6D f EO TAS pectVve OF tne inhwvent MPreveri bilities oF the cycle ever c A r23p0 (eis Fine on | Stote property ¢ =<} ine vev Ag=3-S = 7/69) JJ int yew mal co rile ot Craveryite "powsy) AS: Q qT for an jyeveriwle pro ccuning betuledn two States pin thim by A ever ble tame ond Find £59 nd huni And OF =By clauuis Inequality, » we hove ae Peo C2 fide j 6 2 They JS S Sra + J 00 4a — >.> T > 2750 a 2 89 a Tc z ASayy = i + Sen dgon 20 for on isolated system Fe =o, 5 = 20 > PSui 20) Prince ot ine Casing enaay hence [Sun 2 A Ssys + OSs ZO) Petan = Ss ys Sar SOF Soon 20 for revewibie process 20 fn itvevenible process <© __ tmpossible Se = Sp +2Stqweer Ap gs cod SOME yor” ew P= tonrPa pe IMP Saturated Ka PS ¢ N Dt <— Vapour liga 4 do -Sw= dU Tdi- Pays du dhe AU+PdvVdp >Tdi= dut Pav Tdi dh -Vdy> fot Liquids and solids, Pav=0 Z 1 for idenlggs 27 dt = cud + aay >AL= wh %)+ R “a as= pst -edy 2) WS = cela [Ty Rh) Ay yest P 8%) - S\ = Naat d ee Cov senWo pre System > bs: S9-2 ~ Bln (72) jk . ex (8%) By : exp (572) Fy treme fo 52% Ny Vow KN aa vy SJuy h Shy Ael pressurefos Steodg Fis devices Cinternally sevenide) Q-We DE from fist fav Q-w__= DE = Dre Ok, + Pe D8q -EW = gh deerdle W 1d3 “Oye = Ahe =~ DAah—Vde- duyey ~ Aht Ake +dve 2 dvyeve - vdp wu, = Sude Akero dPao 1f internally yeversble , ke Ond Pe nsote ied Isenhopie effecioneyy Act ke so yn bias ———_— 'sentropretuibics h=ba,s Compresior cont le. NE Work inpar to the Steady fled. —[ydp~ —snis_should be Com piosiol Atgo tive Os Worle i¢ dors on comp, Doreyin = (Vdp = +e‘uM uN ~ Q fy a swe Ce p qo 4 xa lence max _toork req used fy p bec Adiabatic is maximum eh ° _ _\. = ke IN pyOC2>)_ cont nues, I | tha eevelad ve of gas? So #p keep - —__________| 5. i 0 mini pOSsi ble enug, ~ Hence caberconling nN ve sak ft a mo etl LS wala 4 12%, , KE Vi ob Vv _ yy ee zg = °; Rs See e = 2 SPR DScystem = Sian OS, = - | DSsgstein = Sin Sout +Olgen = Se, Na Sysltm “hal iytem ennopy hans 0 Enkopy > haat Horst Steak= SEQ oO Fenster Li» wore Somk-< TT b Moss Fars S=msin Tatalrm Sig Sut +. = OAS, de closed system convolvolum EM 4, + 5 = Mspaten Misi —¥, _ f&- he Te Meso * Sge,= Ed, tend, Mow Ae “eens Ene fis o ‘ Tk > + ane = . Cron ot onailability of Availabe enorgeg — Deod stale = Thermodynamic equililtium eoitlo enyivonment I » sonounds Soundings | __, onviyonrunt Graigy osouated wth kwetic and porertial Wwe oundors wstt tye * ¥ Xe? qe x oie 2 \ f 21 ciated with haat Fes Qe} pron energy arailodse = Wrey "0, Qin Tr — 19 ake \r = \ Qin Uselal worle as W=Wouye = WE P9L\,=¥)Trevewibsitt YS) 1z9 Seeondlyus efecioney Aye wa > yh Wev hiev Clo) Sysseon Gergy = UUs tB(U-Us) —To( $-Se) + v7 ge u-Uo (V=Us) =o ) aan ae Flovs ex0%4 Pe h-ho —tol5-Ss) “My ge Ayan 2.2 Alwar, ordigy is deshoged DX syle * Xgop = © Xgas * ToS gor 2° Trlr alone Kin Xour~ * des = DXspslem . tse Ker Xoue — ike ~ bts ae E (YVR War) “To Sen ha) WwACB) a4 We RAY -Toh = ae 'y — Te dae de Controll Volumnt. $ (1-22) Qe LW" A) Jt Re = im Bi Me BA Te £(1- 12) Q—(W—te dy + Snip. = Erp gs hey he de ae Wey if Yges © bus Wrey Waev = RU, ~ e,)+ s(t) oe Th Badrabatic Woe = oP)