Sri Chaitanya IIT Academy., India.: Key Sheet

Sri Chaitanya IIT Academy 24-03-2020_Sr.
Icon All_GTM-14_Key & Sol's
Sri Chaitanya IIT Academy., India.

AP, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant
ICON Central Office , Madhapur – Hyderabad
Sec: Sr.Icon All GTM-15 Date: 24-03-2020
Time: 09.00am to 12.00 Max.Marks:300
Key Sheet
MATHEMATICS:
1 2 2 1 3 2 4 2 5 2
6 3 7 1 8 2 9 3 10 4
11 3 12 2 13 3 14 2 15 1
16 3 17 1 18 1 19 4 20 2
21 0002.67 22 0 23 4 24 34 25 8
PHYSICS:
26 3 27 1 28 1 29 3 30 3
31 3 32 1 33 1 34 3 35 2
36 2 37 4 38 4 39 3 40 1
41 1 42 2 43 1 44 1 45 1
46 188.4 47 250.00 48 0.45 49 1.05 50 4.00
CHEMISTRY
51 3 52 4 53 2 54 4 55 2
56 2 57 1 58 1 59 2 60 1
61 2 62 1 63 3 64 4 65 2
66 2 67 3 68 3 69 3 70 1
71 20.00 72 375.45 73 19.50 74 2.45 75 48.14
Sec: Sr.Icon All 1

Sri Chaitanya IIT Academy 24-03-2020_Sr.Icon All_GTM-14_Key & Sol's
SOLUTIONS:
MATHEMATICS
1. [SolutionStep1]:
Given equation is x 4  2πx  2019  0       1
[SolutionStep2]:
Since a, b, c, d are the roots of equation (1), then
Sum of the roots S1  a  b  c  d  0         2 
Product of the roots S4  abcd  2019        3

[SolutionStep3]:
Now from equation (1)
a  b  c  d ,
b  c  d  a
c  d  a  b
d  a  b  c
[SolutionStep4]:
 a  b  c  b  c  d  c  d  a  d  a  b 
Required Product      
 abc  bcd  cda  adb 
 d   a  b  c 
    
 abc  bcd  cda  abd 
1

2 fromequation  3 
 abcd 
1

2019
2. [SolutionStep1]:
5  9  13  ...upto n terms 17
Given that 
7 + 9 +11+....upto n +1 terms 16
n
 2.5   n  1 4  17
By the given condition 2 
n 1
 2.7   n  1  1 2  16
2
n 10  4n  4  17
 
n  1  14  2n  16
n  4n  6  17
 
 n  1 2n  14  16
Sec: Sr.Icon All 2
n  2n  3  17
 
 n  1 n  7  16
 32n2  48n  17n 2  136n  119
[SolutionStep2]:
 15n2  88n  119  0
 17 
  n  7 15n  17   0  n  7.  n   is not possible 
15 
3. [SolutionStep1]:
  2 3 12  
Given that sin 1 cot  sin 1  cos 1  sec 1 2  
  4 4 

2
Consider,
2 3

42 3

 3 1  
3 1
4 8 8 2 2
2 3 3 1 π
Now, sin 1  sin 1  15
4 2 2 12
12  3 π
Also cos 1  cos 1  
4  2  6
π
sec 1 2 
4
[SolutionStep2]:
  2 3 12  
1   1 1 1
 sin cot  sin  cos  sec 2 
   4 4 

 π π π
 sin 1 cot    
 12 6 4 
π
 sin 1 cot
2
 sin 1  0 
0
4. [SolutionStep1]:
2 2 2 2
Given circles are  x  3   y  2   49 and  x  2    y  1  4
Sec: Sr.Icon All 3

The given circles have centre at C1  2, 2  , C2  2,  1
and redii r1  7, r2  2
[SolutionStep2]:
2 2
Now C1C2   2  2    1  2 
 16  9  5  r1  r2
[SolutionStep3]:
given circles touch internally.
there is only one common tangent
5. [SolutionStep1]:
Passengers refusing to sit in the lower deck (resp. upper deck) will sit in the upper
deck (resp. lower deck)
 5 passengers will sit only in the lower deck and 8 passengers will sit in the upper
deck.
Remaining passengers  20 –  5  8   7
[SolutionStep2]:
Seats remaining in lower deck  7  5  2
number of ways of filling 2 seats in the lower deck  7 C2  21
[SolutionStep3]:
Corresponding to each choice, the remaining 5   7 – 2  passengers will sit in the
upper deck.
number of choice  21
6. [SolutionStep1]:
1
Since f  x  
1
1
x
x
 is not differentiable at x  0,  1
x 1
[SolutionStep2]:
1
also g  x  
2
1
f  x
1

