Hemistry Tructure of TOM: Evel Bjective Type Questions

FIITJEE KVPY (QUESTION BANK) CHEMISTRY 1
CHEMISTRY
STRUCTURE OF ATOM
LEVEL 1 OBJECTIVE TYPE QUESTIONS
1. Uncertainty in position and momentum are equal. Uncertainty in velocity is:
h h
(a) (b)
 2
1 h
(c) (d) None
2m 
2. The two electrons present in an orbital are distinguished by

(a) Principal quantum number
(b) Azimuthal quantum number
(c) Magnetic quantum number
(d) Spin quantum number
3. The correct set of four quantum numbers for the valence electron of rubidium (Z=37) is:
(a) n = 5, l = 0, m = 0, ms = +1/2
(b) n = 5, l = 1, m = 0, ms = +1/2
(c) n = 5, l = 1, m = 1, ms = +1/2
(d) n = 6, l = 0, m = 0, ms = +1/2
4. The orbital angular momentum of a 4s electron is

(a) zero (b) 2h
(c) 3h (d) 6h
5. According to Bohr’s theory the angular momentum for an electron of 5th orbit is:
(a) 2.5 h /  (b) 5h / 
(c) 25 h /  (d) 6h / 2
6. The probability of finding an electron residing in a px orbital is not zero:

(a) In the yz plane (b) In the xy plane
(c) In the y direction (d) In the z direction
7. The maximum number of electrons possible in sublevel is equal to

(a) 2 +1 (b) 2n2
(c) 2 2 (d) 4 +2
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8. Which represents an impossible arrangement?

n m s
(a)  3 2 –2 1/2
(b) 4 0 0 1/2
(c)  3 2 –3 1/2
(d) 5 3 0 1/2
9. Which set of quantum number represents the electron of lowest energy?

(a) n = 2, = 0, m = 0, S = +1/2
(b) n = 2, = 1, m = 0, S = +1/2
(c) n = 4, = 0, m = 0, S = +1/2
(d) n = 4, = 0, m = 0, S = –1/2
10. The orbital diagram in which Aufbau principle is violated is:

(a) ns np (b) ns np
(c) ns np (d) ns np
11. Which will have 3d54s1 configuration?

(a) Cr(Z = 24, e = 24)
(b) Fe2+ (Z = 26, e = 24)
(c) Mn+(Z = 25, e = 24)
(d) A, C
12. When the frequency of light incident on a metallic plate is doubled, the K.E of the
emitted photoelectrons will be
(a) doubled
(b) halved
(c) increase but more than double of the previous K.E.
(d) unchanged
13. Maximum magnetic moment for Cu2+

(a) 1.732 B.M. (b) 5 B.M.
3
(c) B.M. (d) 2 B.M.
2

14. [N2, CO, CN ] are example of
(a)Isoelectronic (b) Isotonic
(c)Isotopes (d) Isobars
15. Isoelectronic structures among the following structures are:

(I) CH3+ (II) H3O+ (III) NH3 (IV) CH3
(a) I and III (b) III and IV
(c) I and II (d) II, III and IV
16. What did Rutherford's Alpha - particle scattering experiment prove?

(a) Atoms consists of electrons, protons and neutrons
(b) All atoms have a nucleus at their centre, which is positively charged
(c) The nucleus occupies the major space in an atom.
(d) Atoms are neutral
17. Increasing the intensity of photon, incident on metal surface will

(a) increase the no. of electrons ejected
(b) decrease the no. of electrons ejected
(c) increase the kinetic energy of electron
(d) decrease the kinetic energy of electron
18. Balmer series of Hydrogen spectrum comes in ------- range

(a) U.V. range (b) visible range
(c) Infra-red range (d) microwave
19. Anode ray

(a) Are produced from anode
(b) Are negatively charged
(c) Have constant e/m ratio of particles
(d) May be beams of He+ ions
20. Which ions has the maximum magnetic moment?

(a) Mn3+ (b) Cu2+
(c) Fe3+ (d) V3+
LEVEL 2
1. Electron are emitted with zero velocity from the surface of metal when it is exposed to
radiation of wavelength 800 A, threshold frequency  will be
(a) 2.48  1018 sec–1 (b) 11  1019 sec–1
(c) 4.4  1014 sec–1 (d) None
2. The wave no. of longest wavelength transition in Balmer series of atomic hydrogen
(a) 1011 m–1 (b) 1.529  109 m–1
(c) 1021 m–1 (d) 1.523  106 m–1
3. The transition in hydrogen spectrum which have the same wavelength on the Balmer
transition n = 4 to n = 2 of He+ spectrum.
(a) 2 1 (b) 3  1
(c) 4  1 (d) 5  1
4. The no. of photon of light with a wavelength 400 pm that provides 1 1014 Joule, will be
(a) 16 (b) 17
(c) 18 (d) 20
5. If the shortest wavelength of H atom in Lyman series is x, then longest wave length in
Balmer series of He+ is:
9x 36x
(a) (b)
5 5
x 5x
(c) (d)
4 9
6. De Broglie wavelength of a proton moving with velocity of 2  108 cm/sec will

