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IGCSE Chemistry TEST YOUR SELF CHAPTER 4
IGCSE Chemistry TEST YOUR SELF CHAPTER 4
a/Silicon
b/Tellurium
c/Polonium
d/Iodine
e/Arsenic
2.
a/Electronegativity will increase from left to right because the atom has more
effective nuclear charge so it will attract the electron more stronger
b/Atom radius will decrease from left to right because the atom has more effective
nucleus charge which will attract the electron more stronger, making the electrons closer
to the nucleus.
3.
a/ Mg Ca Sr Ba
b/ Na+, F-, O2- (isoelectronic configurations, consider Z. The more Z, the less
R)
c/ Al3+ Na+ Na K
d/ S Cl Cl- S2- I-
4.
a/False
b/False
c/True
d/False
e/True
5.
X is the metal because most metal has smaller effective nucleus charge than nonmetal so it’s
electronegativity and ionisation energy will be smaller.
6.
a/ 2Ru + 2H2O = 2RuOH + H2
b/ 2K + Br2 = 2KBr
c/ Cl2 + 2KBr = 2KCl + Br2
d/ Na2O + H2O = 2NaOH
e/ SO3 + H2O = H2SO4
7.
8.
a/ SO3 + H2O = H2SO4 (Acidic)
=> It formed acidic solution
9.
a/1s2 2s2 2p6 3s2 3p6 3d8
b/1s2 2s2 2p6 3s2 3p6 3d6
c/1s2 2s2 2p6 3s2 3p6 3d2
d/1s2 2s2 2p6 3s2 3p6 3d3
10.
a/ +2
b/ +2
c/ +2
d/ +3
e/ +3
f/ +3
g/ +6
h/ 0
11. - Electron configuration of ions:
Cu2+ : 1s2 2s2 2p6 3s2 3p6 3d9
Fe2+ : 1s2 2s2 2p6 3s2 3p6 3d6
Sc3+ : 1s2 2s2 2p6 3s2 3p6
Co3+ : 1s2 2s2 2p6 3s2 3p6 3d6
Mg2+ : 1s2 2s2 2p6
=> Cu2+,Fe2+, Co3+ is paramagnetic because Cu2+ has unpaired electron at the outer
shell (orbital p and energy level 3)
12.
Ti+4 : 3s2 3p6
V+5 : 3s2 3p6
Mn+3 : 3d4
Co+2 : 3d7
Cu+1 : 3d10
Zn+2 : 3d10
=> MnF3 and CoF2 produces color.
13. Longer wavelengths of lights → less (delta energy) (E = hc/(lamda))
a/
Co2+ :1s2 2s2 2p6 3s2 3p6 3d7
Co3+ :1s2 2s2 2p6 3s2 3p6 3d6
=> Co2+ will absorb the longer wavelengths because Co2+ has a smaller oxidation state
than Co3+, which will affect the delta energy and then affect the wavelength.
b/
Fe2+ :1s2 2s2 2p6 3s2 3p6 3d6
Fe3+ :1s2 2s2 2p6 3s2 3p6 3d5
=>Fe2+ will absorb the longer wavelengths because Fe2+ has a smaller oxidation state
than Fe3+, which will affect the delta energy and then affect the wavelength.
1.
a/ Ionic bonding
b/ Covalent bonding
c/ Ionic bonding
d/ Covalent bonding
e/ Covalent bonding
f/ Ionic bonding
2.
a/ MgO
b/ BaSO4
c/ Ca(OH)2
d/ Na2O
e/ SrS
f/ Al2O3
g/ Li3N
h/ Mg3(PO4)2
i/ MgF2
j/ K2SO4
k/ (NH4)2CO3 ( Ammonia = NH4+)
l/ Ag2S
m/ AgNO3
n/ NH4Cl
o/ Cu(NO3)2
p/ Rb2CO3
3.
Cl = 3.16
O = 3.44
H = 2.2
Br = 2.96
Na = 0.93
In order: Na H Br Cl O
4.
a/H-S(4 unbonded electrons)-H
Cl
c/Cl-C(0 unbonded electrons)-Cl
Cl
Cl
j/Cl-P+(0 unbonded electrons)-Cl
Cl
6.
a/
-lewis structure
-classify: AB2E2 → molecular geometry = bent
7.
● Polar molecules
HBr
HCN
SCl2
OCl2
● Non polar
PH3
CF4
N2
8.
8.
9.
10.
a/
b/
11.
a/K Na Li
b/Na Mg Al
12. Cl
a/Cl-P-O
Cl
O
b/O-Cl-O
O
O
c/ O-Xe-O
O
13.
a/Trigonal pyramidal, 107 degrees
b/T-Spahe, <90 degrees
c/Tetrahedral, 109 degrees
d/Sawhorse or Seesaw, <90 degrees and <120 degrees
e/Linear, 180 degrees
f/Octahedral, 90 degrees
g/
h/
i/
j/
14.
SOCl2
CIF5
17.
a/B = Boron
b/N = Nitrogen
c/O = Oxygen
d/C = Carbon
e/Be = Beryllium
f/S = Sulfur
g/P = Phosphorus
h/C = Carbon
i/Se = Selenium
j/N = Nitrogen
18.
19.
11.
a/
i/Because Aluminium has a larger effective nucleus charge
ii/
● Determine electron configuration
Al+:1s2 2s2 2p6 3s2
Al:1s2 2s2 2p6 3s2 3p1