope composition of 22 gas samples was analysed
coal-bearing sequences with good gas generation potential. using a Finnigan MAT-252 instrument. The oven temperature
(Liang et al., 2003). was initially held at 50 °C for 2 min, elevated to 180 °C at the rate
of 25 °C/min and held at the maximum temperature for 10 min.
2.2.2. Reservoir-cap combinations The C isotope ratios are reported in per mil (‰), based on the
The Mesozoic–Cenozoic stratigraphy present in the Kuqa PDB standard.
Depression includes the Quaternary (Q) units; the Kuqa (N2k), Five samples from the Cretaceous and Jurassic reservoirs were
Kangcun (N1-2k) and Jidike (N1j) formations; the Suweiyi (E2-3s) doubly polished as thick sections, according to the description
Formation; the Kumugeliemu (E1-2km) Group; the Lower reported in (Goldstein, 2001), and the polished samples were
Cretaceous Bashijiqike (K1bs), Baxigai (K1bx) and Sushanhe subjected to observation under the microscope to identify the
(K1s) formations, and the Jurassic and Triassic units (Fig. 1d). formation phase of inclusions. To better characterize the fluid
Drilling results and stratigraphic correlation confirmed that the inclusions, the specimens were also observed under UV light.
reservoir-cap combination in the Kela–Keshen area is different This examination was conducted using a ZEISS Imager A1m
from that in the Dibei area. For the Kela 2 and Keshen gas fields, microscope.
the reservoir is located in the Bashijiqike Formation (K1bs), which To determine the hydrocarbon charging history, the samples
was deposited in fan delta and braided river delta environments were further examined to determine the homogenization
and features lithofacies dominated by sandstone. Extensive evaporitic temperature (Th) and final ice melting temperature (Tm) of
rocks and thick mudstone are present in the Kumugeliemu saline inclusions. The samples were grounded into wafers with a
Group and serve as effective seals. For the Dibei gas field, the thickness of 0.2–0.5 mm and doubly polished. A detailed description
reservoir rocks are the internal sand layers in the Jurassic Ahe of the analysis method is provided by Roedder (1984). These
(J1a) and Yangxia (J1y) formations, and the mudstones developed measurements were conducted with a Linkam THM600 heating-
in the Jurassic Yangxia (J1y) and Kezilenuer (J2kz) formations act cooling stage.
as the cap rocks.
4. RESULTS AND DISCUSSION
3. SAMPLES AND METHODS
4.1. Oil and Source Rock Geochemistry
Oil, gas and core samples were collected from the reservoirs
of the Kela 2, Keshen and Dibei gas fields. Several analytical Because the T3h source rock developed in a lacustrine

http://www.springer.com/journal/12303 https://doi.org/10.1007/s12303-018-0011-6
72 Xu Song, Xiuxiang Lü, Yunqi Shen, and Song Guo

Fig. 2. TIC, m/z 191 and m/z 217 of the saturated hydrocarbons for the source rock extractions and oil samples. Pr: pristane; Ph: phytane; TT:
tricyclic terpanes; Ts: C2718α(H)-22,29,30-trisnorneohopane; Tm: C27 17α(H)-22,29,30-trisnorhopane; C24TeT: C24 tetracyclic terpane; C30H: C30
hopane; C27-29: C27-C29 5α(H),14α(H),17 α(H)-regular steranes (R).

environment whereas the J2kz and J1y source rocks were differences in the relative abundances of the isoprenoids, terpanes,
deposited in a swamp-lacustrine environment, they show obvious hopanes and steranes. The T3h source rock is characterized by a

https://doi.org/10.1007/s12303-018-0011-6 http://www.springer.com/journal/12303
Hydrocarbon accumulation history in deep reservoirs of the Kuqa Depression 73

