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PAPER-2

Answer Key
REVIEW TEST-24 –P2-JEE ADV.
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Q. No. PHYSICS CHEMISTRY MATHEMATICS

1. A, C A, B, C B, C, D

2. C, D A, C, D B, D

3. A, D A, B, C C, D

4. A, B, C, D A, B B, C

5. C A, C A, B, C

6. B A, B, C, D B, C

7. A, C A, B A, C, D

8. B, C A, B, C A, B, C

9. A, C A, B, D C, D

10. A, B, C A, C, D C, D

(A)  (p, r, t) A → p, q, r, s, t; (A)  (t),

(B)  (p, s, t) B → s, t; (B)  (p, q, r),
1. C → t; D → p, q, r, t
(C)  (t) (D)  (s) (C)  (q, r, s, t),
(D)  (q)
(A)  (r, t) A → r; B → s; (A)  (p, r, t),
(B)  (p, r) C → q; D → p (B)  (p, r, s),
2.
(C)  (q, s, t) (C)  (r, s, t),
(D)  (q, s, t) (D)  (q, t)
8 4 9
1.
6 1 4
2.
3 3 3
3.
4 4 1
4.
5 4 2
5.
3 3 1
6.
3 4 6
7.
5 6 3
8.

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 2 REVIEW TEST-24-P2-PCM-JEE ADV.-2020

Physics PART – I

1.
G4R2 t
(4R t)  2 
G 44R2 t  (4R2 )  C 4Rt
2 2
(2R) 2(4R )
12G2R2t22 = C4Rt
2
 C = 3GRt

2. from empirical relation R  (A)1/3

 R = 2R

3. a = g sin 
1 2h
 t , v  2gh
sin  g
mg 2h
Img 
sin  g

dQ dT
4.  kA
dt dx
dT
is increasing
dx


5. 2L = (2n  1)
2

L  (2n  1)
4
2I L I L I BL2
6. Torque =   LB  LB 
3 2 3 2 3 2
IL2B IB
 2

6 mL 6 m

7. Increase in momentum of the air in time t = v 2At

v 2 At
mg 
t
1 mg
v
r 
k 1 mg mg
Power of the engine P   r 2 v 3 
t 2 2r 

Q
8. v
2r
1 Q2
p   2 2 2
2 4  r

9. Voltmeter has infinite resistance

Ammeter has zero resistance

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REVIEW TEST-24-P2-PCM-JEE ADV.-2020 3

SECTION – C
1. From the center of mass frame
1F 2 Gm2
h = 2 t , where F  2
2m h
2
Gm  2v sin  
  
h2  g 

 1
20 11
 2  200 3  2  8
  10    8  10 m
3  10 
 

3R mgx N
2. 0 = 0  mg sin   cos 
8 8  O x
 x = 3R tan 
mg mg C
f= sin  and N = cos  (for the object) 
8 8
f
 tan  
N mg/8
f mg
 tan m  m  
N
 xm = 3R tan m = 3R
= (3) (10) (0.2) = 6

3. For small angular displacement  from mean position

3 3
U  mg (1  cos  )  mg 2
2 4
2
3 7m
T  mg   
2 12
18g

7

4. Average Intensity = 5I
5I  I  4I  2 (I)(4I) cos   

 
2
2 y 
 d 
 D 2
D 
 y 
4d 4

3R
5. U  n ( T)
2
nR( T)
W 
2
Q  n2RT  5 Joule

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 4 REVIEW TEST-24-P2-PCM-JEE ADV.-2020

K
6. 1  , because only one spring exerts a force
m
3K
2  because two springs are exerting forces
m
22
3
12

7. Total potential energy of the drops system = U  n(UE  UST )

V 4R 5 2   R 22 3T 
   4R 2 T   V   
4 3  150   50 R 
R
3
For equilibrium radius
dU
0
dR
2R2 3T
  2
50 R
1/3
15T0 
 R 2 
 3  103 m
 2 

Dh
8. f  50cm
d

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REVIEW TEST-24-P2-PCM-JEE ADV.-2020 5

Chemistry PART – II

SECTION – A
2. O
C
O CH3
OH O OH O
C C
AlCl3 / CS2 CH3 O
  CaOCl2


 Ca  CHCl3

CH3 CH3 CH3

2

OH O OH

C
 CaCO 3

CH3 CH3
3. A, B & C are facts. Glyptal is a polymer of ethylene glycol and phthalic acid.