2
1
x
x 1
Sec: Sr.Icon All 4
1

2  x  1
1
x
x

x  2  x  1
x 2
 is not differentiable at x  0,  1,
3x  2 3
 g  x  is not differentiable at 3 points
7. [SolutionStep1]:
2x  5
Let I   dx
2
7  6x  x
2x  6 1
 dx
2
7  6x  x
2 x  6 1
  dx   dx
2 2
7  6x  x 16   x  3
[SolutionStep2]:
x3
 2 7  6 x  x 2  sin 1
4
x3
 I  2 7  6 x  x 2  sin 1
4
x3
 A 7  6 x  x 2  B sin 1
4
 A  2, B  1
8. [SolutionStep1]:
| z |2  | z | 1
Since log 1  2
2 | z |
3
2
 1 
 log 1  
 3
3
[SolutionStep2]:
2
| z |2  | z | 1  1 
   [ log a x  log a y  x  y if 0  a  1]
2 | z |  3
[SolutionStep3]:
Sec: Sr.Icon All 5
| z |2  | z | 1
 3
2 | z |
[SolutionStep4]:
2
 z  z 1 6  3 z
2
 z 4 z 50
  z  5  z  1  0
But z  1  0
 z 50
 z 5
9. [SolutionStep1]:
G  Original signal green. A  A receive correct signal, B  B receive signal
correct. E is signal received by B is green.
 G  P G  E 
P  
E PE
[SolutionStep2]:
P  E   P  GAB   P  GAB   P  GAB   P  GAB 
4 3 3 4 1 1 1 3 1 1 1 3 46
 . .  . .  . .  . . 
5 4 4 5 4 4 5 4 4 5 4 4 80
40
P  G  E   P  GAB   P  GAB  
80
 G  P  G  E  20
P   
E PE 23
10. [Solutionstep1]:
Since f  x   x x
  x 2 , if x  0

 f ( x )    0, if x  0
 2
  x , if x  0
[Solutionstep2]:
The function f is differentiable everywhere and its derivative is given by
Sec: Sr.Icon All 6

2 x if x  0

f '( x )   0 if x  0
 2 x if x  0

[Solutionstep3]:
f '(0  h)  f '(0)
f "(0 )  lim
h 0 h
2h  0
 lim 2
h 0 h
[Solutionstep4]:
f (0  h)  f '(0)
f "(0  )  lim
h 0  h
2(  h)  0
 lim  2
h 0 h
Hence f is not twice diff. at x  0
But f "( x )  2 , if x0
 2, if x0
Thus, the set of points.Where f is twice differentiable is  ,    0 .
11. [SolutionStep1]:
The sum of all the co-efficients in an expansion is obtained by putting x  1 in the
expression.
n
1 
   2.1  6561
1 
 3n  38  n  8
[Solutionstep2]:
8 8 r
1  1 r
In   2 x  , Tr 1  8 Cr    2 x   8Cr x r 8 r 2r
x  x
This is constant if 2r – 8  0  r  4
 constant term  24.8 C4
dy
 xy  x  y  1
dx
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 x  y  1   y  1
  x  1 y  1
dy
  x 1
y 1
[Solutionstep2]:
Integration on both sides
dy
  dx
y 1 
x2
log  y  1   xC
2
 1,2,6
P
 2,3, 4A N parallel to  6,3, 4 
From the figure


Dr’s of AP   3, 1,10   x2  x1, y2  y1, z2  z1 
[SolutionStep2]:

AP  110

PN vector is perpendicular to the line
[SolutionStep3]:
 
