TEAM ANUOLUWA

TEAM ANUOLUWA
.
..
maki
ngadi
sti
nctdi
fference.
08160860820

CHM 101QUESTI
ONSANDANSWERS

1.Thevar
iabi
li
tyi
ner
ror
sinas
etofmeas
urement
,whi
chi
s

us
ual
lyes
timat
edbyl
eas
tsquar
emet
hodi
scal
led

A.Per
sonaler
ror

B.I
ndet
ermi
nat
eer
ror

C.Oper
ati
veer
ror

D.Rel
ati
veer
ror

Ans
wer:B

2.Whi
choft
het
ypesofer
ror
sisbes
tdes
cri
bedast
he

r
epr
oduc
ibi
li
tyofmeas
urement
s?

A.Rel
ati
veac
cur
acy

B.Pr
obabl
eer
ror

C.Pr
eci
sion

D.Aver
agedevi
ati
on

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maki
ngadi
sti
nctdi
ff
erence.
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Ans
wer:C

G
3.I
fZ= ,t
hemaxi
mum er
rori
nZi
sbes
texpr
ess
edas
Y

A.Ez=
( EG EY
+
G Y )
B.Ez=Z
( EA EB
+
A B )
C.Ez=Z
( -
A B )
EA EB

D.Ez=Z
( EG EY
+
G Y )
Ans
wer:D

4.Gi
vent
hes
ummat
i 05(
onY=1. 02)+4.
±0. 10( 03)
±0. -1.
97(±0.
05)
,

t
heabs
olut
eer
rorandper
cent
ager
elat
iveer
rori
nthe

meas
urementi
s

A.0.
06and1.
89%

B.0.
05and1.
87%

C.0.
06and1.
87%

D.0.
05and1.
89%

Ans
wer:A

5.As
olut
ionof0.
5mol
dm-
3NaOHwast
itr
atedagai
nst0.
2mol
dm-
3

.
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maki
ngadi
sti
nctdi
ff
erence.
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H2SO4i
nthebur
ett
eus
ingphenol
pht
hal
einasi
ndi
cat
or.The

r
esul
tsobt
ainedar
e:

3
I
nit
ialBur
ett
ereadi
ng=2.
98±0.
05c
m

3
Fi
nalBur
ett
ereadi
ng=38.
75±0.
05c
m wher
e±0.
05i
sthe

maxi
mum er
ror
s

Det
ermi
net
heabs
olut
eer
rorandr
elat
iveer
rori
nppt
.oft
he

meas
urement
s.

A.±0.
20,2.
8‰

B.±0.
20,3.
8‰

C.±0.
10,4.
8‰

D.±0.
10,2.
8‰

Ans
wer:D

6.Whi
choft
hef
oll
owi
ngi
s/ar
etr
ue? I
.Number
s1-
9ar
e

s
igni
fic
ant I
I.0di
giti
smos
tti
mes I
II.Zer
osbef
oref
igur
esar
e

nots
igni
fic
ant I
V.Zer
osaf
terdec
imalar
esi
gni
fic
ant

A.I
,II
,II
I

B.I
,II
I,I
V

C.I
,IV

D.I
II,I
V

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ngadi
sti
nctdi
ff
erence.
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Ans
wer:B

3
22.
1dm x751.2mmHg
7.Eval
uat
eV=
760mmHg

3
A.76.
20dm

3
B.76.
2dm

3
C.76dm

3
D.76.
2072dm

Ans
wer:B

8.Ther
elat
ions
hipbet
weent
hes
ubs
tanc
esunder
goi
ngc
hemi
cal

r
eac
tionsi
sknownas

A.Chemi
calFor
mul
a

B.Mol
ecul
arf
ormul
a

C.St
oic
hiomet
ry

D.Mas
sSpec
tromet
ry

Ans
wer:C

9.Thegener
alf
ormul
aforbal
anc
ingor
gani
cchemi
calr
eac
tionsi
s

wr
itt
enas
:

y
A.CxHy+yO2→ xCO2+ H2O
2

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erence.
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B.CxHy+
() x+y
4
y
O2→ xCO2+ H2O
2

() y y
C.CxHy+ x+ O2→ xCO2+ H2O
4 2

D.CxHy+
() x-
y
4
y
O2→ xCO2+ H2O
2

Ans
wer:C

10.Empi
ric
alf
ormul
aisbes
tdef
inedas

A.Thes
impl
estf
ormul
athats
howst
henumberofat
omsofa

c
ompound

B.Thes
impl
estf
ormul
athats
howst
henumberofat
omsof

eac
hel
ementi
nonei
onofac
ompound

C.Thes
impl
estf
ormul
athats
howst
henumberofat
omsof

eac
hel
ementi
nonemol
ecul
eofac
ompound

D.Thes
impl
estf
ormul
athats
howst
heac
tualc
ompos
iti
onof

amol
ecul
eofac
ompound

Ans
wer:C

11.Mol
ecul
arf
ormul
aisbes
tdef
inedas

A.Thef
ormul
athats
howst
henumberofat
omsofa

c
ompound

B.Thef
ormul
athats
howst
henumberofat
omsofeac
h

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sti
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ff
erence.
TEAM ANUOLUWA

el
ementi
nonei
onofac
ompound

C.Thef
ormul
athats
howst
henumberofat
omsofeac
h

el
ementi
nonemol
ecul
eofac
ompound

D.Thef
ormul
athats
howst
heac
tualc
ompos
iti
onofa

mol
ecul
eofac
ompound

Ans
wer:D

12.6gofmet
alM r
eac
tsc
ompl
etel
ywi
th23.
66gofc
hlor
inet
ofor
m

29.
66goft
hemet
all
icc
hlor
ide.Fi
ndt
heempi
ric
alf
ormul
aoft
he

met
all
icf
luor
ide

A.MCl

B.MCl
3

C.MCl
4

D.MCl
2

Ans
wer
:B

13.Theequi
val
enc
eof1mol
eofanygasats
.t.
p.i
s

A.22.
4cm3

B.22400dm3

0224m3
C.0.

