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Achieving a higher level of efficiency in posterior tooth restorations –

through the combined use of

Tetric® N-Ceram Bulk Fill


 and Bluephase N®

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Table of contents

4-mm  3
bulk fillings:
placed in one increment and polymerized in one curing cycle

From conventional layering to the  8


4-mm bulk-filling technique
Requirements placed upon composite restoratives and curing lights

Low shrinkage and  13


low shrinkage stress:
an essential prerequisite

More than  18
just time-saving
Enhancing the profitability of dental practices
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4-mm
bulk Dr Laurent Schenck

fillings:
Ivoclar Vivadent AG

placed in one increment and polymerized in one curing cycle

Dr Laurent Schenck, from Ivoclar Vivadent AG, discusses a major breakthrough in the field of posterior
composite resins

Ivoclar Vivadent, Liechtenstein, has developed a dental filling cured to ensure the long-term success of the filling. In order to
material called Tetric® N-Ceram Bulk Fill in response to the refute this principle, the physical and chemical parameters of
demand for an efficient posterior composite resin that can be composites have to be rethought. Ivoclar Vivadent has done
placed in one increment. Due to its unique composition just that and developed a new approach.
featuring patented ingredients, this material can be placed in
increments of up to 4 mm. The composite smoothly adapts to
the cavity walls. Furthermore, it can be contoured without the The composition and its implications
pressure of time.
Tetric N-Ceram Bulk Fill has been developed in the tradition of
The entire filling completely polymerizes in one curing cycle of the proven Tetric N-Collection of products established in 2007.
10 seconds with powerful curing lights, such as the new The components of this new bulk-filling composite are
Bluephase N. This particular device cures composite resins with delicately balanced in order to achieve an optimum blend of
a high light intensity of 1,200 milliwatts per square millimetre shrinkage characteristics, wear resistance, polishing properties,
(mW/cm2). It features a parallel-walled 10-mm light probe. The
wide light tip cures fillings with large surfaces in a single
exposure. In addition, the special fibre optics of the light probe
helps the intense light of the Bluephase N to penetrate deep
into the material to be polymerized. Even when curing from a
greater distance – for example in the proximal box – excellent
Relative intensity

polymerization results are achieved. As the light probe can be


rotated 360 degrees, all restored areas can be optimally
accessed. With these two products, which can be used
independently, quality bulk fillings can be placed quickly and
Acyl phosphine Camphor-
easily. quinone
oxide

Is there really a way around the multiple increment technique? 300 340 380 420 460 500
It is a well-known fact that conventional composite resins can Wavelength (nm)
only be placed in increments of maximum two millimetres.
Fig. 1 Standard initiator system plus polymerisation booster Ivocerin = complete
Furthermore, the different layers have to be individually light polymerization of 4-mm increments. Ivocerin keeps the light curing time short,
even if 4-mm thick increments are involved (Ivoclar Vivadent AG).
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Fig. 2 Working steps, from left to right: filling, contouring, polymerization: finished bulk filling. Tetric N-Ceram Bulk Fill is a composite restorative that can be placed without
having to use a special instrument or having to apply a covering layer. It can be placed in increments of up to 4-mm. Curing takes only 10 seconds with the Bluephase N, for
example, due to the high light intensity of 1,200 millimetres per square centimetre and the wide light tip of this device.

shade adaptation and placement and polymerization time. monomer matrix are carefully coordinated. Therefore, shades
Tetric N-Ceram Bulk Fill contains the same clinically proven IVA (universal A shade), IVB (universal B shade) and IVW
ingredients of Tetric N-Ceram and therefore also demonstrates (whitish; e.g. deciduous teeth) cover almost the entire spectrum
this product’s excellent properties. To make the composition of tooth colours. After the fillings have been contoured, they
suitable for the new application method, several innovative are polymerized in one light-curing cycle. As a result of the
components have been added. For example, the product coordinated filler technology, cured Tetric N-Ceram Bulk Fill
contains a light sensitivity inhibitor to lengthen its working restorations are easy to polish to a high-gloss finish – e.g. with
time under operating light. In order to ensure complete cure the OptraPol® one-step polishers. The fillings are highly wear
of the filling in only ten seconds, the composite resin features resistant due to the well-balanced composition of primarily
an additional, patented photo-initiator (Ivocerin®) as a part of small fillers. Therefore, the restorations do not have to be
the light initiation system (Fig. 1). Due to its high reactivity, covered with another composite resin, in contrast to
Ivocerin acts as a polymerization booster (accelerator). commercially available flowable bulk-fill material.
Moreover, a shrinkage stress reliever keeps the volume
shrinkage and shrinkage stress to a minimum. The material
can be cured with all conventional polymerization devices.

The clinical steps

The new Tetric N-Ceram Bulk Fill is highly efficient. Due to its
smooth consistency, it is very convenient to use in posterior
teeth. The composite does not stick to instruments and is easy
to pack. It readily adapts to the floor and walls of the cavity.
Therefore, an initial layer of liner does not have to be placed.
The material’s thixotropic properties allow the tooth anatomy
to be recreated in detail. Once the filling has been contoured,
it retains its shape. Cavities of up to 4-mm depth can be filled
in one step without any misgivings (Fig. 2). The new composite
resin comes in three universal shades, which are adequate for
achieving the appropriate match to the surrounding tooth
substance (Fig. 3) as they are characterized by lifelike
translucency and shade adaptation. Furthermore, the light
Fig. 3 Three universal shades are sufficient to cover
refraction indices of the fillers, nano-pigments and the the entire spectrum of tooth shades.
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Camphorquinone
Acyl phosphine
oxide (e. g. Lucirin
TPO)
Ivocerin
Absorption

PPD
Bluephase N

Fig. 4 Due to the polywave LED, Bluephase N reliably


350 360 370 380 390 400 410 420 430 440 450 460 470 480 500 cures any type of dental material. This advanced
technology is responsible for the halogen-like
Wavelength [nm] wavelength range of 385 to 515 nanometres.
Source: R&D Ivoclar Vivadent AG, 2014

