OSHAD-SF - Occupational Standards and Guideline Values v3.0 English

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Abu Dhabi Occupational Safety and Health System

Framework

(OSHAD-SF)

Occupational Standards and Guideline Values

Version 3.0

July 2016
Table of Contents

1. Introduction ..................................................................................................................3
2. Derivation of Occupational Exposure Limits ................................................................. 4
2.1 Occupational Air Quality Threshold Limit Values ............................................... 4
2.2 Occupational Noise Standards .......................................................................... 4
3. Applicable Occupational Exposure Limits ..................................................................... 5
3.1 General Provisions............................................................................................ 5
3.2 Occupational Air Quality Threshold Limit Values ............................................... 5
3.3 Occupational Noise Standards .......................................................................... 5
4. References ...................................................................................................................7
5. Document Amendment Record .................................................................................... 8
Schedule A: Maximum Allowable Limits for Air Pollutants (Chemical Substances) in Working
Areas ............................................................................................................................9
Schedule B: Occupational Noise Exposure Limits .................................................................. 65

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1. Introduction
(a) This document has been developed by OSHAD to document the air quality Threshold Limit
Values (TLVs) and noise standards set for occupational exposure under the OSHAD-SF and
the derivation and sources of such TLVs and standards.

Important Note: OSH Standards and Guideline Values are currently non-mandatory requirements,
however are based on international and local best practice. Entities are encouraged to incorporate these
requirements to the extent possible, alongside other international and local standards.

At the discretion of OSHAD, the standards presented in this document or amendments thereafter, may
be submitted to the Executive Council of Abu Dhabi for approval as mandatory standards.

(b) The standards and threshold limit values addressed in this document for the OSHAD-SF
cover:

(i) occupational air quality in terms of chemical substances; and


(ii) occupational noise.
(c) Section 2 of this document defines the sources and derivation of the standards and
threshold limit values set under the OSHAD-SF.

(d) The occupational air threshold limit values and noise standards set under the OSHAD-SF
are documented in Section 3 of this document and in schedules attached to it.

(e) For guidance on interpretation and implementation of the TLVs and standards set under the
OSHAD-SF, reference shall be made to the following documents:

(i) OSHAD-SF – Glossary of Terms: for definitions of the terms used in the set standards;
and
(ii) OSHAD-SF – Technical Guideline – Occupational Air Quality Management - for
guidance on occupational air monitoring and assessment methodology.

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2. Derivation of Occupational Exposure Limits
2.1 Occupational Air Quality Threshold Limit Values

(a) Any exposure limits on occupational air quality will have to consider the maximum allowable
limits for chemical substances in working areas as stipulated in the Regulation concerning
Protection of Air from Pollution under Federal Law No. (24) of 1999. These limits were
adopted from the Threshold Limit Values (TLV) (Time Weighted Average (TWA) and Short-
Term Exposure Limit (STEL)) for Chemical Substances specified by The American
Conference of Governmental Industrial Hygienists (ACGIH).

(b) The limits stipulated in Schedule A of this document have incorporated the updated TLVs
and STELs specified by ACGIH (version of 2010) whenever the updated values are more
stringent than those stipulated in the existing federal Regulation. In the event that the TLV
and/or STEL stipulated in the existing Regulation are more stringent than those stipulated by
ACGIH, there was no amendment to the existing TLV and STEL (i.e. the most stringent
TLVs and STELs were adopted).

(c) At the discretion of OSHAD, values in Schedule A shall be similarly updated where required
to reflect future updates of TLVs and STELs by ACGIH. Updates shall come into force when
incorporated in a revised version of this document.

2.2 Occupational Noise Standards

(a) The occupational noise exposure levels recommended by the National Institute for
Occupational Safety and Health (NIOSH), USA were adopted as Occupational Exposure
Limits (OELs) with an ultimate objective to protect workers from hearing losses resulting
from occupational noise exposure. The OELs thus adopted are listed in Schedule B in the
form of exposure-duration tables, where OELs are given as the maximum duration of
exposure permitted for various noise levels. In addition, certain maximum levels for
occupational exposure are defined in Section 3.3.

(b) The OELs thus adopted are additional requirements to those enacted in Regulation
concerning Protection of Air from Pollution under Federal Law No. (24) of 1999 for the
Protection and Development of the Environment.

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3. Applicable Occupational Exposure Limits
3.1 General Provisions

(a) The standards and TLVs stipulated by this document shall be in addition to those stipulated
by the Federal Law No. (24) of 1999 and other applicable federal laws. In case of
discrepancy between the standards and TLVs stipulated by this document and those
federally set, whether existing or enacted in future, the more stringent stipulations shall
prevail.

(b) If, after exhausting all potential engineering and administrative control measures, employees
are still exposed to levels exceeding the occupational exposure limits stipulated by this
document, employers shall provide such employees with appropriate personal protective
equipment and enforce their use, and such employees shall use such equipment.

(c) Where justified by risk assessment or other information, employers shall provide
occupational exposure monitoring and health surveillance, protection and / or awareness
programs for workers exposed at or above the occupational exposure limits stipulated by
this document.

(d) OSHAD shall issue the codes of practice and technical guidelines required for implementing
provisions of this document.

(e) OSHAD shall monitor implementation of all standards related to the OSHAD-SF and put
forth appropriate recommendations.

3.2 Occupational Air Quality Threshold Limit Values

(a) The Threshold Limit Values (TLVs) stipulated in Schedule A shall be adopted as maximum
allowable limits for occupational exposure to air pollutants (chemical substances) in working
areas in the Emirate.

(b) TLVs are guidelines designed for making decisions regarding safe levels of exposure to
various chemical substances and physical agents found in the workplace. These guidelines
are one of multiple factors to be considered in evaluating specific workplace situations and
conditions.

(c) Except as stipulated in Clauses (a) to (b) above, all concerned shall pursue the provision of
acceptable indoor air quality, which is satisfactory to no less than 80% of the people
exposed, and in which there are no known contaminants at harmful concentrations as
determined by the authorities concerned.

3.3 Occupational Noise Standards

(a) The values stipulated in Schedule B shall be adopted as limits for occupational exposure to
noise in the Emirate. Exposures at and above these limits are considered hazardous.

(b) At no time shall occupational noise exposure exceed a sound pressure level of 140dB(A),
including all continuous, intermittent and impulse noises.

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(c) Where the worker is restricted to a space that serves as both workplace and sleeping
space, the ambient sound level in that sleeping space shall not exceed 70dB(A).

(d) Noise measurements for enforcing the standards thus defined shall be as described by
NIOSH (1998).

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4. References
• ACGIH (2010), TLVs and BEIs based on the Documentation of the Threshold Limit Values
for Chemical Substances and Physical Agents & Biological Exposure Indices, ACGIH

• NIOSH (1998), Occupational Noise Exposure Revised Criteria, Publication No. 98-126
(1998)

• UAE Federal Law No. (24) of 1999; and associated Regulations

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5. Document Amendment Record
Revision Page/s
Version Description of Amendment
Date Affected
Change of Logo All

Change from AD EHS Center to OSHAD Throughout

Change of document title: AD EHSMS RF to OSHAD-SF Throughout

EHS changes to OSH Throughout

1st July Clause 2.1(c) deleted 4


3.0
2016 Clause 3.2(c) deleted 5
Important note added under Clause 1(a) 3
Clause 2.1(c) updated 4

Clause 3.1(f) deleted 5


Clause 3.2 (c) deleted 5

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‫اﻟﺠﺪول )أ( اﻟﺤﺪود اﻟﻘﺼﻮى اﻟﻤﺴﻤﻮح ﺑﮭﺎ ﻟﻤﻠﻮﺛﺎت اﻟﮭﻮاء )اﻟﻤﻮاد اﻟﻜﯿﻤﺎوﯾﺔ( داﺧﻞ أﻣﺎﻛﻦ اﻟﻌﻤﻞ‬

Schedule A: Maximum Allowable Limits for Air


Pollutants (Chemical Substances) in Working Areas

‫ﻣﻼﺣﻈﺎت ﺣﻮل اﻟﺠﺪول )أ( وﺑﯿﺎن اﻻﺧﺘﺼﺎرات‬


Notes and Abbreviations for Schedule A

() Adopted values or notations enclosed are those for which changes are proposed in the
Notice of Intended Change (NIC).

A# Carcinogen: Substances for which no human or experimental animal carcinogenic data


have been reported are assigned no carcinogen designation.

Exposures to carcinogens must be kept to a minimum. Workers exposed to A1


carcinogens without a TLV® shall be properly equipped to eliminate to the fullest extent
reasonably practicable all exposure to the carcinogen. For A1 carcinogens with a
TLV® and for A2 and A3 carcinogens, worker exposure by all routes shall be carefully
controlled to levels as low as reasonably practicable below the TLV®.

A1 Confirmed Human Carcinogen: The agent is carcinogenic to humans based on the


weight of evidence from epidemiologic studies.

A2 Suspected Human Carcinogen: Human data are accepted as appropriate in quality but
are conflicting or insufficient to classify the agent as a confirmed human carcinogen;
OR, the agent is carcinogenic in experimental animals at dose(s), by route(s) of
exposure, at site(s), of histologic type(s), or by mechanism(s) considered relevant to
worker exposure. The A2 is used primarily when there is limited evidence of
carcinogenicity in humans and sufficient evidence of carcinogenicity in experimental
animals with relevance to humans.

A3 Confirmed Animal Carcinogen with Unknown Relevance to Humans: The agent is


carcinogenic in experimental animals at a relatively high dose, by route(s) of
administration, at site(s), of histologic type(s), or by mechanism(s) that may not be
relevant to worker exposure. Available epidemiologic studies do not confirm an
increased risk of cancer in exposed humans. Available evidence does not suggest that
the agent is likely to cause cancer in humans except under uncommon or unlikely

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routes or levels of exposure.

A4 Not Classifiable as a Human Carcinogen: Agents which cause concern that they could
be carcinogenic for humans but which cannot be assessed conclusively because of a
lack of data. In vitro or animal studies do not provide indications of carcinogenicity
which are sufficient to classify the agent into one of the other categories.

A5 Not Suspected as a Human Carcinogen: The agent is not suspected to be a human


carcinogen on the basis of properly conducted epidemiologic studies in humans.
These studies have sufficiently long follow-up, reliable exposure histories, sufficiently
high dose, and appropriate statistical power to conclude that exposure to the agent
does not convey a significant risk of cancer to humans; OR, the evidence suggesting a
lack of carcinogenicity in experimental animals is supported by mechanistic data.

C Ceiling limit; The concentration that shall not be exceeded during any part of the
working exposure.

(D) Simple asphyxiant: ”Inert” gas or vapor that displaces oxygen and acts as an
asphyxiant without other significant physiologic effects when present in high
concentrations in air.

(E) The value is for particulate matter containing no asbestos and <1% crystalline silica.

(F) Respirable fibers: length > 5µm; aspect ratio > 3:1, as determined by the membrane
filter method at 400-450 X magnification (4-mm objective), using phase-contrast
illumination.

(G) As measured by the vertical elutriator, cotton-dust sampler; see the TLV
Documentation of ACGIH (2010).

(H) Aerosol only.

(I) Measured as inhalable fraction of the aerosol.

(IFV) Measured as inhalable fraction and vapour.

(J) Does not include stearates of toxic metals.


3
(K) Shall not exceed 2 mg/m respirable particulate mass.

(L) Exposure by all routes shall be carefully controlled to levels as low as reasonably
practicable.

(M) Classification refers to sulfuric acid contained in strong inorganic acid mists.

(O) Sampled by method that does not collect vapour.

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(P) Application restricted to conditions in which there are negligible aerosol exposures.

(R) Measured as respirable fraction of the aerosol.

(T) Measured as thoracic fraction of the aerosol.

(V) Vapor and aerosol.

BEI ACHIH has recommended a Biological Exposure Index or Indices for this substance
®
BEIA: see BEI for Acetylcholinesterase Inhibiting Pesticides.
®
BEIM: see BEI for Methemoglobin Inducers.
®
BEIp: see BEI for Polycyclic Aromatic Hydrocarbons (PAHs).

MW Molecular weight.

NOS Not otherwise specified.

SEN TLV-confirmed potential for worker sensitization as a result of dermal contact and/or
inhalation exposure, based on the weight of scientific evidence.

Skin Danger of cutaneous adsorption.

STEL Short-term Exposure Limit. Usually a 15-minute time-weighted average (TWA)


exposure that shall not be exceeded at any time during a workday, even if the 8-hour
TWA is within the TLV-TWA.

TLV Threshold limit value.

TWA 8-hour, time-weighted average exposure concentration.

ppm Parts of vapour or gas per million parts of contaminated air by volume at NTP
o
conditions (25 C; 760 torr).
3
mg/m Milligrams of substance per cubic meter of air.

Source: ACGIH (2010), TLVs and BEIs based on the Documentation of the Threshold Limit Values for
Chemical Substances and Physical Agents & Biological Exposure Indices, ACGIH.