24m3
D.2.

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ngadi
sti
nctdi
ff
erence.
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Ans
wer:C

14.How manymol
esofat
omsofoxygenar
ether
ein0.
3mol
eofSO2?

A.0.
3mol
e

B.0.
6mol
e

C.0.
9mol
e

D.1.
2mol
e

Ans
wer:B

15.How manyat
omsofoxygenar
ether
ein10gofH2SO4?

47x1023
A.2.

46x1023
B.2.

45x1023
C.2.

44x1023
D.2.

Ans
wer:B

16.Whati
sthenumberofc
opperat
omsi
na1nai
rac
oinwhi
ch

wei
ghs7.
39g,as
sumet
hemat
eri
alf
rom t
hec
oini
smadei
s

c
ont
ains86% c
opper

02x1023
A.6.

02x1022
B.6.

02x1021
C.6.

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erence.
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2x1023
D.6.

Ans
wer:B

17.Whati
sthemas
sofoxygenO2neededt
obur
n4.
6gofNai
nthe

r
eac
tionbel
ow?

4Na+O2 → 2Na2O

A.1.
3g

B.1.
6g

C.1.
5g

D.1.
4g

Ans
wer:B

18.How manymol
esofNH3ar
ether
ein500c
m3oft
hegas
?

A.0.
02mol

B.0.
2mol

C.0.
002mol

D.2.
00mol

Ans
wer:A

19.Whati
sthemas
singr 45x1023 mol
amsof1. ecul
esofs
ucr
ose

C12H22O11?

A.82.
11g

B.82.
09g

C.82.
08g

D.82.
12g

Ans
wer:C

20.Whatmas
sofCuSO4 wi
llbeobt
ainedbys
tar
tingwi
th10gof

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sti
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ff
erence.
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CuOf
rom t
hef
oll
owi
ngr
eac
tion (
Cu=63.
5g)
?

A.20.
04g

B.20.
05g

C.20.
06g

D.20.
07g

Ans
wer:C

21.Cal
cul
atet
he s
olubi
li
ty ofa s
olut
ion c
ont
aini
ng 6g ofNaCl

{
NaCl=58.
44}i m3ofs
n200c olut
ion

A.1.
531

B.0.
153

C.0.
513

D.1.
153

Ans
wer:C

22.Cal
cul
atet
heamounti
nmol
esandgr
amsofKMnO4 pr
esenti
n

3dm3of0.
250mol

A.1.
23mol&54g

B.0.
75mol&119g

C.0.
25mol&233g

D.0.
135mol&23g

Ans
wer:B

23.A 0.
6025gofs
ampl
eofac
hlor
ides
altwasdi
ssol
vedi
nwat
er

andt
hec
hlor
idepr
eci
pit
atedbyaddi
ngexc
esss
ilverni
trat
e.The

pr
eci
pit
ateofs
ilverni
trat
ewasf
il
ter
ed,was
hed,dr
iedandf
ound

t
owei
ght0.
7134g.Cal
cul
atet
heper
cent
agec
hlor
idei
nthes
ampl
e

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ngadi
sti
nctdi
ff
erence.
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[
Cl=35.
45,Ag=107.
87]

A.22.
95%

B.95.
22%

C.29.
25%

D.25.
29%

Ans
wer:C

24.The s
mal
les
tuni
tofmat
tert
han hast
he pr
oper
tiesofan

el
ementi
scal
led

A.At
om

B.Mol
ecul
e

C.I
on

D.Par
tic
les

Ans
wer:A

25.Thenuc
leusofanat
om c
ont
ribut
est
oit
s..
..
..
..
.whi
leel
ect
rons

c
ont
ribut
est
oit
s..
..
..
..
..
..

A.Mas
s/wei
ght

B.Vol
ume/
Mas
s

C.Mas
s/vol
ume

D.vol
ume/
vol
ume

Ans
wer:C
D
26.Gi
ven an at
omi
cspec
ies
: X,The at
M
omi
cident
ity ofX i
s

det
ermi
nedbyi
ts

A.D

B.M

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ff
erence.
TEAM ANUOLUWA

C.M-
D

D.D-
M

Ans
wer:B

27.I
sot
opesar
e

A.At
omsofs
ameel
ementwi
thdi
ffer
entat
omi
cnumber
s

B.At
omsofs
ameel
ementwi
thdi
ffer
enc
esi
nthei
rnumberof

neut
rons

C.At
omsofdi
ffer
entel
ement
swi
ths
amemas
snumber

D.At
omsofdi
ffer
entel
ement
swi
tht
hes
ameat
omi
cnumber

Ans
wer:B

28.I
sobar
sar
e

A.At
omsofs
ameel
ementwi
tht
hes
amenumberofneut
rons

B.At
omsofs
ameel
ementwi
thdi
ffer
enc
esi
nthei
rnumberof

neut
rons

C.At
omsofdi
ffer
entel
ement
swi
ths
amemas
snumber

D.At
omsofdi
ffer
entel
ement
swi
tht
hes
ameat
omi
cnumber

Ans
wer:C

29.I
sot
onesar
e

A.At
omsofs
ameel
ementwi
tht
hes
amenumberofneut
rons

B.At
omsofs
ameel
ementwi
thdi
ffer
enc
esi
nthei
rnumberof

neut
rons

C.At
omsofdi
ffer
entel
ement
swi
ths
amemas
snumber

D.At
omsofdi
ffer
entel
ement
swi
tht
hes
ameat
omi
cnumber

Ans
wer:A

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nctdi
ff
erence.
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30.Thef
atherofat
omi
ctheor
ywas

A.J
.J
.Thomps
on[
1766–1823]

B.Er
nes
tRut
her
for
d[1911–1934]

C.J
ohnDal
ton[
1766–1844]

D.R.
A.Mi
ll
ikan[
1835-
1927]

Ans
wer:C

31.At
omsar
e..
..
..
.