Table 1. Molecular geochemical parameters of the source rock and oil samples in Kelasu-Yiqikelike structural belt of the Kuqa Depression
Well Depth (m) Formation Sample type 1 2 3 4 5 6 7 8 9 10
YN2 5244–5245 T3h Mudstone 0.95 0.32 0.36 0.9 0.09 0.11 0.65 0.75 0.45 0.42
YN2 4263 J2kz Mudstone 2.5 1.5 0.50 4.43 0.81 0.92 0.3 0.33 0.4 0.47
YN2 4400–4408 J1y Mudstone 2.15 3 0.68 7.6 0.49 1.34 0.47 0.39 0.51 0.53
KL2 3820–3836 K1bs Oil 0.86 1.1 0.16 0.92 0.2 0.14 0.98 1.55 0.45 0.42
KL201 3672–3688 K1bs Oil 1.28 1.24 0.31 0.95 0.29 0.15 0.62 0.92 0.52 0.57
KL201 3770–3795 K1bs Oil 1.14 0.82 0.39 0.33 0.07 0.16 0.54 0.7 0.41 0.51
KL203 3814–3826 K1bs Oil 1.08 0.78 0.07 0.87 0.11 0.15 0.73 0.79 0.49 0.56
YN2 4706 J1y Oil 2.01 3.7 0.79 2.64 1.11 0.73 0.33 0.52 0.53 0.59
YN2 4710–4725 J1y Oil 2.27 2.14 0.51 2.29 1.03 0.69 0.41 0.5 0.4 0.6
YN2 4746–4760 J1y Oil 2.01 3.32 0.54 2.62 1.12 1.75 0.3 0.54 0.53 0.59
YN2 4776–4785 J1a Oil 2.41 2.37 0.47 3.36 1.14 1.1 0.42 0.52 0.45 0.62
YN2 4905–4913 J1a Oil 1.05 0.6 0.40 0.03 0.09 0.26 0.58 0.68 0.48 0.51
YN2C 4606–4620 J1y Oil 2.62 6.04 0.79 4.45 0.68 0.89 0.39 0.53 0.4 0.6
YN5 4529–4538 J1y Oil 1.93 0.61 0.38 0.39 0.07 0.19 0.61 0.78 0.47 0.45
1, Pr/Ph; 2, C24 tetracyclic terpane/C26 tricyclic terpane; 3, C29Ts/C30 norhopane; 4, C19 tricyclic terpane/C23 tricyclic terpane; 5, C30 diahopane/
C30 hopane; 6, C27 diasterane/C27 regular sterane; 7, Regular sterane αααC28 20R/C29 20R; 8, Regular sterane αααC27 20R/C29 20R; 9, Regular
sterane αααC29 20S/(20S + 20R); 10, Regular sterane C29ββ/C29(αα + ββ).

low pristine to phytane ratio (Pr/Ph), a low abundance of C24 and diasteranes can indicate acid catalysis by clay minerals in an
tetracyclic terpane (C24 TeT) relative to C26 tricyclic terpane (C26 oxidizing or sub-oxidizing depositional environment (Rubinstein
TT), and scarce rearranged hopanes, with a low C30 rearranged et al., 1975). In addition, the ratio of C19/C23 tricyclic terpane in
hopane (diaC30H) to C30 hopane (C30H) ratio of 0.09 (as shown coal-derived oil is generally more than 1.5, while this ratio in
in Fig. 2 and Table 1). In the J2kz and J1y source rocks, the lacustrine oil is approximately 1.0; hence, this ratio can be used
distributions of the hopanes and terpanes are similar overall. as an indicator to determine the sources of the oil in the Kuqa
Compared with the T3h source rock, the J2kz and J1y source Depression (Bao et al., 2007).
rocks have higher proportions of C29 sterane, with C27/C29 Based on the criteria discussed above, the oil in the Kela 2 and
sterane ratios of 0.33 and 0.39, respectively (Table 1). Therefore, Dibei gas fields can be classified into two groups (Fig. 3). Group
the input of higher plants was more abundant in the lower- 1 includes all the oil samples from the Kela 2 gas field and two
middle Jurassic source rocks (Huang and Meinschein, 1979). samples from wells YN2 and YN5. The Pr/Ph ratios of the
The abundances of terpanes, hopanes and steranes were Group 1 oil are generally lower than those of the Group 2 oil,
measured in the oil samples (Fig. 2). The Pr/Ph ratios of the oil except one sample from well YN5 with a value of 1.93, which is
samples range from 0.86 to 2.62. Most of the oil samples from similar to the Pr/Ph ratios of the Group 2 oil from the Dibei gas
the Dibei gas field show higher C24 TeT/C26 TT, C19 tricyclic field. The Group 1 oil also shows lower ratios of diaC30H/C30H
terpane (C19TT) to C23 tricyclic terpane (C23TT) and diaC30H/ and diaC27/C27 sterane than the Group 2 oil, indicating that the
C30H values than the oil samples from the Kela 2 gas field, Group 1 oils came from a source rock that was deposited in a
except for the oil samples from the wells YN2 (4905–4913 m) relatively oxygen-deficient lacustrine environment. The C24TeT/
and YN5. The C27/C29 sterane values in the oil from the Kela 2 C26TT and C19TT/C23TT ratios in the Group 2 oil are higher
gas field are generally higher than those in the oil samples from than those in the Group 1 oil, indicating that the Group 2 oil
the Dibei gas field (Table 1). came from a source rock with relatively abundant higher plant
The biomarker parameters that are influenced by the source input. The Group 1 oil has relatively high C27/C29 and C28/C29
rock depositional environments and organic matter input can sterane ratios, suggesting that the oil source rock was primarily
be selected to determine the sources of oil in the Kela 2 and Dibei dominated by aquatic organisms, with little higher plant input.
gas fields. Oil generated from lacustrine source rocks often In summary, the Group 1 and Group 2 oils have different
contains relatively more 20R-C27 14α (H), 17α (H) sterane and biomarker characteristics, suggesting that the oils belonging to
less 20R-C29 14α (H), 17α (H) sterane, indicating little influence these two groups came from different source rocks. The Group
by higher plants (Peters et al., 2005). Oil from coaly humic 1 oil includes all the samples from the Kela 2 gas field and a
depositional environments contains more diasteranes and diahopanes small portion of the samples from the Dibei gas field. They are
than oil of the lacustrine oils. The relative abundance of diahopanes typical lacustrine, sapropelic oils, with relatively low contents of

http://www.springer.com/journal/12303 https://doi.org/10.1007/s12303-018-0011-6
74 Xu Song, Xiuxiang Lü, Yunqi Shen, and Song Guo

