Fiitjee All India Test Series: Concept Recapitulation Test - Iii

FIITJEE
ALL INDIA TEST SERIES

CONCEPT RECAPITULATION TEST – III
JEE (Advanced)-2021
PAPER – 2
TEST DATE: 04-07-2021
ANSWERS, HINTS & SOLUTIONS

Physics PART – I
SECTION – A
1. ABC
Sol. When C2    shorted
Then the circuit becomes
 V1  V  12 volt
C1 C3 C1
V V
When C2 = 0 then circuit becomes

3 Volt
C1 C3
 VC3  12  3  9V
Since, C1 and C3 are in series, so charge will be same on both the capacitors.
C
C1  3  C3  9  1  3
C3
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2
AITS-CRT-III (Paper-2)-PCM(Sol.)-JEE (Advanced)/2021
2. B
Sol. 0  dU  PdV  d a  bPV   PdV
After solving
b 1
b
PV = constant
3. ABC
2
 f  36  22.5   36 
Sol. VIP         3cm / s
 f u   22.5  90   4 / 3 
4. AB
2m
Sol. Distance of the target x  (n) v cos  , where n is an integer
qB
nv v 0

B B0
5. BC
Sol. The frequency received by the reflector is
 V  W  Vr 
f1   f
 V  W  Vs 
The frequency of the reflected wave received by the detector is
Vr

VS VD
S D
Reflector
 V  W  VD   V  W  Vr 
f2    f
 V  W  Vr  V  W  Vs 
 330  10  10  330  10  20 
   527
 330  10  20  330  10  30 
 310  320 
f2      527  496Hz
 340  310 
The wavelength of the reflected wave received by the detector is
V  W  VD 330  10  10 5
2    m
f2 496 8
6. BD
Sol. When switch S is open
250
V1   6000   150 V
10000
250
V2   4000   100 V
10000
3
250 V
V1 V2
R1 R2
When switch S is closed circuit reduces to shown in the figure.

250
So both the voltmeters show readings V1  V2   125 V
2
SECTION – B
7. 8
4T
Sol. Initially Pin  , where Pin = inside pressure …(i)
r
Poutside = 0 (always)
2 4T
When charge is sprayed, for equilibrium Pin'   ...(ii)
2 0 2r
Since, isothermal process
PV P
 Pin'  in i  in ...(iii)
Vf 8
4T 2 4T 3T0
Using equations (i), (ii) and (iii) we have,   
8r 20 2r r
8. 5
  
Sol.   
FB  I L  B  I LKˆ  B 0 aˆ r  B 0ILaˆ t 

Fexternal  B0IL  aˆ t 
Work done by external agent to turn the conductor by 2 radian
FB  B0IL  aˆ t 
â t
âr
d B0 aˆ r
conductor

Fext  B0IL  aˆ t 
2
W  B IL  aˆ .rdaˆ
0
0 t t  2rB 0IL
P  2rB0ILN  0.5 W
9. 5
Sol. When the wedge has moved through a distance y, let the point of contact of cylinder have moved
down the plane through x (with respect to wedge). Let F be the friction between the cylinder and
the plane.
Since there is no horizontal force on 9wedge + cylinder system)
4
d2 y  d2 y d2 x 
M  m  2  cos  0 ...(i)
dt 2  dt dt 2 
 d2 y d2 x  ma d2 x ma2 d2 
Also, m  2 cos   2   F  mgsin  and   Fa, so that
 dt dt  2 dt 2 2 dt 2
d2 y  d2 x 
2 2 cos   3  2   2gsin  ...(ii)
dt  dt 
Equation (i) and (ii) implies acceleration of the centre of the cylinder down the face, and relative to
2gsin   M  m 
the wedge, is  5 m / s2
3M  m  2m sin2 
10. 5
Sol. Assume that the drum rolls away from the force P, so that the friction F is away from P. Then:
P
600
fs Side view
d2  d2  d2 x
Mk 2  Pa  Fb andMb  M  F  P cos 600
dt 2 dt 2 dt 2
d2   b

M k 2  b2
dt 2 
 P a  
 2
2
d
 0.25  8 2  10 1.5  1
dt
2
d
 2  2.5rad / s2
dt
d2 
and the required acceleration  b 2  2  2.5  5 m / s2
dt
11. 6
E
Sol. With both switches open: IA 
R1  R2  R3
R1
A
R
R3
E
R2 _
+
1.5 V
With both switches closed:
Current through E and R2
5
E
I' 
RR1
R2 
R  R1
Current through the ammeter
RI'
I'A 
R  R1
IA  I'A
R1R2
R  600
R3
12. 2
Sol. v1 cos   v 2 sin 
v1  v 2 tan 
Fixed
0 Vertical
v1  v 2 3 (given   60 ) Guide
Now using conservation of energy m
1 1 v1
mga 1  cos    mv12  Mv 22
2 2
P
 2ga  2v12  4v 22 
M
40  6v 22  4v 22 v2
 10v 22  40 O
 v2  2 m / s
 v1  2 3 m / s
v1 sin   v 2 cos 
  2 rad / s
a
SECTION – C
13. 00000.80
Sol. IC.B.F  K  A12  A 22  2A 1A 2 cos    I0
I0
KA 2 
16