A.I
ndes
truc
tibl
eandunc
hangeabl
e

B.I
ndes
truc
tibl
eandpr
edi
ctabl
e

C.Thes
mal
les
tpar
tic
leofani
on

D.Al
loft
heabove

Ans
wer:A

32.Whenel
ement
scombi
ne,t
heydos
oin

A.Si
mpl
ewhol
enumberf
rac
tions

B.Mul
ti
plewhol
enumberr
ati
os

C.Si
mpl
ewhol
enumberr
ati
os

D.Mul
ti
plewhol
enumberf
rac
tions

Ans
wer:C

33.At
om oft
hes
amet
woormor
egi
ven el
ement
scan c
ombi
ne

i
ndi
ffer
ent s
ingl
e whol
e number
s r
ati
o t
o f
orm di
ffer
ent

c
ompounds
.Thi
sst
atementi
sbes
tdes
cri
bedas

A.Law ofMas
sAc
tion

B.Law ofVar
iabl
epr
opor
tion

C.Law ofSt
andar
dpr
opor
tion

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sti
nctdi
ff
erence.
TEAM ANUOLUWA

D.Law ofMul
ti
plepr
opor
tion

Ans
wer:D

34.Thepar
amet
erst
hatdes
cri
bet
hedi
str
ibut
ionofel
ect
ronsi
nan

at
om andt
hei
rfundament
alnat
urear
ecal
led

A.ThePr
inc
ipalquant
um number
s

B.TheAzi
mut
halquant
um number
s

C.TheMagnet
icquant
um number
s

D.TheQuant
um number
s

Ans
wer:D

35.Pr
inc
ipalquant
um numberdes
cri
bes

A.Mai
nener
gydi
str
ibut
ion

B.Mai
nener
gys
hel
l

C.Mai
nener
gys
ub-
level

D.Mai
nener
gyor
ient
ati
on

Ans
wer:B

36.Azi
mut
halquant
um numberdes
cri
bes

A.Mai
nener
gydi
str
ibut
ion

B.Mai
nener
gys
hel
l

C.Mai
nener
gys
ub-
level

D.Mai
nener
gyor
ient
ati
on

Ans
wer:C

37.Azi
mut
halquant
um numberi
sot
her
wis
eknownas

A.Subor
dinat
equant
um number

B.Pr
opor
tionalquant
um number

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erence.
TEAM ANUOLUWA

C.Anal
yti
calquant
um number

D.Subs
idi
aryquant
um number

Ans
wer:D

38.Ther
espec
tives
hapesofd,f
,s&p-
orbi
tal
sar
e

A.Dumbbel
l,s
pher
ical
,char
act
eri
sti
c s
hape & doubl
e-

dumbbel
l

B.Spher
ical
,doubl
e-dumbbel
l,dumbbel
l& c
har
act
eri
sti
c

s
hape

C.Dumbbel
l,doubl
e-dumbbel
l,s
pher
ical & c
har
act
eri
sti
c

s
hape

D.Doubl
e-dumbbel
l, c
har
act
eri
sti
c s
hape, s
pher
ical &

dumbbel
l

Ans
wer:D

39.Thenumberofpos
sibl
eor
ient
ati
onsi
na3-
dimens
ionals
pac
e

f
oreac
htypeofor
bit
alc
anbes
tbedes
cri
bedas

A.Spi
nQuant
um number

B.Magnet
icQuant
um number

C.Azi
mut
halquant
um number

D.Pr
inc
ipalquant
um number

Ans
wer:B

40.Thenumberofpos
sibl
eor
ient
ati
onst
hatanel
ect
ronc
anhave

i
nthepr
esenc
eofamagnet
icf
iel
dori
nrel
ati
ont
oanot
heri
sbes
t

bedes
cri
bedas

A.Spi
nQuant
um number

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erence.
TEAM ANUOLUWA

B.Magnet
icQuant
um number

C.Azi
mut
halquant
um number

D.Pr
inc
ipalquant
um number

Ans
wer:A

41.I
fst
udentt
ookar
eadi
ngf
or20.
44% i
nst
eadof20.
34%.c
alc
ulat
e

t
heabs
olut
eer
rorandt
her
elat
iveer
rorr
espec
tivel
y

A.0.
10%,0.
05

B.0.
10%,0.
005

C.1.
0%,0.
005

D.1.
0%,0.
05

Ans
wer:B

42.Themol
arc
onc
ent
rat
ion ofas
olut
ion i
sdet
ermi
nedbyf
our

s
epar
atet
itr
ati
ons
,the r
esul
tsbei
ng 0.
2041,0.
2039.0.
2049 and

0.
2043.c
alc
ulat
ethemean&medi
anoft
hedat
a

A.0.
2042&0.
2044

B.0.
2043&0.
2042

C.0.
2043&0.
2043

D.0.
2043&0.
2041

Ans
wer:B

43.Cal
cul
atet
her
ootmeans
quar
evel
oci
ty(
r.m.
s.
)of1mol
eofCO2

at270C( -1
mm =44gmol )

12x102m/
A.4. s

B.12x102m/
s

2x102m/
C.5. s

.
..
maki
ngadi
sti
nctdi
ff
erence.
TEAM ANUOLUWA

2x102m/
D.1. s

Ans
wer:A

44.I
naf
irs
tor
derr
eac
tion,hal
foft
her
eac
tanti
sdec
ompos
edi
n

300s
econds
.Thet
imet or2/
akenf 3oft
her
eac
tantt
obedec
ompos
ed

i
s…………….
.