Fig. 3. Correlation between various biomarker parameters on source rock depositional environments and organic matter input for the oils,
showing that the oils from Kela 2 and Dibei gas fields can be categorized into two groups. diaC27/C27: 20R 13β(H),17α(H)-diasterane/20R
14α(H),17α(H)-sterane; diaC30H: C30 diahopane; C29Ts: 18α(H)-30-norneohopane; Pr: pristane; Ph: phytane; TT: tricyclic terpanes; C24TeT: C24
tetracyclic terpane; H: hopane; C27-29: C27-29 20R 14α(H),17α(H)-sterane.

diasteranes and diahopanes, high concentrations of 20R-C27 range from 0.03–4.45, indicating that some oil samples show
14α (H), 17α (H) sterane and low Pr/Ph ratios, except for the oil characteristics of lacustrine oils. Therefore, the oils from the Kela
sample from well YN5, which has a high Pr/Ph ratio of 1.93. The 2 gas field came from the T3h source rock, and the oils from the
biomarker characteristics indicate that the Group 1 oil came Dibei gas field primarily came from the lower–middle Jurassic
from the T3h mudstones rather than the J2q mudstones. Liu et coal measures, with some contribution from the T3h source
al. (2016) reported that the oil derived from the J2q source rock rock.
has a high concentration of the diahopane series. Thus, the Group In terms of oil maturity, the sterane αααC29 20S/(20S + 20R)
1 oil came from the T3h source rock because it is characterized ratios of the oil samples from the Kela 2 gas field range from
by low diaC30H/C30H and diaC27/C27 sterane ratios. The Group 0.41–0.52 (Table 1), clearly indicating that most of the oils have
2 oil includes most of the samples from the Dibei gas field, and not reached an equilibrium point (0.52–0.55) in sterane isomerization
they are typical coaly humic oils with higher abundances of (Seifert and Moldowan, 1981; Peters and Moldowan, 1993).
20R-C29 14α (H), 17α (H) sterane, diasteranes and diahopanes. Moreover, the C29ββ/C29(αα + ββ) values of 0.42–0.57 are even
The biomarker characteristics of the Group 2 oil correlate well further from the equilibrium point (0.70), indicating that the
with the extracts of the J2kz and J1y mudstone, thus suggesting a Kela 2 oils are in the mature stage. Zhuo et al. (2012) reported
source in the lower–middle Jurassic coal measures. The C19/C23 that the interpreted maturity of the KL201 oil corresponds to
tricyclic terpane ratios in the samples from the Dibei gas field equivalent Ro values between 0.7 and 0.8 based on the sterane

https://doi.org/10.1007/s12303-018-0011-6 http://www.springer.com/journal/12303
Hydrocarbon accumulation history in deep reservoirs of the Kuqa Depression 75

αααC29 20S/(20S + 20R) stereoisomer ratio. This finding also 4.2. Gas Geochemistry
implies that the sample is within the oil generation window.
However, the diamondoids maturity parameter based on the The compositional data for all the samples from the gas fields
methyldiamantane index suggests that the equivalent Ro values is shown in Table 2. The natural gas from the Kela 2 gas field
are 1.64–1.82%, indicating that the oil was generated at the very displays a high content of CH4 with a deficiency of heavy
high maturity stage (Guo et al., 2016a). Such a maturity discrepancy hydrocarbons. The CH4 content in the gas ranges from 96.41–
implies that multi-stage hydrocarbon accumulation occurred in 98.63%, indicating that the gas type is typically dry gas. Similar
the Kela 2 gas field and that the oil is actually a mixture of the to the Kela 2 gas field, the methane content of the Keshen gas
hydrocarbons generated during different maturity stages of the field is 96.3–97.9%, hence, the Keshen gas field can be classified
source rock. Thus, a single maturity parameter cannot effectively as a dry gas field. In the Dibei gas field, the content of CH4 ranges
describe the properties of this oil mixture. The sterane parameters from 80.88–93.39%, hence, this field can be classified as a wet
appear to reflect only the low-maturity oil, while the diamondoids gas field.
parameter reflects only the high-maturity oil that interfused For the gases that have not been affected by migration or
into the reservoir. Further supporting evidence for multi-stage mixing with biogenic gas, the carbon isotope value of the hydrocarbon
hydrocarbon accumulation derived from inclusion petrography component can reflect their maturation and origin. Figure 4a
and homogenization temperature will be discussed later. In the shows that the δ13C values of the natural gas vary greatly among
oil from the Dibei gas field, the sterane αααC29 20S/(20S + 20R) these gas fields. The points representing the Kela 2 and Keshen
ratios range from 0.4 to 0.53, and the C29ββ/C29(αα + ββ) ratios gases are located in the upper right of the graph, showing a
range from 0.45 to 0.6. Therefore, this oil was derived from higher maturity with δ13C1 values higher than –31‰. In contrast,
source rocks in the mature stage. the plot shows that the Dibei natural gas is less mature than the

