Ashwani Tyagi Sir (Code: ATJEE)

M.M. 100 Time: 1 Hour

General Instruction:
(i) There are two section in this paper. Section A and B.
(ii) Section A contain 20 multiple choice question with single correct option. All questions are mandatory in
this section.
(iii) Section B contain 10 integer type question out of which 5 question is mandatory.
(iv) Each section carries 4 marks for correct answer and –1 for wrong answer.

SECTION A
This section contains 20 multiple choice question with single correct answer. All questions are mandatory in
this section.
Each question in this section contains 4 marks for correct answer and –1 for wrong answer.

1. Nature of SnO2 is
(A) Acidic (B) Basic (C) Amphoteric (D) Neutral
2. Aerosols present in air are
(A) Negatively charged (B) Positively charged
(C) Neutral (D) Combination of all of the above.
3. Which of the following has highest pKsp value at 25°C?
(A) Mg(OH)2 (B) Ca(OH)2 (C) Sr(OH)2 (D) Ba(OH)2
4. In which of the following compounds does deuteration take place easily on treatment with D2O?
(A) CH3CH2OH (B) CH3—CH3
(C) CH3CH2—O—CH2CH3 (D) CH3CH2Cl
5. Which of the following is arranged in order of increasing radius?
(A) K+ (aq) < Na+ (aq) < Li+ (aq) (B) K+ (aq) < Na+ (aq) < Zn2+ (aq)
(C) K+ (aq) < Li+ (aq) < Na+ (aq) (D) Li+ (aq) < Na+ (aq) < K+ (aq)
6. Orthoboric acid cannot titrated effectively in the presence of
(A) Glycerol (B) Mannose (C) Ethylene glycol (D) Ethanol
7. MgSO4 is soluble while BaSO4 is insoluble in water. This is because
(A) Lattice energy of BaSO4 is greater than that of MgSO4
(B) BaSO4 is more covalent than MgSO4

(C) Hydration energy of Mg2+ compensate the lattice enthalpy factor but it is not possible in BaSO 4
(D) Hydration energy of SO42– in BaSO4 is lesser than that in MgSO4
8. Heavy water freezes at
(A) 270.7 K (B) 276.1 K (C) 269.2 K (D) 276.8 K
9. Which of the following is arranged in order of decreasing boiling point?
(A) Mg > Ca > Hg > Zn (B) Hg > Zn > Mg > Ca (C) Ca > Mg > Zn > Hg (D) Zn > Hg > Ca > Mg

Ashwani Tyagi Sir 1 Code: ATJEE

11-Inorganic Chemistry JEE Main Test
10. Which of the following statements is incorrect?
(A) Boron carbide is used as an abrasive.
(B) Boron is used to increase the hardenability of steel.
(C) Boron sesquioxide, B2O3, is used in the manufacture of borosilicate glass.
(D) Orthoboric acid undergoes intramolecular hydrogen bonding.
11. Boron nitride is a
(A) white solid with a diamond-like structure
(B) slippery white solid with a layered structure similar to that of graphite
(C) covalent liquid and is structurally similar to carbon monoxide
(D) soft low-melting solid with a rock-salt–like structure
12. Which of the following statement is false?
(A) London smog is oxidising in nature (B) London smog contains H2SO4 droplets
(C) London smog is formed in winter (D) London smog causes bronchitis
13. Lake containing excess of nutritious substances are called
(A) Polluted Lakes (B) Eutrophic Lakes (C) Dead Lake (D) Green Lake
14. Which of the following is incorrect?
(A) NH4  D2 O  NH3D  HDO (B) PH3 + D2O  PD3 + H2O
(C) CH3NH2 + D2O  CH3NHD + HDO (D) CH3OH + D2O  CH3OD + HDO
15. Which of the following halides is stable to hydrolysis?
(A) SiCl4 (B) PF3 (C) NCl3 (D) NF3
16. Carbon suboxide (C3O2) may be obtained by heating
(A) malonic acid with P4O10 (B) malic acid with P4O10
(C) oxalic acid strongly (D) maleic acid with P4O10
17. SO2 causes
(A) Respiratory and lung disease (B) Acid rain
(C) Corrosion of building material (D) All of the above.
18. Hydrogen is obtained as a by-product in the
(A) electrolysis of water (B) manufacture of caustic soda
(C) Bosch process (D) Lane process
19. Which of the following pairs of molecules have the identical bond dissociation energies?
(A) F2 and H2 (B) N2 and CO (C) F2 and I2 (D) HF and O2
20. Carbon-60 contains
(A) 20 pentagons and 12 hexagons (B) 12 pentagons and 20 hexagons
(C) 30 pentagons and 30 hexagons (D) 24 pentagons and 36 hexagons

SECTION B
This section contains 10 integer type question out of which only 5 question is mandatory.
Each question in this section contains 4 marks for correct answer and –1 for wrong answer.

21. How many of the following alkaline earth metals have density greater than beryllium?
Magnesium, Calcium, Strontium, Barium and Radium
22. Total number of sp3 hybridised central atoms (B and P) in one molecule each of borax and P4O10 is
23. 10 ml of water requires 1.47 mg of K2Cr2O7(M. wt. =294) for oxidation of dissolved organic matter
C.O.D is
24. HBr molecule has internuclear distance of 1.27  10–10 m. The electronic charge is 4.8  10–10 esu.
Observed dipole moment is 1.03 D. find % ionic character of the bond.
25. Ferric alum has the composition (NH4 )2 SO4 .Fe2 (SO 4 )3 .xH2 O

Ashwani Tyagi Sir 2 Code: ATJEE

11-Inorganic Chemistry JEE Main Test
26. The electronegativity of H, N are 2.1, 3.0 respectively. Calculate percentage ionic character of H – N
bond.
27. The amount of H2O2 present in 1 L of 1.5 N H2O2 solution is
28. Calculate Alred Rochow electronegativity in F using Slater rule, rF = 0.7065 Å.
29. A mixture containing 2.0 mol each of H2 and O2 is ignited so that water is formed. The amount of water
formed is
30. A commercial sample of hydrogen peroxide is labelled as 10 volume. Its percentage strength is nearly
_________.

Space for Rough Work

Ashwani Tyagi Sir 3 Code: ATJEE