, A 1  A,A 2  3A and   00 
16
I0  K  A12  A 22  2A 1A 2 cos    1
25 
2 2 2 3
 x   dsin   d
   5
So,   
I0 16 5  16
Hence, I     0.80 W / m 2
4 25 100
6
14. 00032.50
Sol. Loss in gravitational potential energy = Gain in Kinetic energy
2
L L  1 ML 2
Mg   cos 600    N
2 2  2 3
3g
  15 rad / s
2L
When rod is at its lowest position the forces acting on it are as FB mg
shown in the diagram.
Magnetic force on the rod
  x L
q  1
 
FB   dq v  B    dx    X   B  qBL
x0  L  2
L
 N  mg  FB  m 2
2
L
N  mg  FB  M2
2
1 2 1
 1 10   1 15  2 15  1  1 15 
2 2
 
 10  15  7.5  32.5N
15. 00195.00
Sol. Coordinates of the ball at t = t is
x  ucos t
1
y  usin t  gt 2
2
y
u

x
2usin 
and time of light is
g
Area under trajectory is
2 sin 
x g
 gt 2 
A   ydx    u sin t   ucos dt
0 0  2 
4
2u
A  sin3  cos 
3g2
dA
For A to be maximum, 0
d
   600
3u4
 A max   194.85  195m2
8g2
16. 00015.38
Sol. Total work done by gas per cycle, Wcycle  P0 V0
During the process AB
7
3R 3 3
Q AB  nCv T  n T  V0  2P0  P0   P0 V0
2 2 2
During the process BC
5R 5
QBC  nCP T  n T   2P0  2V0  V0   5P0 V0
2 2
Efficiency of the cycle
Wcycle P0 V0 1
  100   100   100  15.38%
Qsup plied  3P0 V0  13
 2  5P0 V0 
 
17. 00002.50
Sol. v 0  h sin 
v0 2v
   0  2.50 rad/s
hsin  h
18. 00004.50
Sol. When the ball A leaves the horizontal surface
T = mg … (i)
2
m  2v 
T  mg 

4mv 2
2m 

g
v ...(ii)
2
Now, using conservation of Energy
B
T + mg
A v
mg
1 1
mu2  2  mv 2  mg
2 2
u  2v  2g
2 2
u2  g  2g
 umin  3g  3  10  0.675  4.50 m / s
8
Chemistry PART – II
SECTION – A
19. ACD
Sol. Cl Cl Cl
(A) N: N: :N
Cl Cl Cl Cl
Cl Cl
sp2 sp3
sp3
(electronegative nitrogen become more electronegative because chlorine atoms pull
electron density away from nitrogen than methyl group in N(CH3)3, creating electron
defficient N, and destabililising the T.S)
(B) After charge separation due to shifting of  electron
(1) 2 aromatic ring stabilised by resonance.
(2) 2 aromatic ring more stable than (1) due to extra resonance
1 aromatic ring
(3)
1 anti - aromatic ring required more energy for charge separation
Bond rotation energy is III > I > II

Bond rotation order II > I > III
N N
Et
(C) Et Et
Least basic N N
due to amine inversion
Less basic most basic

due to - I of 2nd N
No amine inversion
9
(D) Stability of conjugate base  Acidic nature of conjugate acid

CO 2Et O O
O EtCOO COOEt COOEt

O
COOEt
(stability order of C.B.)
20. ABCD
Sol. (A) Co-ordination number in HCP = 12
B  Volume  Base area  height  h 
Base area = 6  area of equilateral triangle
3 2
 6 a
4
E
E
A
2r 2r = a
2r
h B
B
A
D O
A D
B
30oA
r
a = 2r O
OA  r
AOB  30o
2r
OB  BD 
3
2
2  2r 
EB   2r   
 3
2 h
 2r =
3 2
2
h  4r
3
Now, volume = h  area of base
2 3 2
=4r 6 a
3 4
2 3 2
 4r 6  2r 
3 4
 24 2 r 3
10
4 3
r 6
3
 C   Packing fraction =
volume of unit of unit cell
4
6  r 3
3 
 3