Table 2. Molecular, stable carbon and dryness coefficient (C1/C1-4) gases from Kuqa Depression in the Tarim Basin, China
Main composition (vol%) Dryness coefficient δ13C (PDB, ‰)
Gas field Well Strata Depth (m)
CH4 C2H6 C3H8 C4H10 CO2 N2 (C1/C1-C4) δ C1 δ13C2 δ13C3
13
δ13C4
Kela2 KL2 E,K 3499.9–3809 98.63 0.56 0.04 0.00 0.74 0.04 99.40 –28.2 –18.2 –19.3 –19.1
KL2 E 3499.87–3534.66 96.90 0.31 0.04 0.00 1.24 1.55 99.64 –31.1 –16.8 –18.5 –17.8
KL2 K 3803–3809 96.63 0.09 0.00 0.00 0.76 2.52 99.91 –27.8 –18.7
KL2 K 3888–3895 98.22 0.53 0.04 0.03 0.55 0.60 99.39 –27.8 –19.0
KL201 K 4016–4021 96.88 0.91 1.00 0.00 0.00 1.21 98.07 –27.3 –19.0 –19.5 –20.9
KL201 K 3630–3640 97.04 0.78 0.03 0.00 0.55 1.61 99.17 –27.1 –18.5 –19.1 –20.3
KL201 K 3770–3795 96.41 0.77 0.02 0.00 0.88 1.92 99.19 –27.2 –17.9 –19.1 –20.6
KL201 K 3936–3938 97.45 0.79 0.03 0.00 0.57 1.15 99.17 –26.2 –18.1 –19.1 –22.1
KL201 K 3630–4021 96.96 0.82 0.03 0.00 0.54 1.65 99.13 –27.2 –18.5 –19.5 –20.9
KL202 E 1472–1481 97.39 0.80 0.03 0.00 0.65 1.13 99.15 –28.2 –18.9 –19.2 –20.9
KL203 E,K 3968.5–3916.5 97.83 0.79 0.07 0.09 0.65 0.47 99.04 –28.9 –18.0 –20.1 –21.8
Keshen KS2 K 6573–6697 97.50 0.51 0.04 0.04 0.83 1.10 99.40 –28.3 –17.7 –15.7
KS201 K 6735–6755 97.20 0.57 0.04 0.01 0.74 1.34 99.37
KS201 K 6505–6700 97.10 0.56 0.04 0.01 0.89 1.38 99.37
KS202 K 6705–6969 97.00 0.60 0.05 0.02 0.82 1.54 99.32
KS5 K 6703–6742 97.00 0.27 0.01 0.01 0.76 1.92 99.70 –26.5 –17.8 –19.2
KS5 K 6813–6875 97.90 0.28 0.02 0.00 0.83 0.93 99.69 –26.4
KS8 K 6684.42–6827.8 96.30 0.40 0.05 0.13 0.57 2.18 99.40
Dibei YN2 J 4726–4785 89.63 5.49 1.26 0.49 2.52 0.62 92.54 –32.2 –24.6 –23.1 –22.8
YN2 J 4578.8–4758 88.61 6.83 2.15 0.88 0.28 0.93 89.99 –34.8 –22.4 –25.9 –21.7
YN2 J 4776–4785 90.06 4.95 1.01 0.40 2.59 93.41 –32.2 –24.6 –23.0 –22.8
YN2C J 4606–4620 81.94 8.98 3.21 1.33 1.50 2.24 85.84 –36.0 –27.6 –24.4 –23.6
YN4 J 3619.39–3677.13 93.39 2.49 1.41 1.34 0.98 0.89 94.69 –30.7 –25.8 –24.4 –25.4
YN5 J 3276.5–3282.5 87.96 5.56 1.16 0.53 0.60 3.97 92.39 –33.1 –19.4 –23.5 –25.0
YS4 J 1759–1761 81.14 13.14 2.32 0.85 0.17 2.28 83.26 –37.7 –25.6 –22.3 –22.3
YS4 J 3554–3564 80.88 12.26 2.64 0.99 0.10 2.93 83.58 –36.9 –25.1 –26.5 –27.4

http://www.springer.com/journal/12303 https://doi.org/10.1007/s12303-018-0011-6
76 Xu Song, Xiuxiang Lü, Yunqi Shen, and Song Guo

