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9-Chapter-4-Atomic Structure
9-Chapter-4-Atomic Structure
4 Atomic Structure
Introduction
In Chapter 3, we have learnt that atoms and molecules are the fundamental building
blocks of matter. The existence of different kinds of matter is due to different atoms
constituting them. Now the questions arise: (i) What makes the atom of one element different
from the atom of another element? and (ii) Are atoms really in divisible, as proposed by
Dalton, or are there smaller constituents inside the atom? We shall find out the answers to
these questions in this chapter. We will learn about sub-atomic particles and the various
models that have been proposed to explain how these particles are arranged within the atom.
A major challenge before the scientists at the end of the 19th century was to reveal the
structure of the atom as well as to explain its important properties. The elucidation of the
structure of atoms is based on a series of experiments.
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Class IX: Atomic Structure Chemistry
tube, the glass wall opposite to the cathode began to glow with very faint greenish
light. This glow or fluorescent is formed due to the bombardment on the glass by
certain rays which are emitted from the cathode-surface and move towards the anode
with tremendous velocity. These rays are called cathode rays. Irrespective of the
nature of the cathode or residual gas inside the discharge tube, the following
properties of cathode rays are recorded.
i) They travel in straight lines perpendicular to the cathode surface.
ii) They are deflected from their original straight line path by the application of both
electric and magnetic fields and the direction of deflection indicates that they consist
of negatively charged particles.
iii) They cast a sharp shadow when an opaque object is placed in their path.
iv) They produce a mechanical motion on small and very light paddle wheel when it is
placed in the path of cathode rays. This confirms the presence of material particles in
cathode rays.
v) These rays affect a photographic plate
vi) Metal foils are heated to white hot when bombarded by cathode rays.
vii) They emit fluorescent radiation when they are allowed to fall on glass wall coated
with zinc sulphide or barium platinocyanide.
viii) They can penetrate very thin metal sheet and ionise air or any gas through which they
pass. The properties of cathode rays and their behaviour in electric and magnetic
fields, prove that cathode rays are made up of fast moving tiny material particles
charged with negative electricity. These particles are called electrons:
a) Charge on electron : R.A. Milliken in 1913 determined the charge on an electron
by his classical oil drop experiment and found the value to be 1.6022 × 10–19 coulomb
or 4.8 × 10–10 e.s.u.
No fundamental particle is known which contains charge less than this. This is the
minimum value of negative charge. The quantity of electricity carried by all
negatively charged ions is multiple of this value. That is why the numerical magnitude
of electronic charge represents the fundamental unit of electricity.
b) Mass of an electron is 9.109 × 10–28 g.
One gram atom of hydrogen weighs 1.008 g.
1.008
∴ mass of one hydrogen atom = = 1.673 × 10−24 g.
6.023×1023
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Class IX: Atomic Structure Chemistry
3. Discovery of Neutrons
J. Chadwick was successful in discovering a new fundamental particle by bombarding
beryllium with fast moving alpha particles. In 1932 he concluded that the radiation
consisted of particles of mass nearly equal to that of the proton and with no net charge.
This particle was identified as neutron, the existence of which was predicted earlier by
Rutherford. Rutherford after his α-particle scattering experiment concluded that mass of
an atom is more than the sum of protons and electrons which proves the existence of a
third particle in the atom. The bombardment of the nuclei of light metals (Be, B etc.) with
alpha particles may be expressed as follows :
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4Be + 2He4 → 6C
12
+ 0n1
10
5B + 2He4 → 7N
13
+ 0n1
Properties of Neutron:
i) Since the neutron carries no electrical charge, its penetrating power is more than that of
electron and proton.
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Class IX: Atomic Structure Chemistry
ii) Except hydrogen atom, all atoms contain neutron, hence neutron is also a
fundamental particle of matter.
iii) The mass of neutron is 1.00893 a.m.u. (on the physical atomic weight scale) or 1.675
× 10–24 g.
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Class IX: Atomic Structure Chemistry
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Class IX: Atomic Structure Chemistry
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Class IX: Atomic Structure Chemistry
(vi) The emission or absorption of energy in the form of radiation can only occur when an
electron jumps from one stationary orbit to another.
∆E = Ehigh –Elow = ℎ𝜈
A Brief Introduction to Quantum numbers
The concept of quantum number was first introduced by Bohr, where it was postulated that
while an electron moves in a circular orbit, its angular momentum becomes an integral
ℎ ℎ
multiple of i.e., angular momentum mvr = n × , where n = principle quantum number
2𝜋 2𝜋
which indicates the energy state of an electron.
Normally the term quantum number is used to indicate the various energy levels or orbits of
an atom. They also denote the region of space or orbitals where the electron is likely to be
found. Each electron in an atom is confined to its own orbital.
Bohr’s model predicts only one quantum number (n), but the quantum mechanical model of
atom introduces three more quantum numbers.
1. The principal quantum number (n): This indicates the size of the atom and the
distance of the electron from the nucleus and also the energy of the electrons.
2. Azimuthal quantum number (l): This gives the shape of the orbital in which electron
is present.
3. Magnetic quantum number (m): Indicates the orientation of the electronic orbit in
space under the influence of magnetic field.
4. Spin quantum number (s): This indicates the spin of the electron while moving about
its axis either clockwise or anticlockwise.