AN  The projection of AP one the line  on  6,3, 4  

AP. 6,3, 4 

 6,3, 4 

 3, 1,10 . 6,3, 4 
 6,3, 4 
18  3  40
  61
61
From figure PN 2  AP 2  AN 2
 110  61  49
 PN  7
Sec: Sr.Icon All 8
π
sin x   cos x   1,0   
2
Since equality holds for x  2
If x  2 , both cos  and sin  increase (being + ve fraction).
 cos x   sin x   1 if x  2
Thus x  2 i.e. x   ,2 
  
2b   a  2 c
squaring both sides
   
4b 2  a 2  4c 2  4a.c

4  1  4  4a.c
 1
 a.c  
4
[SolutionStep2]:
2 2
a c  a 2c 2   a .c 
1 15
1 
16 16
18 18
2
Given that   xi  8  9 and   xi  8  45,
i 1 i 1
Let di  xi  8
2
1 1 
But  x2   d2   di2    di 
18  18 
2
1 9
  45   
18  18 
5 1 9
  
2 4 4
3
Standard deviation,  x 
2
Sec: Sr.Icon All 9

We have y 2  2 y  1  4( x  1)
 ( y  1)2  4( x  1)
 Equation of axis is y  1  0
[SolutionStep2]:
Also  2, 1 lies on the axis and it is exterior to the parabola.
12  4(2)  2(1)  3  1  8  5  4  0
Hence only one normal is possible.
sin x  sin 3 x
Given that f  x  
cos x  cos3 x
sin  π  x   sin  3  π  x  
Clearly f  π  x  
cos  π  x   cos  3  π  x  
 sin x  sin 3 x

 cos x  cos3 x
sin x  sin 3 x

cos x  cos3 x
 f  x
[SolutionStep2]:
sin  2π  x   sin  3  2π  x  
And f  2π  x  
cos  2π  x   cos  3  2π  x  
sin x  sin 3 x

cos x  cos3 x
 f  x
[SolutionStep3]:
 π,2π are periods of f  x 
 π is the fundamental period of f  x 
dy
Given that sin x  y cos x  4 x
dx
d
  y sin x   4 x
dx
Integration on both sides
[SolutionStep2]:
Sec: Sr.Icon All 10

 d  y sin x    4 xdx
x2
 y sin x  4  C
2
 y sin x  2 x 2  C
[SolutionStep3]:
π
Given y    0
2
π2
C
2
[SolutionStep4]:
π2
2
Thus y sin x  2 x 
2
 π  π2  π2
Now y  sin   2   
 6  36  2
 
2
1 π π2
 y   
 2  18 2
y 8π 2
 
2 18
8π 2
y 
9
1
Given that x  2cosec t
1
y  2sec t
[SolutionStep2]:
1 1 1 1
Now, xy  2sec t . 2cosec t 2cosec t sec t
π
xy  22
Differentiate with respect to ' x '
[SolutionStep3]:
dy
x  y.1  0
dx
Sec: Sr.Icon All 11
dy y
 
dx x
(NUMERICAL VALUE TYPE)

This section contains 5 questions. Each question is numerical value type. For each
question, enter the correct numerical value (in decimal notation, truncated/rounded-off
to second decimal place. (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30).
Marking scheme: +4 for correct answer, 0 if not attempted and 0 in all other cases.
y 4
y 1
x1 x4
for y [1,4),  y   1  y 2  4 x
for x  [1, 4),  x   1  x 2  4 y

[SolutionStep2]:
2 4
x2 
 
A   2 x  1 dx    2 x   dx
 4 
1 2
2 4
x2 
 
  2 x  1 dx    2 x  dx
 4 
1 2
3 2 3 4
   
 2 2   2 2 x3 
 2. x  x  2. x 
 3   3 12 
 1  2
4  4  4 64   4 8
  .2 2  2     1   .8     .2 2  
3  3  3 12   3 12 
8 1 8 8
 2 2  2
3 3 3 12
Sec: Sr.Icon All 12

