QUIZ

CHEMICAL BONDING
1. The hybridisation of Cationic Part in Cl2O6
(a) sp (b) sp2 (c) sp3 (d) sp3d
Ans. (b)

O O
Cl O Cl O ClO2 ClO4
O
Sol. Q.1 O
unsymmetric
cleavage sp2 sp3

Correct opton is (b).

2. Correct order of bond angle?

(a) BH4– > NH4+ > SiH4 > PH4+
(b) PH4+ > SiH4 > NH4+ > BH4–
(c) SiH4 > PH4+ > NH4+ > BH4–
(d) None of these
Ans. (d)
Sol. All Surrounding roups same, SO NO NBEPR AND No lone Pair present SONOVSEPR.
BH 4  NH 4  SiH 4  PH 4
Correct opton is (d).
3. The shape of SF4
(a) Trigonal bipyramidal (b) T – shape
(c) Distorted tetrahedral (d) bent
Ans. (c)
Sol. SF4

F geometry TBP
S F Shape See Saw
OR
F F distorted td

4. The correct order of Bond energy

(a) B2 > B2+ > B2– (b) B2– > B2 > B2+
(c) B2+ > B2 > B2– (d) B2 > B2– > B2+
Ans. (b)
Sol. B2 B2 B2
Bondorder 1 1.5 0.5
Bondenergy  Bond . order. thats why. B2  B2  B2
Correct option is (b).

5. Geometry of K3CrO8 is
(a) Square anti prismatic (d) Dodecahedron
(c) Cubic (d) None of these
Ans. (b)
Sol. K 3CrO8  AB8n  , wher if B is ‘O’ then geometry is dodecanedron
CrO38
geometry  dodecanedron.


13.6 eV
1s

18.7 eV
  2p


 40.17 eV
 2s

6. The number of non bonding electron present in the frontier molecular orbital
of HF is
(a) 10 (b) 4 (c) 6 (d) 2
Ans. (b)

7. The number of species with bond order 0.5 is (H2+, H2–, B2+, C2–)
(a) 1 (b) 2 (c) 3 (d) 4
Ans. (c)
Sol. H 2  1S1 Bondorder = 0.5
H 2  1S2  1S1 Bondorder = 0.5
' '
B2  1S2 1S2 2S2 2S2 2px  2py B.O = 0.5
Correct option is (*)

8. Which of the following molecule is not fluxional?

(a) NH3 (b) IF7 (c) SF6 (d) PF5
Ans. (c)
Sol. In ammonia  pyramidal inversion take place.
PF5 shows berry pseudorotation
IF7 due to axial equational exchange.
SF6 is symmetrical structure has no exchange. take place
9. The shape of [CIF4]– and [ClF2]– ions is respectively.
(a) see – saw and linear (b) see – saw and bent
(c) tetrahedral and linear (d) square planar and linear
Ans. (d)

ClF4 ClF2

F F
F
Cl Cl
Sol.
F F F
Square Planar Linear

10. HOMO and LUMO of I3– respectively are

(a) bonding and antibonding
(b) non – bonding and antibonding
(c) bonding and non – bonding
(d) both non – bonding
Ans. (b)
Sol. I 2  I   I 3
Lewis acid lewis bese

I2 I


(Antibonding) LUMO


(LUMO of I2)
5p

Nonbonding
(HOMO)

(bonding)
So HOMO and LUMO of I3 is nonbonding and antibonding
Correct option is (b).