Light curing and the curing light Large fillings need to be exposed to the curing light only once
due to the wide diameter of the probe tip of 10 mm (Fig. 5).
The light-curing unit itself plays an important role in the This satisfies a real clinical need, as large cavities often occur
polymerization of 4-mm thick composite resin layers within in posterior teeth. Since the wide tip covers the entire bulk
10 seconds. The polymerization unit Bluephase N from Ivoclar filling surface, only one curing cycle is necessary to fully
Vivadent is finely tuned to this task. However, this third- polymerize the restoration, which saves considerable time.
generation LED unit also completely cures all the commercially Moreover, the fact that the light probe can be freely rotated
available filling composites and adhesives (Fig. 4). Its light further enhances the efficiency of the device. The light tip of
intensity measures 1,200 mW/cm2. Bluephase N offers more flexibility as it can be held very closely
to areas that are usually difficult to reach.
The polywave LED, which has been developed by Ivoclar
Vivadent, is responsible for the high-performance of this
curing light. It has a wide halogen-like light spectrum with a
wavelength range between 385 and 515 nanometres. The
energy released in this spectrum is capable of activating all the
different types of photo-initiators, unlike the spectra of the
first and second generation of LED devices, which were only
effective on camphorquinone. As a result of its outstanding
polymerization properties and exceptionally reliable light
output, Bluephase is considered to be the best-selling brand of
LED polymerization units in Europe. It is regarded as the
standard in clinical studies (IADR Barcelona 2010) and has
received numerous prestigious awards. For example, it was
given the highest rating of five pluses by the highly recognized
Fig. 5 The 10-mm light tip covers the entire surface of large Tetric N-Ceram Bulk Fill
and independent American test institute “The Dental Advisor”.
restorations. Therefore, only one exposure to the curing light is necessary, which saves time.
In addition, “CR Clinicians Report” ranked the product as The light tip can be rotated 360 degrees for optimal access to all restored areas.
number 1.

An entire filling composed of a 4-mm increment of Tetric


N-Ceram Bulk Fill can be completely cured with Bluephase N.
The light probe featuring special fibre optics plays a significant
role in this process. The probe’s parallel-walled design keeps
the beam focused.
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Fig. 6 The balanced weight distribution makes the Bluephase N


very comfortable to hold and helps keep the hand and arm relaxed.
The ergonomic design ensures convenient, relaxed curing.

Ergonomic design, ease of handling and


customized curing

The Bluephase N impresses users with its outstanding and


multiple award-winning design (Fig. 6). The balanced weight
distribution makes the device very convenient to hold. Due to
its ergonomic design, Bluephase N comfortably fits the human
hand and allows it to be conventionally held like a gun. Thus
relaxed working is ensured. The device offers three, easy-to-
operate curing programs for the coordinated and efficient
curing of all types of restorations: the High Power program,
which ensures quick polymerization, and the Low Power and
Soft Start programs for polymerization in areas near the pulp
(Fig. 7).

Outlook

The demand of practitioners for an economical and easy-to-


use solution for restoring posterior teeth has been fulfilled
with the development of the new nano-hybrid composite
Tetric N-Ceram Bulk Fill and the efficient Bluephase N curing
light. Evaluations have shown that the bulk-filling technique is
up to 50 percent faster compared with the increment
technique involving conventional composites and multiple
polymerization cycles.
Fig. 7 The device features three different curing modes for various
indications. Operation is simple and self-explanatory.
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Literature references

[1] ADA, American Dental Association. Professional Product Review. Vol. 1. Issue 2.
(2006).

[2] The Dental Advisor. Top Light-Curing Unit. http://www.dentaladvisor.com. (2009,


2010, 2011).

[3] Clinicians’ Report: CRA. Vol. 3. www.clinicians report.org. (2010).


(Ivoclar Vivadent stellt Interessierten auf Anfrage den gesamten Bericht zur
Verfügung).

[4] Ernst CP, Busemann I, Kern T, Willershausen B. Feldtest zur Lichtemissionsleistung


von Polymerisationsgeräten in zahnärztlichen Praxen. In: DZZ Vol. 9. Issue 61.
466- 471. (2006).

[5] Enggist L. Nur auf den Preis schauen kann teuer werden. Dr. Lukas Enggist zu
den Kriterien für die Auswahl von LED-Polymerisationsgeräten – Was ist beim
Kauf zu beachten? In: DZW Vol. 18. Issue 46. (2009).

[6] Ernst CP. Die richtige Auswahl eines Polymerisationsgerätes. In: Dental Kompakt.
220-221. (2009).

[7] Ivoclar Vivadent. Gut, wenn man die Fakten kennt. Leitfaden über klinisch
entscheidende Kriterien bei der Auswahl eines Polymerisationsgerätes.

[8] IADR – International Association for Dental Research/General Session, Barcelona,


July 14-17, 2010. www.iadr.org. (Die meisten Produkt­nennungen in Abstracts).

[9] Price R BT. Fahey J, Felix C. Knoop hardness of five different composites cured
with singlepeak and Polywave LED curing lights. In: Quintessence International.
Vol. 41. e181-e191. (2010).

[10] Price R BT. Evaluation of a dual peak third generation LED curing light.
Department of Dental Clinical Sciences, Dalhousie University, Halifax, Nova Scotia,
Canada. In: Compend Contin Educ Dent. Vol. 26. 331-2, 334, 336-8 passim, quiz
348 (2010).

[11] Price R BT. Third generation vs a second generation LED curing light: effect on
Knoop microhardness. Department of Dental Clinical Sciences, Dalhousie
University, Halifax, Canada. In: Compend Contin Educ Dent. Vol. 27. 490-6; quiz
497, 518. (2006).

[12] Repetto-Bauckhage T. Beunruhigende Ergebnisse für Polymerisations­geräte. Wenn


die Leistung nicht mehr stimmt. In: DZW Vol. 21. 20-21. (2011).

[13] Ivoclar Vivadent. Ivoclar Vivadent Report. Nr. 18. 29-39. (2007).

[14] Kleverlaan CJ, Feilzer AJ. Polymerization shrinkage and contraction stress of
dental resin composites. In: Dent Mater. Vol. 21. 1150-1157. (2005).