16 2 7
  
3 3 3
18  7 11
   3.67 sq.units
3 3
 3 3 3 3 
Let A 1, 2  , B  2, 1 , C  ,  be the vertices of the triangle.
 2 2 
AB   2  12  1  2 2  2
2 2
3 3  3 3 
BC    2    1
 2   2 
2 2
 3 1  3 1
=    
 2   2 
8
  2
4
CA  2
ABC is equilateral.
[SolutionStep2]:
 orthocentre and circumcentre coincide with centroid.
 The distance between orthocentre and circumcentre is zero.
P  97sec,79tan
O T N
 97cos,0
x2 y2
Given hyperbola is  1
2 2
 97   79 
Let PT be the equation of the tangent at ' P ' cuts the transverse axis at 'T '
Sec: Sr.Icon All 13
[SolutionStep2]:
ON .OT  97sec .97cos  97 2
2
 ON .OT   97 
  
 2020   2020 
 9409 
   4.657   4
 2020 
Let a1, a2 , a3 ,........, a49 be in A.P
Let ' d ' be the common difference
[SolutionStep2]:
12
Given  a4k 1  416
k 0
 a1  a5  a9  ....  a49  416
Here n  13 , common difference D  4d
[SolutionStep3]:
n
 Sn  2a   n  1 D 
2
13
  2a1  12  4d    416
2
 a1  24d  32.................1
Given a9  a43  66
 a1  8d  a1  42d  66
 a1  25d  33.............. 2 
 2   1  d  1
From (1) , a1  8
[SolutionStep4]:
Let a12  a22  ....  a17
2
S
2
 82  92  .....   24   S  a17  a1  16d  8  16 1  24
2

 S  12  22  .....  7 2  82  92  ....   24   12  2 2  ....  7 2 
 24  25 49   7  815  2 n  n  1 2n  1 
   n  
6 6  6 
Sec: Sr.Icon All 14

1
  29400  840
6
 4760
 140  34 
 m  34
Given that MM T  I ; M 2  I
And M 1  adj  M   0  M 1   adjM
[SolutionStep2]:
M 1   adj M
1 3
   1 adj M
M
1 2
M
M
 M  1
[SolutionStep2]:
 
det PPT P 1  P PT P 1
1
 P P  P
P
Given P  2M  0
 P  2M
[SolutionStep3]:
3
P  2M   2  M   8  1  8  kA  k n A 
 
 det PP T P 1  8
Sec: Sr.Icon All 15

PHYSICS
T
B
T1 A
D
T2 C
Process AB and CD are isothermal

V 
W  nRT ln  f 
 Vi 
Dotted lines are isochoric lines as they pass through origin
V
 f is same for both process
Vi
V 
W A B  nRT1 ln  f 
 Vi 
V 
WC  D  nRT2 ln  f 
 Vi 
T
So, 1  2
T2
Given
Nuclear reaction
228
Th 224 Ra  
Atomic mass of 228 Th  mTh  228.02874 u
Atomic mass of 224 Ra  mRa  224.02024 u
Atomic mass of 4 He  m  4.00264 u
 Q   m in amu  931.5MeV
 Q   mTh  mRa  m in amu  931.5MeV
 Q   228.0287  224.0202  4.0026   931.5MeV

 Q  5.49 MeV
Sec: Sr.Icon All 16
Q m
y B
x
Given
Angular moment J  7.5  10 4 kg-m2 s
Magnetic field B  0.1T
Q
Specific charge  105 C kg
m
Angular momentum J  I 
angular momentum J
  =
mR 2 mR 2
Where mR 2 is the moment of inertia of the ring magnetic moment of loop
[Solutionstep2]:
 
Magnetic moment,   nIA
Q  Q 
 1    πR 2    R 2  nˆ
 2π  2 
( n̂ is normal to plane outward )
[Solutionstep3]:
  
Torque,     B
Q
 R 2 B (up the plane)
2
Q  J   1  Q 
 R2   B      J  B 
2  mR 2   2  m 
1
=  105  7.5  104  0.1  3.75  10 10 N upward along the plane
2
1 main scale division
Least count =
Number of Vernier scaledivisions
Sec: Sr.Icon All 17