A.198.
84s
ec

B.475.
49s
ec

54x10-3s
C.2. ec

D.4.
75s
ec

Ans
wer:B

45.Ther
atec
ons
tantf
ort
hef
irs
tor
derr
eac
tionat500Ci
stwi
ce

hatat300C.t
t heac
tivat
ionener
gy(
Ea)oft
her
eac
tioni
s……………….
-1
(
R=8.
314J
mol )

A.178KJ

B.187KJ

C.188KJ

D.177KJ

Ans
wer:C

46.Addi
ti
onofc
atal
ystt
oar
eac
tionatapar
tic
ulart
emper
atur
e

……….
ther
ateofr
eac
tionby…………….
theac
tivat
ionener
gy

A.i
ncr
eas
e,l
ower
ing

B.dec
reas
ing,l
ower
ing

C.i
ncr
eas
e,i
ncr
eas
ing

D.dec
reas
ing,i
ncr
eas
ing

.
..
maki
ngadi
sti
nctdi
ff
erence.
TEAM ANUOLUWA

Ans
wer:A

47.The el
ect
roni
cconf
igur
ati
on ofpot
ass
ium wi
tht
he at
omi
c

number19i
s……………
2 2 6 2 6
A.1s2s2p3s3p
2 2 6 2 6 1
B.1s2s2p3s3p4s
2 2 6 9
C.1s2s2p3d
2 2 6 2 4 1
D.1s2s2p3s3p3d

Answer:B

48.………….
ions
/mol
ecul
esar
eal
waysl
argert
hant
heat
omsf
rom

whi
cht
heyar
efor
med

A.neut
ral

B.pos
iti
ve

C.negat
ive

D.none

Ans
wer:C

49.Theval
ueofm1whe
nl=2i
s

A.+2,+1,0,-
1,-
2

B.+2,+1,0

C.+2,+1,0,-
1

D.-
2,-
1,0

Ans
wer:A

50.………….
isas
ubs
tanc
ewhi
chac
cept
sal
onepai
rofel
ect
ronsi
n

f
ormi
ngac
o-or
dinat
ebond

A.bas
e

.
..
maki
ngadi
sti
nctdi
ff
erence.
TEAM ANUOLUWA

B.ac
id

C.s
alt

D.pr
oton

Ans
wer:B

51.……….
isanexampl
eofLewi
sbas
e

A.NH3

B.H+

C.SO3

D.He

Ans
wer:B

52.………… i
sanexampl
eofamonopr
oti
cac
id

A.CH3COOH

B.H2SO4

C.H2C2O4

D.H3PO4

Answer:A

53.Fi
ndt
hepOHof0. dm-hydr
1mol ochl
ori
cac
id

A.1

B.12

C.13

D.8

Ans
wer:C

54.A0.
453gs
ampl
eofal
iqui
dcons
ist
ingC,HandOwasbur
nedi
n

pur
eoxygenand1.
039gofCO2 and0.
6369ofH2O wer
eobt
ained.

.
..
maki
ngadi
sti
nctdi
ff
erence.
TEAM ANUOLUWA

Whati
stheempi
ric
alf
ormul
aoft
hisc
ompound?[
C=12.
01115,

H=1.
00797,
O=15.
9994]

A.CHO

B.C4H12O

C.C2H6O2

D.C2H6O2

Ans
wer:B

55.Ar
educ
ingagentdoes

A.ac
cept
sel
ect
rons

B.donat
esal
onepai
rofel
ect
rons

C.donat
esel
ect
rons

D.donat
esandac
cept
satt
hes
amet
ime

Ans
wer:C

56.How manymol
esofoxygenat
om ar
ecombi
nedwi
th4.
20mol
es

ofClat
omsi
nCl
2O7?

A.4.
20

B.42.
00

C.17.
40

D.14.
70

Ans
wer:D

57.Whati
sthepH ofas
olut
iont
hati
s0.
5mol
/dm3 i
nac
eti
cac
id

(
CH3COOH)adn2.
5mol
/dm3 i
nsodi
um ac
etat
e(CH3COONa)
,Kaof

ac
eti
cac
idi 75x10-3
s1.

.
..
maki
ngadi
sti
nctdi
ff
erence.
TEAM ANUOLUWA

A.5.
23

B.4.
12

C.5.
44

D.3.
50

Ans
wer:D

58.Kp=Kcwhenandonl
ywhenΔni
s

A.<1

B.>1

C.Zer
o

D.>1

Ans
wer:C

59.Theoxi
dat
ionnumberof‘
B’i
nthec
ompoundE2BK3i
s…….[
E=

+1;K=-
2]

A.+3

B.+2

C.+4

D.-
2

Ans
wer:C

60.Thef
oll
owi
ngpr
inc
ipl
esar
eappl
icabl
etowr
iti
ngel
ect
roni
c

c
onf
igur
ati
onsexc
ept

.
..
maki
ngadi
sti
nctdi
ff
erence.
TEAM ANUOLUWA

A.Hundi
’spr
inc
ipl
e

B.Auf
baupr
inc
ipl
e

C.Paul
i’
spr
inc
ipl
e

D.Hund’
spr
inc
ipl
e

Ans
wer:A

61.Thepr
oces
sofbui
ldi
ngat
omsf
rom t
hegr
oundl
evel
,pl
aci
ng

t
hef
irs
tel
ect
ronatt
hel
owes
tpot
ent
ialener
gyi
sknownas

A.Hundi
’spr
inc
ipl
e

B.Auf
baupr
inc
ipl
e

C.Paul
i’
spr
inc
ipl
e

D.Hund’
spr
inc
ipl
e

Ans
wer:B

62.Theel
ect
roni
cconf
igur
ati
onofoxygeni
s

2 2 2 1 1
A.1s 2s 2px 2py 2pz

2 2 2 2
B.1s 2s 2p 4d

2 2 2 2
C.1s 2s 3p 4d

2 2 1 1 1
D.1s 2s 2px 2py 2pz

Ans
wer:A

.
..
maki
ngadi
sti
nctdi
ff
erence.
TEAM ANUOLUWA

63.Thei
deaofar
rangi
ngel
ect
ronsi
ntogener
atedor
bit
alsoneby

onebef
orepai
ringi
sknownas

A.Hundi
’spr
inc
ipl
e

B.Auf
baupr
inc
ipl
e

C.Paul
i’
spr
inc
ipl
e

D.Hund’
spr
inc
ipl
e

Ans
wer:D

64.Thes
tat
ement“
Elec
tronst
otheoppos
ites
pinc
anoc
cupyt
he

s
ameor
bit
al”i
sbes
tdes
cri
bedas

A.Hundi
’spr
inc
ipl
e

B.Auf
baupr
inc
ipl
e

C.Paul
i’
spr
inc
ipl
e

D.Hund’
spr
inc
ipl
e

Ans
wer:C

65.Thes
tat
eofequi
li
bri
um i
sli
mit
edt
ochemi
calr
eac
tionsi
n

A.Anopens
yst
em

B.Ar
ever
sibl
esys
tem

C.Ac
los
eds
yst
em

D.Adynami
csys
tem

.
..
maki
ngadi
sti
nctdi
ff
erence.
TEAM ANUOLUWA

Ans
wer:C

66.TheLaw ofMas
sAc
tions
tat
est
hat
:

A.Rat
e∝Conc
ent
rat
ionofr
eac
tion

B.Rat
e∝Conc
ent
rat
ionofpr
oduc
ts

C.Rat
e∝Conc
ent
rat
ion

D.Rat
e∝Conc
ent
rat
ionofr
eac
tant
s

Ans
wer:D

67.Cons
iderahypot
het
icalr
eac
tion:aA+bB→c
C+yY

Whi
choft
hef
oll
owi
ngs
tat
ement
sisc
orr
ect
?

y
A.kf[
C][
c
Y]=kr[
A]a
[B]
b

B.kf[
A]a
[B]
b
=kr[
C][
c
D]
d

y
C.kf[
A]a
[B]
b
=kr[
C][
c
Y]

y
D.kr[
C][
c
Y]=kf[
A]a
[B]
b

Ans
wer:C

68.Fort
her
eac
tion:N2+3H2 ↔ 2NH3,t
heval
ueofkpi
s

2
PNH
A. 3
3
PN PH
2 2

.
..
maki
ngadi
sti
nctdi
ff
erence.
TEAM ANUOLUWA

2
PNH
B. 3
3
PN PH
2

3
PNH
C. 3
2
PN PH
2 2

PNH
D. 3
3

PN PH
2 2

Ans
wer:A

69.Ther
elat
ions
hipbet
weenkpandkci
s

A.kp =kp.
(RT)

(
B.kp =kc.RT)
∆n

(
C.kc=kp.RT)
∆n

(
D.kp =kc.RT)

Ans
wer:B

70.When ∆ni
spos
iti
ve,t
heval
ueofkpi
s

A.Gr
eat
ert
hankc

B.Les
sthankc

C.Equalt
okc

D.Les
sthankcby1

.
..
maki
ngadi
sti
nctdi
ff
erence.
TEAM ANUOLUWA

Ans
wer:A

71.When ∆ni
snegat
ive,t
heval
ueofkpi
s

A.Gr
eat
ert
hankc

B.Les
sthankc

C.Equalt
okc

D.Les
sthankcby1

Ans
wer:B

72.When ∆ni
szer
o,t
heval
ueofkpi
s

A.Gr
eat
ert
hankc

B.Les
sthankc

C.Equalt
okc

D.Les
sthankcby1

Ans
wer:C

73.Fort
her
eac
tion:N2+O2↔2NO,t
heval
ueofkci
s

2
4x
A.
[a-
x][ x]
b-

2
4x
B.
[a-
x][
b+x]

.
..
maki
ngadi
sti
nctdi
ff
erence.
TEAM ANUOLUWA

2
2x
C.
[a-
x][ x]
b-

2
4x
D.
[ [
a+x]b+x]

Ans
wer:A

74.Phos
phor
uspent
achl
ori
dedi
ssoc
iat
esonheat
ingac
cor
dingt
o

t
heequat
ionPCl
5
↔ PCl
3
+Cl
2
.I
fthekcf
ort
her
eac
tioni
s0.
0326
-
3 0
dm ,c
mol alc
ulat
etheval
ueofkpi
nPas
calat191CandR=