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Acetaldehyde - C 25 ppm
1 3 A3
75-07-0 - C 45 mg/m

Acetic acid 10 15 ppm


2 3 --
64-19-7 25 37 mg/m

Acetic anhydride 5 - ppm


3 3 --
108-24-7 21 - mg/m

Acetone 500 750 ppm


4 3 A4; BEI
67-64-1 1188 1782 mg/m
3
Acetone cyanohydrins C5 mg/m
5 Skin
75-86-5 (as CN)

Acetonitrile 20 60 ppm
6 3 Skin; A4
75-05-8 34 101 mg/m

Acetophenone 10 ppm
7 3
98-86-2 49 mg/m

2-(Acetylamino) fluorine - - ppm


8 3 A2
53-96-3 - - mg/m

Acetylene Simple
9 (D)
74-86-2 Asphyxiant

Acetylene tetra bromide 1 - ppm


10 3
79-2-6 14 - mg/m

Acetylsalicylic acid (Asprin) - - ppm


11 3 --
50-78-2 5 - mg/m

Acrolein - C 0.1 ppm


12 3 Skin; A4
107-02-8 - -C 0.23 mg/m

Acrylamide - - ppm
13 (IFV) 3 Skin; A3
79-06-1 0.03 - mg/m

Acrylic acid 2 - ppm


14 3 Skin; A4
79-10-7 5.9 - mg/m

Acrylonitrile 2 4 ppm
15 3 Skin; A3
107-13-1 4.3 9 mg/m

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Adipic acid - - ppm


16 3 --
124-04-9 5 - mg/m

Adiponitrile 2 - ppm
17 3 Skin
111-69-3 8.8 - mg/m

Alachlor - ppm
18 (IFV) 3 SEN; A3
15972-60-8 1 - mg/m

Aldrin - - ppm
19 (IFV) 3 Skin; A3
309-00-2 0.05 0.25 mg/m
Aliphatic hydrocarbon gases
- ppm
20 Alkane [C1-C4] (#76) 800 3 --
- mg/m

Allyl alcohol 0.5 4 ppm


21 3 Skin; A4
107-18-6 1.9 9.5 mg/m

Allyl chloride 1 2 ppm


22 3 A3
107-05-1 3 6 mg/m

Allyl glycidyl ether 1 10 ppm


23 3 A4
106-92-3 4.7 47 mg/m

Allyl propyl disulfide 0.5 3 ppm


24 3 SEN
2179-59-1 3 18 mg/m
Aluminum metal and
- - ppm
25 insoluble compounds (R) 3 A4
1 - mg/m
7429-90-5
Aluminum Oxide - - ppm
26 (R) 3 A4
1344-28-1 1 - mg/m

(L)
4-Aminodiphenyl - - ppm
27 (L) 3 Skin; A1
92-67-1 - - mg/m

2-Aminopyridine 0.5 - ppm


28 3 --
504-29-0 1.9 - mg/m

Amitrole - - ppm
29 3 A3
61-82-5 0.2 - mg/m

Ammonia 25 35 ppm
30 3 -
7664-41-7 17 24 mg/m

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Ammonium chloride fume - - ppm


31 3 -
12125-02-9 10 20 mg/m

Ammonium
- - ppm
32 perfluorooctanoate 3 Skin; A3
0.01 - mg/m
3825-26-1

Ammonium persulfate, as
- - ppm
33 S2O8 3
0.1 - mg/m
7727-54-0

Ammonium sulfamate - - ppm


34 3 -
7773-06-0 10 - mg/m

Amyl acetate
[Pentyl acetate], All isomers 50 100 ppm
35 3 -
628-63-7; 626-38-0; 123-92-2; 266 532 mg/m
625-16-1; 624-41-9; 620-11-1
Tert-Amyl methyl ether
20 - ppm
36 (TAME) 3
84 - mg/m
994-05-8
Aniline 2 - ppm
37 3 Skin; A3; BEI
62-53-3 7.6 - mg/m

p-Anisidine 0.1 - ppm


38 3 Skin; A4; BEIM
104-94-9 0.5 1.5 mg/m

o-Anisidine and its salts 0.1 - ppm


39 3 Skin; A3; BEIM
90-04-0 0.5 1.5 mg/m

Antimony [7440-36-0] and - - ppm


40 3 -
compounds, as Sb 0.5 - mg/m

Antimony hydride (Stibine) 0.1 - ppm


41 3
708-52-3 0.51 - mg/m

Antimony oxide - - ppm


42 3
1327-33-9 0.5 - mg/m

Antimony trioxide, as Sb - - ppm


43 3
1309-64-4 0.5 - mg/m
(L)
Antimony trioxide production - - ppm
44 (L) 3 A2
1309-64-4 - - mg/m

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

ANTU - - ppm
45 3 A4; Skin
86-88-4 0.3 - mg/m

Argon Simple - ppm


46 (D) 3
7440-37-1 Asphyxiant - mg/m
Arsenic and inorganic
compounds (except arsine),
- - ppm
47 as As (includes elemental, 3 A1; BEI
0.01 - mg/m
organic, and soluble)
7440-38-2
Arsenic acid and its salts, as
- - ppm
48 As 3 A1
0.01 - mg/m
7778-39-4
Arsenic Pentaoxide - ppm
49 3 A1
1303-38-2 0.01 - mg/m

Arsenic trioxide - ppm


50 3 A1
1327-53-3 0.01 - mg/m
Arsenous acid and its salts, as
- ppm
51 As 3 A1
0.01 - mg/m
13464-58-9
Arsine [arsenic hydride] 0.005 - ppm
52 3 -
7784-42-1 0.01 - mg/m

Asbestos, All forms - (F)


53 0.1 f/cc A1
1332-21-4 -
Asphalt (Bitumen) fume
- - ppm
54 [8052-42-4] as benzene- (I) 3 A4; BEIP
0.5 - mg/m
soluble aerosol
Atrazine - - ppm
55 3 A4
1912-24-9 5 - mg/m

Azinphos methyl - - ppm Skin; SEN; A4;


56 (IFV) 3
86-50-0 0.2 - mg/m BEIA

Barium [7440-39-3] and - - ppm


57 3 A4
soluble compounds, as Ba 0.5 - mg/m

Barium sulphate - - ppm


58 3 -
7727-43-7 10 - mg/m

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Benomyl - - ppm
59 (I) 3 A3; SEN
17804-35-2 1 - mg/m
(L)
Benz[a]anthracene - - ppm
60 (L) 3 A2; BEIP
56-55-3 - - mg/m

Benzene 0.5 2.5 ppm


61 3 Skin; A1; BEI
71-43-2 1.6 8 mg/m
(L)
Benzidine and Benzidine Salts - - ppm
62 (L) 3 Skin; A1
92-87-5 - - mg/m
(L)
- - ppm
63 Benzo[b]fluoranthene (L) 3 A2; BEIP
- - mg/m
(L)
Benzo[a]pyrene - - ppm
64 (L) 3 A2; BEIP
50-32-8 - - mg/m
Benzotrichloride (Benzyl
- C 0.5 ppm
65 trichloride) 3 A2
- C 2.8 mg/m
98-07-7

Benzoyl chloride - C 0.5 ppm


66 3 A4
98-88-4 - C 2.8 mg/m

Benzoyl peroxide - - ppm


67 3 A4
94-36-0 5 - mg/m

Benzyl acetate 10 - ppm


68 3 A4
140-11-4 61 - mg/m
-
Benzyl chloride 1 ppm
69 - 3 A3
100-44-7 5.2 mg/m

Beryllium [7440-41-7] and - - ppm


70 (I) 3 Skin; SEN; A1
compounds, as Be 0.00005 - mg/m

Biphenyl (Diphenyl) 0.2 - ppm


71 3
92-52-4 1.3 - mg/m

Bismuth telluride, Undoped,


- - ppm
72 as Bi2,Te3 3 A4
10 - mg/m
1304-82-1
Bismuth telluride, Se-doped,
- - ppm
73 as Bi2,Te3 3 A4
5 - mg/m
1304-82-1

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Borate compounds, inorganic


- -
74 1330-43-4; 1303-96-4; 10043- (I) (I) A4
2 6
35-3; 12179-04-3
Bis92-Chloroethyl) ether
5 10 ppm
75 [Dichloroethyl ether] 3 Skin; A4
29 58 mg/m
111-44-4
Bis (2-chloro ethyl hexel)
phthalate
- - ppm
76 [Di(2-ethylhexyl)phthalate 3 A3
5 - mg/m
(DEHP)]
117-81-7
Boron oxide - - ppm
77 3 --
1303-86-2 10 - mg/m

Boron tribromide - C1 ppm


78 3 -
10294-33-4 - C 10 mg/m

Boron trifluoride - C1 ppm


79 3 -
7637-07-2 - C 2.8 mg/m

Bromacil - - ppm
80 3 A3
314-40-9 10 - mg/m

Bromine 0.1 0.2 ppm


81 3 -
7726-95-6 0.66 1.3 mg/m

Bromine pentafluoride 0.1 - ppm


82 3 -
7789-30-2 0.72 - mg/m

Bromoform 0.5 - ppm


83 3 A3
75-25-2 5.2 - mg/m
Bromo methane
1 - ppm
84 [Methyl bromide] 3 Skin; A4
3.9 - mg/m
74-83-9
1-Bromopropane 10 - ppm
85 3
106-94-5 50 - mg/m
Bromotrifluoro methane
1000 - ppm
86 [Trifluorobromomethane] 3 -
6090 - mg/m
75-63-8
1,3- Butadiene 2 - ppm
87 3 A2
106-99-0 4.4 - mg/m

Butane, All isomers See Aliphatic hydrocarbon gases: Alkane


88 -
106-97-8; 75-28-5 [C1-C4]

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

n-Butanol [Butane-1-ol] 20 ppm


89 50152 3 -
71-36-3 61 mg/m
sec-Butanol
100 - ppm
90 [sec- Butane- 2- ol] 3 -
300 - mg/m
78-92-2
Tert- Butanol 100 - ppm
91 3 A4
75-65-0 303 - mg/m
2-Butanone
200 300 ppm
92 [Methyl ethyl ketone (MEK)] 3 BEI
590 885 mg/m
78-93-3
Butanone peroxide
- C 0.2 ppm
93 [Methyl ethyl ketone peroxide] 3 -
- C 1.5 mg/m
1338-23-4
Trans-2-Butenal 3
C 0.3 mg/m
94 [trans-Crotonaldehyde] 3 A3; Skin
C 0.86 mg/m
123-73-9
Butenes, all isomers
106-98-9; 107-01-7; 590-18-1; 250 - ppm A4
95 3
624-64-6; 25167-67-3; 574 - mg/m CAS 115-11-7 only
115-11-7
2-Butoxyethanol
20 - ppm
96 [1-Butoxy ethanol] 3 A3
97 - mg/m
111-76-2
2-Butoxyethyl acetate
20 - ppm
97 (EGBEA) 3 A3
130 - mg/m
112-07-2
n-Butyl acetate 150 200 ppm
98 3
123-86-4 713 950 mg/m

Sec-Butyl acetate 200 - ppm


99 3 -
105-46-4 950 - mg/m

Tert-Butyl acetate 200 - ppm


100 3 -
540-88-5 950 - mg/m

n-Butyl acrylate 2 - ppm


101 3 SEN; A4
141-32-2 11 - mg/m

n-Butylamine - C5 ppm
102 3 Skin
109-73-9 - C 15 mg/m

Butylated hydroxytoluene - - ppm


103 (IFV) 3 A4
128-37-0 2 - mg/m

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

tert-Butyl chromate, as CrO3 - - ppm


104 3 Skin
1189-85-1 - C 0.1 mg/m
Butyl-2,3-epoxy propyl ether
3 - ppm
105 [n-Butyl glycidyl ether (BGE)] 3 Skin; SEN
16 - mg/m
2426-08-6
n-Butyl lactate 5 - ppm
106 3
138-22-7 30 - mg/m

n-Butyl mercaptan 0.5 - ppm


107 3 -
109-75-5 1.8 - mg/m

o-sec-Butylphenol 5 - ppm
108 3
89-72-5 31 - mg/m

p-tert-Butyl toluene 1 - ppm


109 3 -
98-51-1 6.1 - mg/m
3
Cadmium [7440-43-9] and 0.01 - mg/m
110 (R) 3 A2; BEI
compounds, as Cd 0.002 - mg/m

3
Calcium arsenate - mg/m
111 3
7778-44-1 0.2 mg/m

Calcium chromate - - ppm


112 3 A2
13765-19-0, as Cr 0.001 - mg/m

Calcium cyanamide - - ppm


113 3 A4
156-62-7 0.5 - mg/m

Calcium cyanide, as CN - - ppm


114 3
592-01-8 - C5 mg/m

Calcium hydroxide - - ppm


115 3 -
1305-62-0 5 - mg/m

Calcium oxide - - ppm


116 3 -
1305-78-8 2 - mg/m
Calcium silicate,
- - ppm
117 synthetic nonfibrous (E) 3 A4
10 - mg/m
1344-95-2
Calcium sulfate (Gypsum)
- - ppm
118 [7778-18-9,10034-76-1; (I) 3 -
10 - mg/m
10101-41-4; 13397-24-5]