1 main scale division
0.1mm=
20
1 Main scale division  2 mm
a a aa
Q P
Charge will induce over inner surface and outer surface. Due to shielding effect all
the effects due to charge kept inside and inner surface charge will be zero outside.
Now the induced charge on outer surface Q and already existing charge Q total
2Q distributes uniformly to maintain same potential as radius of curvature is
same everywhere.
[Solutionstep2]:
So the total charges are effectively equal to 2Q charge which is uniformly
distributed over conducting sphere of radius 3a .
The electric field due to this charged sphere at a distance 4a from centre
k (2Q) kQ
E 
2
(4a) 8a 2
According to Brewster’s law
The intensity of light as seen through the Polaroid shall go through a minimum but
not zero for two orientations of the Polaroid as transmitted light is partially
polarized.
Given
Mass of particle m  5kg
Potential energy U   7 x  24 y  J
Sec: Sr.Icon All 18

  U ˆ U
Conservative Force F  U    i ˆj 
 x y 
 
   7iˆ  24 ˆj  .

 F  7 2  242  25units
z0
z
T
dz
T  dT
From diagram
 Fz  0
(T  dT )   gdz  T  0
dT    gdz.........(i)
alsoT   v 2
dT  d  v 2  2vdvd 
As v is independent of z
dv  0
dT  v 2 d  ..... ii 
[Solutionstep2]:
From equation (1) and (2) we get
 z
du g
    dz
 v2 0
 g 
  z
2
   o e v 
Sec: Sr.Icon All 19


or   oe  g / v 2 z 
P2  3 j E1 
2k
2
2
P1  i
k 3
E2  3
 2
 
If we write the field due to dipole an the sum of fiend due to Px 1iˆ and Py  3 ˆj  ,
Total field E  E1iˆ  E2 ˆj
E  E12  E22
k
= 3  4
8
k
= 7
8
q 
C  2R
O i
2
Applying Kirchhoff’s voltage Law
q
Vo  2  2iR   vo
C
 q
i 
R 2 RC
[Solutionstep2]:
dq  q dq
Also, i    
dt R 2 RC dt
Sec: Sr.Icon All 20

dq
  dt
 q

R 2RC
Integrating both sides
q t
dq
    dt
 q 
C    0
 R 2 RC 
q
 q 
ln   
 R 2 RC  C
 t
 1 
 
 2 RC 
 2 C  q  t
 ln  
 C  2 RC
 q  2 C   Cet /2 RC

 q   C 2  e t /2 RC 
Due to shielding charges are adjusted as follows
P1 P2
3
 Q
2 Q
Q 2
2 3
Q
2
2Q d Q
 A
Capacitance C  0
d
2
1.5Q  2.25Q 2d
Energy stored U i  
2C 2C
9Q 2 d
 Ui   U outer charge
8 0 A
[Solutionstep2]:
After connecting
Sec: Sr.Icon All 21
U f  0  U outer charge
Q Q
2 2
O O
9Q 2d
Heat lost = U i  U f 
8 0 A
ig
i R
G
V
We know,
R  r Ig V
R = series resistance
r = galvanometer resistance
Now, 1680  r  I  20......1
 2930  r  I  30...... 2 
[Solutionstep2]:
2  1  3   2 
 2  2930  2r  3  1680  3r
 r  820 
[Solutionstep3]:
From equation (1),
20
 Ig   0.008  8mA
2500
Sec: Sr.Icon All 22

b

B
i1 c
a
 I
Magnetic field duo to current carrying wire at a distance x from the wire B  0
2πx
 I
Small amount of Magnetic flux associated with the strip d  BdA  0  adx 
2πx
 i
Magnetic flux linked with the square loop    0 adx  Mi
2πx
c b
 ia 1
 0  dx  Mi
2π x
c
c b
0
M  adx
2πx
c
 a  1 1
 M  0 ln   
2π  c  b c 
 a b  c 
 M  0 ln
2π c
When an object approaches a convergent length from the left of the lens with a
uniform speed of 5m s .The image moves away from the lens with a non- uniform
acceleration
The slope of x  t graph at t  0 is +ve i.e., initial velocity of the particle is +ve and
x  t graph is concave down, so it means acceleration is –ve but whether it is
constant or not it can’t be predicted from given information.
As v and acceleration are in opposite directions, the motion is the retarded one
and finally particle stops.
Sec: Sr.Icon All 23

