25

tiempo (min) volumen (V∞-Vt) (ml)

0 2 13.4 (V∞-Vt) vs
1 3.8 11.6 16
2 5.6 9.8
3 7 8.4 14
4 8.1 7.3
5 9 6.4 12
6 9.8 5.6
10
7 10.3 5.1

(V∞-Vt) (ml)
8 10.9 4.5
8
9 11.5 3.9
10 12 3.4 6
11 12.3 3.1
12 12.5 2.9 4
13 12.7 2.7
14 13.4 2 2
15 13.4 2
16 13.6 1.8 0
0 5 10 1
17 13.8 1.6
18 14 1.4
19 14.2 1.2
20 14.3 1.1
21 14.4 1
y = -0.3463x + 8.5458
22 14.5 0.9
23 14.6 0.8
24 14.6 0.8
25 14.6 0.8
26 14.8 0.6
30 15 0.4
32 15.1 0.3
33 15.4 0
15.4
 (V∞-Vt) vs t (min) para 25°C

10 15 20 25 30 35

Tiempo (min)

y = -0.3463x + 8.5458

8.5458
para 25.1
log v rxn log (V∞-Vt)
0.2552 1.127 log rxn vs log (V∞-Vt) para 25°C
0.2552 1.064 0.3
0.1461 0.9912 0.25

log v rxn
0.041 0.9243
0.2
-0.04 0.8633
0.15
Log V rxn =nlog(V-Vt) + C 0.1

0.05
orden de reaccion = n = 1.2078= 2
0
0.85 0.9 0.95 1 1.05
Vrxn (V∞-Vt) -0.05
1,8 13,4 0.0746 -0.1
1,8 11,6 0.0862
log (V∞-Vt)
1,4 9,8 0.102
1,1 8,4 0.119
0,9 7,3 0.1369
y = 1.2078x - 1.069

orden 1
g (V∞-Vt) para 25°C

1 1.05 1.1 1.15

log (V∞-Vt)
 1/(V∞-Vt) vs t (min) a T= 25°C
1/(V∞-Vt) t (min) 0.16
0.0746 0
0.14
0.0862 1 f(x) = 0.01574 x + 0.07226
0.12
0.102 2
0.1
0.119 3

1/(V∞-Vt)
0.1369 4 0.08
0.06
0.04
0.02
0
0 0.5 1 1.5 2 2.5 3 3.5 4 4.
t (min)
 1/V∞ = 1/Vt + kt
a T= 25°C 1/V∞ = 0,0723 + 0,0157t

donde
m=k=0,0157 min

.5 3 3.5 4 4.5
25.2

tiempo (min) volumen (ml) (V∞-Vt) (ml)

0 2.1 14.8 (V∞-Vt) vs t(mi
1 3.5 13.4
16
2 6.1 10.8
3 8.6 8.3
14
4 10.4 6.5
5 11.5 5.4 12
6 12 4.9
7 12.4 4.5 10

(V∞-Vt) (ml)
8 12.8 4.1
9 13.2 3.7 8
10 13.6 3.3
11 14.2 2.7 6
12 14.7 2.2
4
13 15.1 1.8
14 15.3 1.6
2
15 15.4 1.5
16 15.6 1.3
0
17 15.8 1.1 0 5 10 15
18 16 0.9
tiemp
19 16.1 0.8
20 16.2 0.7
21 16.3 0.6 y = -0.3626x + 8.5968
22 16.4 0.5
23 16.4 0.5
24 16.4 0.5
25 16.5 0.4
26 16.5 0.4
27 16.6 0.3
28 16.7 0.2
29 16.8 0.1
30 16.8 0.1
16.9
 (V∞-Vt) vs t(min) para 25°C

5 10 15 20 25 30 35

tiempo (min)
para 25
25.2 log V rxn log(V∞-Vt)
0.1461 1.17
0.4149 1.1271 y = 0.5379x - 0.2935 orden de rxn = 1
0.3979 1.0334
0.2552 0.919
0.0414 0.8129 log V rxn vs log(V∞-Vt) a 25°C
0.45
0.4
0.35
0.3

log V rxn
0.25
V rxn (V∞-Vt) 0.2
1,4 14,8 0.15
2,6 13,4
0.1
2,5 10,8
0.05
1,8 8,3
1,1 6,5 0
0.75 0.8 0.85 0.9 0.95 1 1.05 1.1 1
log(V∞-Vt)
rden de rxn = 1

vs log(V∞-Vt) a 25°C

5 1 1.05 1.1 1.15 1.2

V∞-Vt)
 1/(V∞-Vt) vs t (min) a 25°C
0.18
0.16
1/(V∞-Vt) t (min) 0.14 f(x) = 0.02184 x + 0.0581
0.0675 0 0.12
0.0746 1

1/(V∞-Vt)
0.1
0.0926 2 0.08
0.1204 3 0.06
0.1538 4 0.04
0.02
0
0 0.5 1 1.5 2 2.5 3 3.5 4 4.5
t (min)
n) a 25°C 1/V∞ = 1/Vt + kt
1/V∞ = 0,0851 + 0,0218t

donde
m=k=0,0218 min

2.5 3 3.5 4 4.5

34,1

tiempo (min) volumen (ml) (V∞-Vt) (ml)

