IMPORTANT NOTES ON ANA CHEM LECTURE 4

Some important Units of Measurements

B. Mass and Weight
Mass – it is the specific value or quantity of matter
that is in a specific object.
Weight – it is the force that acts on that object. It is
typically attributed as the force that is applied due to
gravity that we have here on Earth.
w = mg
where: D.
w = weight of the object
m = its mass
Millimole
g = acceleration due to gravity
Sometimes millimoles is more convenient to use in
C. Moles Analytical Chemistry because there are times that
Avogadro’s Number = 6.022 x 1023 you will be calculating for trace analysis, meaning

 X is
what
we are looking for analyzing very small concentration units.
 mx is the mass of X
 Mx
is
the

Sample Problem #1
Find the number of moles and millimoles of benzoic
moles of X acid (M=122.1 g/mol) that are contained in 2.00 g of
the pure acid.
 IMPORTANT NOTES ON ANA CHEM LECTURE 4

Sample Problem #2
What is the mass in grams of Na+ (22.99 g/mol) in
25.0 g of Na2SO4 (142.0 g/mol)?
Solutions and their Concentrations
A.1. Concentrations of Solutions: Molar
Concentration
Unit of Molar Concentration = molar
molar = M
Molar will be convenient on how you express the
concentrations because you can use it to convert one
concentration unit to another. The same with moles,
molar concentration can also be expressed in
millimoles.

where:

 cx is the concentration of the species or the

solute
 nx is the moles of the solute
Sample Problem #3

Calculate the molar concentration of ethanol in an
 aqueous solution that contains 2.30 g of C2H5OH
 (M = 46.07 g/mol) in 3.50 L of solution.
V is the overall liter or the volume of the solution A.2. Concentration of Solutions: Molar Analytical
Concentration
Molar Analytical Concentration – tells us what
happens to the solute when it is being dissolved into
the solution, whether it remains intact or dissociates.
If it dissociates, the concentration of that solute or
that species is not necessarily the same with molar
concentration.
A.3. Concentration of Solutions: Molar Equilibrium
Concentration
 IMPORTANT NOTES ON ANA CHEM LECTURE 4

Example
Sulfuric Acid dissociates into: (have different
concentrations)
 H+
 HSO4-

 SO42-

Sample Problem #5
Describe the preparation of 2.50 L of 0.120 M
BaCl2 from BaCl2 · 2H2O (244.3 g/mol).
Sample Problem #6
Describe the preparation of 500 mL of 0.0740 M Cl
solution from solid BaCl2 · 2H2O (244.3 g/mol).
B. Percent Concentration
C. Parts per Million and Parts per Billion
Sample Problem #7

Sample Problem #4
Calculate the analytical and equilibrium molar
concentrations of the solute species in an aqueous
solution that contains 285 mg of trichloroacetic acid,
Cl3CCOOH (163.4 g/mol), in 10.0 mL (the acid is
73% ionized in water).
 IMPORTANT NOTES ON ANA CHEM LECTURE 4

What is the molar concentration of K+ in a solution

that contains 63.3 ppm of K3Fe(CN)6 (329.3 g/mol)?

D. Solution-Diluent Volume Ratios

E. p-functions
Sample Problem #8
 IMPORTANT NOTES ON ANA CHEM LECTURE 4
Calculate the p-value for each ion in a solution that is
2.5 x 10-3 M in BeCl2 and 5.4 x 10-4 M in HCl.
Sample Problem #9
Calculate the molar concentration of Ca2+ in a solution
that has a pCa of 7.90.
F. Density and Specific gravity of solutions
Sample Problem #10
Calculate the molar concentration of HNO3 (63.0
g/mol) in a solution that has a specific gravity of 1.42
and is 70.5% HNO3 (w/w).
Chemical Stoichiometry
Where can we get Stoichiometric Ratio?
- From a balanced chemical reaction.
- Kung ano yung coefficient na nakadikit before the
chemical formula, we use that as a mole.
- Mole Ratio = Stoichiometric Ratio
Sample Problem #11
(a) What mass of AgNO3 (169.9 g/mol) is needed to
convert 2.33 g of Na2CO3 (106.0 g/mol) to AgCO3?
(b) What mass of Ag2CO3 (275.7 g/mol) will be
formed?
Since equal lang ang ratio ng Na2CO3 and Ag2CO3
(which is 1), yung nakuhang mass nang Na2CO3 ay
ginamit para makuha naman ang mass ng Ag2CO3.
Kung ilan yung moles ng Na2CO3 na nasa reaction,
ganun din yung number of moles ng Ag2CO3 that will
 IMPORTANT NOTES ON ANA CHEM LECTURE 4

come out after the reaction. We can use it so that we

can convert the moles to grams because we are asked
to find the mass of Ag2CO3.