R C2
^^^^
C1
E1 E2
In steady state, capacitor can be treated as open circuit:
Apply Kirchhoff’s voltage law to two loops
 E1  V1  0  V1  E1
 E2  V1  V2  0  V2  V1  E2
 E1  E2 .
[Solutionstep2]:
Charge on C1, Q1  V1C1  C1E1
Charge on C2 , Q2  C2V2  C2  E1  E2 
Let us assume that the spheres are moving with velocities v1 and v2 when they
are at a separation of d.
Then from momentum conservation, mv1  Mv2 .
[Solutionstep2]:
From energy conservation,
Change in kinetic energy = change in potential energy
 mv 2 Mv 2 
 1  2   0     GMm  0 
 2 2   d 

2gmM m2v12 M 2v2 2
  
d m M
2gmM M 2v2 2 M 2v22
  
d m M
2Gm 2
 v2 
d m  M 
Sec: Sr.Icon All 24

2GM 2
Similarly  v1 
d m  M 
2G  M  m 
 v1  v2  .
d
I 
Light
Given area of mirror  A

Mass= m
Intensity of light= I
From diagram,
T cos   mg........1
T sin  component would be balanced by force exerted on mirror by light.
2 IA
T sin  
c
2 IA
So, tan   for small angle tan    .
cmg
The force acting on the ball are buoyancy force and gravitational force.
Net force on the ball will be zero when
Buoyancy force FB  mg
 v xg  v o g
 v   xg  v o g
 
 x  o , i.e., mean position is at a depth of o from free surface.
 
But, it moves down from this mean position due to acquired speed.
Sec: Sr.Icon All 25

[Solutionstep2]:
o
When it is at a depth of  x from the free surface,

 
net force acting on ball is F  v    o  x  g  v o g  v xg .
 
[Towards mean position]
F  x so simple harmonic motion.
2
Velocity of ball becomes zero when x  0 from free surface,


i.e., amplitude of simple harmonic motion become o .

y 
For proper resolution,  1.22
D d
where y  1mm,   500 nm, d  3mm .
yd
D
1.22
1  103  3  103
D
1.22  500  10 9
D  4.92 m
 Dmax  4.92 m .
Given
Inductance L  1µH
Capacitance C  0.01µF
1
Angular frequency    107   2πf 
LC
107
f 
2π
[Solutionstep2]:
c f
Sec: Sr.Icon All 26

c
 f 
 
 c  3  108 m s 
3  108
  2π  60π
7
10
   60  3.14  188.4 m
Given
Inner diameter of ring r  40cm=0.4 m
Area of cross section A  1mm 2  106 m
Diameter R  40.05cm=0.4005m
 steel  105  C , Y  200GPa=200  109 Pa
Coefficient of linear expansion
R

Rt
[Solutionstep2]:

Tension T  YA  t  R  R '  R 
R
 YA
R
0.05
 200  109  106 
40
 250 N
Given
Volume of balloon V  0.09 m3
Depth h  40 m
Density  w  103 kg m3
Pressure P  1  105 N m2
Pressure of gas inside the balloon is same as the pressure of surrounding.
Also gas inside the balloon obeys isothermal process, then
 Po   gh V1  PoV2
Sec: Sr.Icon All 27
 103  10  40 
V2   1    0.09  0.45m3
 105 
 
For Li 2  ion, ground state energy is 13.6  9  122.4eV and on absorbing 91.8eV
energy electron transits from 1st energy level to 2nd energy level.
[Solutionstep2]:
So, increase in angular momentum,
L  L2  L1
2h h
 L  
2π 2π
h
 L 
2π
6.63  1034
 L 
2  3.14
L  1.05  1034 J-s.
  0.2
m
smooth vo  4 m s
M
Draw the free body diagram of block and platform.