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Camphor (synthetic) 2 3 ppm


119 3 A4
76-22-2 12 19 mg/m

Caprolactam - - ppm
120 (IFV) 3 A5
105-60-2 5 - mg/m

Captafol - - ppm
121 3 Skin; A4
2425-06-1 0.1 - mg/m

Captan - - ppm
122 (I) 3 SEN; A3
133-06-2 5 - mg/m

Carbaryl - - ppm
123 (IFV) 3 Skin; A4; BEIA
63-25-2 0.5 - mg/m

Carbofuran - - ppm
124 (IFV) 3 A4; BEIA
1563-66-2 0.1 - mg/m

Carbon black - - ppm


124 3 A4
1333-86-4 3.5 - mg/m

Carbon dioxide 5000 30000 ppm


126 3 -
124-38-9 9000 54000 mg/m

Carbon disulfide 1 - ppm


127 3 Skin; A4; BEI
75-15-0 3.13 - mg/m

Carbon monoxide 25 - ppm


128 3 BEI
630-08-0 29 - mg/m

Carbon tetrabromide 0.1 0.3 ppm


129 3 -
558-13-4 1.4 4.1 mg/m

Carbon tetrachloride 5 10 ppm


130 3 Skin; A2
56-23-5 31 63 mg/m
Carbonyl chloride
0.1 - ppm
131 [Phosgene] 3 -
0.4 - mg/m
75-44-5
Carbonyl fluoride 2 5 ppm
132 3 -
353-50-4 5.4 13 mg/m

Catechol 5 - ppm
133 3 Skin; A3
120-80-9 23 - mg/m

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Cellulose - - ppm
134 3 -
9004-34-6 10 - mg/m

Cesium hydroxide - - ppm


135 3 -
21351-79-1 2 - mg/m

Chlordane - - ppm
136 3 Skin; A3
57-74-9 0.5 - mg/m

Chlorinated camphene - - ppm


137 3 Skin; A3
8001-35-2 0.5 1 mg/m

o-Chlorinated diphenyl oxide - - ppm


138 3 -
31242-93-0 0.5 - mg/m

Chlorine 0.5 1 ppm


139 3 A4
7782-50-5 1.5 2.9 mg/m

Chlorine dioxide 0.1 0.3 ppm


140 3 -
10049-04-4 0.28 0.83 mg/m

Chlorine trifluoride - C 0.1 ppm


141 3 -
7790-91-2 - C 0.38 mg/m

Chloroacetaldehyde - C1 ppm
142 3 -
107-20-0 - C 3.2 mg/m

Chloroacetone - C1 ppm
143 3 Skin
78-95-5 - C 3.8 mg/m

2-Chloroacetophenone 0.05 - ppm


144 3 A4
532-27-4 0.32 - mg/m

Chloroacetyl chloride 0.05 0.15 ppm


145 3 Skin
79-04-9 0.23 0.69 mg/m

Chlorobenzene 10 - ppm
146 3 A3; BEI
108-90-7 46 - mg/m

o-Chlorobenzylidene
- C 0.05 ppm
147 malononitrile 3 Skin; A4
- C 0.39 mg/m
2698-41-1
Chlorobromomethane
200 - ppm
148 (Bromochloromethane) 3
1060 - mg/m
74-97-5

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Chlorodifluoromethane 1000 - ppm


149 3 A4
75-45-6 3540 - mg/m

Chlorodiphenyl
- - ppm
150 (42% chlorine) 3 Skin
1 - mg/m
53469-21-9

Chlorodiphenyl
- - ppm
151 (54% chlorine) 3 Skin; A3
0.5 - mg/m
11097-69-1

2- Chloro ethanol
- C1 ppm
152 [Ethylene chlorohydrin] 3 Skin; A4
- C 3.3 mg/m
107-07-3

Chloroform 10 20 ppm
153 3 A3
67-66-3 49 100 mg/m
Chloro methane
50 100 ppm
154 [Methyl chloride] 3 Skin; A4
103 207 mg/m
74-87-3
(L)
Chloromethyl methyl ether - - ppm
155 (L) 3 A2
107-30-2 - - mg/m

1-Chloro -4- nitro benzene


0.1 - ppm
156 [p-Nitrochlorobenzene] 3 Skin; A3; BEIM
0.64 - mg/m
100-00-5

1-Chloro-1-nitropropane 2 - ppm
157 3 -
600-25-9 10 - mg/m

Chloropentafluorethane ppm
158 1000 6320 3
76-15-3 mg/m
Chloropicrin
0.1 - ppm
159 (Trichloronitromethane) 3 A4
0.67 - mg/m
76-06-2
1-Chloro-2-propanol 1 - ppm
160 3 A4
127-00-4 4 - mg/m

2-Chloro-1-propanol 1 - ppm
161 3 A4
78-89-7 4 - mg/m
β-Chloroprene
10 - ppm
162 (2-Chloro-1,3-butadiene) 3 Skin
36 - mg/m
126-99-8
2-chloro propionic acid 0.1 - ppm
163 3 Skin
598-78-7 0.44 - mg/m

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Allyl chloride
1 2 ppm
164 [3- chloro propene] 3 A3
3 6 mg/m
107-05-1
o-Chlorostyrene 50 75 ppm
165 3 -
2039-87-4 283 425 mg/m

o-Chlorotoluene 50 - ppm
166 3 -
95-49-8 259 - mg/m
α- Chloro toluene -
1 ppm
167 [Benzyl chloride] - 3 A3
5.2 mg/m
100-44-7
4- Chloro-o-toluidine 2 ppm
168 3
95-69-2 12 mg/m
2-Chloro-6- (trichloro methyl)-
pyridine - - ppm
169 3 A4
[Nitrapyrin] 10 20 mg/m
1929-82-4
Chlorpyrifos -
170 (IFV) Skin; A4; BEIA
2921-88-2 0.1

Chromates - - ppm
171 3 A1; BEI
.05 0.1 mg/m

Chromic Acid - - ppm


172 3 A1; BEI
7738-94-5 .05 .02 mg/m

Chromite - - ppm
173 3 A1
1308-31-2 .05 - mg/m
Chromite (processing
- - ppm
174 chromate) as Cr and 3 A1
0.05 - mg/m
(inorganic compounds)
Chromium III – Chromate - - ppm
175 3
24613-89-6 0.5 - mg/m A2
Chromium (III) inorganic
- - ppm
176 compounds, as Cr 3 A4
0.5 - mg/m
7440-47-3
Chromium VI – compounds
- ppm
177 (soluble forms) 3
0.05 mg/m A1
Chromium VI – compounds
- ppm
178 (insoluble) 3
0.01 mg/m A1

OSHAD-SF
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SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Chromium metal - - ppm


179 3 A4
7440-47-3 0.5 - mg/m

Chromyl chloride
0.025 - ppm
180 [Chromium oxychloride] 3 -
0.16 - mg/m
14977-61-8

Chromium trioxide - - ppm


181 3 A2
1333-82-0 0.05 - mg/m

(L)
Chrysene - - ppm
182 (L) 3 A3; BEIP
218-01-9 - - mg/m

Cl – direct – black- 38 - - ppm


183 3 A1
1937-37-7 0.01 - mg/m

Cl- pigment yello- 36


- - ppm
184 [zinc chromate] 3 C1
0.01 - mg/m
13530-65-9

Cirtral - - ppm
185 (IFV) 3 A4; Skin; SEN
5392-40-5 5 - mg/m

Clopidol - - ppm
186 3 A4
2971-90-6 10 - mg/m

- - ppm
187 Coal dust, (Anthracite) (R) 3 A4
.4 - mg/m

- - ppm
188 Coal dust, (Bituminous) (R) 3 A4
.9 - mg/m

Coal tar pitch volatiles


- - ppm
189 as benzene soluble aerosol 3 A1; BEIP
0.2 - mg/m
65996-93-2

Cobalt [7440-48-4] and - - ppm


190 3 A3, BEI
inorganic compounds, as Co 0.02 - mg/m

OSHAD-SF
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SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Cobalt carbonyl [10210-68-1], - - ppm


191 3 -
as Co 0.1 - mg/m

Cobalt hydrocarbonyl - - ppm


192 3 -
[16842-03-8], as Co 0.1 - mg/m

Copper, dusts and mists, as


- - ppm
193 Cu 3 -
1 - mg/m
7440-50-8
Copper [7440-50-8]
194 0.2 3
Fume - mg/m -

- - ppm
195 + Cotton dust, raw (T) 3 A4
0.1 0.6 mg/m

Coumaphos - - ppm
196 (IFV) 3 A4; Skin; BEIA
56-72-4 0.05 - mg/m
+ Cresol (all isomers)
- - ppm
197 [1319-77-3; 95-48-7; (IFV) 3 Skin; A4
20 - mg/m
108-39-4;106-44-5]
Crotonaldehyde - C 0.3 ppm
198 3 Skin; A3
4170-30-3 - C 0.86 mg/m

Crufomate - - ppm
199 3 A4; BEIA
299-86-5 5 - mg/m

Cumene 50 ppm
200 - 3 -
98-82-8 246 mg/m

Cyanamide 0.2 ppm


201 - 3 -
420-04-2 1 mg/m
2-Cyano acrylic acid methyl
ester 0.2 4 ppm
202 3 -
[Methyl 2-cyanoacrylate] 1 18 mg/m
137-05-3
Cyanogen 10 - ppm
203 3 -
460-19-5 21 - mg/m

Cyanogen chloride - C 0.3 ppm


204 3 -
506-77-4 - C 0.75 mg/m

Cyclohexane 100 - ppm


205 3 -
110-82-7 344 - mg/m

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Cyclohexanol 50 - ppm
206 3 Skin
108-93-0 206 - mg/m

Cyclohexanone 20 ppm
207 3 A3, Skin
108-94-1 50 - mg/m

Cyclohexene 300 - ppm


208 3 -
110-83-8 1010 - mg/m

Cyclohexylamine 10 - ppm
209 3 A4
108-91-8 41 - mg/m

Cyclonite - - ppm
210 3 Skin; A4
121-82-4 0.5 - mg/m

Cyclopentadiene 75 - ppm
211 3 -
542-92-7 203 - mg/m

Cyclopentane 600 - ppm


212 3 -
287-92-3 1720 - mg/m

Cyhexatin - - ppm
213 3 A4
13121-70-5 5 - mg/m
2,4-D (2,4-
- - ppm
214 Dichlorophenoxyacetic acid) 3 A4
10 - mg/m
94-75-7
D.D.T (Dichlorodiphenyl-
- - ppm
215 trichloroethane) 3 A3
1 - mg/m
50-29-3
Decaborane 0.05 0.15 ppm
216 3 Skin
17702-41-9 0.25 -0.75 mg/m

Demeton - - ppm
217 (IFV) 3 Skin, BEIA
8065-48-3 0.05 - mg/m

Demeton-S-Methyl - - ppm A4, Skin, SEN,


218 (IFV) 3
919-86-8 0.05 - mg/m BEIA

Diacetone alcohol 50 - ppm


219 3 -
123-42-2 238 - mg/m

4,4-Diacetyl benzidine - - ppm


220 3 A1
613-35-4 - - mg/m
4,4-Diamino diphenyl methane
0.1 - ppm
221 [4,4'-Methylene dianiline] 3 Skin; A3
0.81 - mg/m
101-77-9

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Diazinon - - ppm
222 (IFV) 3 A4, Skin, BEIA
333-41-5 0.01 - mg/m

Diazomethane 0.2 - ppm


223 3 A2
334-88-3 0.34 - mg/m

Diborane 0.1 - ppm


224 3 -
19287-45-7 0.11 - mg/m
1,2-Dibromo-3-chloropropane
0.001 - ppm
225 [BDCP] 3
0.01 - mg/m
96-12-8
2-N-Dibutylaminoethanol 0.5 - ppm
226 3 Skin, BEIA
102-81-8 3.5 - mg/m

Dibutyl phenyl phosphate 0.3 - ppm


227 3 Skin, BEIA
2528-36-1 3.5 - mg/m
(IFV)
Dibutyl phosphate 0.6 - ppm
228 (IFV) 3 Skin
107-66-4 5 - mg/m

Dibutyl phthalate - - ppm


229 3 -
84-74-2 5 - mg/m

Dichloroacetic acid 0.5 - ppm


230 3 A3, Skin
79-43-6 2.64 - mg/m

Dichloroacetylene - C 0.1 ppm


231 3 A3
7572-29-4 - C 0.39 mg/m

o-Dichlorobenzene 25 50 ppm
232 3 A4
95-50-1 150 301 mg/m

p-Dichlorobenzene 10 - ppm
233 3 A3
106-46-7 60 - mg/m

(L)
3,3’-Dichlorobenzidine - - ppm
234 (L) 3 Skin; A3
91-94-1 -0.1 - mg/m

1,4-Dichloro-2-butene 0.005 - ppm


235 3 Skin; A2
764-41-0 0.025 - mg/m

Dichlorodifluoromethane 1000 - ppm


236 3 A4
75-71-8 4950 - mg/m

OSHAD-SF
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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

1,3-Dichloro-5,5-dimethyl
- - ppm
237 hydantoin 3 -
0.2 0.4 mg/m
118-52-5
1,1-Dichloroethane 100 - ppm
238 3 A4
75-34-3 405 - mg/m
1,1-Dichloro ethylene
5 - ppm
239 [Vinylidene chloride] 3 A4
20 - mg/m
75-35-4
1-2-Dichloroethylene, all
200 - ppm
240 isomers [540-59-0; 156-59-2; 3 --
793 - mg/m
156-60-5]
Dichlorofluoromethane 10 - ppm
241 3 -
75-43-3 42 - mg/m

