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ME-112 Thermodynamics Assig

QUESTION 1
Note: I have converted MPa into Bars where 1 Bar=0.1 MP
Compressed Liquid Values
Temperature (Centigrade) Pressure (Bars) Specific volume (m^3/kg)
100 25 0.00104225
100 50 0.001041
100 75 0.00103975
100 100 0.0010385
100 150 0.0010361
100 200 0.0010377
100 250 0.00103335
100 300 0.001029
Saturated Liquid Values
Temperature (Centigrade) Pressure (Bars) Specific volume (m^3/kg)
100 1.0142 0.001043
Percent Deviation Properties
Temperature (Centigrade) Pressure (Bars) Specific volume (m^3/kg)
100 25 -0.07%
100 50 -0.19%
100 75 -0.31%
100 100 -0.43%
100 150 -0.67%
100 200 -0.51%
100 250 -0.93%
100 300 -1.36%

500
Single Graph of All Values
450
Specific Volume Specific Internal Energy
Enthalpy Entropy
400

350
Single Graph of All Values
450
Specific Volume Specific Internal Energy
Enthalpy Entropy
400

350

300

All Values
250

200

150

100

50

0
25 50 75 100 150 200 250 300
Pressure (Bars)
rmodynamics Assignment
0.001045

Specific Volume (m^3/Kg)


0.00104
nverted MPa into Bars where 1 Bar=0.1 MPa
ompressed Liquid Values
Specific Internal Energy (KJ/Kg) 0.001035
Enthalpy (KJ/Kg) Specific Entropy (KJ/Kg.K)
418.36 420.965 1.3053
417.650.00103 422.85 1.3034
416.94 424.735 1.3015
416.23 426.62 1.2996
0.001025
414.85 430.39 1.2958
413.5 434.17 1.292
412.1850.00102 437.955 1.28825
410.87
100 100 100
441.74
100 100 1.2845
100 100 100
aturated Liquid Values Temperature (C)
Specific Internal Energy(KJ/Kg)

420
Specific Internal Energy (KJ/Kg) Enthalpy (KJ/Kg) Entropy (KJ/Kg)
419.06 418 419.17 1.3072
cent Deviation Properties
416
Specific Internal Energy (KJ/Kg) Enthalpy (KJ/Kg) Entropy (KJ/Kg)
-0.17% 414 0.43% -0.15%
-0.34% 0.87% -0.29%
-0.51% 412 1.31% -0.44%
-0.68% 1.75% -0.58%
-1.01% 410 2.61% -0.88%
-1.34% 3.45% -1.18%
408
-1.67% 4.29% -1.47%
-1.99% 406 5.11% -1.77%
100 100 100 100 100 100 100 10

Temperature (C)

aph of All Values


me Specific Internal Energy
Entropy
aph of All Values
me Specific Internal Energy
Entropy

50 200 250 300


s)
100 100 100

Entropy V/S Te
1.31

Specific Entropy(KJ/Kg.K) 1.305

1.3

1.295

1.29

100 100 100 1.285

1.28

1.275

1.27
100 100 100 100

Tempe
Enthalpy V/S Temperature
445

440

435
Enthalpy(KJ/Kg)

430

425

420

415

410
100 100 100 100 100 100 100 100

Temperature (C)
Entropy V/S Temperature

100 100 100 100 100 100

Temperature (C)
Question 2
Superheated Water Vapor
Pressure (Bars) Temperature (Centigrade) Specific Enthalpy (KJ/Kg)
1 100 2675.8
1 150 2776.6 5000
1 200 2875.5
1 250 2974.5
1 300 3074.5
1 400 3276.6 4500
1 500 3488.7

Specific Enthalpy (KJ/Kg)


1 600 3705.6
1 700 3929.4
1 800 4160.2 4000
1 900 4398
1 1000 4642.8
0.1 50 2592
0.1 100 2687.5 3500
0.1 150 2783
0.1 200 2879.6
0.1 250 2977.5
0.1 300 3076.7 3000
0.1 400 3280
0.1 500 3489.7
0.1 600 3706.3
0.1 700 3929.9
2500
0.1 800 4160.6
0.1 900 4398.3
0.1 1000 4642.8
2000
0.7 100 2679.7 0 2
0.7 150 2778.73333333333
0.7 200 2876.86666666667
0.7 250 2975.5
0.7 300 3075.23333333333
0.7 400 3277.73333333333 1. Since the curves nea
0.7 500 3489.03333333333 2. However
0.7 600 3705.83333333333 We can concl
0.7 700 3929.56666666667
0.7 800 4160.33333333333
0.7 900 4398.1 Question:
0.7 1000 4642.8 Answer:
0.35 100 2684.25 (2) At below 10 Kp
0.35 150 2781.22222222222 (3) At press
0.35 200 2878.46111111111 See: T
0.35 250 2976.66666666667 For most part, the ra
0.35 300 3076.08888888889
0.35 400 3279.05555555556 Answer:
0.35 500 3489.42222222222
0.35 600 3706.10555555556
0.35 700 3929.76111111111 Since our graph show
0.35 800 4160.48888888889
0.35 900 4398.21666666667
0.35 1000 4642.8
0.06 100 2688.02
0.06 150 2783.28444444444
0.06 200 2879.78222222222
0.06 250 2977.63333333333
0.06 300 3076.79777777778
0.06 400 3280.15111111111
0.06 500 3489.74444444444
0.06 600 3706.33111111111
0.06 700 3929.92222222222
0.06 800 4160.61777777778
0.06 900 4398.31333333333
0.06 1000 4642.8
Pressure (Bars) Critical Pressure (Bars) Reduced Pressure
1 220.6 0.00453309156845
0.7 220.6 0.003173164097915
0.35 220.6 0.001586582048957
0.06 220.6 0.000271985494107
5000

4500
Specific Enthalpy (KJ/Kg)

4000

3500

3000

2500

2000
0 200 400 600 800 1000 1200
Temperature (C)

Conclusion from Graph:


1. Since the curves nearly overlap each other, it seems that values slowly change with pressure (Bars).
2. However, it can be seen that with temperature (Centigrade) they rise more.
We can conclude, therefore, that it depends more on temperature than pressure.
Question: What is the largest value of Pr?
Answer: The largest value of Pr is 0.004533092 at 1 Bar pressure as evaluated.
Question: Does water behave as an ideal gas for the range of temperature and pressure?
Answer: (1) We can treat superheated vapor as an ideal gas when temperature is higher.
(2) At below 10 Kpa which is the case with 0.01 Bar, it works ideally comfortably.
(3) At pressures greater than 10 Kpa, it will work ideally if temperature is high.
See: Thermodynamics By Cengel, 5th edition, Graph 3-49, Pg # 140
For most part, the range of pressure and temperature will act ideally unless temperature is low.
Question: Illustrate cp=(∂h/∂T)p=dh/dT from the graph.
Answer: (1) For ideal gases, partial derivative symbol can be replaced with ordinary signs.
(2) The reason for this is that in an ideal gas, c p depends on temperature only.
(3) h and cp have constant values.
Since our graph shows that curves overlap and and gas behaves ideally, this relation will be true.

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