As M  m , the acceleration of the platform,
 mg
a can be taken as zero and hence its velocity remains constant as 4 m s .
M
[Solutionstep2]:
Acceleration of the block is, ablock,ground   g  2m s 2 towards right.
Let velocity of block with respective to ground at time t be v (towards right), then
v  2t .
Solve the question with respective to platform frame of reference.

ablock,platform  2m s2 (towards right)
Sec: Sr.Icon All 28


vblock,platform   2t  4  m s (towards right)
Initial velocity of block with respective to platform is 4 m s towards left.
[Solutionstep3]:

Let s be the required distance, then v 2  u 2  2a.s
2
0   4   2  2  s
 s  4m
CHEMISTRY
Total pairs  p   n   n LP
 
NH 4 P  4  0  4 sp 3
PC 6 P  6  0  6 sp 3d 2 
2
 Ni  NH3    xx xx xx xx xx xx
 6
3 2
sp d
1)Basically, in the case of sodium and potassium the increase in shell size
outweighs the pull of the core on the outer shell electron and so potassium is less
dense than sodium. When we move from Na to K , effect of increase in volume is
more pronounced as compared to effect of increase in atomic mass.
[SolutionStep2]:
2) In addition, due to the presence of two valence electrons, atoms have stronger
metallic bonding. Hence, alkaline earth metals have more density and harder than
Sec: Sr.Icon All 29

alkali metals. Density generally increases from magnesium to radium while
calcium has the lowest density among the alkaline earth metals.
[SolutionStep2]:
3) Aluminium oxide is an amphoteric oxide because it reacts with acids as well as
bases and form salts and water.
NO 2  Oxidation state of nitrogen in NO2 x  4
HNO3  Oxidation state of nitrogen in HNO3 x  5
HNO3 can only act as oxidizing agent as N is its highest Oxidation state
HNO 2  Oxidation state  3
[SolutionStep2]:
SO 2  Oxidation state of sulphur in SO 2   4
White phosphorous is the most reactive due to angle strain.
The principle of froth flotation process is that sulphide ores are preferentially
wetted by the pine oil, whereas the gangue particles are wetted by the water. In
this process, a suspension of a powdered ore is made with water. In this process,
a suspension of a powdered ore is made with water.
In the case of post lanthanide elements like Hf , 4f subshell is filled and it is not
very effective at shielding the outer shell electrons. Therefore, Zr and Hf have
Sec: Sr.Icon All 30

almost similar atomic radii. (ii) The transition metals have their valence electrons
in  n - 1 d and ns orbitals.
Acidic medium : KMnO 4 oxidises KI to I 2
K 2Cr2O7  6KI  7H 2SO4  4k 2SO4  Cr SO4 3  7H2O  I2
[AllConcepts]: General class of compounds & ions in transition elements

Cis   Pt  en 2 C 2  shows optical isomer due to its non-superimposable mirror
image relationship.
en
en
C C
Pt
Pt
C
en C
en
2) Trans   Pt  en  2 C 2 
C
en Pt en
C
Trans-dichloro bis ethelene diammine (II) palatinate. It does not exhibits optical
isomerism, due to symmetry present.
3)  Pt  NH3 N  4 C 2 
Sec: Sr.Icon All 31

This compound exhibit geometrical isomerism due to presence of two types of
ligand whose  Pt  NH 3 4 C 2  arrangement around central metal atom.
NH3 C
H3N NH3 H3N NH3
Pt Pt
C NH3 H3N NH3

C C
Cisisomer Transisomer
4) Square planar complexes (Coordination number four) exhibit geometrical

isomerism.
 Pt  NH3 N  C 2 
 2 
H3N C
Pt
C NH3
Trans-isomer
H3N NH3
Pt
C C
Cis-isomer
Sec: Sr.Icon All 32

&
1) are resonating structures
O O
&
OH OH
2) are resonating structures
[SolutionStep2]:
OH
Pentan  1  O
Positional
isomers
OH
3) Pentan  3  O
OH
O
&
CH 2
4) H are tautomers
Nitrogen atom bears the positive charge . This decrease the electron density on
benzene. Hence, the electron density on benzene ring is maximum in aniline.
Hence aniline is the most reactive towards electrophilic aromatic subst. NH 2 is
better +R group than -OH group .
Sec: Sr.Icon All 33

CH  CH  HC  C Na  
1mol 3  CH I
NaNH 2
1mol  CH CH I
3 2 
HC  C  CH3  C  C  CH 3 
NaNH 2
2 H /Pd
CH3CH 2  C  C  CH 3 
BaSO 4 ,Quinoline
CH3
H3C H 2C
D
2
C C  Recemic mixture
Ni
H H
1) Molisch's test is a chemical test which is used to check for the presence of
carbohydrates in a given analyte
2) Biuret solution is used to identify the presence of protein. Biuret reagent is a
blue solution that, when it reacts with protein, will change color to pink-purple.
3) Glucose can be oxidized into gluconic acid, the tollens test may produce
positive results for easily reducing sugars, sucrose does not fall into the category
of reducing sugar due to the alpha and beta bonds holding the two ring structures
together; the sucrose cannot be reduced to a chain
Sec: Sr.Icon All 34