Dichloromethane 50 ppm
242 - 3 A3; BEI
75-09-2 174 mg/m
-
2,2-Dichloro -4,4-methylene
dianiline and salts
[4,4'-Methylene bis(2- 0.01 - ppm
243 3 Skin; A2; BEI
chloroaniline)] 0.11 - mg/m
[MBOCA; MOCA]
101-14-4
Dichlorofluoromethane (FC-
10 - ppm
244 21) 3 -
42 - mg/m
75-43-4
Dichloromethane (Methylene
50 - ppm
245 chloride) 3 A3; BEI
174 - mg/m
75-09-2
1,1-Dichloro-1-nitroethane 2 - ppm
246 3 -
594-72-9 12 - mg/m
1,2- /ducgkiri orioabe
10 - ppm
247 [Propylene dichloride] 3 SEN; A4
46 - mg/m
78-87-5
1,3-Dichloropropene 1 - ppm
248 3 Skin; A3
542-75-6 4.5 - mg/m
Ciz –(z)- 1,3- Dichloro
1 - ppm
249 propene 3
5 - mg/m
10061-01-5
trans –(z)- 1,3- Dichloro
1 - ppm
250 propene 3
5 - mg/m
10061-02-6
2,2-Dichloropropionic acid - - ppm
251 (I) 3 A4
75-99-0 5 - mg/m

OSHAD-SF
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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Dichlorvos (DDVP) - - ppm Skin; SEN; A4;


252 (IFV) 3
62-73-7 0.1 -- mg/m BEIA

Dicrotophos - - ppm
253 (IFV) 3 A4; Skin; BEIA
141-66-2 0.05 -- mg/m

Dicyclopentadiene 5 - ppm
254 3 -
77-73-6 27 - mg/m

Dicyclopentadienyl iron, as Fe - - ppm


255 3 -
102-54-5 10 - mg/m

+ Dieldrin - - ppm
256 (IFV) 3 Skin; A3
60-57-1 0.1 - mg/m

- ppm
257 Diesel (engine emissions) 3
0.15 - mg/m
Diesel fuel
[68334-30-5; 68476-30-2; 68476- - - ppm
258 31-3; 68476-34-6; 77650-28-3] (IFV) 3 Skin, A3
100 - mg/m
as total hydrocarbons
(IFV)
Diethanolamine 0.2 - ppm
259 (IFV) 3 Skin; A3
111-42-2 1 - mg/m

Diethylamine 5 15 ppm
260 3 Skin; A4
109-89-7 15 45 mg/m

2-Diethylaminoethanol 2 - ppm
261 3 Skin
100-37-8 9.6 - mg/m

Diethylene triamine 1 - ppm


262 3 Skin
111-40-0 4.2 - mg/m
Di(2-ethylhexyl)phthalate
- - ppm
263 (DEHP; Di-secoctyl phthalate) 3 A3
5 - mg/m
117-81-7
Diethyl ether
400 500 ppm
264 [Ethyl ether] 3 -
1220 1520 mg/m
60-29-7
Diethyl ketone 200 300 ppm
265 3 -
96-22-0 705 1057 mg/m

Diethyl phthalate - - ppm


266 3 A4
84-66-2 5 - mg/m

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Diethyl sulfate 0.03 - ppm


267 3 A2
64-67-5 0.2 - mg/m

Difluorodibromomethane 100 - ppm


268 3 -
75-61-6 858 - mg/m

Diglycidyl ether (DGE) 0.01 - ppm


269 3 A4
2238-07-05 0.05 - mg/m
1,4- Dihydrobenzene
- - ppm
270 [Hydroquinone] 3 SEN; A3
1 - mg/m
123-31-9
Diisobutyl ketone 25 - ppm
271 3 -
108-83-8 145 - mg/m
Diiso cyanato toluene
0.01 - ppm
272 (all isomers) 3 A3
0.08 - mg/m
26471-62-2
2,4- Diiso cyanatotuene
[Toluene-2, 4-diisocyanate] 0.005 C 0.02 ppm
273 3 SEN, Skin, A3
(TDI) 0.036 C 0.14 mg/m
584-84-9
2,6- Diiso cyanatotoluene
0.005 C 0.02 ppm
274 [Toluene-2, 6-diisocyanate] 3 SEN, Skin, A3
0.036 C 0.14 mg/m
91-08-7
Diiso propyl amine
5 - ppm
275 [Diisopropylamine] 3 Skin
21 - mg/m
108-18-9
Dimethyoxy methane
1000 - ppm
276 [Methylal] 3 -
3110 - mg/m
109-87-5
N,N-Dimethylacetamide 10 - ppm
277 3 Skin; A4; BEI
127-19-5 36 - mg/m

Dimethylamine 5 15 ppm
278 3 A4
124-40-3 9.2 27.6 mg/m
Dimethyl amino azo benzene
ppm
279 [4-Dimethylaminoazobenzene] 3 A1
mg/m
60-11-7
Dimethyl-1,2- dibromo 2,2- di
chloro ethyl phosphate] - - ppm Skin; SEN; A4;
280 (IFV) 3
[Naled] 0.1 - mg/m BEIA
300-76-5
Bis(2-Dimethylaminoethyl)
0.05 0.15 ppm
281 ether (DMAEE) 3
0.33 0.98 mg/m
3033-62-3

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Dimethylaniline
5 10 ppm
282 (N,N-Dimethylaniline) 3 A4; Skin; BEIM
25 50 mg/m
121-69-7
Dimethylcarbamoyl chloride 0.005 - ppm
283 3 A2; Skin;
79-44-7 0.02 - mg/m

Dimethyl disulfide 0.5 - ppm


284 3 Skin
624-92-0 2 - mg/m

Dimethylethoxysilane 0.5 1.5 ppm


285 3
14857-34-2 2.1 6.4 mg/m

Dimethylformamide 10 - ppm
286 3 Skin, A4; BEI
68-12-2 30 - mg/m

1,1-Dimethylhydrazine 0.01 - ppm


287 3 Skin; A3
57-14-7 0.025 - mg/m
Dimethyl nitroso amine (L)
- - ppm
288 [N-Nitrosodimethylamine] (L) 3 Skin; A3
- - mg/m
62-75-9
Dimethyl phthalate - - ppm
289 3 -
131-11-3 5 - mg/m

Dimethyl sulfate 0.01 ppm


290 3 Skin; A3
77-78-1 0.05 mg/m

Dimethyl sulfide 10 - ppm


291 3
75-18-3 25 - mg/m
Dinitolmide
- - ppm
292 [3,5-Dinitro-o-toluamide] 3 A4
1 - mg/m
148-01-6
Dinitrobenzene, All isomers
0.15 - ppm
293 528-29-0; 99-65-0; 3 Skin; BEIM
1 - mg/m
100-25-4; 25154-54-5
4,6-Dinitro-o-cresol - - ppm
294 3 Skin
534-52-1 0.2 - mg/m

Dinitrotoluene - - ppm
295 3 Skin; A3; BEIM
25321-14-6 0.15 - mg/m

1,4-Dioxane 20 90 ppm
296 3 Skin; A3
123-91-1 72 135 mg/m

Dioxathion - - ppm
297 (IFV) 3 Skin; A4; BEIA
78-34-2 0.1 - mg/m

OSHAD-SF
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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

1,3-Duixikabe 20
298
646-06-0 61

Diphenyl amine - - ppm


299 3 A4
122-39-4 10 - mg/m
Diphenyl methane di
isocyanate
0.005 - ppm
300 [Methylene bisphenyl 3 -
0.051 - mg/m
isocyanate (MDI)]
101-68-8
Dipropylene glycol methyl
ether
100 150 ppm
301 [(2-Methoxymethylethoxy) 3 Skin
606 909 mg/m
propanol (DPGME)]
34590-94-8
Dipropyl ketone 50 - ppm
302 3 -
123-19-3 233 - mg/m

Diquat 3
(I) - mg/m Skin; A4
303 [2764-72-9; 85-00-7; 0.5 3
(R) - mg/m
6385-62-2] 0.1
Di(2-ethylhexyl)phthalate
- - ppm
304 (DEHP) 3 A3
5 - mg/m
117-81-7
Disulfiram - - ppm
305 3 A4
97-77-8 2 - mg/m

Disulfoton - - ppm
306 (IFV) 3 Skin; A4; BEIA
298-04-4 0.05 - mg/m
2,6- Di- tert- butyl-p- cresol
[Butylated hydroxytoluene - - ppm
307 (IFV) 3 A4
(BHT)] 2 - mg/m
128-37-0
Diuron - - ppm
308 3 A4
330-54-1 10 - mg/m

Divinyl benzene 10 - ppm


309 3 -
1321-74-0 53 - mg/m

Dodecyl mercaptan 0.1 - ppm


310 3 SEN
112-55-0 0.8 - mg/m

Emery See Aliminum metal and ppm


311 3
1302-74-5 insoluble compounds (#20) mg/m

OSHAD-SF
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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

(IFV)
Endosulfan 0.006 - ppm
312 (IFV) 3 Skin; A4
115-29-7 0.1 - mg/m

Endrin - - ppm
313 3 Skin; A4
72-20-8 0.1 - mg/m

Enflurane 75 - ppm
314 3 A4
13838-16-9 566 - mg/m

EPN - - ppm
315 (I) 3 Skin; A4; BEIA
2104-64-5 0.1 - mg/m

Epichlorohydrin 0.5 - ppm


316 3 Skin; A3
106-89-8 1.9 - mg/m
1,2- Epoxy-4- epoxy ethyl
cyclohexane 0.1 20 ppm
317 3 Skin; A3
[Vinyl cyclohexene dioxide] 0.57 120 mg/m
106-87-6
Ethanol (Ethyl alcohol) - 1000 ppm
318 3 A3
64-17-5 - 1880 mg/m

Ethanolamine 3 6 ppm
319 3 -
141-43-5 7.5 15 mg/m

Ethion - - ppm
320 (IFV) 3 Skin; A4; BEIA
563-12-2 0.05 - mg/m

2-Ethoxyethanol (EGEE) 5 - ppm


321 3 Skin; BEI
110-80-5 18 - mg/m
2- Ethoxyethyl acetate
5 - ppm
322 (EGEEA) 3 Skin; BEI
27 - mg/m
111-15-9
Ethyl acetate 400 - ppm
323 3 -
141-78-6 1440 - mg/m

Ethyl acrylate 5 15 ppm


324 3 A4
140-88-5 20 61 mg/m

Ethylamine 5 15 ppm
325 3 Skin
75-04-7 9.2 27.6 mg/m

Ethyl amyl ketone 10 - ppm


326 3 -
541-85-5 52 - mg/m

OSHAD-SF
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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Ethyl benzene 100 125 ppm


327 3 A3; BEI
100-41-4 434 543 mg/m

Ethyl bromide 5 - ppm


328 3 Skin; A3
74-96-4 22 - mg/m

Ethyl tert-butyl ether (ETBE) 5 - ppm


329 3 -
637-92-3 21 - mg/m
Ethyl butyl ketone
50 75 ppm
330 [3- Heptanone] 3 -
234 350 mg/m
[106-35-4]
Ethyl chloride 100 - ppm
331 3 Skin; A3
75-00-3 264 - mg/m
Ethyl cyanoacrylate (Ethyl 2-
0.2 - ppm
332 cyanoacrylate) 3
1 - mg/m
7085-85-0
Ethylene 200 - ppm
333 3 A4
75-85-1 230 - mg/m
[Ethylene chlorohydrin
- C1 ppm
334 [2- Chloro ethanol] 3 Skin; A4
- C 3.3 mg/m
107-07-3
Ethylenediamine 10 - ppm
335 3 Skin; A4
107-15-3 25 - mg/m

Ethylene dibromide 20 30 ppm


336 3 Skin; A3
106-93-4 145 220 mg/m

Ethylene dichloride 10 - ppm


337 3 A4
107-06-2 40 - mg/m

Ethylene glycol - - ppm


338 (H) 3 A4
107-21-1 - C 100 mg/m
Ethylene glycol dinitrate
0.05 - ppm
339 (EGDN) 3 Skin
0.31 - mg/m
628-96-6
Ethylene glycol methyl ether
[2-Methoxyethyl acetate] 0.1 - ppm
340 3 Skin; BEI
(EGMEA) 0.5 - mg/m
110-49-6
Ethylene oxide (EtO) 1 - ppm
341 3 A2
75-21-8 1.8 - mg/m

OSHAD-SF
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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Ethyleneimine 0.05 0.1 ppm


342 3 Skin; A3
151-56-4 0.09 0.18 mg/m
Ethyl ether
400 500 ppm
343 [Diethyl ether] 3 -
1220 1520 mg/m
60-29-7
Ethyl formate 100 - ppm
344 3 -
109-94-4 303 - mg/m

2-Ethylhexanoic acid - - ppm


345 (IFV) 3 -
149-57-5 5 - mg/m

Ethylidene norbomene - C5 ppm


346 3 -
16219-75-3 - C 25 mg/m

Ethyl mercaptan 0.5 - ppm


347 3 -
75-08-1 1.3 - mg/m

N-Ethylmorpholine 5 - ppm
348 3 Skin
100-74-3 24 - mg/m

Ethyl silicate 10 - ppm


349 3 -
78-10-4 85 - mg/m

Fenamiphos - - ppm
350 (IFV) 3 Skin; A4; BEIA
22224-92-6 0.05 - mg/m

Fensulfothion - - ppm
351 (IFV) 3 Skin; A4; BEIA
115-90-2 0.01 - mg/m

Fenthion - - ppm
352 (IFV) 3 Skin; A4; BEIA
55-38-9 0.05 - mg/m

Ferbam - - ppm
353 (I) 3 A4
14484-64-1 5 - mg/m

Ferrovanadium dust - - ppm


354 3 -
12604-58-9 1 3 mg/m

- - ppm
355 Flour dust (IFV) 3 SEN
0.5 - mg/m

- - ppm
356 Fluorides, as F 3 A4; BEI
2.5 - mg/m

Fluorine 1 2 ppm
357 3 -
7782-41-4 1.6 3.1 mg/m

OSHAD-SF
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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Fonofos - - ppm
358 (IFV) 3 Skin; A4; BEIA
944-22-9 0.01 - mg/m