[15] Ferracane JL, Mitchem JC. Relationship between composite contraction stress and
leakage in Class V cavities. In: Am J Dent. Vol. 4. Issue 16. 239-243. (2003).
Contact details:
[16] Watts DC, Marouf AS, Al-Hindi AM. Photo-polymerization shrinkage-stress kinetics
in resin-composites: methods development. In: Dent Mater. Vol. 1. Issue 19.
Dr Laurent Schenck
1-11. (2003). Marceting Director clinical
Ivoclar Vivadent AG, Schaan, Liechtenstein
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From conventional
layering to the Dr Peter Burtscher

4-mm
Ivoclar Vivadent AG

bulk-filling technique
Requirements placed upon composite restoratives and curing lights

Dr Peter Burtscher reports on challenges and solutions in the development of state-of-the-art


composites – Major breakthrough in the field of direct posterior composite restorations

In classical composite resins, features such as wear resistance, can now be accomplished using a single increment and single-
esthetics (i.e. shade and translucency), mouldability, polishability, cure polymerization with a high light intensity curing unit, e.g.
strength, volumetric shrinkage and shrinkage stress are the new Bluephase N® LED light (both products from Ivoclar
carefully balanced in line with the principle of cause and effect Vivadent) which offers an intensity of 1,200 milliwatts per
and ultimately result in a restriction of the layer thickness to square centimetre (mW/cm2). A newly developed initiator
two millimetres. In the anterior region, this restriction does not system containing patented proprietary ingredients has been
necessarily mean more work, because the esthetic requirements incorporated into this new nano-hybrid bulk-fill composite to
of these restorations command a great deal of attention to achieve the desired profile of properties (Figs 1 and 2).
detail and hence the application of thin layers anyway. In the
posterior region, however, an efficient working method takes
the priority, particularly when basic restorations are fabricated. Technological achievements of
In addition, dental professionals – and patients – would like Tetric N-Ceram Bulk Fill
the chairtime to be short.
The first single-increment material that offers uncompromising
Now a material that meets exactly these requirements has quality: Patented layered silicates and the well-balanced
become available. With Tetric N-Ceram Bulk Fill, restorations organic matrix composition impart a pleasant mouldable

Fig. 1 Initial situation: defective amalgam fillings Fig. 2 Tetric N-Ceram Bulk Fill restorations, two weeks after placement

(Pictures courtesy of Dr Eduardo Mahn, Las Condes, Santiago, Chile)


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Style and ergonomics: The new LED curing light Bluephase N

Polymerization process under operatory light Sec. Light insensitivity


250
Polymerization of a
standard composite 200
200
Polymerization of
Conversion rate [%]

Tetric N-Ceram Bulk Fill


150 140

Extended working time because of the light sensitivity inhibitor 100


100
60
50
Time / Sec.

100 s 200 s 0
Tetric N-Ceram Filtek Z250* Ceram.X Spectrum TPH*
The conversion rate of a composite is 50 – 70% at maximum.
Bulk Fill mono +*

Fig. 3 The patented light sensitivity inhibitor delays the polymerization Fig. 4 Tetric N-Ceram Bulk Fill showed a working time of 200 seconds when tested
reaction to ambient light, e.g. operatory light, and thus facilitates sculpting under the defined ambient light conditions of 8000 lux according to ISO 4049.
and contouring. Source: R&D Ivoclar Vivadent AG, July 2012

consistency to this bulk-fill material. The composite easily exposed to the intensive light of a LED source.
adapts to the cavity walls, eliminating the need for an initial To accelerate the cross-linking process of the monomers, a
coating of flowable composite. patented polymerization booster (Ivocerin®) has been added to
A material that is applied in 4-mm increments and subsequently the standard initiator system (Fig. 5). As a result, the material
contoured needs to offer a longer working time than features an absorption maximum in the blue-light range from
conventional composites. It must not polymerize prematurely around 370 to 460 nanometres. When exposed to the light of
when exposed to operatory light. A patented light sensitivity a high-energy polymerization unit – e.g. Bluephase N – at an
inhibitor ensures that premature polymerization does not accurately set emission spectrum, the bulk filling cures rapidly
occur in the new bulk-fill material, granting a working time of to a consistent depth of cure. By contrast, other commercially
more than three minutes under defined light conditions of available materials contain conventional stabilizers, which start
8000 lux (Figs 3 and 4). An important additional feature of this to polymerize after a shorter time and offer less time to sculpt
molecule is that it does not impair polymerization when and contour the restoration.

* Not registered trademarks of Ivoclar Vivadent.


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Effect of standard
initiator system & Ivocerin
Relative intensity

2 mm
Effect of Ivocerin
4 mm

Acyl phosphine Camphor-


oxide quinone

300 340 380 420 460 500


Wavelength (nm)

Fig. 5 Standard initiator system + polymerization booster Ivocerin = complete Fig. 6 The innovative light initiator Ivocerin initiates polymerization even if only a
polymerization of 4-mm increments. A patented polymerization booster (accelerator) few photons reach the deep layers of the cavity. Consequently, there is no need to
is used in Tetric N-Ceram Bulk Fill as an additional photo-initiator. increase the translucency to allow more photons to pass through the depth of the
material and start polymerization.

The polymerization booster allows Tetric N-Ceram Bulk Fill to To initiate the polymerization of resins, the absorption
be set to an enamel-like translucency. This is not possible with spectrum of the photo-initiators and the light emission
conventional composites that do not contain a polymerization spectrum of the curing light have to be compatible with each
booster. Whilst the number of photons that reach the cavity other. The polywave technology, which Ivoclar Vivadent has
floor is significantly smaller than the number of photons on the developed specifically for its range of Bluephase curing lights,
restoration surface, it is still sufficient for the light sensitive ensures that polymerization is triggered reliably (Fig. 7). As the
booster molecules to trigger the polymerization reaction even polywave LEDs achieve a broadband spectrum in the blue light
in layers that are 4 mm deep or even deeper (Fig. 6). wavelength range of 385 to 515 nanometres, similar to
halogen lights, they are suitable for dental composites that
A welcome co-effect: The finely balanced translucent properties typically contain champorquinone or Lucirin as initiators as
and the specifically coordinated refractive indices of the fillers, well as for materials that incorporate the new light initiator
nano-pigments and monomer matrix enable the material to Ivocerin. The first and second generation of LED lights are not
blend seamlessly into the natural dentition without producing capable of emitting light in such a comprehensive range; they
the greyish discolouration so often encountered in highly can only polymerize composite resins containing
translucent composites. Masking the underlying tooth structure camphorquinone and Ivocerin. Only the third generation of
with a cavity liner (e.g. Tetric N-Flow A3.5 Dentin) is required LED lights, which includes the newly introduced Bluephase N,
only in exceptional cases, for instance if an amalgam filling is is suitable for all initiators.
replaced.
This cutting-edge polymerization unit is capable of reliably
The development of the filler technology is marked by polymerizing all composite restoratives currently available on
additional technological achievements, which enable the the market. These lights offer a consistent high light intensity
material to be used in the bulk-fill technique in conjunction and easy operation. By virtue of these features, Bluephase has
with a single-cure polymerization step: The fillers are restricted been regarded as the brand that sells the most LED
to a small size to produce a compact, wear-resistant surface polymerization lights in Europe. The lights have earned several
that does not require coating with an additional composite. In renowned awards from recognised bodies and they are often
addition, a shrinkage stress reliever ensures that the shrinkage mentioned as the standard in clinical studies.
stress and volumetric shrinkage are kept low during
polymerization.
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100 %