0 0.3 15
0.5 2.8 12.5 (V∞-Vt) vs t (m
1 4.2 11.1
16
1.5 6.3 9
2 8.2 7.1 14
2.5 9.2 6.1
3 10.3 5 12
3.5 10.9 4.4
4 11.6 3.7 10

(V∞-Vt) (ml)
4.5 12.1 3.2
5 12.5 2.8 8
5.5 12.8 2.5
6 13.2 2.1 6
6.5 13.4 1.9
7 13.5 1.8 4
7.5 14.1 1.2
8 14.3 1 2
8.5 14.6 0.7
9 14.6 0.7 0
0 2 4 6 8
9.5 14.7 0.6
tiemp
10 14.8 0.5
10.5 14.9 0.4
11 14.9 0.4 y = -0.7092x + 8.4778
11.5 14.9 0.4
12 15 0.3
12.5 15.1 0.2
13 15.1 0.2
13.5 15.1 0.2
14 15.2 0.1
14.5 15.2 0.1
15 15.2 0.1
15.5 15.2 0.1
15.3
 (V∞-Vt) vs t (min) para 34°C

2 4 6 8 10 12 14 16 18

tiempo (min)

0.7092x + 8.4778
a 34,1
Vrxn (V∞-Vt)
5 15
2,8 12,5 y = 0.9021x - 0.3948
4,2 11,1
3,8 9
2 7,1 logVrxn vs log(V∞-Vt) a 34°C
0.8

0.7

logVrxn
0.6

0.5
logVrxn log(V∞-Vt)
0.6969 1.176 0.4
0.4471 1.097 0.3
0.6232 1.045
0.2
0.5797 0.9542
0.301 0.8512 0.1

0
0.8 0.85 0.9 0.95 1 1.05 1.1 1.15

log(V∞-Vt)
 orden de reaccion = 1

∞-Vt) a 34°C

1 1.05 1.1 1.15 1.2

-Vt)
log(V∞-Vt) tiempo (min)
1.176 0
1.097 0.5
1.045 1
0.9542 1.5
0.8512 2 log(V∞-Vt) vs tiempo (min)
1.4

1.2
f(x) = − 0.15848 x + 1.18316
1

log(V∞-Vt)
0.8

0.6

0.4

0.2

0
0 0.5 1 1.5 2 2
tiempo (min)
 log(V∞) = log(Vt) -kt
log(V∞ = 1,1832 -0,1585log(Vt)
(min) donde:
m = -k/2,303
-0,1585 = -k/2,303
k= 0,3650 min

1.5 2 2.5
34,2
tiempo (min) volumen (ml) (V∞-Vt) (ml) y = -0.5801x + 7.1085
0 1.5 12.6
0.5 2.8 11.3
1 5 9.1 (V∞-Vt) vs t(min) pa
1.5 6.8 7.3
14
2 8.3 5.8
2.5 9.2 4.9 12
3 10.1 4
3.5 11 3.1 10
4 11.2 2.9
4.5 11.3 2.8

(V∞-Vt) (ml)
8
5 11.7 2.4
5.5 11.9 2.2 6
6 12.2 1.9
6.5 12.3 1.8 4
7 12.6 1.5
2
7.5 12.6 1.5
8 12.8 1.3
0
8.5 13 1.1 0 2 4 6 8 1
9 13.1 1
tiempo (min)
9.5 13.2 0.9
10 13.4 0.7
10.5 13.4 0.7
11 13.5 0.6
11.5 13.7 0.4
12 13.7 0.4
12.5 13.7 0.4
13 13.9 0.2
13.5 13.9 0.2
14 13.9 0.2
14.5 13.9 0.2
15 14 0.1
15.5 14 0.1
14.1
0.5801x + 7.1085

(V∞-Vt) vs t(min) para 34°C

4 6 8 10 12 14 16 18

tiempo (min)
a 34,2

V rxn (V∞-Vt) y = 0.66x - 0.1561

2,6 12,6
4,4 11,3
3,6 9,1 LogVrxn vs log(V∞-Vt)
3 7,3
0.7
1,8 5,8

LogVrxn
0.6

0.5

0.4
LogVrxn log(V∞-Vt)
0.3
0.4149 1.1
0.6434 1.053 0.2
0.5563 0.959
0.4771 0.8633 0.1
0.2552 0.7634
0
0.7 0.75 0.8 0.85 0.9 0.95 1 1.05

log(V∞-Vt)
 orden de reacccion = 1

log(V∞-Vt)

.9 0.95 1 1.05 1.1 1.15

og(V∞-Vt)
log(V∞-Vt) t(min)
1.1 0
1.053 0.5
0.959 1
0.8633 1.5
0.7634 2 log(V∞-Vt) vs t(min)
1.2
f(x) = − 0.17258 x + 1.12032
1

0.8

log(V∞-Vt)
0.6

0.4

0.2

0
0 0.5 1 1.5 2 2.5
t(min)
min) log(V∞) = log(Vt) -kt
log(V∞ = 1,1203 -0,1726log(Vt)
donde:
m = -k/2,303
-0,1726 = -k/2,303
k= 0,3975 min

1.5 2 2.5