Formaldehyde - C 0.3 ppm


359 3 SEN; A2
50-00-0 - C 0.37 mg/m

Formamide 10 - ppm
360 3 Skin
75-12-7 18 - mg/m

Formic acid 5 10 ppm


361 3 -
64-18-6 9.4 19 mg/m

Furfural 2 - ppm
362 3 Skin; A3; BEI
98-01-1 7.9 - mg/m

Furfuryl alcohol 10 15 ppm


363 3 Skin
98-00-0 40 60 mg/m

Gallium arsenide - - ppm


364 (R) 3 A3
1303-00-0 0.0003 - mg/m

Gasoline 300 500 ppm


365 3 A3
86290-81-5 890 1480 mg/m

Germanium tetrahydride 0.2 - ppm


366 3 -
7782-65-2 0.63 - mg/m

Glutaraldehyde [111-30-8], - C 0.05 ppm


367 3 SEN; A4
activated and inactivated - C 0.2 mg/m

Glycerin mist - - ppm


368 3 -
56-81-5 10 - mg/m
Glycidol
2 - ppm
369 (2,3-Epoxy-1-propanol) 3 A3
6.1 - mg/m
556-52-5
Glyoxal - - ppm
370 (IFV) 3 SEN; A4
107-83-6 0.1 - mg/m

- - ppm
371 Grain dust (oat, wheat, barley) 3 -
4 - mg/m
Graphite (all forms except
graphite fibers) - - ppm
372 (R) 3 -
7782-42-5 2 - mg/m

Graphite, synthetic (all forms - - ppm


373 (R) 3 -
except graphite fibers) 2 - mg/m

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Hafnium [7440-58-6] and - - ppm


374 3 -
compounds, as Hf 0.5 - mg/m

Halothane 50 ppm
375 - 3 A4
151-67-7 404 mg/m
-
Helium (D)
376 Simple asphyxiant
7440-60-8

Heptachlor - - ppm
377 3 Skin; A3
76-44-8 0.05 - mg/m

Heptachlor epoxide - - ppm


378 3 Skin; A3
1024-57-3 0.05 - mg/m
Heptane (n-Heptane)
400 500 ppm
379 142-82-5 3 -
1640 2050 mg/m
2- Heptanone
50 - ppm
380 [Methyl n-amyl ketone] 3 -
233 - mg/m
110-43-0
3- Heptanone
50 75 ppm
381 [Ethyl butyl ketone] 3 -
234 350 mg/m
[106-35-4]

Hexachlorobenzene - - ppm
382 3 Skin; A3
118-74-1 0.002 - mg/m

Hexachlorobutadiene 0.02 - ppm


383 3 Skin; A3
87-68-3 0.21 - mg/m

Hexachlorocyclopentadiene 0.01 - ppm


384 3 A4
77-47-4 0.11 - mg/m

Hexachloroethane 1 - ppm
385 3 Skin; A3
67-72-1 9.7 - mg/m

Hexachloronaphthalenen - - ppm
386 3 Skin
1335-87-1 0.2 - mg/m

Hexafluoroacetone 0.1 - ppm


387 3 Skin
684-16-2 0.68 - mg/m

Hexafluoropropylene .01 - ppm


388 3 -
116-15-4 0.6 - mg/m

OSHAD-SF
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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Hexahydrophthalic anhydride,
all isomers - - ppm
389 (IFV) 3 SEN
85-42-7; 13149-00-3; 14166- - 0.005 mg/m
21-3
1,6-Hexamethylene
diisocyanate[Hexamethylene 0.005 - ppm
390 3 -
diisocyanate] 0.034 - mg/m
822-06-1
n-Hexane 50 - ppm
391 3 Skin; BEI
110-54-3 176 - mg/m
Hexane, other isomers
500 1000 ppm
392 107-83-5; 96-14-0; 75-83-2; 3 -
1760 3500 mg/m
79-29-8; 96-37-7
1,6-Hexanediamine 0.5 - ppm
393 3 -
124-09-4 2.3 - mg/m

1-Hexene 50 - ppm
394 3 -
592-41-6 295 - mg/m
2- Hexanone
5 10 ppm
395 [Methyl n-butyl ketone] 3 Skin; BEI
20 40 mg/m
591-78-6
Hexone
20 75 ppm
397 [Methyl isobutyl ketone] 3 (); BEI
82 307 mg/m
108-10-1
Sec-Hexyl acetate 50 - ppm
398 3 -
108-84-9 295 - mg/m

Hexylene glycol - C 25 ppm


399 3 -
107-41-5 - C 121 mg/m

Hydrazine 0.01 - ppm


400 3 Skin; A3
302-01-2 0.013 - mg/m

Hydrogen (D)
401 Simple asphyxiant
1333-74-0
Hydrogenated terphenyls
0.5 - ppm
402 (nonirradiated) 3 -
4.9 - mg/m
[61788-32-7]
Hydrogen bromide - C2 ppm
403 3 -
10035-10-6 - C 6.8 mg/m

Hydrogen chloride - C2 ppm


404 3 A4
7647-01-0 - C 2.98 mg/m

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

ppm
Hydrogen cyanide, as Cn - C 4.7 3
405 mg/m Skin
74-90-8 - C

Hydrogen fluoride 0.5 C2 ppm


406 3 Skin; BEI
7664-39-3 0.41 C 1.64 mg/m

Hydrogen peroxide 1 - ppm


407 3 A3
7722-84-1 1.4 - mg/m

Hydrogen selenide 0.05 - ppm


408 3 -
7783-07-5 as Se 0.16 - mg/m

+ Hydrogen sulfide 1 5 ppm


409 3 -
7783-06-4 1.4 7 mg/m

Hydroquinone - - ppm
410 3 SEN; A3
123-31-9 1 - mg/m

2-Hydroxypropyl acrylate 0.5 - ppm


411 3 Skin; SEN
999-61-1 2.8 - mg/m
2- Imidazolidine thione
- - ppm
412 [Ethylene thiourea] 3 A2
.02 - mg/m
96-45-7
Indene 5 - ppm
413 3 -
95-13-6 24 - mg/m
Indium
- - ppm
414 7440-74-6 and compounds, as 3 -
0.1 - mg/m
In
(IFV) (V)
Iodine 0.01 0.1 ppm A4
415 (IFV) 3
7553-56-2 0.01 1 mg/m

(IFV)
0.01 ppm A4
416 Iodides (IFV) 3
0.01 mg/m

Iodoform 0.6 - ppm


417 3 -
75-47-8 10 - mg/m

Iron oxide (Fe2O3) - - ppm


418 (R) 3 A4
1309-37-1 5 - mg/m

Iron pentacarbonyl 0.1 0.2 ppm


419 3 -
[13463-40-6], as Fe 0.23 0.45 mg/m

OSHAD-SF
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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Iso amyl acetate 100 - ppm


420 3 -
123-92-2 532 - mg/m

Isoamyl alcohol 100 125 ppm


420 3 -
123-51-3 361 452 mg/m

Isobutyl acetate 150 - ppm


421 3 -
110-19-0 713 - mg/m
(IFV)
Isobutyl nitrite - C1 ppm
422 (IFV) 3 A3; BEIM
542-56-3 - C 4.2 mg/m
Iso butyl alcohol
50 - ppm
423 [Isobutanol] 3 -
152 - mg/m
78-83-1
Isooctyl alcohol 50 - ppm
424 3 Skin
26952-21-6 266 - mg/m
Isopentyl acetate
50 100 ppm
425 (Isoamyl acetate) 3 -
266 532 mg/m
123-92-2
Isophorone - C5 ppm
426 3 A3
78-59-1 - C 28 mg/m

Isophorone diisocyanate 0.005 - ppm


427 3 -
4098-71-9 0.045 - mg/m

Isopropyl acetate 100 200 ppm


428 3 -
108-21-4 418 836 mg/m

2-Isopropoxyethanol 25 - ppm
429 3 Skin
109-59-1 106 - mg/m
Iso propyl alcohol
200 400 ppm
430 [2-Propanol] 3 A4; BEI
492 984 mg/m
67-63-0
Isopropylamine 5 10 ppm
431 3 -
75-31-0 12 24 mg/m

N-Isopropylaniline 2 - ppm
432 3 Skin; BEIM
768-52-5 11 - mg/m

Isopropyl ether 250 310 ppm


433 3 -
108-20-3 1040 1300 mg/m

Isopropyl glycidyl ether (GE) 50 75 ppm


434 3 -
4016-14-2 238 356 mg/m

OSHAD-SF
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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Kaolin - ppm
435 (E,R) 3 A4
1332-58-7 2 - mg/m
Kerosene/Jet fuels as total
- - ppm
436 hydrocarbon vapor (P) 3 Skin, A3
200 - mg/m
8008-20-6; 64742-81-0
Ketene 0.5 1.5 ppm
437 3 -
463-51-4 0.86 2.6 mg/m

Lead [7439-92-1] and - - ppm


438 3 A3; BEI
inorganic compounds, as Pb 0.05 - mg/m

Lead arsenate - - ppm


439 3 A3
3687-31-8 0.15 - mg/m

Lead chromate (as Pb) - ppm


440 3 A2; BEI
[7758-97-6] 0.05 -- mg/m

Lead chromate (as Cr) - - ppm


441 3 A2
[7758-97-6] 0.012 - mg/m

Tetraethyl lead [78-00-2], as - - ppm


442 3 Skin; A4
Pb 0.1 - mg/m

Tetramethyl lead - - ppm


443 3 Skin
75-74-1, as Pb 0.15 - mg/m

Lindane - - ppm
444 3 Skin; A3
58-89-9 0.5 - mg/m

Lithium hydride - - ppm


445 3 -
7580-67-8 0.025 - mg/m
L.P.G
1000 - ppm
446 (liquefied petroleum gas) 3 -
1800 - mg/m
68476-85-7
-
Magnesite - ppm
447 - 3
546-93-0 10 mg/m

Magnesium oxide - - ppm


448 (I) 3 A4
1309-48-4 10 - mg/m

Malathion - ppm
449 (IFV) -- 3 Skin; A4; BEIA
121-75-5 1 mg/m

OSHAD-SF
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Standards and Guideline Values – Version 3.0 – 1 July 2016 Page 41 of 67
‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

+ Maleic anhydride 0.1 - ppm


450 3 SEN; A4
108-31-6 0.4 - mg/m

+ Manganese [7439-96-5] and - - ppm


451 3 (-)
inorganic compounds, as Mn 0.2 - mg/m
Manganese cyclopentadienyl
- - ppm
452 tricarbonyl [12079-65-1 ], as 3 Skin
0.1 - mg/m
Mn
Mercury [7439-97-6], as Hg - - ppm
453 3 Skin; A4; BEI
Elemental and inorganic forms 0.025 - mg/m

Mercury [7439-97-6], as Hg - - ppm


454 3 Skin
Alkyls compounds 0.01 0.03 mg/m

Mercury [7439-97-6], as Hg - - ppm


455 3 Skin
Aryl compounds 0.1 - mg/m

Mesityl oxide 15 25 ppm


456 3 -
141-79-7 60 100 mg/m

Methacrylic acid 20 - ppm


457 3 -
79-41-4 70 - mg/m

Methanol 200 250 ppm


458 3 Skin; BEI
67-56-1 262 328 mg/m

Methomyl - - ppm
459 3 A4; BEIA
16752-77-5 2.5 - mg/m
2- Methoxy aniline
0.1 - ppm
460 [o-Anisidine] 3 Skin, A3; BEIM
0.5 1.5 mg/m
90-04-0
2-Methoxy chloride
- - ppm
461 [Methoxychlo] 3 A4
10 - mg/m
72-43-5
2-Methoxyethanol 0.1 - ppm
462 3 Skin; BEI
109-86-4 0.3 - mg/m
[2-Methoxyethyl acetate
(EGMEA) [Ethylene glycol 0.1 - ppm
463 3 Skin; BEI
methyl ether] 0.5 - mg/m
110-49-6
(2-Methoxymethylethoxy)
propanol (DPGME)
100 150 ppm
464 [Dipropylene glycol methyl 3 Skin
606 909 mg/m
ether]
34590-94-8

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

1-Methoxy-2-propanol
(PGME) [Propylene glycol 100 150 ppm
465 3 -
mono methyl ether] 369 553 mg/m
107-98-2
Methyl acetate 200 250 ppm
466 3 -
79-20-9 606 757 mg/m

Methyl acetylene 1000 - ppm


467 3 -
74-99-7 1640 - mg/m
Methyl acetylene-propadiene
1000 1250 ppm
468 mixture (MAPP) 3 -
1640 2050 mg/m