8.
314J
/mol
Kis

A.152.
67

B.125.
69

C.125.
76

D.127.
56

Ans
wer:C

75.Fac
tor
saf
fec
tingr
eac
tionsi
nequi
li
bri
um ar
e

A.Cat
alys
t,Li
ght
,Conc
ent
rat
ion,Pr
ess
ure

B.Cat
alys
t,Temper
atur
e,Conc
ent
rat
ion,Pr
ess
ure

C.Cat
alys
t,Li
ght
,Conc
ent
rat
ion,Sur
fac
eAr
ea

D.Cat
alys
t,Sur
fac
eAr
ea,Conc
ent
rat
ion,Pr
ess
ure

Ans
wer:B

.
..
maki
ngadi
sti
nctdi
ff
erence.
TEAM ANUOLUWA

76.Thes
hif
tingoft
heequi
li
bri
um pos
iti
ont
oannult
heef
fec
tof

c
hangest
ore-
est
abl
ishequi
li
bri
um i
ster
med

A.Paul
i’
sExc
lus
ionPr
inc
ipl
e

B.Le-
Chat
eli
erPr
inc
ipl
e

C.Auf
bauPr
inc
ipl
e

D.Exc
lus
ionPr
inc
ipl
e

Ans
wer:B

77.I
nanequi
li
bri
um r
eac
tion,pr
ess
urei
ncr
eas
ewi
llf
avourt
he

s
idewi
th

A.LowerVol
ume

B.Equi
val
entVol
ume

C.Hi
gherVol
ume

D.Vol
ume

Ans
wer:A

78.I
nther
eac
tion:H2+I
2
↔ 2HI
,

A.Pr
ess
urehasnoef
fec
t

B.I
ncr
eas
einpr
ess
urewi
llc
aus
eequi
li
bri
um t
oshi
ftt
othe

r
ight

C.dec
reas
einpr
ess
urewi
llc
aus
eequi
li
bri
um t
oshi
ftt
othe

.
..
maki
ngadi
sti
nctdi
ff
erence.
TEAM ANUOLUWA

r
ight

D.dec
reas
einpr
ess
urewi
llc
aus
eequi
li
bri
um t
oshi
ftt
othe

l
eft

Ans
wer:A

79.I
nther
eac
tion:PCl
5
↔ PCl
3
+Cl
2
,

A.Pr
ess
urehasnoef
fec
t

B.I
ncr
eas
einpr
ess
urewi
llc
aus
eequi
li
bri
um t
oshi
ftt
othe

r
ight

C.dec
reas
einpr
ess
urewi
llc
aus
eequi
li
bri
um t
oshi
ftt
othe

l
eft

D.NoAns
wer

Ans
wer:D

80.I
ncr
eas
eint
hec
onc
ent
rat
ionofpr
oduc
tsi
nar
eac
tionwi
ll

c
aus
etheequi
li
bri
um pos
iti
ont
o

A.Shi
ftt
othel
eft

B.Shi
ftt
other
ight

C.Wi
llhavenoef
fec
t

D.Shi
ftt
obot
hri
ghtandl
eft

Ans
wer:A

.
..
maki
ngadi
sti
nctdi
ff
erence.
TEAM ANUOLUWA

81.Whati
stheef
fec
tofi
ncr
eas
einc
onc
ent
rat
ionont
he

equi
li
bri
um c
ons
tantofar
eac
tion?

A.Theval
ueofequi
li
bri
um c
ons
tanti
ncr
eas
es

B.Theval
ueofequi
li
bri
um c
ons
tantdec
reas
es

C.Theval
ueofequi
li
bri
um c
ons
tantr
emai
nsc
ons
tant

D.Theval
ueofequi
li
bri
um c
ons
tantf
irs
tinc
reas
es,andl
ater

dec
reas
es

Ans
wer:C

82.I
ncr
eas
eint
emper
atur
ewi
ll

A.Favourt
hef
orwar
dreac
tionofanexot
her
micr
eac
tion

B.Favourt
her
ever
ser
eac
tionofanexot
her
micr
eac
tion

C.Favourbot
hfor
war
dandr
ever
ser
eac
tionofan

exot
her
micr
eac
tion

D.Havenoef
fec
t

Ans
wer:B

83.Doest
emper
atur
echangesaf
fec
ttheequi
li
bri
um c
ons
tantofa

r
eac
tion?

A.No,i
tdoes
n’t

B.Yesi
tdoes

.
..
maki
ngadi
sti
nctdi
ff
erence.
TEAM ANUOLUWA

C.Yes
,itdoes
n’t

D.No,i
tdoes

Ans
wer:B

84.Cat
alys
tspeedsupt
her
ateof

A.For
war
dreac
tion

B.Rever
ser
eac
tion

C.Bot
hfor
war
dandr
ever
ser
eac
tion

D.Al
lreac
tions

Ans
wer:C

85.Cat
alys
tspeedsupt
her
ateof

A.For
war
dreac
tion

B.Rever
ser
eac
tion

C.Bot
hfor
war
dandr
ever
ser
eac
tion

D.Al
lreac
tions

Ans
wer:C

86.Cat
alys
t..
..
..
..
..
..
..
..
..
.ther
ateofr
eac
tionby.
..
..
..
..
..
..
..
..
..t
he

ac
tivat
ionener
gy

A.dec
reas
es/
rai
sing

.
..
maki
ngadi
sti
nctdi
ff
erence.
TEAM ANUOLUWA

B.dec
reas
es/
lower
ing

C.i
ncr
eas
es/
rai
sing

D.i
ncr
eas
es/
lower
ing

Ans
wer:D

87.Cal
cul
atet
hes
olubi
li
tyi
ngdm-
3at298Kofc
alc
ium f
luor
ide

(
CaF2)i
na0.
1M NaFs
olut
ion.

[K =3.9x10 moldm ,Ca=40,F=19g]

s
p
14 3 -
9

-
9 -
3
A.3.
04x10 gdm

-
10 -
3
B.3.
04x10 gdm

-
8 -
3
C.3.
04x10 gdm

-
7 -
3
D.3.
04x10 gdm

Ans
wer:A

88.Ther
educ
ingandoxi
dizi
ngagent
sres
pec
tivel
yint
her
eac
tion

Fe2O3+3CO → 2Fe+3CO2ar
e

A.Fe2O3andCO

B.FeandCO

C.COandFe2O3

D.CO2andNH3

.
..
maki
ngadi
sti
nctdi
ff
erence.
TEAM ANUOLUWA

Ans
wer:C

89.Theoxi
dat
ionnumber
sofhydr
ogenandoxygenar
e

r
espec
tivel
y+1and-
2exc
epti
n

A.Per
oxi
desandHal
ogens

B.Per
oxi
desandMet
all
icHal
ides

C.Met
all
ichydr
idesandper
oxi
des

D.Per
oxi
des

Ans
wer:C

- 2+ + 2+ 3+
90.I
nther
eac
tionMnO4 +Fe +H → Mn +Fe ,t
heoxi
dat
ion

numberofmanganes
echangesf
rom

A.+5t
o+2

B.+7t
o+2

C.+2t
o+3

D.+6t
o+2

Ans
wer:B

91.Tobal
anc
ear
edoxr
eac
tioni
nbas
icmedi
um,H2Oi
saddedt
o

t
hes
idewi
th

A.Les
sernumberofoxygenat
oms

B.Les
sernumberofhydr
ogenat
oms

.
..
maki
ngadi
sti
nctdi
ff
erence.
TEAM ANUOLUWA

C.Mor
eoxygenat
oms

D.Equi
val
entnumberofoxygenat
oms

Ans
wer:C

92.Theval
uesofw,xandgi
nther
edoxr
eac
tion:
- 3+ - - 2-
O3 +wCr +xOH → zI+2Cr
I O4 +5H2Oi
s