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Class IX: Atomic Structure Chemistry
numbers. For example, hydrogen has three isotopes, protium (H), deuterium (D) and
tritium (T). All the three isotopes have atomic number 1. However, their mass numbers
are 1, 2 and 3 respectively. The isotopes of other elements do not have special names,
they are indicated by giving mass number value on the symbol. Mass number and atomic
number of an element are generally indicated as shown below :
Thus, three isotopes of hydrogen can be represented as 11𝐻 , 21𝐻 and 31𝐻
Similarly, the three isotopes of carbon are represented as 126𝐶 , 131𝐶 and 146𝐶
It may be mentioned here that atoms of different elements may have same mass number.
The atoms of different elements which have same mass number are called isobars. For
example, 146𝐶 and 147𝑁 are isobars.
Sometimes atoms of different elements contain same number of neutrons. Such atoms
are known as isotone. Thus, isotones may be defined as the atoms of different elements
containing same number of neutrons. For example, 136𝐶 and 147𝑁. For isotones, the
difference of mass number and atomic number is same.
Isotopes are the atoms of same element whereas isobars and isotones are atoms of
different elements.
Calculation of Number of Electrons, Protons and Neutrons
From the knowledge of atomic number and mass number of an element it is possible to
calculate number of electrons, protons and neutrons in an atom of the element. For
example, atomic number and mass number of aluminium are 13 and 27 respectively.
Number of electrons, protons and neutrons in an atom of it can be calculated as under:
Number of protons = Atomic number = 13
Number of electrons = Atomic number = 13
Number of neutrons = Mass number – Atomic number = 27 – 13 = 14.
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Class IX: Atomic Structure Chemistry
REVISION EXERCISE
LEVEL - I
10. The number of protons, neutrons and electrons in particles A to E are given below :
Electrons Protons Neutrons Electrons
A 17 18 17
B 3 4 2
C 18 22 18
D 17 20 17
E 9 10 10
Giving reasons, find a pair of isotopes from the above particles.
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Class IX: Atomic Structure Chemistry
11. The atomic species A and B have different number of protons but the same number
of nucleons. On the other hand, the atomic species X and Y have the same number of
protons but different number of nucleons. Which pair is an example of isobars? Why?
12. An atom of an element X may be written as 49𝑋 .
(a) What is the number of protons in atom X?
(b) What is the number of neutrons in atom X?
(c) What is the number of electrons in atom X?
(d) How many electrons are there in the outermost shell of an atom of element X?
(f) Write the symbol of ion formed by an atom of element X.
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13. Bromine occurs in nature mainly in the form of two isotopes 35 𝐵𝑟 and 81 35𝐵𝑟 If the
79 81
abundance of 35𝐵𝑟 isotope is 49.7% and that of 35𝐵𝑟 isotope is 50.3%, calculate the
average atomic mass of bromine.
14. Describe the Rutherford’s model of an atom. State one drawback of Rutherford’s
model of the atom.
15. The mass number of an element is 23 and it contains 11 electrons. What is the number
of protons and neutrons in it? What is the atomic number of the element?
LEVEL –II
1. The statement that no two electrons can have same set of four quantum numbers
is called _____________.
2. Size of the orbital is determined by _____________ quantum number.
3. The angular momentum of the electron, according to Bohr’s model, is whole
number multiple of _____________.
4. The shape of orbital is determined by _____________ quantum number.
5. Write down the values of azimuthal quantum number possible for electron present
in 3rd shell.
6. How many orbitals are present in p-subshell?
7. Write down the conclusion made from α -scattering experiment and the defects of
the Rutherford model of atom.
8. (a) Write the two limitations of Bohr’s model.
(b) Name the various sub-shells associated with (i) n = 4, l = 2, (ii) n = 3, l = 1.
(c) Arrange the sub-shells in 3rd shell in the order of increasing energy incase of
(i) Hydrogen atom and (ii) iron atom.
9. Define an orbital.
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Class IX: Atomic Structure Chemistry
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Class IX: Atomic Structure Chemistry
ADDITIONAL EXERCISE
1. A radioactive element 90R232 emits one alpha (α) particle and then two beta (β)
particles. The daughter element will have
(A)Atomic no 90, Mass No. 228 (B)Atomic no. 90, Mass no. 232
(C)Atomic no. 88, Mass No. 228 (D)Atomic no. 88, Mass no. 232
2. The last electron of the element of atomic member 31will have the following
quantum numbers
n l m s
(A) 3 0 0 –1/2
(B) 3 1 1 +1/2
(C) 4 1 –1 –1/2
(D) 4 0 0 +1/2
3. In photoelectric effect, the maximum kinetic energy (EK) of photoelectrons depends
on frequency (f) of light incident on a metal surface of work function (ϕ). In an
experiment f is varied and EK is measured, To determine value for plank’s constant
(h)
(A) Plot EK against ϕ and find intercept of best fitted line.
(B) Plot EK against f and find slope of line of best fit.
(C) Plot EK against ϕ and find slope of line of best fit.
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Class IX: Atomic Structure Chemistry
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Class IX: Atomic Structure Chemistry
ANSWERS
MULTIPLE CHOICE QUESTIONS
1. b 2. c 3. d 4. a 5. c
6. c 7. d 8. a 9. a 10. c
11. c 12. b 13. d 14. c 15. c
16. c 17. a 18. c 19. b 20. b
21. b 22. c 23. c 24. c 25. a
ADDITIONAL EXERCISE
1. A 2. C 3. B 4. D 5. A
6. C 7. B 8. D 9. C 10. B
11. A 12. B 13. B 14. B 15. D
16. C 17. A 18. D 19. B 20. B
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