24 2 r 3 2
1 1
(D)  Z  12  at corner    2  face centres   3  in the body   6
6 2
h B
a = 2r
Z = No. of atoms per unit cell.
21. ABCD
Sol. (A) Due to stabilization of intermediate
(B) Less steric hindrance
(C) Fact
OCOCH 3
COOH
(D) A is Aspirin, an antipyretic.
22. ABC
Sol. Molten Zn and Pb are immiscible liquid and Ag is more soluble in molten Zn than molten Pb.
23. ABC
2NaOH
Sol. ZnCl2  2NaOH  Zn  OH2   Na2 ZnO 2  2H2 O
Na2 ZnO2  H2 S  ZnS  2NaOH
Na2 ZnO2  4CH3 COOH   CH3 COO  2 Zn  2CH3 COONa  2H2 O
2  CH3 COO 2 Zn  K 4 Fe  CN 6   Zn2 Fe  CN6   4CH3 COOK
3Zn2 Fe  CN 6   K 4 Fe  CN6   2Zn3K 2 Fe CN 6   White
2
24. ABCD
Sol. (A) Unacceptable because it is infinite over a finite region
(B) Unacceptable because it is not single valued
(C) Unacceptable because it is not continuous
(D) Unacceptable because its slope is discontinuous
11
SECTION – B
25. 4
Sol. Statement – 1 Singlet carbene has zero unpaired electron hence spin multiplicity
 2s  1  s = total spin
n
1 s , n0
2
Statement – 2 HO ,no. of electron = 2
According to (n +  ) rule
1s2 2s0 2p0

ground state 1st excited state 2nd excited state
Hence
1s 1 2s o 2p 1  2p 1  
Degeneracy = 3
Statement – 3 In presence of Mg vicinal dihalides involved in elimination reaction.
 
Statement – 4  AgF4  and  AuCl4  both are dsp2 hybridized.
26. 5
Sol.
NH 2 N2 Cl N N OCH 3
NO 2 NO 2
NaNO2, HCl NO 2
Anisole
00C
NO 2 NO 2 NO 2
A
27. 3
Sol. The lower IP indicates that X will be alkali metal hen X-OH should be a hydroxide of alkali metal
and higher value of IP Q indicates that It should be a halogen so QOH be an oxyacid. Hence the
statement that pH of QH is more than 7 is incorrect.
28. 3
Sol. Xe  Xe   1e  , I.E  1170 kJmol1
O 2  O2  1e , I.E  1175 kJ mol1
29. 6
Sol. change in oxidation state in Cr = 2 (+6 - 3) = 6
-3 +6
O +3
(NH4)2 Cr2O7 N2 + Cr2O3 + 4H2O
change in oxidation state = 2(-3-0)

In 'N" =-6
Hence nfactor = 6
12
30. 4
Sol. CH3 CH3
C2H5 C C C2H5
Br H
2
=2 =4
SECTION – C
31. 00009.65
 dEo 
Sol. So  nF  
 dT P

 2  96500C  5  105 VK 1 
 9.65 JK 1
32. 00001.69
Sol. q  0, w = - P  v 2  v1 
 1 20  10  dm3 atm (  1 atm dm3  101.3 J)
 1013 J
U  q  W  from FLOT 
dU  1013 J
 U=nCV T and H = nCP T
H CP  C V  R 
  
U CV CV
5 / 2R

3 / 2R
5 5
H  U  H    1013 
3 3
 1688 J
33. 00034.89
Sol. V    1 1 10  103 Litre
 3.14  10 4 Litre
P  0.8  26  20.8 mm of Hg
PV=nRT
20.8
 3.14  10 4  n  0.0821 300  n  34.89 mol
760
34. 00116.42
Sol. P  x T PTo  x BPTo x T , x B mole fraction of Toluene and Benzene respectively.
= 67.525 mm of Hg = a
1 1
When last trace of liquid will disappear then xB  vapour phase   , x T  vapour phase  
2 2
1 xT xB
Then  
P PT0 PB0
13
0.5 0.5
 
32.05 103
P = 48.9 mm of Hg = b
Then, a  b  116.42 mm of Hg
35. 00052.50
Sol. N O O
O
NH 3 N NH 3 N NH 3
Pt Pt Pt
O N NH 3 O NH 3
NH 3
N O N
(i) (ii) (iii)
NH 3 NH 3
N O N N
Pt Pt
O O O
N
NH 3 NH 3
(iv) (v)
100  5
 x  5 hence   52.5
2
36. 00001.60
Sol. Br
Br
NaOH
- H2O - Br-
OH O
O
M = 160
14
Mathematics PART – III
SECTION – A
37. AD
Sol. Using family of lines  a,b   1,1
   lim
sin x   cos x  2
x 0 x  1 0
38. AB
Sol. Using integration by parts
1
1
1
 n  .2x
In  x.   x. dx
2 n 2 n 1
1  x  0
0 1  x 
1 2
1 x  1 1
 n
 2n  dx
2 2 n 1
0 1 x  
1
  2n In  2n In 1
2n
39. AC
Sol. AB : y  x  2
AC : x  y  2
 For P (h, k),
hk 2 hk 2
 2k 2
2 2
y
 0,2  A
P  h,k 
x
B   2,0  C  2,0 
2
x2