Kela 2 and Keshen gases. As a maturation parameter, the carbon


isotope ratios of the gas generated by different types of kerogen
tend to undergo different evolution trends, and these gases have
typical carbon isotope kinetic models. The maturity evolution
trends for sapropelic type II and humic type III kerogen established
by Rooney et al. (1995) are used to analyse the gas origins in this
paper, as shown in (Fig. 4a). The carbon isotope ratios of type II
kerogen differ from those of type III kerogen, and the majority
of the carbon isotope values of the samples in this study plot
along the type III kerogen line, indicating that the natural gas
was generated from humic type III organic matter. In addition,
based on their study of giant gas fields discovered in China, Dai
et al. (2005) proposed that the gas from a sapropelic source has
δ13C2 and δ13C3 values generally lower than –29‰ and –27‰,
respectively, whereas the gas from a humic source has values
higher than –27.5‰ and –25.5‰, respectively. According to
this criterion, the natural gas δ13C2 values from these gas fields,
which range between –17.8‰ and –27.6‰ and are therefore
higher than –28‰, are characteristic of coal-type gas (Fig. 4b).
The comparison between the calculated Ro values based on
the δ13C values of natural gas and the measured Ro values of source
rocks provides an effective method for gas-source correlation.
The empirical model proposed by Berner and Faber (1996) can
be used to estimate the maturity of gases based on maturity
curves in plots of δ13C2 vs. δ13C3, and this model has been widely
in previous studies (Rodriguez and Philp, 2010; Kotarba et al.,
2014). One essential element that must be constrained is the
δ13C value of the precursor kerogen. According to a previous
study, the measured δ13C values of the type III kerogen in the
Kuqa Depression range from –23.8‰ to –25.2‰ (Liang et al.,
2003). An average value of –24.5‰ was used to calculate the
maturity curve, and the results are shown in Figure 4c.
Figure 4c demonstrates that most of the samples from the
Dibei gas field fit well on the curve with a Ro value between
0.8% and 1.3%, and the calculated Ro value is consistent with
the maturity of the Jurassic source rocks in the Dibei gas field,
which have Ro values of 1.0–1.3%, as reported by Tang et al.
(2014). Thus, the gas in the Dibei gas field was primarily derived
from the Jurassic coal measures. Notably, some samples from the
Dibei gas field show anomalously high δ13C2 values, suggesting
that these samples experienced gas diffusive leakage (Xiao, 2012).
Almost all the samples from the Kela 2 gas field and the Keshen
gas field depart from the maturity curve due to anomalously
high δ13C2 values. The Kela 2 and Keshen gas could have been
generated from a source rock with a maturity of Ro = 2.0–2.5%, Fig. 4. Correlation of carbon isotopic ratios of (a) methane and eth-
which is consistent with the Jurassic source rocks in the Kela 2 ane, (b) ethane and propane from gases in the Kela 2, Keshen and
Dibei fields, (c) predicting maturity levels for the gases analyzed,
and Keshen gas fields, which have Ro values of > 2% (Tang et al., based on calculation model proposed by Berner and Faber (1996),
2014). Thus, the gas in the Kela 2 and Keshen gas fields was derived numbers on the lines indicate the maturity of the respective source
from the Jurassic coal measures. The samples with anomalously rock.

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Hydrocarbon accumulation history in deep reservoirs of the Kuqa Depression 77

high δ13C2 values can be explained by leakage of earlier oil and These inclusions in secondary fractures in quartz are typical dry
the gas associated with the oil. Hence, the gas in the Kela 2 and gas inclusions, indicating that the associated gas charging event
Keshen gas fields is the gas generated in the highly to post- was late (Fig. 5e).
mature stage. This reservoir destruction model is supported by In contrast to the KL201 well samples, the inclusions of the
the following lines of evidence. (1) In the hydrocarbon generation Keshen well samples are remarkably different. In the KS8 well
process, the δ13C value of gas increases as the maturity of the samples, only single-phase gaseous inclusions are present, and
source rock increases, and the δ13C value of the gas and source they are abundant in the secondary quartz overgrowth in cracks
rock are approximately equal (Galimov, 1974; Stahl, 1974). However, (Figs. 5f and g). These inclusions range in size from 1–10 μm,
the δ13C2 value of the Kela 2 gas is clearly much higher than that and they appear dark grey under plane-polarized light but are
of the source rock (δ13Ckerogen: –23.8 ~ –25.2‰), indicating that the colourless under UV light. Because the inclusion-bearing quartz
gas originating from the early charge has dissipated. (2) Abnormally overgrowth is well developed, as evidenced by orthogonal
high benzene and toluene contents were found in light hydrocarbon polarization microscopic observations (Fig. 5h), the reservoir is
component of the Kela 2 gas. Coal pyrolysis experiments have inferred to have experienced strong diagenesis, and the gas
verified that high yields of aromatics are generated when the charging event likely occurred relatively late.
source rocks reach high thermal maturity (Hu et al., 2014). (3) In the Dibei well samples, the inclusions are mainly round
Reservoir bitumen formed by evaporative fractionation was and ellipsoidal in shape and are generally smaller than 10 μm.
widely detected in the Cretaceous reservoir (Zhao, 2003), implying Two types of inclusions have been identified in the YN wells of
that the petroleum generated in the early stage was destroyed in the Dibei gas field. One type is mainly located in micro-fissure
a later period. In summary, the gas in the Kela 2, Keshen and shear zones across quartz grains and associated secondary
Dibei gas fields was derived from the Jurassic coal measures. overgrowth. These inclusions contain light oil and gas. The
liquid hydrocarbons appear light yellow in colour, while the gas
4.3. Petrography of Hydrocarbon Charge bubbles are grey under plane-polarized light (Fig. 5i), and their
fluorescent colour is green (Fig. 5j). The other type exhibits
The fluid inclusion petrography can provide general information linear distributions along diagenetic microfractures in quartz.
on the composition of pore fluids trapped in different diagenetic These inclusions are single-phase gaseous inclusions that appear
minerals and the generation, migration and accumulation of charcoal grey in colour under plane-polarized light (Fig. 5k)
hydrocarbons. In this paper, numerous oil and gas inclusions and exhibit a blue-white fluorescence colour (Fig. 5l). As most
distributed in secondary diagenetic minerals were observed of the inclusions are spread along micro-fractures intersecting
under a microscope. In the KL201 well samples, the shape and the quartz overgrowth, the formation of these inclusions likely
size of fluid inclusions are heterogeneous. These inclusions are occurred relatively late. The two types of fluid inclusions observed
commonly irregular in shape and have diameters ranging from present different fluorescence colours, indicating that they
2–8 μm. Three types of inclusions are observed under the formed during at least two stages of charging with hydrocarbons of
microscope. The first type, with gas and liquid phases, is rare different maturities.
and is mainly distributed in early calcite cement. The gaseous
component of these inclusions appears charcoal grey, and the 4.4. Inclusion Homogenization Temperature and
liquid component is light grey under plane-polarized light (Fig. Salinity
5a), and both present a light yellow colour under UV light (Fig.
5b). As the inclusions exist in early cement, the formation of these Based on the analysis of the petrography above, it is clear that
inclusions and the charging of the hydrocarbons associated with the gas reservoirs of the Kelasu-Yiqikelike structural zone have
these inclusions are inferred to have occurred relatively early. experienced different hydrocarbon charging processes, and some
The second type primarily exists in quartz veins. These two- of them have the characteristics of multi-stage hydrocarbon
phase (gas and liquid) inclusions are dark grey in colour (Fig. 5c), accumulation. The formation time of reservoirs can be determined
and exhibit a blue-white fluorescence colour (Fig. 5d). Because by measuring inclusion homogenization temperature (Th),
these inclusions occur in secondary mineral veins that developed which can also reveal the reservoir burial and evolution history
during the middle diagenetic period, they formed after those (Karlsen et al., 1993; Feely and Parnell, 2003). As the homogenization
presenting a light yellow fluorescence colour. The third type temperature of contemporaneous saline inclusions is closer to
features single-phase gaseous inclusions present primarily in the fluid capture temperature than that of hydrocarbon inclusions,
secondary fractures in quartz. These inclusions appear black or it is suitable for determining the reservoir formation periods
grey in transmitted light and exhibit no fluorescence colour. (Nedkvitne et al., 1993; Munz et al., 1999).