A.2,
10,1

B.2,
1,10

C.10,
1,2

D.10,
2,1

Ans
wer:A

93.Ar
eac
tioni
nwhi
cht
hes
ames
ubs
tanc
eont
her
eac
tants
idei
s

bei
ngoxi
dizedandr
educ
eds
imul
taneous
lyi
sknownas

A.Combus
tionr
eac
tion

B.Addi
ti
onr
eac
tion

C.Di
spr
opor
nat
ionr
eac
tion

D.Subs
tit
uti
onr
eac
tion

Ans
wer:C

94.Subs
tanc
est
hatdi
ssol
vei
nwat
ert
orel
eas
ehydr
oxoni
um i
oni
s

knownas

.
..
maki
ngadi
sti
nctdi
ff
erence.
TEAM ANUOLUWA

A.Bas
e

B.Sal
t

C.Lewi
sBas
e

D.Ac
id

Ans
wer:D

95.As
ubs
tanc
ethati
oni
zesi
nsol
uti
ont
opr
oduc
ehydr
oxyli
oni
s

A.Bas
e

B.Sal
t

C.Ac
id

D.Lewi
sAc
id

Ans
wer:A

96.Thedef
ini
ti
onsofAr
rheni
usemphas
izes.
..
..
..
..
.and.
..
..
..
..
.in

wat
er

- 2+
A.I
O3 & H

- +
B.OH & H

2+ -
C.H & 2OH

3- 3+
D.I
O3 & H

Ans
wer:B

.
..
maki
ngadi
sti
nctdi
ff
erence.
TEAM ANUOLUWA

97.TheAr
rheni
usac
idandbas
eres
pec
tivel
yint
her
eac
tion
+ -
NH3+H2O ↔ NH4 +OH

A.H2O and NH3

B.NH3 and H2O

-
C.OH andH2O

+
D.NH4 andNH3

Ans
wer
:A

98.Thec
onj
ugat
ebas
eandac
idr
espec
tivel
yinques
tion97above

ar
e

A.H2O and NH3

B.NH3 and H2O

-
C.OH andH2O

+
D.NH4 andNH3

Ans
wer
:A

99.Wat
eri
sbes
tdes
cri
bedas

A.Ac
id

B.Bas
e

C.Amphi
prot
ic

.
..
maki
ngadi
sti
nctdi
ff
erence.
TEAM ANUOLUWA

D.Ampi
ter
ic

Ans
wer:C

+ -
100.I
nthedi
ssoc
iat
ionofwat
er:H2O ↔ H +OH,t
heval
ueofkw i
s

[OH][H ]
- +

A.k =
w
[H O]
3

[OH][H ]
- +

B.k =
w
[H O]
2

C.kw =
[H O]
2

[OH][H ]
- +

D.kw =
[H O]3

[OH][H ]
- +

Ans
wer:B

101.Thehydr
ogeni
onc
onc
ent
rat
ionofpur
ewat
eri
s

14
A.1x10

-
14
B.1x10

-
7
C.1x10

7
D.1x10

Ans
wer:C

102.ThepHofpur
ewat
eri
s

A.14
.
..
maki
ngadi
sti
nctdi
ff
erence.
TEAM ANUOLUWA

B.-
14

C.-
7

D.7

Ans
wer:D

103.Whati
sthepHofaneut
rals
olut
ionat250C?

A.14

B.3

C.7

D.1

Ans
wer:C

104.Whati
sthepHofabas
ics
olut
ionwhos
ehydr
oxyli
on

c
onc
ent
rat
ioni
s0.
00001M?

A.9

B.5

C.1

D.4

Ans
wer:A

105.ThepHofa0.
25M s
olut
ionofac
eti
cac
id[
HC2H3O2]i
sfoundt
o

be2.
68.Whati
stheKaf
ort
hiss
olut
ionandwhatper
cent
ageoft
he

.
..
maki
ngadi
sti
nctdi
ff
erence.
TEAM ANUOLUWA

ac
idi
oni
zed?

A.1.
76x10-
5M and 0.
74%

B.1.
76x10-
5M and 0.
84%

C.6.
17x10-
5M and0.
64%

D.6.
71x10-
5M and0.
54%

Ans
wer:B

106.Thec
hangei
nthec
onc
ent
rat
ionofr
eac
tantorpr
oduc
tper

uni
tti
mei
sknownas

A.Rat
eLaw

B.Or
derofar
eac
tion

C.Rat
eofar
eac
tion

D.Mol
ecul
ari
tyofar
eac
tion

Ans
wer:C

107.I
nahypot
het
icalr
eac
tion A → B,t
her
ateoft
her
eac
tioni
s

expr
ess
edas
:

d[A] +d[
B]
A. =
dt dt

-d[A] -d[B]
B. =
dt dt

.
..
maki
ngadi
sti
nctdi
ff
erence.
TEAM ANUOLUWA

±d[
A] +d[
B]
C. =
dt dt

d[
- A] +d[
B]
D. =
dt dt

Ans
wer:D

108.Rat
eofar
eac
tioni
smeas
uredi
n

-
1 -
1
A.moll
itmi
n

-
1 -
3
B.molc
m s
ec

-
3 -
1
C.molc
m s
ec

-
1 -
1
D.molc
m hr

Ans
wer
:A

109.Ther
ateofar
eac
tioni
sdi
rec
tlypr
opor
tionalt
othe

c
onc
ent
rat
ionofr
eac
tant
s.Thi
sisr
efer
redt
oas

A.Or
derofaReac
tion

B.Rat
eofaReac
tion

C.Over
allor
derofaReac
tion

D.Mol
ecul
ari
tyofaReac
tion

Ans
wer:B

110.Thec
orr
ectexpr
ess
ionf
ort
her
ateoft
her
eac
tion:A

.
..
maki
ngadi
sti
nctdi
ff
erence.
TEAM ANUOLUWA

→Pr
oduc
tsi
s

e=[
A.Rat A]n

e=[
B.Rat B]n

e=k[
C.Rat A]n

e∝k[
D.Rat A]n

Ans
wer:C

111.Thec
orr
ectexpr
ess
ionf
ort
her
ateoft
her
eac
tion:2A+B

→Pr
oduc
tsi
s

y
e=k[
A.Rat A]2x
[B]

y
e=[
B.Rat A]x
[B]

y
e∝[
C.Rat A]x
[B]

y
e∝[
D.Rat A]2x
[B]