The glucose would react with tollens reagent positively and yield a silver mirror,
the glucose would not as it is a ketone.
4) The iodine test is used to test for the presence of starch
Phthalic acid reacts with ammonia to give ammonium salts which on further
heating at high temperature give phtalamide.
COOH COONH
4
+ NH3
COOH COONH
4
AmmoniumPhthalate 
-2H2O
CONH2
CONH2
Phthalamide
Strong
NH3
heating
O
C
NH
Phthalamide
Sec: Sr.Icon All 35

COOH O
COOH COOH
COOH COOH
Mist are produced by particles of spray liquids and by condensation of vapours in
air
1)LiAH
CH3  CH  4 CN  3 4 2 2
4  CH CH CH NH
2)H3O
CH3  CH 4  C  NH2
O
OH
NH3  CH3  CH2 4  C  CH3
CH 3
Heat lost by substance  heat gained by water
ms Cs 100  t f   m H O t f  25 C
 
2
Cs 100  t f 
 25  t f a
100
As CS increases t f increase
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At Boyle’s temperature, real gases behaves as ideal gases
At equilibrium
G  0, H  TS
Hence decrease in enthalpy compensating the decreases in entropy
πV  n1ST  n 2 1    ST
For non electrolyte For NaC
 x 
 4.92 x 1    0.05 1  1  x0.082x300
 200 
On solving, x = 20 g
72. [Question]:
[SolutionStep1]:
Molar conductivity 240 12
α= = =
Limiting molar conductivity 420 21
i  1 i  1 12 33
   i
n  1 2  1 21 21
[SolutionStep2]:
Tb  iK b m   33 / 21 0.52  3  2.45K
 Tb  Tb  Tb  373  2.45  375.45K
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 0.4 F  0.4  96,500C  Q  Q  0.4 F 
W  ZQ
W  Weight of metal deposited;
Z  Electro chemical equivalent
Q  Charge
E
W Q
96,500
195
W   0.4  96,500
4  96,500
 W  19.5g
KSP  S2  9  106
S  3  103 mol / L  3  103  136g / L  0.408g / L

Thus, for dissolving 0.408g of CaSO 4 , water required  1 L
1
For dissolving 1 g of CaSO 4 , water required  L  2.45L
0.408
8 1
 r H   H1   H 2
9 9
8 1
  r H   45.54   68.91
9 9
 r H  48.137kJ
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Sri Chaitanya IIT Academy., India.: Key Sheet

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Sri Chaitanya IIT Academy 24-03-2020_Sr.

Icon All_GTM-14_Key & Sol's

Sri Chaitanya IIT Academy., India.

Time: 09.00am to 12.00 Max.Marks:300

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Product of the roots S4  abcd  2019        3

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 2,3, 4A N parallel to  6,3, 4 

From the figure

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(NUMERICAL VALUE TYPE)

for x  [1, 4),  x   1  x 2  4 y

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Process AB and CD are isothermal

 Q   mTh  mRa  m in amu  931.5MeV

 Q   228.0287  224.0202  4.0026   931.5MeV

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Given area of mirror  A

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Draw the free body diagram of block and platform.

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HNO3  Oxidation state of nitrogen in HNO3 x  5

HNO 2  Oxidation state  3

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K 2Cr2O7  6KI  7H 2SO4  4k 2SO4  Cr SO4 3  7H2O  I2

[AllConcepts]: General class of compounds & ions in transition elements

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ligand whose  Pt  NH 3 4 C 2  arrangement around central metal atom.

C NH3 H3N NH3

4) Square planar complexes (Coordination number four) exhibit geometrical

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1) are resonating structures

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 Tb  Tb  Tb  373  2.45  375.45K

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S  3  103 mol / L  3  103  136g / L  0.408g / L

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