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78 Xu Song, Xiuxiang Lü, Yunqi Shen, and Song Guo

Fig. 5. Photomicrographs of inclusions under plane polarized and UV light from the Kuqa Depression. (a, c, and e) hydrocarbon inclusions
under plane polarized light, well KL201, 3936 m, Cretaceous; (b and d) oil-gas inclusions under UV light, well KL201, 3936 m; Cretaceous; (f–
h) gas inclusions under plane polarized light, well KS8, 6732–6740 m, Cretaceous; (i and j) oil-gas inclusions under plane polarized and UV
light, respectively, well YN4, 4419 m, Jurassic; (k and l) gas inclusions under plane polarized and UV light, respectively, well YN2, 4787 m, Jurassic.

To determine the hydrocarbon charging processes, the final inclusions is generally lower than that of the saline inclusions
ice melting temperatures (Tm) of the saline inclusions were measured, coeval with oil inclusions, ranging from 4.03–8.68 wt%. In the
and the salinities of those saline inclusions were calculated (Figs samples from the Keshen gas field, the saline inclusions coeval
6a–c). The salinity values of the saline inclusions from the Kela 2 with gas inclusions have similar salinity values of approximately
gas field range from 4.03–22.38 wt% NaCl equivalent. The 19.05–23 wt%. In the samples from the Dibei gas field, the
saline inclusions coeval with the yellow-coloured oil inclusions salinity values of the saline inclusions coeval with oil inclusions
have relatively higher salinity values (18.17–22.38 wt%) than the range from 17.86–23 wt%, which are higher than the saline
saline inclusions coeval with blue-coloured oil inclusions (7.59– inclusions coeval with gas inclusions (2.9–8.35 wt%).
12.05 wt%). The salinity of the saline inclusions coeval with gas The homogenization temperature of the saline inclusions

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Hydrocarbon accumulation history in deep reservoirs of the Kuqa Depression 79

Fig. 6. Cross plot of homogenization temperature and salinity of saline inclusions coeval with oil inclusions and gas inclusions and their
homogenization temperature histograms from the Mesozoic reservoir sandstone in the Kelasu-Yiqikelike structural belt of the Kuqa Depres-
sion. OI: oil inclusions; SI: saline inclusions; GI: gas inclusions.

coeval with hydrocarbon inclusions in the Cretaceous reservoir characteristics of multiple peaks distribution (Fig. 6d). The
of the Kela 2 gas field ranges from 70–140 °C, showing the saline inclusions coeval with the oil inclusions show variable

