NAMA : ZALFA FATIN NABILA

KELAS : 2B TEKNIK KIMIA

NIM : 33118026
KODE MATA
KULIAH : 331P1730132
MATA KULIAH : TERMODINAMIKA

Dit:
Dik V :…?
T : 323 K Z :…?
P : 15 bar Dengan
B : -156.7 cm³/mol persamaan:
ω : 0.087 a.
R : 83.1447 cm³ bar/mol K Virial
Tc : 305.42 K b. Redlich
Pc : 48.283 bar Kwong
Tr : 1.057560081 c. Soave Redlich Kwong
V gas Ideal : 1790.38254 cm³/mol d. Peng
Robinson
Penyelesaian :

a. Persamaan Virial
RT
V= +B
P
83.1447 cm ³ ¯¿ mol K ×323 K
V=
15 ¯¿ +(−156.7)¿
V =1633.68254 cm ³/mol
PV
Z=
RT
15 ×
¯ 1633.68254 cm ³/mo l
Z=
83.1447 cm³ ¯¿ mol K ×323 K
Z=0.912476805
b. Persamaan Redlich Kwong
Tr−0.5 R2 Tc 2 .(83.1447 cm ³ ¯¿ mol K)2 (305.42 K )2
−0.5
1.057560081
a=0.42748 × a=0.42748 ×
Pc 48.283 ¯¿ ¿
a=5551791.1 cm⁶ ¯¿ mol ²
 RTc
b=0.08662
Pc
83.1447 cm ³ ¯¿ mol K ×305.42 K
b=0.08662
48.283 ¯¿ ¿

b=45.5570901 cm 3 /mol

Iterasi
RT a Vo−b
V= +b− ×
P P Vo (Vo+ b )
83.1447 cm ³ ¯¿ mol K ×323 K
V=
5551791.1cm ⁶ ¯¿ mol ²
15 ¯¿ +b− 3 3
¿
1790.38254 cm /mol−45.5570901 cm /mol
15 ¯¿ × ¿
1790.38254 cm3 / mol(1790.38254 cm3 /mol +45.5570901 cm3 /mol)

V =1619.96479937 cm3 /mol

Error
V −Vo
Error=
V
V Error
1790.38254  
PV
1639.47262992 0.0920478374 Z=
RT
1622.39167057 0.0105282588
1620.26970879 0.0013096349 15 ×
¯ 1619.96479937cm ³ /mol
Z=
1620.00315511 0.0001645390 83.1447 cm³ ¯¿ mol K ×323 K
1619.96962503 0.0000206980
1619.96540651 0.0000026041 Z=0.9048149003
1619.96487576 0.0000003276
1619.96480898 0.0000000412
1619.96480058 0.0000000052
1619.96479952 0.0000000007
1619.96479939 0.0000000001
1619.96479937 0.0000000000

c. Persamaan Soave Redlich Kwong

 R2 Tc2
a=0.42748 ×
Pc
a=0.42748 ׿ ¿ ¿
a=5709336.508 cm⁶ ¯¿ mol ²

RTc
b=0.08662
Pc
83.1447 cm ³ ¯¿ mol K ×305.42 K
b=0.08662
48.283 ¯¿ ¿

b=45.5570901 cm3 /mol

2
α =(1+ ( 0.48508+ ( 1.55171 ×ω 2 ) )− ( 0.15613× ω 2) × ( 1−Tr 0.5 ) )
2
α =(1+ ( 0.48508+ ( 1.55171 ×0.087 2) )−( 0.15613× 0.0872 ) × ( 1−1.0575600810.5 ))

α =0.96513069

Iterasi
RT aα Vo−b
V= +b− ×
P P Vo ( Vo+ b )
83.1447 cm ³ ¯¿ mol K ×323 K
V=
5709336.508 cm ⁶ ¯¿ mol ² ×0.96513069
15 ¯¿ +b− 3 3
¿
1790.38254 cm /mol−45.5570901 cm /mol
15 ¯¿ × ¿
1790.38254 cm3 / mol(1790.38254 cm3 /mol +45.5570901 cm3 /mol)
V =1621.7976015 cm 3 /mol
Error
V −Vo
Error=
V
V Error
1790.38254  
1640.9318970 0.091076688
1624.1558284 0.010329100
1622.0910722 0.001272898
1621.8341664 0.000158404 PV
Z=
1621.8021580 0.000019736 RT
1621.7981693 0.000002459
1621.7976723 0.000000306
1621.7976103 0.000000038
1621.7976026 0.000000005
1621.7976017 0.000000001
1621.7976015 0.000000000
 15 ×
¯ 1621.7976015 cm³ /mol
Z=
83.1447 cm³ ¯¿ mol K ×323 K
Z=0.905838593

d. Persamaan Peng Robinson

R2 Tc2
a=0.45724 ×
Pc
a=0.45724 × ¿ ¿¿
a=6106805.055 cm⁶ ¯¿ mol ²

RTc
b=0.778
Pc
83.1447 cm³ ¯¿ mol K ×305.42 K
b=0.778
48.283 ¯¿ ¿

b=40.91828226 cm3 /mol

2
α =(1+ ( 0.37464+ ( 1.54226 × ω ) ) −( 0.6299 ×ω 2) × ( 1−Tr 0.5 ) )
2
α =(1+ ( 0.37464+ ( 1.54226× 0.0872 ) ) −( 0.6299 × 0.0872 ) × ( 1−1.0575600810.5 ) )

α =0.9715 97396
Iterasi
RT aα Vo−b
V= +b− ×
P P Vo+ 2 ( b × Vo )−b 2
 83.1447 cm ³ ¯¿ mol K × 323 K
V=
6106805.055 cm ⁶ ¯¿ mol ² ×0.971597396
15 ¯¿ +b−
2065.8527170 cm3 /mol−40.91828226 cm3 /mol
15 ¯¿ ×
2065.8527170 cm3
+ 2(40.91828226 cm3 /mol ×2065.8527170 cm3 /mol)−(40.91828226 cm3 /
mol
V =1602.2820125 cm 3 /mol
Error
V −Vo
Error=
V
V Error PV
Z=
2065.8527170   RT
1650.7027047 0.25149896 15 ×
¯ 1602.2820125 cm³ /mol
1608.5192636 0.02622501 Z=
83.1447 cm³ ¯¿ mol K ×323 K
1603.1049525 0.00337739
1602.3909296 0.00044560 Z=0.894938359
1602.2964333 0.00005898
1602.2839215 0.00000781
1602.2822647 0.00000103
1602.2820454 0.00000014
1602.2820163 0.00000002
1602.2820125 0.00000000