Ans
wer:C

112.Anexpr
ess
ionwhi
chs
howshow ar
eac
tioni
srel
atedt
o

c
onc
ent
rat
ioni
ster
med

A.Or
derofr
eac
tion

B.Mol
ecul
ari
tyofr
eac
tion

C.Equi
li
bri
um Law

D.Rat
eEquat
ion

.
..
maki
ngadi
sti
nctdi
ff
erence.
TEAM ANUOLUWA

Ans
wer:D

113.Thepower
stowhi
cht
hec
onc
ent
rat
ionofeac
hreac
tanti
s

r
ais
edt
ogi
veac
orr
ectdependenc
eofr
ateonc
onc
ent
rat
ioni
s

t
ermed

A.Or
derofr
eac
tion

B.Mol
ecul
ari
tyofr
eac
tion

C.Equi
li
bri
um Law

D.Rat
eEquat
ion

Ans
wer:D

114.Foragi
venr
eac
tionwhos
erat
eexpr
ess
ioni
sgi
venas
:

e=k[
Rat A]m
[B]
n
,t
heor
derofr
eac
tioni
s

A.m,n

B.m+n

C.m-
n

D.n-
m

Ans
wer:A

115.Thes
um ofal
lexponent
soft
her
eac
tant
sasc
ont
ainedi
nthe

exper
iment
all
ydet
ermi
nedr
atel
aw i
sknownas

A.Over
allr
atel
aw

.
..
maki
ngadi
sti
nctdi
ff
erence.
TEAM ANUOLUWA

B.Over
allmol
ecul
ari
tyofr
eac
tion

C.Over
allor
derofr
eac
tion

D.Over
allequi
li
bri
um l
aw

Ans
wer:C

116.Or
derofagi
venr
eac
tionc
anonl
ybedet
ermi
ned

A.Exper
iment
all
y

B.Fr
om t
heRat
eEquat
ion

C.Fr
om t
heMol
ecuar
ityofr
eac
tion

D.Fr
om t
hec
hemi
calr
eac
tion

Ans
wer:A

117.Thenumberofmol
ecul
es/
ionsoft
her
eac
tant
spr
esenti
nthe

bal
anc
eds
toi
chi
omet
ricequat
ioni
sref
err
edt
oas
:

A.Or
derofr
eac
tion

B.Mol
ecul
ari
tyofr
eac
tion

C.Equi
li
bri
um Law

D.Rat
eEquat
ion

Ans
wer:B

118.Foras
econdor
derr
eac
tionA+B→Pr
oduc
t,t
her
atec
ons
tant

expr
ess
ioni
s

.
..
maki
ngadi
sti
nctdi
ff
erence.
TEAM ANUOLUWA

2.
303 b(
a-x)
A.k2= log10
t a(
b-x)

B.k2=
2.
303
t
log10
()a
a-
x

1 x
C.k2= log10
t a-
x

x
D.k2=
t

Ans
wer
:A

119.Forazer
oor
derr
eac
tionA+B→Pr
oduc
t,t
her
atec
ons
tant

expr
ess
ioni
s

2.
303 b(
a-x)
A.k0= log10
t a(
b-x)

B.k0=
2.
303
t
log10
()a
a-
x

1 x
C.k0= log10
t a-
x

x
D.k0=
t

Ans
wer:D

120.Foraf
irs
tor
derr
eac
tionA+B→Pr
oduc
t,t
her
atec
ons
tant

expr
ess
ioni
s

.
..
maki
ngadi
sti
nctdi
ff
erence.
TEAM ANUOLUWA

2.
303 b(
a-x)
A.k0= log10
t a(
b-x)

B.k0=
2.
303
t
log10
()
a
a-
x

1 x
C.k0= log10
t a-
x

x
D.k0=
t

Ans
wer:B

121.Thehal
f-
li
feofaf
irs
tor
derr
eac
tiondependson

A.I
nit
ialc
onc
ent
rat
ionoft
her
eac
tions

B.Conc
ent
rat
ionoft
her
eac
tantl
eft

C.Conc
ent
rat
ionofpr
oduc
t

D.Rat
econs
tant

Ans
wer:D

122.Thehal
f-
li
feofaf
irs
tor
derr
eac
tiondependson

A.I
nit
ialc
onc
ent
rat
ionoft
her
eac
tant
s

B.Conc
ent
rat
ionoft
her
eac
tantl
eft

C.Conc
ent
rat
ionofpr
oduc
t

D.Rat
econs
tant

.
..
maki
ngadi
sti
nctdi
ff
erence.
TEAM ANUOLUWA

Ans
wer:A

123.Theuni
tofr
atec
ons
tant
,K,i
naf
irs
tor
derr
eac
tioni
s

-
1 -
1
l
A.moli
tres
ec

-
1
B.s
ec

-
1 -
1
C.l
it
remols
ec

-
1 -
1
D.s
ecl
it
re mol

Ans
wer:B

124.Phot
olyt
icr
eac
tionst
akepl
acei
nthepr
esenc
eof

A.Pr
ess
ure

B.Li
ght

C.Cat
alys
t

D.Heat

Ans
wer:B

125.Theuni
tofr
atec
ons
tant
,K,i
naf
irs
tor
derr
eac
tioni
s

-
1 -
1
l
A.moli
tres
ec

-
1
B.s
ec

-
1 -
1
C.l
it
remols
ec

-
1 -
1
D.s
ecl
it
re mol

.
..
maki
ngadi
sti
nctdi
ff
erence.
TEAM ANUOLUWA

Ans
wer:A

BestWi
shes!
!!

.
..
maki
ngadi
sti
nctdi
ff
erence.