4 mm
80 %

Profile measurement of Vickers hardness according to Watts

Fig. 7 The visible light spectrum ranges from 380 to 780 nanometres. The polymerization Fig. 8 Watts states that a material exhibits a clinically sufficient depth of cure if the
of modern composites requires blue light in the wavelength range from 385 to 515 value measured on the bottom surface amounts to at least 80 per cent of the value
nanometres to ensure that all photo-initiators are capable of absorbing energy. The measured on the top surface of the restoration. 
Bluephase N curing light achieves this spectrum by means of polywave LED technology  (Figs 3 to 8: Ivoclar Vivadent AG)
specifically developed by Ivoclar Vivadent.

The light produced in the polywave light diodes is guided With its ergonomic design and balanced weight distribution,
through a parallel-walled light probe. In this way, the light Bluephase N sits more comfortably in the hands of women
beam does not scatter and the light intensity remains high and men than other polymerization units. Moreover, it can be
until the beam reaches the restoration surface. For instance, conventionally held like a gun. Due to its handy proportions,
Bluephase N produces a light intensity of around 1,200 mW/cm2 the light does not cause fatigue. The unit features three
(milliwatts per square centimetre), allowing 4-mm increments customized curing modes with adjustable light intensities and
of Tetric N-Ceram Bulk Fill to be polymerized in ten seconds. exposure times which can be set easily and quickly depending
on the indication. Consequently, the user has a light at hand
In order to ensure high-quality restorations, the light intensity that ensures successful and efficient light curing at all times.
of every curing light has a narrow specification of +/- 10 per
cent. By contrast, conventional curing lights may show
considerable fluctuations of performance and thus entail the
risk of inadequate polymerization.

In addition, the large 10-mm diameter of the light probe


ensures that even extensive restoration surfaces are completely
covered with light, allowing polymerization to be carried out
in a single step. Light units with a narrower probe often
require several exposures to cure the restoration in its entirety.
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Curing depth: a decisive factor for bulk-fill materials

If we assume that the light intensity and curing time are set of cure is usually obtained particularly on the surface of a
correctly and the emission spectrum of the light unit is composite irrespective of the degree of translucency or
compatible with the absorption spectrum of the photo- shade. However, users have no way of assessing the degree
initiators, the shade and translucency of a composite resin of cure across the entire thickness of the restoration.
are the two factors that have the most significant effect on Profile measurements, which measure the degree of cure
the curing depth. step by step in ever deeper layers, provide information on the
Measurements have shown that the degree of cure curing depth down to the bottom surface of the test
continuously decreases in areas deeper than approx. 0.5 ­samples. As far as the evaluation of results is concerned,
mm. The degree of cure is highest at a depth of 0.5 mm, Professor David Watts (Watts DC, Amer O, Combe EC.
because the covering layer is slightly softer due to the effects Characteristics of visible light-activated composite systems.
of inhibition. In practice, however, this layer tends to be Br Dent J 1984; 156:209-215.) from the University of
removed in the course of polishing and grinding, so that the Manchester in Great Britain has come to the following
hardest layer forms the top surface of the restoration. From ­conclusion: The curing depth meets the clinical requirements
this layer downwards, the light intensity entering the if the degree of cure measured on the bottom surface is at
material decreases steadily: the filler particles scatter the light least 80 per cent of the value measured on the top surface
and the colour pigments absorb it. Remaining radicals (Fig. 8).
undergo a post-curing reaction, mostly within 24 hours after Bulk fillings that consist of Tetric N-Ceram Bulk Fill and are
the initial polymerization. This is accompanied by a decrease cured for 10 seconds in a single-cure procedure meet this
in the yellowish tinge if camphorquinone is used as photo- requirement. In addition, they also offer favourable esthetic
initiator. qualities and a well-balanced translucency of 15 per cent due
To determine the degree of cure in deep layers, test samples to the polymerization booster. In compliance with ISO
are first stored for 24 hours before the measurements are standards, conventional composites should not exceed a
carried out. If the manufacturer’s directions regarding the layer thickness of two millimetres to ensure an adequate
curing times and light intensities are followed, a good degree degree of cure for all translucencies and shades.

Source: Burtscher P. Visible light curing of composite resin. In: Ivoclar Vivadent Report
No. 18 – The secrets of composites. Raw material research, material development,
materials testing, clinical trials, equipment design, competence. 2007; August: 29 – 39.

Contact details:
Dr Peter Burtscher
Director of Organic Chemistry
Ivoclar Vivadent AG, Schaan, Liechtenstein
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Low
shrinkage Dipl.-Ing. Karin Vogel

and low
Ivoclar Vivadent AG

shrinkage stress:
an essential prerequisite

Dipl.-Ing. Karin Vogel discusses the prerequisites for the bulk-filling technique – Major breakthrough in the
field of direct posterior composite resins