Methyl acrylate 2 - ppm


469 3 Skin; SEN; A4
96-33-3 7 - mg/m

1 - ppm
470 Methylacrylonitrile 3 Skin
2.7 - mg/m
Methylal
1000 - ppm
471 [Dimethyoxy methane] 3 -
3110 - mg/m
109-87-5
Methylamine 5 15 ppm
472 3 -
74-89-5 6.4 19 mg/m
Methyl n-amyl ketone
50 - ppm
473 [2- Heptanone] 3 -
233 - mg/m
110-43-0
N-Methyl aniline 0.5 - ppm
474 3 Skin; BEIM
100-61-8 2.2 - mg/m
Methyl bromide
1 - ppm
475 [Bromo methane] 3 Skin; A4
3.9 - mg/m
74-83-9
Methyl tert-butyl ether 40 - ppm
476 3 A3
1634-04-4 145 - mg/m
Methyl n-butyl ketone
5 10 ppm
477 [2- Hexanone] 3 Skin; BEI
20 40 mg/m
591-78-6
Methyl chloride 50 100 ppm
478 3 Skin; A4
74-87-3 103 207 mg/m

Methyl chloroform 350 450 ppm


479 3 A4; BEI
71-55-6 1910 2460 mg/m

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Standards and Guideline Values – Version 3.0 – 1 July 2016 Page 43 of 67
‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Methyl 2-cyanoacrylate
[2-Cyano acrylic acid methyl 0.2 4 ppm
480 3 -
ester] 1 18 mg/m
137-05-3
Methylcyclohexane 400 - ppm
481 3 -
108-87-2 1610 - mg/m

Methylcyclohexanol 50 - ppm
482 3 -
25639-42-3 234 - mg/m

o-Methylcyclohexanone 50 75 ppm
483 3 Skin
583-60-8 229 344 mg/m
2-Methylcyclopentadienyl
- - ppm
484 manganese tricarbonyl, as Mn 3 Skin
.02 - mg/m
12108-13-3
Methyl demeton - - ppm
485 (IFV) 3 Skin; BEIA
8022-00-2 0.05 - mg/m
Methylene bisphenyl
isocyanate (MDI)
0.005 - ppm
486 [Diphenyl methane di 3 -
0.051 - mg/m
isocyanate]
101-68-8
4,4'-Methylene bis(2-
chloroaniline) [MBOCA]
0.01 - ppm
487 [2,2-Dichloro -4,4-methylene 3 Skin; A2; BEI
0.11 - mg/m
dianiline and salts]
101-14-4
4,4'-Methylene dianiline
[4,4-Diamino diphenyl 0.1 - ppm
488 3 Skin; A3
methane] 0.81 - mg/m
101-77-9
Methyl ethyl ketone (MEK)
200 300 ppm
489 [2-Butanone] 3 BEI
590 885 mg/m
78-93-3
Methyl ethyl ketone peroxide
- C 0.2 ppm
490 [Butanone peroxide] 3 -
- C 1.5 mg/m
1338-23-4
Methyl formate (formic acid
100 150 ppm
491 methyl ester) 3 -
246 368 mg/m
107-31-3
Methyl hydrazine 0.01 - ppm
492 3 Skin; A3
60-34-4 0.019 - mg/m

Methyl iodide 2 - ppm


493 3 Skin
74-88-4 12 - mg/m

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Methyl isoamyl ketone 50 - ppm


494 3 -
110-12-3 234 - mg/m

Methyl isobutyl carbinol 25 40 ppm


495 3 Skin
108-11-2 104 167 mg/m
Methyl isobutyl ketone
20 75 ppm
496 [Hexone] 3 A3; BEI
82 307 mg/m
108-10-1
Methyl isocyanate 0.02 - ppm
497 3 Skin
624-83-9 0.047 - mg/m
Methyl isopropyl ketone
200 - ppm
498 (KIIPK) 3 -
705 - mg/m
563-80-4
Methyl mercaptan 0.5 - ppm
499 3 -
74-93-1 0.98 - mg/m

Methyl methacrylate 50 100 ppm


500 3 SEN; A4
80-62-6 205 410 mg/m

1-Methyl naphthalene 0.5 - ppm


501 3 Skin
90-12-0 3 - mg/m

1-Methyl naphthalene 0.5 - ppm


502 3 Skin
91-12-0 3 - mg/m

Methyl parathion - - ppm


503 (IFV) 3 Skin; A4; BEIA
298-00-0 0.02 - mg/m
Methyl propyl ketone
- 150 ppm
504 [2-Pentanone] 3 -
- 529 mg/m
107-87-9
Methyl silicate 1 - ppm
505 3 -
681-84-5 6 - mg/m

α-Methyl styrene 10 - ppm


506 3 A3
98-83-9 48 - mg/m
Methyl vinyl ketone -
C 0.2 ppm
507 (3-Buten-2-one) - 3 Skin; SEN
C 0.6 mg/m
78-94-4
Metribuzin - - ppm
508 3 -
21087-64-9 5 - mg/m

Mevinphos - - ppm
509 (IVF) 3 Skin; A4; BEIA
(Phosdrin®) 0.01 - mg/m

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Mica - - ppm
510 (R) 3 -
12001-26-2 3 - mg/m

Mineral oil, highly and - - ppm


511 (I) 3 A4
severely refined 5 - mg/m

- - ppm
512 Mineral oil, pure (I) 3 A4
5 - mg/m

(I)
Molybdenum [7439-98-7] and 10
513 (R) 3 -
insoluble compounds, as Mo 3 - mg/m
3
- mg/m

Molybdenum [7439-98-7] (R)


514 0.5 A3
soluble compounds, as Mo 3
- mg/m
(IVF) 3
Monochloroacetic acid 0.5 - mg/m
515 (IVF) 3 Skin; A4
79-11-8 2 - mg/m

Monocrotophos - - ppm
516 (IFV) 3 Skin; A4; BEIA
6923-22-4 0.05 - mg/m

Morpholine 20 - ppm
517 3 Skin; A4
110-91-8 71 - mg/m
Naled [Dimethyl-1,2- dibromo
- - ppm Skin; SEN; A4;
518 2,2- di chloro ethyl phosphate] (IFV) 3
0.1 - mg/m BEIA
300-76-5
Naphtha (coal tar) - - ppm
519 3
8030-30-6 400 - mg/m

Naphthalene 10 15 ppm
520 3 Skin; A4
91-20-3 52 79 mg/m
1-Naphthyl amine (L)
- - ppm
521 [α-Napthylamine] (L) 3 A1
- - mg/m
134-32-7
(L)
β-Naphthylamine - - ppm
522 (L) 3 A1
91-59-8 - - mg/m
Natural rubber latex, as
Inhalable allergenic proteins - - ppm
523 (I) 3 Skin; SEN
(Natsyn®) 9006-04-6; 0.0001 - mg/m
9003-31-0
Neon (D)
524 Simple asphyxiant
7440-01-9

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL
(I) 3
525 Nickel Elemental [7440-02-0] 1.5 - mg/m A5
Nickel Insoluble inorganic (I)
0.2 3
526 compounds (NOS) - mg/m A1
7440-02-0
Nickel Soluble inorganic
(I) 3
527 compounds (NOS) 0.1 - mg/m A4
7440-02-0
Nickel (formed in nickel) -
- ppm
528 oreroasting process - 3
0.5 mg/m
7440-02-0
-
Nickel carbonate - ppm
529 - 3
3333-67-3 0.1 mg/m

Nickel carbonyl, as Ni 0.05 - ppm


530 3 -
13463-39-3 0.12 - mg/m

Nickel chloride, as Ni - - ppm


531 (I) 3 A4
7718-54-9 0.1 - mg/m

Nickel chromium phosphate - - ppm


532 3 A3
13977-71-4 0.005 - mg/m

Nickel mono oxide - - ppm


533 3 A1
1313-99-1 0.1 - mg/m

Nickel –III- oxide - - ppm


534 3 A3
1314-06-3 0.1 - mg/m

Nickel subsulfide (I) 3


535 0.01 - mg/m A1
12035-72-2
Nickel sulphide roasting (dust
- - ppm
536 and/or fume) 3 A1
0.5 - mg/m
16812-54-7
Nicotine - - ppm
537 3 Skin
54-11-5 0.5 - mg/m
Nitrapyrin
[2-Chloro-6- (trichloro methyl)- - - ppm
538 3 A4
pyridine] 10 20 mg/m
1929-82-4
Nitric acid 2 4 ppm
539 3 -
7697-37-2 5.2 10 mg/m

Nitric oxide 25 - ppm


540 3 BEIM
10102-43-9 31 - mg/m

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

p-Nitroaniline - - ppm
541 3 Skin; A4; BEIM
100-01-6 3 - mg/m

Nitrobenzene 1 - ppm
542 3 Skin; A3; BEI
98-95-3 5 - mg/m
p-Nitrochlorobenzene
0.1 - ppm
543 [1-Chloro -4- nitro benzene] 3 Skin; A3; BEIM
0.64 - mg/m
100-00-5
4-Nitrodiphenyl (L)
- - ppm
544 (4-Nitrobiphenyl) (L) 3 Skin
- - mg/m
92-93-3
Nitroethane 100 - ppm
545 3 -
79-24-3 307 - mg/m

Nitrogen (D)
546 Simple asphyxiant
7727-37-9

Nitrogen dioxide 3 5 ppm


547 3 A4
10102-44-0 5.6 9.4 mg/m

Nitrogen trifluoride 10 - ppm


548 3 BEIM
7783-54-2 29 - mg/m

Nitroglycerin (NG) 0.05 - ppm


549 3 Skin
55-63-0 0.46 - mg/m

Nitromethane 20 - ppm
550 3 A3
75-52-5 50 - mg/m

1-Nitropropane 25 - ppm
551 3 A4
108-03-2 91 - mg/m

2-Nitropropane 5 40 ppm
552 3 A3
79-46-9 18 150 mg/m
N-Nitrosodimethylamine (L)
- - ppm
553 [Dimethyl nitroso amine] (L) 3 Skin; A3
- - mg/m
62-75-9
Nitrotoluene, All isomers 2 - ppm
554 3 Skin; BEIM
[88-72-2; 99-08-1; 99-99-0] 11 - mg/m

Nitrous oxide 50 - ppm


555 3 A4
10024-97-2 90 - mg/m

Nonane [111-84-2], All 200 - ppm


556 3 -
isomers 1050 - mg/m

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Octachloronaphthalene - - ppm
557 3 Skin
2234-13-1 0.1 0.3 mg/m

Octane, All isomers 300 - ppm


558 3 -
111-65-9, 540-84-1 1401 - mg/m

- - ppm
559 + Oil mist, mineral 3 -
0.2 - mg/m

Osmium tetroxide (as Os) 0.0002 0.0006 ppm


560 0.0016 3 -
20816-12-0 0.0047 mg/m

Oxalic acid - - ppm


561 3 -
144-62-7 1 2 mg/m

Oxygen difluoride - C 0.05 ppm


562 3 -
7783-41-7 - C 0.11 mg/m
Ozone 10028-15-6
3
Heavy work 0.05/0.1 - ppm/mg/m A4
3
Moderate work 0.08/0.16 - ppm/mg/m A4
3
563 Light work 0.10/0.2 - ppm/mg/m A4
3
Heavy,moderate, or light 0.20/0.4 - ppm/mg/m A4
workloads (≤2 hours)

Paraffin wax fume - - ppm


564 3 -
8002-74-2 2 - mg/m

3
Paraquat (as the cation) 0.5 - mg/m
565 (R) 3 -
4685-14-7 0.1 - mg/m

Parathion - - ppm
566 (IFV) 3 Skin; A4; BEI
56-38-2 0.05 - mg/m

Pentaborane 0.005 0.015 ppm


567 3 -
19624-22-7 0.013 0.039 mg/m

Pentachloronaphthalene - - ppm
568 3 Skin
1321-64-8 0.5 - mg/m

Pentachlorophenol - - ppm
569 3 Skin; A3; BEI
87-86-5 0.5 - mg/m

Pentaerythritol - - ppm
570 3 -
115-77-5 10 - mg/m

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Pentane, All isomers


600 - ppm
571 [78-78-4; 109-66-0; 3 -
1770 - mg/m
463-82-1]
1-Pentyl acetate
50 100 ppm
572 (n-Amyl acetate) 3 -
266 532 mg/m
628-63-7
2-Pentyl acetate
50 100 ppm
573 (sec-Amyl acetate) 3 -
266 532 mg/m
626-38-0
3-Pentyl acetate 50 100 ppm
574 3 -
620-11-1 266 532 mg/m
4-Pentyl acetate
50 100 ppm
575 (tert-Amyl-acetate) 3 -
266 532 mg/m
625-16-1
2-Pentanone
- 150 ppm
576 [Methyl propyl ketone] 3 -
- 529 mg/m
107-87-9
Per chloro ethylene
25 100 ppm
577 [Tetrachloroethylene] 3 A3; BEI
170 685 mg/m
127-18-4
Perchloromethyl mercaptan 0.1 - ppm
578 3 -
594-42-3 0.76 - mg/m

Perchloryl fluoride 3 6 ppm


579 3 -
7616-94-6 13 25 mg/m
Perfluorobutyl ethylene
100 - ppm
580 (PFBE) 3 -
1023 - mg/m
19430-93-4
Perfluoroisobutylenes - C 0.01 ppm
581 3 -
382-21-8 - C 0.082 mg/m