 y  2 / 3  1  e=
2
.
16 / 3 16 / 9  3
40. ABD
dy
Sol.  y  f  x   ye x   ex f  x  dx  c
dx
If 0  x  2, ye x   e x .e  x dx  c  ye x  x  c
If x  2, ye x   e x  2 dx  ye x  e x 2  c
41. AD
Sol. f1  x   f2  x   f3  x   0  D  4a2  b2  4ac  0
15
2
f1  x   f2  x   0 D   2a  b   4  2b  c   Nothing can be said.
f1  f3  0 D  b2  4ac  8a2  0
42. ABC
n  n  1
Sol. (A) No. of entries  1 
2
(B) No. of entries  5  1
n  n  1
(C) Minimum no. of zeros 
2
(D) Maximum no. of non-zero entire =10.
SECTION – B
43. 5
1      
Sol. Area  ABC   | a  b  b  c  c  a |
2
      
Given 2a  3b  6c  a  b  2 c  a  
       
   
 2 ba  6 bc  3 bc  ab  
1  1 1
a  b 1   
Ar  ABC  2  2 3  11
      m  11, n  6
Ar  AOB  1 6
ab
2
44. 7
2 2
Sol. C1 :  x  1  y 2  9 C 2 :  x  2   y 2  49
CC1  r  r1 CC 2  r2  r  CC1  CC 2  r1  r2  2a  10
3
C1C2  3  2ae  e 
10
45. 6
2
Sol. Put x =1 f 1 .f " 1   f ' 1  Let f' 1  ,f " 1  
   2
Differentiate w.r.t x and put x = 1
8  2  2      8
   2,  4
46. 3
Sol. f  f  x    4x  3 and so on
 LHS  30x  26  x  3.
47. 4
Sol.      90o  tan=cot
tan   cot   2,tan2   cot 2   2       / 4.
16
48. 7
2 2 2
Sol. 15 2  15  d   15  2d   .......  15  9d   1185
On solving d = - 1
s  n   s  n  1  n  16  nmax  16
SECTION – C
49. 00016.00
Sol. Put x  1/ t  dx  1/ t 2 dt
I

0 t 2  at  1
 t 4 .  1  tan1 t dt
 

1 t4 t 2  t2 

x 2  ax  1
I  tan1 xdx
0
1 x4

x 2  ax  1 1 
 2I   dx  tan1x  tan1 
0 1 x2 x 2
 2 2 
 I  lim     K  16
a 
 8 2a 16 
50. 00006.28
 4 2x 2
Sol. f '  x   a  x2    f  x  
 3 3

x 4 
 Area bounded = 2 
y
2
x
O 2
51. 00003.40
 2x     
Sol.  sin1  2 
   ,   g  x  can be 0, 1, 2, 3
 1 x   2 2 
f  g  x    0  f  0   0 and f  3   0
7 
 a   ,2 
5 
52. 00771.00
Sol. Case 1 – No box empty,
x1  x 2  x 3  x 4  x5  10, xi  1  126
Case 2 – Exactly one empty,  420
Case 3 – Exactly two empty = 216
Case 4 – Exactly three empty = 9
Total ways = 771
17
53. 00001.14
.22 1
Sol. Area   .2.2    2
4 2
y
2
2
x
O
54. 00011.11
2 2
Sol. AB 2   r1  r2    r1  r2 
B
A
 r1  r2  r2
X
P
Q
 2 r1r2
100
r1   r2  9
9

Fiitjee All India Test Series: Concept Recapitulation Test - Iii

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Fiitjee All India Test Series: Concept Recapitulation Test - Iii

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FIITJEE

ALL INDIA TEST SERIES

ANSWERS, HINTS & SOLUTIONS

When C2 = 0 then circuit becomes

When switch S is closed circuit reduces to shown in the figure.

(1) 2 aromatic ring stabilised by resonance.

1 anti - aromatic ring required more energy for charge separation

Bond rotation energy is III > I > II

Less basic most basic

(D) Stability of conjugate base  Acidic nature of conjugate acid

O EtCOO COOEt COOEt

(stability order of C.B.)

change in oxidation state = 2(-3-0)

Mathematics PART – III

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