High demands are placed upon the shrinkage behaviour of How deformable should dental composites be?
composite resins which allow bulk-filling of large cavities and
achieving a complete cure within a short exposure time. Based Shrinkage stress – marginal leakage – resistance against
on these and other specific requirements that need to be chewing forces: How deformable should dental composites
fulfilled by bulk-fill materials, Ivoclar Vivadent has developed be? The modulus of elasticity (elastic modulus) of composite
the nano-hybrid composite Tetric® N-Ceram Bulk Fill, which resins is known to be a relevant factor for achieving marginal
can be placed in 4-mm increments and cured in a single step integrity. The forces acting on the cavity walls during the
with high-performance LED curing lights such as the Bluephase polymerization process are not only influenced by the amount
N®. The outstanding properties of the new dental composite of shrinkage, but also by the elastic modulus of a dental
are based on an innovative initiator system and the clever use composite, which itself is composed of the elastic moduli of
of state-of-the-science filler technology. the filler and the monomer matrix. If a material is hardly
deformable, i.e. shows high resistance to deformation, it is
Composite resins shrink during polymerization. Problems described as being inelastic and having a high modulus of
associated with polymerization shrinkage include marginal elasticity. During the shrinkage process, high stress is generated
discolouration, marginal gap formation, secondary caries, as rigid materials fixed to the tooth structure by means of
debonding along the cavity floor and walls, restoration loss - adhesives tend to “tear” at the cavity walls [1]. As a result
even enamel cracking and hypersensitivity: any of these factors marginal gaps may form [2]. By keeping the modulus of
may impair a restoration’s longevity. Composite manufacturers elasticity at a low level, the build-up of high shrinkage stress is
are putting a lot of effort into further optimizing the dental avoided. However, resilient material is not strong enough to
composites they market. Ivoclar Vivadent for instance has a withstand the masticatory forces in the long term. Composites
large, well-staffed in-house research and development facility with an elastic modulus between 8 and 11 gigapascal (GPa)
equipped with the latest technology and equipment. Their have been shown to perform best in stress-bearing areas.
researchers are working on various aspects of composite Therefore, the elastic modulus of Tetric N-Ceram Bulk Fill has
technology simultaneously in order to provide what today’s been tuned to a favourable level of 10 GPa. Flowable
dental professionals demand: a composite that avoids the composites are examples of restorative materials with a low
problems mentioned above. Controlling the processes involved modulus of elasticity. As a consequence, these materials
in polymerization is one of the keys to success, as will be demonstrate low shrinkage stress. Due to the high monomer
shown in the following article. content, however, their loss of volume during polymerization
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Figs 1 and 2 Pre-operative view (Fig. 1)


and at the recall after three months (Fig. 2)
(Pictures courtesy of Dr Eduardo Mahn,
Las Condes, Santiago, Chile)

Fig. 3 The shrinkage stress reliever attenuates


shrinkage-induced stress.

Shrinkage stress reliever


Modulus of elasticity
10 GPa

Glass filler
Modulus of elasticity
71 GPa
Monomer chain

Force

amounts to at least 3.5 per cent. Therefore, they have to be Low volumetric shrinkage, low shrinkage stress
applied in thin layers. Flowable composites are thus along cavity walls
recommended for use as cavity liners, for extended fissure
sealing and Class V restorations. They should not be used in This is when the shrinkage stress reliever unfolds its action.
cavities requiring thicker layers of material. A composite Due to its size and low modulus of elasticity of 10 GPa, this
restorative such as Tetric N-Ceram Bulk Fill (Figs 1 and 2), filler shows elastic, spring-like behaviour. As a consequence, it
which can be applied in increments of 4 millimetres and cured relieves shrinkage stress; moreover, due to its low surface
in a single step, should exhibit low shrinkage stress and low area, volumetric shrinkage is reduced. As the filler is partially
volumetric shrinkage. In order to achieve this, a special mixture functionalized by silanes, it “holds on” to the cavity walls
of fillers aimed at reducing shrinkage and shrinkage stress is together with the matrix and the adhesive by bonding to the
used in Tetric N-Ceram Bulk Fill (Fig. 3). walls. Moreover, its special silanization gives the stress reliever
a certain amount of freedom during polymerization so that it
can partially react with the polymer network and prevent
The solution: a shrinkage stress reliever shrinkage tension. The effectiveness of the shrinkage stress
reliever has been confirmed in several tests. A 4-mm increment
Apart from standard fillers with a modulus of elasticity of of Tetric N-Ceram Bulk Fill demonstrates volumetric shrinkage
71 GPa and a high degree of silanization, the new filler of only 2 per cent (Fig. 4). Consequently, operators have the
mixture also comprises a composite filler designed to relieve option of placing thicker layers without putting the restoration
shrinkage stress. This filler, which has a highly desirable and at risk. The measured stress level (Fig. 5) does not exceed
very useful elastic modulus of 10 GPa, is silanized in a special 1.13 MPa (Newton per square millimetre = megapascal) – a
way. Tetric N-Ceram Bulk Fill’s mode of action: During sound basis for achieving a good marginal seal. The
polymerization, the individual monomers move closer together investigations were conducted based on the test method
and combine to form a polymer network. As a result, the developed by Professor Dr David Watts of the University of
material starts to shrink: shrinkage forces develop and the Manchester, UK [3].
cavity walls are exposed to shrinkage stress (a measure for
shrinkage force per unit area).
15
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Vol.-% Shrinkage [MPa] Shrinkage stress


3 1.8
2.6
1.6
2.5 2.4
1.4
2.0 2.0
2 1.2

1
1.5
0.8

1 0.6

0.4
0.5
0.2

0 0
Tetric N-Ceram Spectrum TPH* Ceram.X Filtek Tetric N-Ceram Spectrum TPH* Filtek Z250* Ceram.X
Bulk Fill mono +* Z250* Bulk Fill mono +*

Fig. 4 Tetric N-Ceram Bulk Fill’s low volumetric shrinkage of 2 per cent is Fig. 5 Another positive effect of the stress reliever’s spring-like behaviour: the
attributable to the elastic properties and the special particle size of the shrinkage shrinkage stress level does not exceed 1.13 MPa in 0.8-mm layers
stress reliever. (Source: Measurements according to Literature reference [3],
(Source: Measurements according to Literature reference [3], R&D Ivoclar Vivadent AG, February 2013)
R&D Ivoclar Vivadent AG, July 2012)

[N] Shrinkage force Analysis of restoration margins:


140
Tetric N-Ceram Bulk Fill versus Tetric N-Ceram
130
120
110
100 2 mm + 2 mm 4 mm
90 Tetric N-Ceram Tetric N-Ceram
80 Bulk Fill
70
60
50
40
30
20
10
0
Tetric N-Ceram Spectrum TPH* Filtek Z250* Ceram.X
Bulk Fill mono +*

Fig. 6 Comparison of shrinkage forces occurring in different composites. With Fig. 7 Assessment of the marginal quality under the light microscope at 100-
a force of 110 Newton (N) acting on the cavity walls, Tetric N-Ceram Bulk Fill fold magnification. If restorations show 75 per cent or more intact margin, the
applied in 4-mm increments demonstrates a more favourable value than marginal quality is considered to be “excellent“.
conventional composites placed in 2-mm layers. (Source: R&D Ivoclar Vivadent AG, 2014)
(Source: R&D Ivoclar Vivadent AG, 2012)

