Multiple Choice Questions With

Answers
TYBSC SEM IV – Organic Chemistry

Proton Magnetic Resonance

(P.M.R) Spectroscopy
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1. Nature of excitations in NMR Spectroscopy is ….

(a) Electronic excitation

(b) Nuclear excitation
(c) Vibrational excitation
(d) Rotational excitation

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2. Type of radiation used in NMR Spectroscopy is ….

(a) Cosmic rays

(b) Radio wave
(c) Microwave
(d) More energetic wave

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3. PMR spectrum give us information of about...

(a) Chromophore present in molecule

(b) Functional group present in molecule
(c) Type of protons present in molecule
(d) All of these

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4. The separation between the peak position of the sample
proton with respect to TMS proton is known as...

(a) Coupling constant (J)

(b) Chemical shift (𝛿)
(c) Intensity
(d) None of these

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5. The separation between the peak within a multiple is known
as...

(a) Coupling constant (J)

(b) Chemical shift (𝛿)
(c) Intensity
(d) None of these

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6. The separation of PMR peaks into number of
small peaks is known as...

(a) Coupling constant (J)

(b) Chemical shift (𝛿)
(c) Splitting of peaks
(d) All of these
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7. Chemical shift for TMS itself is..

(a) 1.5 ppm

(b) 1 ppm
(c) 0 ppm
(d) 1.2 ppm

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8. As electronegativity increases , deshielding increases and then
chemical value (𝛿) is ...

(a) Decreases
(b) Increases
(c) Lower
(d) Both (b) & (c)

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9. Vicinal coupling is also known as

(a) 1,3 coupling

(b) 1,4 coupling
(c) 1,2 coupling
(d) None of these

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10. Geminal coupling is also known as…

(a) 1,3 coupling

(b) 1,4 coupling
(c) 1,2 coupling
(d) None of these

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11. TMS is…

(a) Tetra methyl sulphur

(b) Tetra methyl silane
(c) Tri methyl silane
(d) Tri methyl sulphur

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12. Incorrect statement for TMS is…

(a) It is highly volatile

(b) It is used as internal reference
(c) It has 9 equivalent protons
(d) It shows one sharp signal

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13. All nuclei that have spin quantum number (I)....Behave as
magnets.

(a) Greater than zero

(b) Less than zero
(c) Equal to zero
(d) None of these

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14. The multiplicity of the peaks is given by …

(a) 𝑛 + 1 n = total number of neighbouring protons.

(b) 𝑛
(c) 𝑛 − 1
(d) (𝑟 + 1)𝑛
15. The number of orientations of the nucleus in external magnetic
field is given by …

(a) 2𝐼 + 1
I = is the spin quantum number of the nucleus.
(b) I
(c) 2I − 1
(d) (I + 1)

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16. The number of signals in the spectrum ….

(a) Not equal to the no. of type of protons

(b) Equal to the no. of type of protons
(c) equal to the no. of atom
(d) equal to the no. of electron

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17. The nucleus with 𝐼 > 0 are said to be ….

(a) magnetic
(b) Non magnetic
(c) Even mass number & even atomic number
(d) Proton + neutrons

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18. If there is one neighbouring proton, the peak split into a doublet
with relative intensity…

(a) 1: 2
(b) 1:2:1
(c) 1:1
(d) 1: 3

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19. RELATION BETWEEN 𝛿 −scale & 𝜏 −scale…

(a) 𝛿 = 10 − 𝜏
(b) τ = 10 + 𝛿
(c) −10 = −𝛿 − 𝜏
(d) All of these

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20. The spin quantum number of hydrogen nucleus is…

(a) 2/3
(b) 1/3
(c) 1/2
(d) None of these

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21. The condition for PMR or NMR active is…

(a) 𝐼 > 0
(b) 𝑒𝑣𝑒𝑛 𝑜𝑑𝑑 𝑛𝑢𝑚𝑏𝑒𝑟 𝑜𝑓 𝑚𝑎𝑠𝑠 𝑎𝑛𝑑 𝑎𝑡𝑜𝑚𝑖𝑐 𝑛𝑢𝑚𝑏𝑒𝑟
(c) 𝐼 = 0
(d) Both (a) & (b)

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22. Number of signal in acetone molecule is...

(a) 2
(b) 3
(c) 1
(d) None of these

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23. Number of peak and type of proton in p- Xylene is...

(a) 2,2
(b) 6 , 6
(c) 3,3
(d) 2,3

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23. Number of peak in propanol is...

(a) 3
(b) 5
(c) 4
(d) 2

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24. How many sets of protons present in ...

(a) 6
(b) 5
(c) 2
(d) 3

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25. Number of peak in propanol is...

(a) 3
(b) 5
(c) 4
(d) 2

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26. How many sets of protons present in ...

(a) 6
(b) 5
(c) 1
(d) 2

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27. How many sets of protons present in ...

(a) 6
(b) 5
(c) 3
(d) 2

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28. How many sets of protons and number of signal present in ...

(a) 1,2
(b) 3,3
(c) 2,2
(d) 1,1

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29. As electron density around the proton increases, shielding
increases and absorption occur at ...

(a) Low field

(b) High field
(c) Both (a) & (b)
(d) Down field

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30. As electron density around the proton decreases, deshielding will
increases and absorption occur at ...

(a) Low field

(b) High field
(c) Both (a) & (b)
(d) Up field

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31. Which of following are NMR inactive ...

1
(a) 1𝐻
13
(b) 6𝐶

(c) 126𝐶
(d) 199𝐹

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