Persulfates, as persulfate - - ppm


582 3 -
7727-21-1; 7727-27-1 0.1 - mg/m

Phenol 5 - 3
583 ppm mg/m Skin; A4; BEI
108-95-2 19 -

Phenothiazine - - ppm
584 3 Skin
92-84-2 5 - mg/m

o-Phenylene diamine - - ppm


585 3 A3
95-54-5 0.1 - mg/m

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

m-Phenylenediamine - - ppm
586 3 A4
108-45-2 0.1 - mg/m

p-Phenylenediamine - - ppm
587 3 A4
106-50-3 0.1 - mg/m

Phenyl ether 1 2 ppm


588 3 -
101-84-8, vapor 7 14 mg/m

Phenyl glycidyl ether (PGE) 0.1 - ppm


589 3 Skin; SEN; A3
122-60-1 0.6 - mg/m

Phenylhydrazine 0.1 - ppm


590 3 Skin; A3
100-63-0 0.44 - mg/m

Phenyl mercaptan 0.1 - ppm


591 3 Skin
108-98-5 0.45 - mg/m
(L)
N-Phenyl-β-naphthylamine - - ppm
592 (L) 3 A4
135-88-6 - - mg/m

Phenylphosphine - C 0.05 ppm


593 3 -
638-21-1 - C 0.23 mg/m

Phorate - - ppm
594 (IFV) 3 Skin; A4; BEIA
298-02-2 0.05 - mg/m
Phosgene
0.1 - ppm
595 [Carbonyl chloride] 3 -
0.4 - mg/m
75-44-5
Phosphine 0.3 1 ppm
596 3 -
7803-51-2 0.42 1.4 mg/m

Phosphoric acid - - ppm


597 3 -
7664-38-2 1 3 mg/m

Phosphorus (yellow) 0.02 - ppm


598 3 -
12185-10-3 0.1 - mg/m

Phosphorus oxychloride 0.1 - ppm


599 3 -
10025-87-3 0.63 - mg/m

Phosphorus pentachloride 0.1 - ppm


600 3 -
10026-13-8 0.85 - mg/m

Phosphorus pentasulfide - - ppm


601 3 -
1314-80-3 1 3 mg/m

OSHAD-SF
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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Phosphorus trichloride 0.2 0.5 ppm


602 3 -
7719-12-2 1.1 2.8 mg/m

Phthalic anhydride 1 - ppm


603 3 SEN; A4
85-44-9 6.1 - mg/m

m-Phthalodinitrile - - ppm
604 (IFV) 3 -
626-17-5 5 - mg/m

Picloram - - ppm
605 3 A4
1918-02-1 10 - mg/m

Picric acid - - ppm


606 3 -
88-99-1 0.1 - mg/m

Pindone - - ppm
607 3 -
83-26-1 0.1 - mg/m

Piperazine dihydrochloride - - ppm


608 3 -
142-64-3 5 - mg/m

Platinum [7440-06-4]
609 3
Metal 1 - mg/m -
3
Soluble salts, as Pt 0.002 - mg/m -
Poly chlorinated biphenyl
- - ppm
610 (PCBs) 3 A3
0.5 - mg/m
1336-36-2
-
Polyvinyl chloride (PVC) - ppm
611 (R) - 3 A4
9002-86-2 1 mg/m

+ Portland cement - - ppm


612 (R) (E) 3 A4
65997-15-1 1 - mg/m

Potassium, cyanide as CN - - ppm


613 3 -
151-50-8 - C8 mg/m

Potassium hydroxide - - ppm


614 3 -
1310-58-3 - C2 mg/m
Potassium zinc chromate See Zinc
- ppm
615 hydroxide Chromates 3 -
- mg/m
11103-86-9 #636
Propane sultone (L)
- - ppm
616 (1,2-Propane sultone) (L) 3 A3
- - mg/m
1120-71-4

OSHAD-SF
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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

n-Propanol (n-Propyl alcohol) 100 250 ppm


617 3 A4
71-23-8 246 614 mg/m
Iso propyl alcohol
200 400 ppm
618 [2-Propanol] 3 A4; BEI
492 984 mg/m
67-63-0
Propargyl alcohol 1 - ppm
619 3 Skin
107-19-7 2.3 - mg/m

β-Propiolactone 0.5 - ppm


620 3 A3
57-57-8 1.5 2 mg/m

Propionaldehyde 20 - ppm
621 3 -
132-38-6 48 - mg/m

Propionic acid 10 - ppm


622 3 -
79-09-4 30 - mg/m

Propoxur - - ppm
623 3 A3; BEIA
114-26-1 0.5 - mg/m

n-Propyl acetate 200 250 ppm


624 3 -
109-60-4 835 1040 mg/m

Propylene 500 - ppm


625 3 -
115-07-1 860 - mg/m
Propylene dichloride
10 - ppm
626 [1,2- /ducgkiri orioabe] 3 SEN; A4
46 - mg/m
78-87-5
Propylene glycol dinitrate 0.05 - ppm
627 3 Skin; BEIM
6423-43-4 0.34 - mg/m
Propylene glycol mono methyl
ether
100 150 ppm
628 [1-Methoxy-2-propanol 3 -
369 553 mg/m
(PGME)]
107-98-2
Propylene oxide 2 - ppm
629 3 SEN; A3
75-56-9 4.8 - mg/m

Propyleneimine 0.2 0.4 ppm


630 3 Skin; A3
75-55-8 0.5 1 mg/m

n-Propyl nitrate 25 40 ppm


631 3 BEIM
627-13-4 107 172 mg/m

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Pyrethrum - - ppm
632 3 A4
8003-34-7 5 - mg/m

Pyridine 1 - ppm
633 3 A3
100-86-1 3.1 - mg/m
Quartz
Silica crystalline – α-Quartz - - ppm
634 (R) 3 A2
[14808-60-7; 1317-95-9] and 0.025 - mg/m
Cristobalite [14464-46-1]
Quinone 0.1 - ppm
635 3 -
106-51-4 0.44 - mg/m

Resorcinol 10 20 ppm
636 3 A4
108-46-3 45 90 mg/m

Rhodium, elemental - - ppm


637 3 A4
7440-16-6 1 - mg/m

Rhodium (elemental), as Rh
Metal and insoluble- - - ppm
638 3 A4
compounds 1 - mg/m

Rhodium, as Rh
- - ppm
639 Soluble compounds 3 A4
0.01 - mg/m

Ronnel - - ppm
640 (IFV) 3 A4; BEIA
299-84-3 5 - mg/m
Rosin core solder thermal (L)
- - ppm
641 decomposition products (L) 3 SEN
- - mg/m
(colophony) 8050-09-7
See Rosin core solder
Rosin core solder, pyrolysis
642 thermal decomposition
products, as formaldehyde
products
Rotenone (commercial) - - ppm
643 3 A4
83-79-4 5 - mg/m

Selenium [7782-49-2] - - ppm


644 3 -
compounds, as Se 0.2 - mg/m

- - ppm
645 Selenium, metal 3 -
0.2 - mg/m

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Selenium hexafluoride, as Se 0.05 - ppm


646 3 -
7783-79-1 0.4 - mg/m

Selenium sulfide, as Se - - ppm


647 3 -
7446-34-6 0.2 - mg/m

Sesone - - ppm
648 3 A4
136-78-7 10 - mg/m
Silane
5 - ppm
649 [Silicon tetrahydride] 3 -
6.6 - mg/m
7803-62-5
- - ppm
650 Silica (inhalable particle) 3
10 - mg/m

- - ppm
651 Silica (respirable particulate) 3
3 - mg/m

Silica fume - - ppm


652 3
69012-64-2 2 - mg/m

Silica fused - - ppm


653 3
60676-86-0 0.1 - mg/m

Silic gel - - ppm


654 3
112926-00-8 10 - mg/m
Quartz
Silica crystalline – α-Quartz - - ppm
655 (R) 3 A2
[14808-60-7; 1317-95-9] and 0.025 - mg/m
Cristobalite [14464-46-1]
Silicon carbide [409-21-2]
(I,E) 3
10 - mg/m -
Nonfibrous (R,E) 3
656 3 - mg/m -
(F)
Fibrous (including whiskers) 0.1 - f/cc A2

Silicon tetrahydride
5 - ppm
657 [Silane] 3 -
6.6 - mg/m
7803-62-5
Silver [7440-22-4]
3 -
658  Metal, dust and fume 0.1 - mg/m
3 -
 Soluble compounds, as Ag 0.01 - mg/m
Sodium azide
[26628-22-8]
659 - 3
 as Sodium azide C 0.29 mg/m A4
-
 as Hydrazoic acid vapor C 0.11 ppm A4

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Sodium bisulfite - - ppm


660 3 A4
7631-90-5 5 - mg/m

Sodium cyanide, as CN - - ppm


661 3 -
143-33-9 - C5 mg/m

Sodium fluoroacetate - - ppm


662 3 Skin
62-74-8 0.05 - mg/m

Sodium hydroxide - - ppm


663 3 -
1310-73-2 - C2 mg/m

Sodium metabisulfite - - ppm


664 3 A4
7681-57-4 5 - mg/m 3

Sodium persulfate, as S2O8 - - ppm


665 3 A4
7775-27-1 0.1 - mg/m
Sodium tetraborate,
See Borate compounds,
666 Anhydrous
inorganic
1330-43-4
Sodium tetraborate,
See Borate compounds,
667 Decahydrate
inorganic
1303-96-4
Sodium tetraborate,
See Borate compounds,
668 Pentahydrate
inorganic
12179-04-3
Starch - - ppm
669 3 A4
9005-25-8 10 - mg/m

- - ppm
670 Stearates (J) 3 A4
10 - mg/m

Stoddard solvent 100 - ppm


671 3 -
10048-13-2 525 - mg/m
Stibine
0.1 - ppm
672 [Antimony hydride] 3 -
0.51 - mg/m
7803-52-3
Stoddard solvent 100 - ppm
673 3 -
8052-41-3 525 - mg/m

Strontium chromate (as Cr) - - ppm


674 3 A2
7789-06-2 0.0005 - mg/m

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Strychnine - - ppm
675 3 -
57-24-9 0.15 - mg/m

Styrene, monomer 20 40 ppm


676 3 A4; BEI
100-42-5 85 170 mg/m
Subtilisins, as crystalline
- - ppm
677 active enzyme 3 -
- C 0.00006 mg/m
1395-21-7; 9014-01-1
Sucrose - - ppm
678 3 A4
57-50-1 10 - mg/m

Sulfometuron methyl - - ppm


679 3 A4
74222-97-2 5 - mg/m

Sulfotepp (TEDP) - - ppm


680 (IFV) 3 Skin; A4; BEIA
3689-24-5 0.1 - mg/m

Sulfur dioxide - 0.25 ppm


681 3 A4
7446-09-5 - 0.65 mg/m

Sulfur hexafluoride 1000 - ppm


682 3 -
2551-62-4 5970 - mg/m
Sulfuric acid - - ppm (M)
683 (T) 3 A2
7664-93-9 0.2 - mg/m
Sulfur monochloride - C1 ppm
684 3 -
10025-67-9 - C 5.5 mg/m
Sulfur pentafluoride - C 0.01 ppm
685 3 -
5714-22-7 - C 0.10 mg/m
Sulfur tetrafluoride - C 0.1 ppm
686 3 -
7783-60-0 - C 0.44 mg/m
Sulfuryl fluoride 5 10 ppm
687 3 -
2699-79-8 21 42 mg/m
(IFV)
Sulprofos 0.008 - ppm
688 (IFV) 3 Skin; A4; BEIA
35400-43-2 0.1 - mg/m
Synthetic vitreous fibers, (I) 3
5 - mg/m
689 continuous filament glass (F) A4
- 1 f/cc
fivers
Synthetic vitreous fibers, glass (F)
690 - 1 f/cc A3
woll fibers

Synthetic vitreous fibers, rock (F)


691 - 1 f/cc A3
wool fibers

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Synthetic vitreous fibers,slag (F)


692 - 1 f/cc A3
wool fibers
Synthetic vitreous
(F)
693 fibers,special purpose glass - 1 f/cc A3
fibers
Synthetic vitreous (F)
694 - 2 f/cc A3
fibers,refractory ceramic fibers
2,4,5-T (2,4,5-Trichloro-
- - ppm
695 phenoxyacetic acid) 3 A4
10 - mg/m
93-76-5
+ Talc [14807-96-6]
 containing no asbestos (E,R) 3
2 - mg/m A4
696 fibers
Use
 containing asbestos fibers asbestos - - A1
® (K)
TLV
+ (Tantalum [7440-25-7] and
3
697 Tantalum oxide [1314-61-0] 5 - mg/m (-)
dusts, as Ta)
Sulfotepp (TEDP) - - ppm
698 (IFV) 3 Skin; A4; BEIA
3689-24-5 0.1 - mg/m
Tellurium [13494-80-9] and
- - ppm
699 compounds (NOS), as Te, 3 -
0.1 - mg/m
excluding hydrogen telluride
Tellurium hexafluoride 0.02 - ppm
700 3 -
[7783-80-4], as Te 0.2 - mg/m

Temephos - - ppm
701 (IFV) 3 Skin; A4; BEIA
3383-96-8 1 - mg/m
Tetraethyl pyrophosphate
- - ppm
702 (TEPP) (IFV) 3 Skin; BEIA
0.01 - mg/m
107-49-3
Terbufos - - ppm
703 (IFV) 3 Skin; BEIA
1307-79-9 0.01 - mg/m

Terephthalic acid - - ppm


704 3 -
100-21-0 10 - mg/m
Terphenyl, o-, m-, p-iso-mers
- C 0.53 ppm
705 26140-60-3; 84-15-1; 92-06-8; 3 -
- C5 mg/m
92-94-4