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80 Xu Song, Xiuxiang Lü, Yunqi Shen, and Song Guo

salinities. The high-salinity saline inclusions coeval with the white fluorescence colour. Therefore, two stages of hydrocarbon
yellow-coloured oil inclusions have Th values ranging from 75– accumulation occurred in the Dibei reservoir; the first stage was
98 °C (with peak values between 80–90 °C), whereas the low- the mature oil charge, and the second stage was the high-maturity
salinity saline inclusions coeval with the blue-coloured oil inclusions wet gas filling stage.
have Th values of 101–127 °C (with peak values between 100–
120 °C). This pattern suggests that the oil inclusions became 4.5. Basin Modelling and Calibration Data
trapped over a prolonged period of time and that there were two
episodes of oil charging in the reservoir. The low-salinity saline Several parameters can be used to calibrate the burial history
inclusions coeval with the single-phase gaseous inclusions that of a unit, including deposition age, lithology, paleo-water depth,
are colourless under fluorescent light exhibit Th values ranging surface temperature, geothermal gradient and heat flow. The
from 120–140 °C (with peak values between 120–130 °C), implying geothermal gradients in the Kela-Keshen and Dibei gas fields
that a late post-mature gas charge event occurred in the reservoir. are 22–24 °C/km and 20.5 °C/km, respectively. The calculated
The Th values from the Cretaceous reservoir samples in the current heat flow of the Kela-Keshen and Dibei gas fields is 52.1
Keshen gas field range from 111–184 °C (with peak values between mW/m2 and 45.2 mW/m2, respectively (Guo et al., 2016a, b).
140–160 °C) and feature a single-peak distribution pattern (Fig. The other parameters are from a previous study (Liu et al., 2016).
6e). The saline inclusions coeval with the gas inclusions have The borehole temperatures derived from the well testing results
similar salinities, suggesting that the Keshen reservoir experienced were used to calibrate the thermal modelling results. Three wells,
one stage of natural gas accumulation. Some saline inclusions i.e., KL 201, KS 8, and YN2, were used to reconstruct the burial
display anomalously high Th values (> 170 °C), which may be history. The goodness of fit between the modelled and measured
due to the re-equilibration of early-trapped inclusions at high temperatures shown in Figure 7 implies that the burial history
temperatures. models are reasonable in this area.
The Th values of saline inclusions in the Dibei gas field range
from 87.7–150 °C (Fig. 6f). The Th values of 87.7–110.3 °C (with 4.6. Hydrocarbon Charge History
peak values between 90–100 °C) are associated with the relatively
high-salinity saline inclusions coeval with the oil inclusions, and Based on the peak Th values of the saline inclusions and the
the Th values of 111.6–150 °C (with peak values between 130– reservoir burial and thermal evolution history, the timing of the
140 °C) are associated with the low-salinity saline inclusions hydrocarbon charge can be determined. As shown in Figures 8a
coeval with the single-phase gaseous inclusions with a blue- and b, the first hydrocarbon charging event in the Cretaceous

Fig. 7. Calibration of thermal maturity modelling of the (a) KL201, (b) KS8, and (c) YN2 wells showing good correlations between the mea-
sured and calculated temperatures.

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Hydrocarbon accumulation history in deep reservoirs of the Kuqa Depression 81

Fig. 8. Burial and thermal histories as well as hydrocarbon charge timing in the Kuqa Depression. The shaded bars represent the main hydro-
carbon charging stages occurred in the gas reservoirs.

reservoir in the Kela 2 gas field occurred in the late Miocene, and middle–late Pliocene, respectively. Because the source rock
and the second and third charging events occurred in the early was buried rapidly starting in the late Miocene, the maturity of

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82 Xu Song, Xiuxiang Lü, Yunqi Shen, and Song Guo

Fig. 9. Hydrocarbon charging history of Kela and Keshen gas fields. (a) The gas reservoir distribution during the late Pliocene–Quaternary.
(b) Dry gas filled into the pools and oil dissipated during the middle–late Pliocene. (c) High mature oil charged into the reservoir during the
early Pliocene. (d) Low mature oil charged into the reservoir during the late Miocene.

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Hydrocarbon accumulation history in deep reservoirs of the Kuqa Depression 83

