You Can Safely Safely Count On Grainger For Identification Products On Safety Protocols. Get What You Need To Maintain Your Facility With Package, Airfreight and Ocean Service.
You Can Safely Safely Count On Grainger For Identification Products On Safety Protocols. Get What You Need To Maintain Your Facility With Package, Airfreight and Ocean Service.
You Can Safely Safely Count On Grainger For Identification Products On Safety Protocols. Get What You Need To Maintain Your Facility With Package, Airfreight and Ocean Service.
a Ae Material Safety Data Sheet
LENMAR Lithium-ton Battery
Effestive Date: Jan 1, 2010
LITHIUM-ION BATTERY
MATERIAL SAFETY DATA SHEET (MSDS)
SECTION | - MANUFACTURER INFORMATION,
Manufactured for: Contact Information
Lenmar Enterprses, Inc. 805 384 9600
4095 Via Pescador 800.424 2703 (US)
Camarilo, CA 93012 Lenmarcom
‘SECTION Il - HAZARDOUS INGREDIENTS.
[MATERIAL OR INGREDIENT PEL (OSHA) | Tver. “hw
‘Aeziylene Black (CASH 1555557) 3.5 main TWA JEmgim WA | OF
____(as carbon black) (ascarbonblack) |
Biphenyl (CASH SESE mejn? TWA 0-2 ppm TWA oO
02pomTWA e soe
Diath Carbonate — (CASE 105-584 Tione established Rone established 8
‘Dimethyl Carbonate (CAS# 616-386) None estabished "None estabished 0:15]
thyi Met Garbonate_ (CASE 623-555) None estabis None estabished [015
Ethylene Carbonate (CAS# 95 49-1) None estabished ‘None estabished | 0-15
Graphite (CASE 7762-4 Singha? TWA (respirable Fackon) | Zriglm" TWA (respirable | 7-22
“WS mgi? TWA (otal dust fraction)
Titium Cobai Oxide — (GAS# 13150753) Ogi TWA (a5 Co OR mgim® TWAas Go) | 1530 |
itium Hexatluorophosphate ‘one established ‘None established 05
(case 21324403) |
“ium Tevafuoroborale_(CAS# 14263-07-8) None established one esiablohed 05,
intetyl Pyrolzinone (CAS 872-50-4) None estabisnec None eslabished | 0-1
‘Oralic Acid (CASH 14852.7) — Tg TWA 1 mgm? TWA ot
= 2 maim STEL
‘Propylene Carbonate (CAS# 108-327) None astabiared Tone estabished ois
IMPORTANT NOTE: The battery siould nol Be opened or incinerated, Exsosure to the maredients contained within oF
the combustion products could be harm
‘SECTION Il - FIRE AND EXPLOSION HAZARD DATA
“+ ffre or exposion oosurs when batteries are on charge, shut of power to charger.
{Incase offre wnere ihm ion batteries are present, food te avea vith water. If any batteries are buming,
‘water may not extinguich thom, but wll €90 the adjacent batteries and conto the spread offre. CO2, dry
‘chemical, and foam exingushers are preferred for small fies, but also may not extinguish burning ithium ion
batteries, Burning batenes wil burn themselves out Vitually al fres involving thiam ion batteries can be
Controlled wth water. When nator is used, however, hydrogen gas may De evolved which can form an
fexlosive mixture with az LITH-X (powdered graphite) o° copper powder fre extinguishers, sand, cry ground
‘dolomite of soda ash may also be used. These maieras act as smotnering agents.
‘Fite fghters should wear self-contained breathing apparatus, Burning lithium ion batteries can produce toxic
fumas including HF, exides of carbon, aluminum, Ith, copper, and cobalt. Volatile phosphors pertafluonde
may form ata temperature above 230" F.
SECTION IV - HEALTH HAZARD DATA
‘Under normal conditions of use, the Bator is hermetically sealed.
Ingestion:
‘Swallowing a battery can be harmful
Contents ofan open battery can causa serious chemical burs of mouth, esophagus. and gastrointestinal tract.
I battery or open Battery i ingested, do nol induce vomiting or ive food 0: crink. Seek medial attention
immediately CALL NATIONAL BATTERY INGESTION HOTLINE for advice and follow-up (202-625-333) collec,
day oF nigh
Inhalation:
CContants ofan open battery can cause respiratory ination. Inhalation of vapors may cause iritation of the upper
recpiatory tract and lungs, Provide fresh air and Seek medical attention
‘Copyright 2008 Lenmar Enterprises - Speciications subject to change without notice Page 103me re JE =} Material Safety Data Shee
_ENIVMAR Lithium-Ion Batter
evecive Ose Jan 1 2
SECTION IV - HEALTH HAZARD DATA - (Continued)
‘Skin Absorption:
Nemetnyl pyroidinone, athylane carbonate, ethyl methyl carbonate, dimethyl carbonate, and biphenyl may be
‘2bsoroed through the skin causing localized inflammation,
‘Skin Contact:
Contents of an open battary can cause skin ration andlor chemical burns. Remove contaminated clcthing and
‘wash skin wth soap and water, Ifa chemical um occurs orf itation persists, seek medical attention,
Eye Contact:
Contents ofan open battery can cause severe itation and chemical buns. Immediately lush eyes thoroughly with
water for atleast 15 minutes, ith upper and ower Ids, un no evidence ofthe chemical remains. Seek medical
tient,
Note: Acetylene black and cobalt compounds are sted as possible carcinogens by the Intemational Agency for
Researen on Cancer (ARC).
