Deber 2: Ejercicios Capitulo 5 viernes, 16 dejulio de2021 15:34 Nombre: Christopher Gavilenes 2 Problem 5.2: A gas is described by the state equation P(V - b) = RT where b is constant. a) Obtain the residual entropy, enthalpy and internal energy as a function of pressure and temperature b) Carbon dioxide undergoes reversible isothermal expansion in a turbine from P. = 20 bar to Ps = 1 bar at aconstant temperature of 300 K. Assuming that CO. is described by the above state equation with b = 44.1 x 10+ m’/mol, calculate AH, AS, the work produced and the amount of heat rejected or absorbed by the gas during the expansion. Un ger whowale por be mann’ Plo WERT BoE c) Wl Se, He, Ua come Popr) 40 le CBE) ie Bie a fp Z 22) [de a ea i He: nfl “Gb fae RIP “f (B48 - RP e P - artbe-eef , = RT +bR-RTUP: ue. pve ves 4ice-4) b) C02) fapaaiot Latbrme raverashle Pas 20dlm, P21 lan , Tedh = sede ) be Wy sn Yoel » Chale AK, AS, W,Q, Tach; Bo Tol Ba J Asua: Rn (d)¢ EH Asaaz o25 tte aces AT © Anao: HE Uf: bP - b= b (4-20): 19-4 y = - 8/3790 bom? 40% ot o1nslT. 46 Bet ata 2 ete 3 all Problem 5.4: Using the volume-temperature relationship for liquid acetone in Example 5,6 calculate the amount of heat and work involved when acetone is compressed isothermally and reversibly from 1 bar, 20 °Cto 10 bar. 5: fatlore Hed « Ure Le rhein’ VT MM fanple 5.6 eemprinaar’ tatters y reaulile Glue Gy us » P24 dans Pre ibn ob 00 BUY ee Vela iasbrarbtadstt) 24° NIT 7 asst tosew Te £12745 PAGE ode 204 yl? ase sere Gb GbE ety 7 2008 12597 KO (A) -veern 3 (&), 2PM AzTASua fof. v oP Pv 4Pi2 dyoos ve? Ko7, 0230392 (40 a] a5 ore PQ = 293, 5° 0/6 35 Thre Vo et e2tus %,Problem 5.8: a) What is the residual volume of saturated liquid water at 1 bar? ) Estimate the residual volume of ethanol vapor at 1 bar and 100 °C. ©) Use the generalized graphs to calculate the entropy change of 1 mole of ethanol undergoing isothermal ‘compression from 1 bar to 100 bar along the critical isotherm. 58 YR ba, Up aesarde a Pe tan 2 100K, Triche 99 61°C 2 372, 69°C a) xo 1 Vers 920100 VA. RT. 33100 es P 2 572,61 TE 5) GWeo4 , wopers 4 bon y y00°C 2 373)5¢e ve ST (z- 4) sere Inblon Jo for kealenr Br Gtso4 Ves 5U21C ) Pext3,7 bon 2 W)20,658 Ve 0, p225 Fo+G9660 12, ,-90129%, 2 ve’ 91 31406 an? we + 372,64 & (0977723 -4 1 bon : > Vv Babes a%d ps aorser IFFT IR PD) Capri’ Predera Amol GoHs0d Pret on jPe 100den F-Te = $16 He Asrae AA(f es. s®Problem 5.9: n-Octane is compressed reversibly at constant temperature along the critical isotherm ttl the cxtical pofnt is reached. The intial pressure is bar. The pressure takes place ina closed system, Use the Lee-Kesler method to calculate the following: a) What is the entropy change of n-octane? ) Calculate the heat that must be supplied to the system to maintain isothermal conditions. ©) Calculate the necessary amount of work. , 2 Te bela. 5607" 559 9 llamo, conponin’ romraalll , aly aitpllaarede ths ob milede Lee beoler w20,394 7 Ae [Gif -#hp DE SACUNS Hi Asvie RA (B) 2% 5" bee hoy Pen Oagasee, Pras A Se Nie 1) Sate 8128067 Ass-22 = % Mee AT 4. (23123167 6,009 | vinehiK aereat |e a mol 02% Aevr Qe 563,7.-311hT - -1907 17 9 BIRT = 1883, AT mole (nl HA, «00582 Alle we edie Hats -3,5963 til (a Gye mi Mi seo, 0567 4 3,526 I2 35 AT Alias Q-W We Athy -B We At, 62 Yueh Y/Problem 5.11: Isobutane is heated ina heat exchanger from 1 bar from 220 K to 300 K. Use the SRK. ‘equation to calculate the following: 4) The amount of heat. 'b) The entropy generation ifthe hea is provided by a bath at 300 K. Additional information: The ideal-gus heat capacity ofisobutaneis CP = 96.5 g/mol K. $94 Kebitms Python ihe Terat0n [Te rtote , Rese, s lan Teese” Frased Peaorrry As Rey cobuske DL emlbhbQ Sa Ah cole 22 poowile por un lass 0 300K Ps Sean Fon Re Be oveouns, w= one , Pie B82 0esr ze teody Cas hase Wi AVG a) 4 Hf, SRrhls 6+ Cafn) y A, 216" d "ee Fre EEE Gr er VND rr AWE TY a irtus « Qn8te PWG sy? CF aaa dT ibe WA 185, 4, 000 352764 . seedy mete Atces [ind de eft) ot. 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