the source rock increased dramatically, and the hydrocarbon 1.4% to more than 2% (Tang et al., 2014). A large amount of
accumulation, including both oil and gas charging, was continuous. expelled highly to post-mature gas generated by the Jurassic coal
In contrast to the Kela 2 gas field, one gas charging event was measures migrated vertically along the faults and accumulated
identified in the Keshen gas reservoir according to the Th values, in the Kela 2 trap. This hydrocarbon charge is characterized by
and this gas charging event occurred in the late Pliocene– the large amounts of dry gas, and the single-phase gaseous
Quaternary (Figs. 8c and d). In the Dibei gas field, two stages of inclusions with no fluorescence colour in the reservoir are evidence
hydrocarbon accumulation were recognized. The first, corresponding of this filling event. At the same time, compressional tectonism
to a mature oil charge, occurred in the early Miocene, and the resulted in the formation of the Kelasu fault and the reactivation
second, corresponding to a highly mature wet gas charge, occurred of its neighbouring faults. The lateral sealing conditions of the
in the Pliocene (Figs. 8e and f). reservoir became poor due to fault activity. Thus, the previously
formed oil was displaced by a large amount of gas and escaped
4.7. Hydrocarbon Accumulation Process and Model (Fig. 9b).
Because of the continuous N-S-directed compressive stress,
4.7.1. Hydrocarbon accumulation model for the the structural deformation event extended from the northern
Kela 2 and Keshen gas fields Kela zone to the southern Keshen zone, and the Keshen zone
During the late Miocene, the Kela 2 structural trap began to experienced continuous subsidence. Numerous thrust faults
form, but its amplitude was low. The T3h lacustrine source rock formed both in the salt overburden and in the subsalt layers,
in the region entered a mature stage, and the expelled oil migrated resulting in the development of various thrust nappe structures
mainly vertically along the faults to the low-amplitude anticline in the Keshen zone since the late Pliocene period. During the
(Fig. 9d). This hydrocarbon charging event was recorded by the late Pliocene–Quaternary period, imbricate fault-related anticlines
gas-liquid inclusions with a light yellow fluorescence colour in formed in the Keshen zone, and the dry gas derived from the
the Cretaceous reservoir. As the Kela 2 anticline was a structural underlying Jurassic coal measures migrated vertically along the
high in the Kela-Keshen area and no traps formed in the Keshen faults into these traps (Fig. 9a).
zone, the oil derived from the deeply buried T3h source rock
bypassed the region and did not become trapped in the Keshen 4.7.2. Hydrocarbon accumulation model for the Dibei
zone, in accordance with the fact that no oil inclusions are gas field
observed under the microscope. During the early Miocene period, the Triassic source rock
In the early Pliocene period, the Kuqa Depression subsided entered the peak stage of oil generation, and the Ro values of the
rapidly, and the T3h lacustrine source rock in Kela-Keshen sequence reached more than 0.8%. Correspondingly, the lower–
region started to enter the highly mature stage. The Kela 2 trap middle Jurassic coal measures began to generate oil with Ro values
formed prior to or during this hydrocarbon generation period, of 0.6–0.8% (Liang et al., 2003). Due to the middle Himalayan
and light oil generated in the source sequence migrated up Orogeny, the Dibei region was compressed, and low-amplitude
along the Kelasu fault and accumulated in this trap, although anticlines formed in the slope zone (Tian, 2001). The oil derived
the maturity of source rock was beyond the oil-generating peak from the lower–middle Jurassic coal measures, along with some
(Fig. 9c). This hypothesis is consistent with the information contributions from the T3h lacustrine source rock, charged the
obtained from the oil-bearing inclusions with a blue-white Jurassic reservoir (Fig. 10c). The gas-liquid inclusions displaying a
fluorescence colour. In contrast to the Kela area, the Keshen area green fluorescence colour are evidence of this oil charging event.
still lacked a trap during this period. Therefore, little hydrocarbon In the Pliocene period, the South Tianshan orogenic event
accumulation occurred in the Keshen zone (Fig. 9c). increased in intensity, and regional faults under the salt layer
In the middle–late Pliocene, the Kuqa Depression evolved were reactivated. Due to the intense tectonic deformation, the
tectonically into an intracontinental foreland (Neng et al., 2012). Dibei slope zone dipped to the south. The lower–middle Jurassic
This region experienced N-S compression in response to the coal measures were buried to a depth of 4–6 km and rapidly
middle Himalayan orogenic event. Due to the intense uplift of entered the peak gas-generation window. As the Jurassic reservoir
the South Tianshan Mountains, the Kuqa Depression subsided had densified during the middle–late Miocene (Xing et al., 2011),
extensively and rapidly. Consequently, the Triassic and Jurassic the gas charging was driven by gas expansion and diffusion
strata were rapidly buried to depths of 6–8 km, leading to a rather than by gas buoyancy. The wet gas derived from lower–
quick maturity increase of the source rock. During the short middle Jurassic coal measures expanded into the Jurassic reservoir,
period of 2–3 Ma since the early Pliocene, the Ro value of the resulting in the formation of the wet reservoirs (Fig. 10b). This
lower–middle Jurassic coal-bearing sequence has increased from hydrocarbon charging event is recorded by the single-phase

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84 Xu Song, Xiuxiang Lü, Yunqi Shen, and Song Guo

Fig. 10. Evolution of hydrocarbon charges in the Dibei Gas Field. (a) The transformation of the Dibei gas reservoir during the Quaternary. (b)
Wet gas charged into the Jurassic reservoirs in the Pliocene. (c) During the early Miocene, the oil generation of the Jurassic source rock com-
bined with some contribution of the Triassic source rock charged into the Jurassic reservoirs.

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Hydrocarbon accumulation history in deep reservoirs of the Kuqa Depression 85

gaseous inclusions with a blue-white fluorescence colour. and the National Science and Technology Major Project (No.
During the Quaternary, the intracontinental Himalayan orogenic 2017ZX05008). The Tarim Oilfield Research Institute, PetroChina,
event reached its peak intensity, and the fault activity increased is thanked for providing some data and core samples.
(Zeng et al., 2010). Therefore, the southward dip of the Dibei
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