Virtually the same low shrinkage forces were observed in The result: tight marginal seal
4-mm increments as in conventional 2-mm increments (Fig. 6).
It is definitely reassuring to know that the shrinkage forces of An analysis of the margins of composite restorations clearly
95 Newton produced in a bulk-cured Tetric N-Ceram Bulk Fill shows that low shrinkage and low shrinkage force or stress (a
increment of 4-mm thickness are lower than those occurring measure for shrinkage force per unit area) are clinically
in 2-mm increments of clinically proven products (e.g. Filtek relevant factors. An investigation involving Tetric N-Ceram
Z250). The measured data confirm that the bulk-filling Bulk Fill and Tetric N-Ceram fillings placed in extracted teeth
material is clinically acceptable and the marginal quality of the has shown that good marginal quality is achieved with both
filling is not compromised. It can thus be concluded that products (measurements with the light microscope showed
intermediate polymerization after the placement of 2-mm ≥75 per cent intact margin on average). For the purpose, one
increments is unnecessary. The entire cavity can be filled in one 4-mm deep and 5-mm wide cavity was prepared on the mesial
go and bulk-cured with any curing light currently available. and distal aspect each of a molar. The cavities were pre-treated

* Not registered trademarks of Ivoclar Vivadent.


16
specialfeature

Fig. 8 Due to the rotating light probe, even difficult-to-reach areas can be accessed.
The 10-mm wide probe enables large fillings to be cured in one curing cycle.

with the Tetric N-Bond adhesive system. One cavity was presented here. Successful restorative results are also
conventionally filled with three increments of Tetric N-Ceram dependent on effective curing lights. When bulk-curing 4-mm
composite (one cervical and two oblique occlusal increments), increments of Tetric N-Ceram Bulk Fill in 10 seconds, the use
which were individually light-cured. The other cavity was filled of a high performance LED curing light is certainly advantageous
with a single 4-mm increment of Tetric N-Ceram Bulk Fill and and saves considerable time. The new Bluephase N from
cured in only one step. Each group comprised 6 fillings. After Ivoclar Vivadent is ideal for this purpose. In addition, it allows
having been stored in water for 24 hours at 37°C, the teeth all the currently available dental composites to be cured
were subjected to thermocycling (10,000 cycles, 5°C/55°C). effectively and efficiently. The broadband wavelength spectrum
Following this, the margins of both fillings were semi- covered by the polywave technology of Bluephase N is suitable
quantitatively analysed under a light microscope (8-fold for the excitation of all photo-initiator systems currently
magnification). If restorations show 75 per cent or more intact employed in composite restoratives. With 1,200 mW/cm2
margin, the marginal quality is considered to be “excellent”. (milliwatts per square centimetre), Bluephase N features a high
This applied to both materials in this case. light intensity. This means that its light intensity corresponds
to that of Bluephase G1, a curing light whose reliability in
terms of light intensity has been confirmed in a study
The role played by the curing light conducted at the University of Mainz (Germany). The German
scientists measured the actual light intensity of LED
Dental manufacturers not only have to provide materials polymerization lights of different manufacturers used on a
suitable for the bulk-filling technique, e.g. by means of the regular basis in 301 dental surgeries [4]. The low fluctuation
incorporation of a shrinkage stress reliever such as in the case range of ±10 per cent mentioned in the Bluephase Operating
17
specialfeature

Instructions was confirmed by the study. Other curing lights


were shown to produce much weaker light intensities than Photo-initiators –
those indicated by the manufacturers. A US study conducted
with brand new LED curing lights provided by the manufacturers Curing lights –
revealed similar results [5]. Because of its excellent curing Composite esthetics
power, Bluephase N allows 4-mm thick layers of Tetric
N-Ceram Bulk Fill to be reliably cured down to the cavity floor
in only ten seconds. Only one curing cycle is required. This is Camphorquinone is the most important photo-initiator.
made possible by the parallel-walled design of the light probe, From their beginnings, polymerization lights were tailored
among other things. It ensures that the light intensity is kept and restricted to the wavelength range of camphorquinone.
constant until the light hits the restoration surface. In contrast This initiator features an absorption peak in the visible blue
to conventional lights, Bluephase N comes with light probes light spectrum between 465 and 475 nanometres and
that feature a wide diameter of 10 millimetres. As a result, therefore produces a pronounced inherent yellowish tinge.
even large restorations can be reliably cured in one curing Since camphorquinone does not completely break down
cycle. Reaching the posterior molars, which can be difficult during polymerization, the composite keeps its slightly
with conventional lights, is no problem at all with Bluephase yellowish hue even when it is cured. This does not represent
N. Its freely rotatable light probe allows excellent accessibility a problem for teeth that fall into the standard range of
to all restored areas. Consequently, time-consuming shades; to the contrary, a slightly yellowish tone is often
prolongation of the irradiation time is unnecessary (Fig. 8). even desirable.

Tetric N-Ceram Bulk Fill contains Ivocerin®, a newly developed


photo-initiator for which Ivoclar Vivadent owns a patent.
Literature This polymerization booster (accelerator) allows the
composite to be endowed with a favourable enamel-like
[1] Kleverlaan CJ, Feilzer AJ. Polymerization shrinkage and contraction stress of translucency (see main text). It has an absorption peak at
dental resin composites. Dent Mater 2005;21:1150- 1157. around 415 nanometres, which is significantly lower than
[2] Ferracane JL, Mitchem JC. Relationship between composite contraction that of camphorquinone. However, its reactivity is so high
stress and leakage in Class V cavities. Am J Dent 2003;16(4): 239-243.
that it is capable of absorbing light in a broad wavelength
[3] Watts DC, Marouf AS, Al-Hindi AM. Photo-polymerization shrinkagestress
range (from 370 to 460 nanometres). This allows the
kinetics in resin-composites: methods development. Dent Mater. 2003
Jan;19(1):1-11. composite to be cured with conventional curing lights.
[4] Ernst C-P et al. Feldtest zur Lichtemissionsleistung von Polymerisationsgeräten With an absorption peak at around 400 nanometres, acyl
in zahnärztlichen Praxen. DZZ 2006;60(9):466-471. phosphine oxide (e.g. Lucirin) is used as photo-initiator in
[5] ADA, American Dental Association. Professional Product Review, Vol. 1, conjunction with shorter wavelength ranges. This photo-
Issue 2, Fall 2006 (2006;1[2], Herbst 2006).
initiator is contained in bleach shades, for example, as it
offers a convenient advantage: the material does not
discolour during polymerization.