(a) 1.98  10–13 m (b) 1.98  10–12 m
(c) 1.98  10–11 m (d) 1.98  10–10 m
7. If  o is the threshold wavelength of photoelectric emission,  is the wavelength of light

falling on the surface of metal and m is the mass of electron then velocity of ejected
electrons is given by
1/ 2 1/ 2
 2h   2hc
(a)   o    (b)   o   
m   m 
1/ 2 1/ 2
 2hc  o      2h  1 1 
(c)    (d)    
 m  o     m  o   
8. The energy required for the process He+(g)  He+2(g) + e will be (Give the ionisation
energy for the H - atom in the ground state is 2.1810-19 J/ atom)
(a) 4.34  10–19 Joule (b) 8.68  10–19 Joule
(c) 13.02  10–19 Joule (d) 16.36  10–19Joule
9. The energy of the electron in second Bohr’s orbit in the hydrogen atom is – 3.41 eV. The
energy of the electron in second Bohr’s orbit of He+ ion would be:
(a) – 85 Ev (b) – 13.62 eV
(c) –1.70 eV (d) –6.82 eV
10. Wavelength of a photon is 2.2 × 10–11 m. The momentum of photon is:

(a) 3.3 × 10–23 kgms–1 (b) 3.3 × 1022 kgms–1
(c) 1.452 × 10–44 kgms–1 (d) 6.89 ×1043kgms–1
11. The wavelength of a moving body of max weight 0.1 mg is 3.310-29 m. The kinetic
energy of the body would be
(a) 2  10–6 J (b) 1  10–3 J
(c) 4  10–3 J (d) 2  10–3 J
12. A certain metal when irradiated by light (  3.2  1016 Hz) emits photons with twice
K.E. as did photoelectrons when the same metal is irradiated by light (  2  1016 Hz).
The  o of the metal is
(a) 1.2  1014 Hz (b) 8  1015 Hz
(c) 1.2  1016 Hz (d) 4  1012 Hz
13. The electron identified by quantum numbers n and (i) n = 4 , = 1, (ii) n = 4,

= 0, (iii) n = 3, = 0 (iv) n = 3, = 1, can be placed in order of increasing energy from
lowest to highest.
(a) (iii)  (iv)  (ii)  (i) (b) (ii)  (iv)  (i)  (ii)
(c) (i)  (iii)  (ii)  (iv) (d) (iii)  (i)  (iv)  (ii)
14. In the emission line spectra of hydrogen atom, how many lines can be accounted for by
all possible electronic transition from 5th energy levels within the atom?
(a) 4 (b) 5
(c) 10 (d) 20
15. The wave number of EM radiation emitted during the transition of electron in between
two levels of Li2+ ion whose principal quantum numbers sum is 4 and difference is 2 is:
16. An electron in a hydrogen atom in its ground state absorbs 1.50 times as much energy as
the minimum required for its escape from the atom. What is the wavelength of the
emitted electron?
(a) 4.7Å (b) 4.7 nm
(c) 9.4Å (d) 9.40 nm
17. The radii of two of the first four Bohr’s orbits of hydrogen atom are in ratio 1:4. The
energy difference between them may be
(a) Either 12.09 eV or 3.4 eV
(b) Either 2.55 eV or 10.2 eV
(c) Either 13.6 eV or 3.4 eV
(d) Either 3.4 eV or 0.85 eV
18. The wave number of EM radiation emitted during the transition of electron in between
two levels of Li2+ ion whose principal quantum numbers sum is 4 and difference is 2 is:
(a) 3.5 RH (b) 4 RH
8
(c) 8 RH (d) RH
9
19. H, D and He+ are all one electron species. The wavelengths of radiations emitted for their
downward transitions from 1st excited state to ground state are 1, 2 and 3 respectively.
Then approximately:
(a) 41 = 22 = 23 (b) 1 = 22 = 2 2 3
(c) 1 = 2 = 23 (d) 1 = 2= 43
20. The radius of Bohr’s first orbit in H atom is 0.053 nm. The radius of second orbit in He+
would be:
(a) 0.0265 nm (b) 0.530 nm
(c) 0.1060 nm (d) 0.2120 nm
ANSWER KEY: LEVEL: 1

1. C 2. A 3. A 4. A 5. A
6. B 7. D 8. C 9. A 10. B
11. D 12. C 13. A 14. A 15. D
16. B 17. A 18. B 19. A 20. C
ANSWER KEY: LEVEL: 2

1. D 2. A 3. A 4. D 5. A
6. A 7. C 8. B 9. B 10. A
11. A 12. B 13. A 14. C 15. C
16. A 17. B 18. C 19. D 20. C

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FIITJEE KVPY (QUESTION BANK) CHEMISTRY 1

2. The two electrons present in an orbital are distinguished by

4. The orbital angular momentum of a 4s electron is

6. The probability of finding an electron residing in a px orbital is not zero:

7. The maximum number of electrons possible in sublevel is equal to

8. Which represents an impossible arrangement?

9. Which set of quantum number represents the electron of lowest energy?

10. The orbital diagram in which Aufbau principle is violated is:

11. Which will have 3d54s1 configuration?

13. Maximum magnetic moment for Cu2+

15. Isoelectronic structures among the following structures are:

16. What did Rutherford's Alpha - particle scattering experiment prove?

17. Increasing the intensity of photon, incident on metal surface will

18. Balmer series of Hydrogen spectrum comes in ------- range

19. Anode ray

20. Which ions has the maximum magnetic moment?

6. De Broglie wavelength of a proton moving with velocity of 2  108 cm/sec will

7. If  o is the threshold wavelength of photoelectric emission,  is the wavelength of light

10. Wavelength of a photon is 2.2 × 10–11 m. The momentum of photon is:

13. The electron identified by quantum numbers n and (i) n = 4 , = 1, (ii) n = 4,

ANSWER KEY: LEVEL: 1

ANSWER KEY: LEVEL: 2

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