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

1.1.2.2-Tetrabromoethane (IFV)
0.1 - ppm
706 (Acetylene tetrabromide) (IFV) 3 -
1.4 - mg/m
79-27-6
1,1,1,2-Tetrachloro-2,2-
difluoroethane 100 - ppm
707 3 -
76-11-9 834 - mg/m
1,1,2,2-Tetrachloro-1,2-
difluoroethane 50 - ppm
708 3 -
76-12-0 417 - mg/m

1,1,2,2-Tetrachloroethane 1 3 ppm
709 3 Skin; A3
79-34-5 6.9 21 mg/m
Tetrachloroethylene
25 100 ppm
710 [Per chloro ethylene] 3 A3; BEI
170 685 mg/m
127-18-4
Tetrachloronaphthalene - - ppm
711 3 -
1335-88-2 2 - mg/m

Tetraethyl lead, as Pb - - ppm


712 3 Skin; A4
78-00-2 0.1 - mg/m
Tetraethyl pyrophosphate
- - ppm
713 (TEPP) (IFV) 3 Skin; BEIA
0.01 - mg/m
107-49-3
Tetrafluoroethylene
2 - ppm
714 (Tetrafluoroethene) 3 A3
8.0 - mg/m
116-14-3
Tetrahydrofuran 50 100 ppm
715 3 Skin; A3
109-99-9 147 295 mg/m
Tetrakis (hydroxymethyl)-
- - ppm
716 phosphonium chloride 3 A4
2 - mg/m
124-64-1
Tetrakis(hydroxymethyl)-
- - ppm
717 phosphonium sulfate 3 A3
2 - mg/m
55566-30-8
Tetramethyl lead - - ppm
718 3 Skin
75-74-1, as Pb 0.15 - mg/m

Tetramethyl succinonitrile 0.5 - ppm


719 3 Skin
3333-52-6 2.8 - mg/m

Tetranitromethane 0.005 - ppm


720 3 A3
509-14-8 0.04 - mg/m
-
Tetra sodium pyro phosphate - ppm
721 - 3
7722-88-5 5 mg/m

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Tetryl - - ppm
722 3 -
479-45-8 1.5 - mg/m
+ Thailium [7440-28-0] and
- ppm
723 soluble compounds, as Tl (I) 3 Skin
.02 -- mg/m
Thimerosal (sodium ethyl-
See Mercury, aryl
724 mercurithiosalicalate)
compounds, as Hg
54-64-8
+ 4,4’-Thiobis (6-tert-butyl-m-
- - ppm
725 cresol) (I) 3 A4
10 - mg/m
96-69-5
Thioglycolic acid 1 - ppm
726 3 Skin
68-11-1 3.8 - mg/m

Thionyl chloride - C 0.2 ppm


727 3 -
7719-09-7 - - mg/m

Thiram - - ppm
728 (IFV) 3 SEN; A4
137-26-8 0.05 - mg/m
Tin 7440-31-5, as Sn
 Metal 2 3 -
- mg/m
 Oxide & inorganic
729
compounds except tin 3
2 - mg/m -
hydride (18282-10-5;
21651-19-4)

Tin 7440-31-5, as Sn - - ppm


730 3 Skin; A4
 Organic compounds 0.1 0.2 mg/m

Titanium dioxide - - ppm


731 3 A4
13463-67-7 10 - mg/m
Tolidine, o-isomer (3,3’-
- - ppm
732 Dimethylbenzidine) 3 Skin
- - mg/m
119-93-7
ppm
Toluene 20 - 3
733 mg/m A4; BEI
108-88-3 75 -

+ Toluene-2,4diisocyanate 0.005
(IFV)
0.003 ppm
734 (TDI) 0.036
(IFV) 3 Skin; SEN; A3
0.021 mg/m
584-84-9

+ Toluene-2,6-diisocyanate (IFV) 0.003 ppm


735 0.005 3 Skin; SEN; A3
91-08-7 (IFV) 0.021 mg/m
0.036

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

o-Toluidine 2 - ppm
736 3 Skin; A3; BEIM
95-53-4 8.8 - mg/m

m-Toluidine 2 - ppm
737 3 Skin; A4; BEIM
108-44-1 8.8 - mg/m

p-Tolidine 2 - ppm
738 3 Skin; A3; BEIM
106-49-0 8.8 - mg/m

Tributyl phosphate 0.2 - ppm


739 3 BEIA
126-73-8 2.2 - mg/m

Trichloroacetic acid 1 - ppm


740 3 A3
76-03-9 6.7 - mg/m

1,2,4-Trichlorobenzene - C5 ppm
741 3 -
120-82-1 - C 37 mg/m

1,1,2-Trichloroethane 10 - ppm
742 3 Skin; A3
79-00-5 55 - mg/m
ppm
Trichloroethylene 10 25 3
743 mg/m BEI; A2
79-01-6 54 135

Trichlorofluoromethane - C 1000 ppm


744 3 A4
75-69-4 - C 5620 mg/m

Trichloronaphthalene - - ppm
745 3 Skin
1321-65-9 5 - mg/m

1,2,3-Trichloropropane 10 - ppm
746 3 Skin; A3
96-18-4 60 - mg/m
1,1,2- Trichloro-1,2,2-
1000 1250 ppm
747 trifluoroethane (CFC-113) 3 A4
7670 9590 mg/m
76-13-1
Trichlorphon - - ppm
748 3 A4
52-68-6 5 - mg/m
Tridymite
- - ppm
749 [Silca, crystalline] 3
0.05 - mg/m
15468-32-2
Triethanolamine - - ppm
750 3 -
102-71-6 5 - mg/m

Triethylamine 1 3 ppm
751 3 Skin; A4
121-44-8 4.1 12.4 mg/m

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Trifluorobromomethane
1000 - ppm
752 [Bromotrifluoro methane] 3 -
6090 - mg/m
75-63-8
1,3,5-Triglycidyl-s-
- - ppm
753 triazinetrione 3 -
0.05 - mg/m
2451-62-9
Trimellitic anhydride - - ppm
754 (IFV) (IFV) 3 Skin; SEN
552-30-7 0.0005 0.002 mg/m

Trimethylamine 5 15 ppm
755 3 -
75-50-3 12 36 mg/m
Trimethyl benzene (mixed
isomers) 25 - ppm
756 3 -
25551-13-7; 526-73-8; 123 - mg/m
95-63-6; 108-67-8
0.5 10 ppm
757 Trimethyl phosphate 3 Slin; A3
2.6 52 mg/m

Trimethyl phosphite 2 - ppm


758 3 -
121-45-9 10 - mg/m

2,4,6-Trinitrotoluene (TNT) - -
759 ppm Skin; BEIM
118-96-7 0.1 - 3
mg/m
Triortho cresyl phosphate - - ppm
760 3 Skin; A4; BEIA
78-30-8 0.1 - mg/m

Tripheneyl amine - - ppm


761 3
603-34-9 5 - mg/m

Triphenyl phosphate - - ppm


762 3 A4
115-86-6 3 - mg/m
Tungsten [7440-33-7], as W
3
763 Metal and insoluble 5 10 mg/m -
compounds
Tungsten [7440-33-7], as W 3
764 1 3 mg/m -
soluble compounds
Turpentine [8006-64-2] and
ppm
selected monoterpenes 20 - 3
765 mg/m SEN; A4
[80-56-8; 127-91-3; 112 -
13466-78-9]
Uranium (natural)
- - ppm
766 [7440-61-1] 3 A1; BEI
0.2 0.6 mg/m
insoluble compounds, as U

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

Uranium (natural)
- - ppm
767 [7440-61-1] 3 A1; BEI
0.2 0.6 mg/m
soluble compounds, as U
n-Valeraldehyde 50 - ppm
768 3 -
110-62-3 176 - mg/m

Vanadium pentaoxide, as V - - ppm


769 (I) 3 A3
1314-62-1 0.05 - mg/m

Vinyl acetate 10 15 ppm


770 3 A3
108-05-4 35 53 mg/m
Vinyl bromide 0.5 10 ppm
771 3 A2
593-60-2 2.2 40 mg/m
Vinyl chloride 1 2.5 ppm
772 3 A1
75-01-4 2.6 5 mg/m

4-Vinyl cyclohexene 0.1 - ppm


773 3 A3
100-40-3 0.44 - mg/m
Cinyl cyclohexeneide
0.1 - ppm
774 [Vinyl cyclohexene dioxide] 3 Skin; A3
0.57 - mg/m
106-87-6
Vinylidene chloride
5 - ppm
775 [1,1-Dichloro ethylene] 3 A4
20 - mg/m
75-35-4
Vinylidene fluoride
500 - ppm
776 (1,1-Difluoroethylene) 3 A4
1310 - mg/m
75-38-7
N-Vinyl-2-pyrrolidone 0..05 - ppm
777 3 A3
88-12-0 0.23 - mg/m

Vinyl toluene 50 100 ppm


778 3 A4
25013-15-4 242 483 mg/m

Warfarin - - ppm
779 3 A4
81-81-2 0.1 - mg/m
-
VM & P-naphtha 300 ppm
780 - 3
8032-32-4 1370 mg/m

Welding fumes – Not - - ppm


781 3
otherwise specified 5 - mg/m

Wood dusts - -
782  Western red cedar 0.5
(I)
- mg/m
3
SEN; A4
(I) 3
 Beech and oak 1 - mg/m A2

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‫اﻟرﻗم‬ ‫اﻟﻣﺎدة‬ ‫ﻗﯾم ﺣدود اﻟﻌﺗﺑﺔ‬ ‫اﻟوﺣدة‬ ‫ﻣﻼﺣظﺎت‬
SUBSTANCE Threshold Limit Value (TLV)
No. Unit Notations
CAS No. TWA STEL

 Birch, mahogany, teak, 3


(I) - mg/m A2
walnut 1
(I) 3
All other species 1 - mg/m A4
Xylene [1330-20-7] (o, m & p
100 150 ppm
783 isomers) [95-47-6; 3 A4; BEI
434 651 mg/m
108-38-3; 106-42-3]
m-Xylene α,α’-diamine - - ppm
784 3 Skin
1477-55-0 - C0.1 mg/m
Xylidine, mixed isomers (IFV)
0.5 - ppm
785 1300-73-8; 87-59-2; 95-67-7; (IFV) 3 Skin; A3; BEIM
2.5 - mg/m
108-69-0
2,4- Xylidine 2 - ppm
786 3
95-68-1 10 - mg/m
Yttrium
- - ppm
787 7440-65-5 and compounds, 3 -
1 - mg/m
as Y
Zinc beryllium silicate, as Be - -
788 (I) ppm A1
39413-47-3 0.00005 - 3
mg/m
Zinc chloride fume - -
789 ppm -
7646-85-7 1 2 3
mg/m
Zinc chromate
[13530-65-9, - - ppm
790 11103-86-9, 3 A1
0.01 - mg/m
3730-23-5], as Cr
Zinc oxide, fume - - ppm
791 (R) (R) 3 -
1314-13-2 2 10 mg/m
Zinc stearate - - ppm
792 3 A4
557-05-1 10 - mg/m
Zirconium, elemental - - ppm
793 3 A4
7440-67-7 5 10 mg/m

Zirconium [7440-67-7] and - - ppm


794 3 A4
compounds, as Zr 5 10 mg/m

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Standards and Guideline Values – Version 3.0 – 1 July 2016 Page 64 of 67
‫ ﺣدود اﻟﺗﻌرض اﻟﻣﮭﻧﻲ ﻟﻠﺿوﺿﺎء‬:(‫اﻟﺟدول )ب‬
Schedule B: Occupational Noise Exposure
Limits
(Combinations of noise exposure levels and durations not to be exceeded)

‫ﻣﺳﺗوى‬ ‫ﻣﺳﺗوى‬
‫اﻟﻔﺗرة اﻟزﻣﻧﯾﺔ‬ ‫اﻟﻔﺗرة اﻟزﻣﻧﯾﺔ‬
‫اﻟﺗﻌرض‬ ‫اﻟﺗﻌرض‬
Exposure Exposure
Duration, T Duration, T
Level, L Level, L
(dBA) Hours Minutes Seconds (dBA) Hours Minutes Seconds
80 25 24 - 106 - 3 45
81 20 10 - 107 - 2 59
82 16 - - 108 - 2 22
83 12 42 - 109 - 1 53
84 10 5 - 110 - 1 29
85 8 - - 111 - 1 11
86 6 21 - 112 - - 56
87 5 2 - 113 - - 45
88 4 - - 114 - - 35
89 3 10 - 115 - - 28
90 2 31 - 116 - - 22
91 2 - - 117 - - 18
92 1 35 - 118 - - 14
93 1 16 - 119 - - 11
94 1 - - 120 - - 9
95 - 47 37 121 - - 7
96 - 37 48 122 - - 6
97 - 30 - 123 - - 4
98 - 23 49 124 - - 3
99 - 18 59 125 - - 3
100 - 15 - 126 - - 2
101 - 11 54 127 - - 1
102 - 9 27 128 - - 1
103 - 7 30 129 - - 1
104 - 5 57 130-140 - - <1
105 - 4 43 - - - -

OSHAD-SF
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Standards and Guideline Values – Version 3.0 – 1 July 2016 Page 65 of 67
OSHAD-SF
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Standards and Guideline Values – Version 3.0 – 1 July 2016 Page 66 of 67
© OSHAD 2016
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which it was intended. Unauthorised use or reproduction of this document is prohibited.

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