The Bluephase N curing light is equipped with polywave


technology and consequently emits light in a broadband
Contact details: spectrum that is suitable for all initiators currently available
Dipl.-Ing. Karin Vogel on the market. This LED light is therefore compatible with
Senior Research Associate: Restoratives and Prosthetics all light-curing composite resins.
Ivoclar Vivadent AG, Schaan, Liechtenstein
18
specialfeature

More than
just Hans-Christian Weinhold, Dentist

time-saving
Ivoclar Vivadent AG

Enhancing the profitability of dental practices

Hans-Christian Weinhold, general dentist, discusses the use of the bulk-filling technique in the dental
practice – Major breakthrough in the field of direct posterior composite resins

Dental practices can now benefit from a new level of addition, the application of several increments allowed dental
efficiency. The need for applying several increments of professionals to combine different shades to improve the
composite material to fabricate posterior restorations has been esthetic outcome. This has been the textbook procedure for
eliminated in many cases. The reason: Ivoclar Vivadent’s generations of dentists.
innovative nano-hybrid composite Tetric® N-Ceram Bulk Fill
allows users to save valuable time.
A true bulk-fill composite
Without having to use a flowable material or apply an
additional covering layer, cavities with a depth of up to four The incremental technique, however, has a major drawback: It
millimetres can be filled in one step. The material does not is very time-consuming. Creating highly esthetic, high-quality
require intermediate polymerization and is cured within ten restorations in a time-saving procedure still was an unmet
seconds. Compared with the conventional layering technique, requirement; amalgam and its short processing time were and
bulk-filled resin restorations are completed in half the time. If still are present in the minds of dental professionals. With the
the material is used in conjunction with a high-performance new posterior composite from Ivoclar Vivadent, dentists can
LED curing light, for instance the new Bluephase N®, one benefit from a time-saving procedure that does not require
curing cycle is sufficient to cure all deep restorations made the application of the incremental technique (Figs 1 and 2).
with this material. This applies even to large restorations, From the point of view of the dentist, there are three aspects
because this state-of-the-art curing light features a large light which make this possible: efficient four-millimetre bulk filling,
probe with a diameter of ten millimetres and a correspondingly one material for the entire restoration from the bottom to the
wide light emission window. Tetric N-Ceram Bulk Fill and top and short one-step curing cycles.
the new Bluephase N are reliable partners in routine work
procedures. It goes without saying that these products can To allow the placement of large increments, the fillers used in
also be used separately. The introduction of the incremental Tetric N-Ceram Bulk Fill had to be modified in such a way that
technique represented a significant step forward in restorative the volumetric shrinkage and the shrinkage stress remained
dentistry. By dividing a restoration into several increments, low and a sound marginal quality could be achieved. In
dentists were able to control the polymerization shrinkage and addition, a “light sensitivity inhibitor”, which slows down the
thus improve the marginal quality of the restorations. For a reaction to light, provides for an ample working time of more
long time, halogen curing lights and a curing time of than three minutes; the operatory light does not initiate the
40 seconds were considered to be the gold standard. In polymerization process. This effect allows users to fully benefit
19
specialfeature

Figs 1 and 2 A great deal of time can be saved thanks to the bulk-filling technique: by placing four-millimetre increments, by using only one material for the entire
cavity from the bottom to the occlusal surface and by curing the entire restoration for ten seconds in a single curing step. Teeth 24 and 25 were restored with Tetric
N-Ceram Bulk Fill, shade IVA; tooth 26 was restored with Tetric N-Ceram.

Tetric N-Ceram Bulk Fill / Ivoclar Vivadent QuiXfil / Dentsply x-tra fil / Voco

Fig. 3 Compared with all other bulk-fill composite materials, Tetric N-Ceram Bulk Fill features very small fillers (left).

1.2
Tetric N-Ceram
Bulk Fill
1
Filtek Z250
0.8
ceram.x mono+
0.6
Spectrum TPH3

0.4
QuiXfil

0.2 Synergy D6 Fig. 4 Mean surface roughness (µm) of various


Brilliant NG composites compared to that of Tetric N-Ceram Bulk Fill
0 after polishing with OptraPol in relation to the polishing
320 grit 10 s 20 s 30 s time
R&D Ivoclar Vivadent, Schaan, 2012
20
specialfeature

from the efficiency potential of this new material. The However, some users might ask themselves how they can
composite features a smooth consistency. It can be easily possibly achieve an adequate esthetic outcome for the
applied in the cavity and it is packable. Furthermore, it does different patient cases and tooth shades if only one material is
not stick to instruments and it readily adapts to the cavity floor applied in only one increment? The most important reason
and walls. In contrast to flowable composite, this material has why Tetric N-Ceram Bulk Fill produces such beautiful
a viscosity that is ideally suited to contouring the occlusal area restorations is the material’s lifelike translucency. In order to
and contact points in a short time. The convenient consistency ensure that restorations are fully polymerized, other bulk-fill
is achieved by means of patented layer silicates. materials exhibit a higher translucency, at the risk of causing
restorations to appear grey in some instances. This is not so in
As opposed to other bulk-fill materials, Tetric N-Ceram Bulk Fill the case of the new bulk-fill material from Ivoclar Vivadent,
does not require an additional covering layer. This is another where the small mean filler size and the coordinated light
aspect that helps save time. The filler particles used in Tetric refraction indices of the fillers, the nano-pigments and the
N-Ceram Bulk Fill have a comparatively small diameter (Fig. 3). monomer matrix, combined with the material’s translucency
Hence a high wear resistance and a compact surface is level, enable a balanced and lifelike shade adaptation to the
achieved, which can be quickly polished to a high gloss. And surrounding tooth substance. Three shades (Fig. 5) are
this, in turn, allows for further time savings (Fig. 4). The level therefore sufficient to cover almost the entire shade spectrum
of efficiency is further boosted by employing the newly from deciduous teeth to permanent teeth showing age-
developed one-step polishing system OptraPol®. Using the related characteristics. With the universal shades IVA (universal
small or the large flame, the cup or the lens, a high gloss can A shade), IVB (universal B shade) and IVW (whitish), time-
be created on the different restoration surfaces within just a consuming shade determination and shade selection are a
few seconds. thing of the past. In addition, with only three shades, stock-
keeping of syringes or Cavifils is reduced. To enhance the
esthetic outcome, an opaque flowable material, for instance
Tetric N-Flow Dentin A3.5, can be used for masking purposes.
A situation where this procedure may prove helpful is when
discoloured tooth substance is left on the preparation after the
removal of an amalgam filling.