SECTION V - PRECAUTIONS FOR SAFE HANDLING AND USE
‘Storage:
‘Tha bhium ion batlery should be between 25% and 78% of fll charge when stored fora long perio of te. Store
4 cool, dr, well ventvated area. Elevated tamperatures can result in loss of batlery performance, leakage, cr rst. C
not expose the battery to open flames.
Mechanical Containment:
Containment of his batlery in a mannor that obstructs or defeats the safety vent or electrical disconnect mechanisr
‘designed into this battery can resut in fre andor explosion and cause porsonal injury and device damage. This
battery i not desgned to be poled, enclosed in hemetic overpackaging, or sealed by any means tat prevents fre
operation ofthe designed safety mechanisms.
Handling:
(Do not expose the baltery to excessive physical shock or vibration. Short circuiting shoul be avoided, however,
‘accidental shor eicuting for a few s2conds il not seriously aff the ator, Prolonged shor cicuts wil cause
the battery to rapidly lose energy, could generate enough heat to bum skin, and may cause the safety release vent
fof the enclosad call to open. Sources of short circuits include jumbled bateres in Duk containers, coins, metal
Jewelry, metal covered tables, of metal bets used for assembly of batteries in devices. To minimize risk of short
Circuting the protective case supplied with the battery should be used to cover the terminals when transporting or
Storing the batery.Do not dsassembe or deform the batery. Should an individual cll within a battery become
ruptured do pot alow contact with water
{soldering or welding tothe battery is required, use of tabbed batteries is recommended. Soldering directly tothe
call can damage the batery safety Seal cause intemal damage or short crcut the cel
Charging:
“This battax is made to be charged many times, Use an approved battery charger. Never use a modified or damag
battery charger. Do not charge for over 120 minutes of repeat cnarging without intermittent discharging. A backup
charge termination based on tme ie racemmendod to prevent overcharging. The charging temperature should be
between O°C and 50°C (82°F and 120°F). The battery pack will normally warm during charging
Charging Voltages and Currents:
Charging votages are prevented from exceeding the specified imits by an intoral battery protection crcut
[Never use a battery which shows signs ofa damaged protection cuit or broken case. (Such damage te the
protection deus may be incleated by voltages atthe battery terminals ouside a thelr specified ranges.) Adhere to
fl specified charging and eiscnarging volages and currents. Do net use batiory its voltage drops below the
‘pected minimum vokage.
Labeling:
Ifthe label or package warnings are not visible, tis important to provide a package andlor device label ating
WARNING: CHARGE ONLY WITH SPECIFIED CHARGERS ACCORDING TO DEVICE MANUFACTURER'S.
INSTRUCTIONS. DO NOT OPEN BATTERY, DISPOSE OF IN FIRE, OR SHORT CIRCUIT - MAY IGNITE,
EXPLODE, LEAK, OR GET HOT CAUSING PERSONAL INJURY.
Disposal:
Dispase in accordance with al applicable federal, state, and local reaulatons.5 ~ Material Safety Data Sheet
LENVIAR sera umion Balery
Effective Date: Jan 1, 2010
SECTION VI - SPECIAL PROTECTION INFORMATION
Ventilation Requirements:
Not necessary under normal cantons.
Respiratory Protection:
Not necessary under normal conations.
Eye Protection:
Not necessary under normal conditions. Wear safety glasses with side shields ifnanding an open or leaking batory.
Gloves:
[Not necessary under notmal conditions. Use neopcene or natura ubber gloves i handling an open ar aking
battery.
Open Battery Storage:
Battery should not be opened, Should 2 cell become disassembled, the electrode shouldbe stored ina feeproot
‘cabinet, away from combusibies.
‘SECTION VII ~ REGULATORY INFORMATION,
The transportation of Lihium-on (and any other rechargeable lithium chemistries) packs with up to 8 grams of
equivalent ithium content, 26 described in tis document. 's rot regulated by the U.S. Deparment of Transportation
fr the major international regulatory Bodies. Equivalent Ithium content for Ithum ion and ithium polymar oats and
batteries in grame on a per cell base calculated as 0.3 times the rated eapacty in ampere-houts. The equivalent
lithium content fora battery or battry pack isthe rated capacy in ampere-hours fora single cell multiplied by 0.3
‘and then mltipiad by the number of cols inthe battery.
‘Transportation:
{Land Transport (ADR/RID) - The produc fulis the requirements of Special Provision 188 of ADRVRID and
therefore, Keeping within the praserbed quantity ims, oxcapted from the application ofthe Dangerous Goods
regulations.
‘Sea Transport (IMG) - The product fulis the requirements of Special Provision 188 of IMDG.Code and is
therefore, Keeping within the prescribed quantity ims, excepted from the application of the Dangerous Goods
regulators.
‘Ave Traneport (IATA) ~The preduc fulfils the requirements of Special Provision AS of IATA-OGR and ie therefore,
keeping within the prescribed quantity its, excepted from the application ofthe Dangerous Goods regulation.
SARAVTITLE III ~ As an artide, this battery and its contents are not subject to the requirements ofthe Emergency
Panning and Community Right-To- Kaan Act.
“The information contained inthis document is provided for information only. The batteries described in his document
‘are articles pursuant to 29 CFR 1910.1200 and, as such, aro nct subjact tothe OSHA Hazard Communication Standard
requirement for preparation ofa material safety data sheet. The information and recommendations inthis document are
‘made n good fats and ae balleved tobe accurate as of the date of preparation. However, LENMAR ENTERPRISES,
INC, MAKES NO WARRANTY, EITHER EXPRESS OR IMPLIED, WITH RESPECT TO THIS INFORMATION AND
DISCLAIMS ALL LIABILITY FROM RELIANCE ON IT.
Copyright 2008 Lenmar Enterprises ~ Specifications subject to change without notice Page 9 of