Efficient light-curing

The efficiency that is achieved with the convenient application


of Tetric N-Ceram Bulk Fill also extends to the polymerization
process. With the new Bluephase N LED curing light, the
polymerization process requires a single step and only takes
ten seconds. First and foremost, this is possible due to the high
light intensity of 1,200 mW/cm2 (milliwatts per square
centimetre) and the light probe’s large diameter of ten
millimetres. The light cone thus completely covers large
restorations, which are encountered quite frequently, and
therefore renders repeated curing cycles unnecessary. Practical
Fig. 5 A natural-looking shade adaptation is achieved with only three universal
experience has shown: An estimated 20 per cent of all fillings
shades. The material is supplied in Cavifils or syringes to suit the user’s preference.
21
specialfeature

Figs 6 and 7 The light is focussed through the parallel-walled light probe of Bluephase N (left) and maintains its high intensity. The curing time must only be doubled at a distance
of approx. 9 mm. If the LEDs are located in the tip of the light probe (right), the curing time has to be doubled already at a distance of only 2 to 4 millimetres.

Fig. 8 The handpiece can be connected to the mains with only one click, so that
even in emergency situations curing can continue without interruption.
22
specialfeature

placed in adult patients are too large to be polymerized with Continuous curing due to
the light of an eight-millimetre light probe in a single curing constant energy supply
step. A large-size light emission window is therefore a
beneficial feature that helps to keep the curing step short in Many dental professionals still have considerable doubts when
all cases. it comes to issues such as battery life and problem-free
continuous operation which is a prerequisite for efficient
The parallel-walled light probe also helps to achieve time curing procedures. Their concerns are justified in conjunction
savings. Due to its design, the light is not diffused but focussed with numerous conventional curing lights, whose batteries
onto the restoration surface (Figs 6 and 7). As a result, a ten- show a declining performance due to the memory effect.
second curing cycle at a high light intensity is possible. Other These devices are not available for use while the battery is
commercially available curing lights which are equipped with being charged. However, Ivoclar Vivadent has found a solution
an LED mounted at the light emission window form a wide to this problem: In addition to employing state-of-the-art
light cone of scattered light. The light of these LEDs is diffuse lithium-polymer technology to ensure a high and continuous
and, due to the irradiation behaviour, dispersed to the entire performance without any memory effect, the battery of the
oral cavity, rather than focused onto the restoration. When Bluephase light can be conveniently replaced with the mains
only 50 per cent of the original light intensity reaches the component of the charging base. As a result, operators may
composite, the curing time has to be doubled. This may be the change to mains operation whenever required. Even if the
case already at a distance of two to four millimetres. In the light has not been placed back into the charging base for a
case of Bluephase N, the time does not have to be doubled at prolonged period of time, curing can still be continued
distances of less than nine millimetres. The curing time of ten without interruption thanks to the Click & Cure function
seconds is therefore applicable in virtually all patient cases. (Fig. 8). Additionally, the virtually noiseless fan ensures

Class II composite filling: Depth 4 mm/diameter 8 mm

Conventional application * Application of Tetric N-Ceram Bulk Fill


with Bluephase N
Application time Polymerization time Application time Polymerization time
1st increment 40 s 10 s
60 s 10 s
2nd increment 60 s 10 s
Total 100 s 20 s 60 s 10 s
Fig. 9 Impressive calculations: Placed in
Total application and
120 s 70 s four-millimetre increments and cured only
polymerization time per filling
once for ten seconds with the Bluephase N
LED light, the Tetric N-Ceram Bulk Fill
* 2-mm, standard composite resin/polymerization according to the manufacturer’s instructions material saves the dental team valuable
time.
23
specialfeature

unlimited use irrespective of the clinical situation. It prevents


overheating of the curing light even during continuous
operation, which can be required in the consecutive
cementation of multiple restorations such as the in placement
of 10 veneers, for example. Annoying waiting times due to
overheating shutdown protection are thus avoided.

The bottom line for the dental practice:


time savings

The time savings that can be achieved by using the bulk-filling


technique in conjunction with a single short curing cycle can
be quantified on the basis of practical experience (Fig. 9).
When two increments are placed and intermediately cured
once, the time that is saved already amounts to one and a half
minutes – or 50 per cent – per restoration. Consequently, for
dentists who are used to working with the conventional
technique involving the application of three or four increments,
the time savings are even higher. Changing from other bulk-
fill materials which are more time-consuming to apply than
Tetric N-Ceram Bulk Fill is also a worthwhile decision. Time
savings are further enhanced with the bulk-fill technique and
direct restorative procedures in general if the new LED light
and its ten-millimetre light probe are used.

The valuable time that is saved can be put to good use: for a
well-deserved break, for one or two additional patient
appointments per day, for a more comprehensive patient
consultation – there are many things we could think of.

Contact details:
Hans-Christian Weinhold
Dentist, Professional Services Manager
Ivoclar Vivadent AG, Schaan, Liechtenstein
Fixed
DirectProsthetics
Restoratives

Tetric® N-Ceram Bulk Fill and Bluephase N® form a part of the “Direct Restoratives” product category. The products of
this category cover the procedure involved in the direct restoration of teeth – from preparation to restoration care. The
products are optimally coordinated with each other and enable successful processing and application.

OptraGate® Tetric® N-Bond Tetric® N-Ceram Bulk Fill Bluephase N® OptraPol® Fluor Protector N

PREPARE BOND fill cure FINISH MAINTAIN

THESE ARE FURTHER PRODUCTS OF THIS CATEGORY:

OptraGate ®
Fluor Protector N
Latex-free lip and cheek retractor The protective fluoride varnish

The gentle solution for a better view Superior protection against dental caries
and erosion
• Considerably enlarged access to the treatment field • Effective– immediate fluoridation of enamel
• Enhanced patient comfort due to three-dimensional flexibility • Efficient– immediately ready for use
• Wide range of indications • High-yielding – economical delivery

Would you like to know more about the products of the “Direct Restoratives” category? Simply get in touch
with your contact person at Ivoclar Vivadent or visit www.ivoclarvivadent.com for more information.
Descriptions and data constitute no warranty of attributes
Printed in Germany © Ivoclar Vivadent AG

Ivoclar Vivadent AG
Bendererstr. 2
674729/en/2014-11-24

9494 Schaan
Liechtenstein
Tel. +423 235 35 35
Fax +423 235 33 60
www.ivoclarvivadent.com

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