4. (A) Cracking of ester takes place via Ei mechanism.

(B) Xanthate formation and then elimination via Ei mechanism.
(C) Aldol condensation step, followed E1CB mechanism.
(D) This is also an example of E1CB mechanism.

5. a  2 2 rA
2(rA + rB) = a
rB
 0.414
rA
Volume of cube = 16 2 rA3
4
Volume occupied by A and B =
3

 4rA3  rB3 
4
3

 4rA3  rB3 
Packing percentage =   100 = 75.4
16 2 rA3
Effective no. of A per unit cell = 4
Effective no. of B per unit cell = 1
 Formula of the compound = A4B

6. Factual.


7. NH4NO3   N2O  2H2 O

NaNO3  NH4 Cl   N2 O  NaCl  2H2 O

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 6 REVIEW TEST-24-P2-PCM-JEE ADV.-2020

NH4 2 Cr2O7 

 N2  4H2O  Cr2O3
NO2  H2 S  NO  S  H2O
OH O
8. O O
O H OH
H OH HO H
HO H HO H
HO H HO H
H OH H OH
HO H H OH
H OH H OH
H OH H OH
OH OH
OH OH
D-Fructose D-Glucose D-Galactose D-Mannose
NHNH2 H C NNHPh
CHOH CHO
C NNHPh
C O CHOH  PhNH2  NH3
or  3  (CHOH)n
(CHOH)n (CHOH)n
CH2 OH
CH2OH CH2OH
10. OH
COOH OH OH O
O 2N NO2
O C CH3 HO O
HN NH
O
HO OH O O
NO2
Aspirin Ascorbic acid Barbituric acid
Picric acid

SECTION –C
1.89  3.65
3.  2.77
2

4.   4  4  2   24 B.M.

6
 1 1
5. After 6t mole of A    
2 64
2
 1 1
After 6t mole of B    
2 4
mole of A 4 1
 
mole of B 64 16
 value  16  1  1  4

6. Ag, Cd, Zn forms colourless soluble ammine complex.

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REVIEW TEST-24-P2-PCM-JEE ADV.-2020 7

7. OH
B 2
O
O
O B OH
HO B

O O 8H2O
+
2Na B
OH

8. CH3  C  N, CH3  N  C, CH2  C  NH

HC C NH2
N N
H

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 8 REVIEW TEST-24-P2-PCM-JEE ADV.-2020

Mathematics PART – III

r  r  1 r  r  1
1. Take m  and n 
2 2

2. The smallest six numbers are a3 b3 c3 ….. f 3 in some order, then a2 b2 ….. f 2 in any order and so
on

x
3.  f  x  dx is positive in [0, 1] since LHS is positive
0
Also 1 – (f(x))2 – (f(x))4 = (f(x))2
 (f(x))2 = 1 – (f(x))2 – (f(x))4
 f(x) < 1 using LMVT
f(x) < x in [0, 1]

4. 9!·331 – 21·428 > 0 and (9!·3 + 21·2 – 1)(331·3 – 428·2 + 1) < 0

Hence (3, 2) lie in acute region, also in the region containing (0, 1)

t2

2
t2 t4
5. e  1  .....
2 24
t2
So e 2  g  t 
Also, f(x) = x f(x) + 1
x2

Solving by multiplying integrating factor e 2  g  x  , we get A

6. As n gets large n! < nn

log n! < n log n
1 1
As 
logn! nlogn
1
Also  x logx dx  loglog x
Which can be used to prove S1 is not finite
n 1
1 1 1 dx
Similarly 1    .....     n  n  1  nn
2 3 n 1
x
1 1
Hence, S 2     n 3 , n3  1
3 n n n
Hence, the summation is finite

2n 2n
7. Let g  n    3 1   3 1  for n  {0, 1, 2, …..}
g(n) is [f(n)] + 1 since it is an integer just greater than f(n)
Also g(n) = 8g(n – 1) – 4g(n – 2)
Which makes it divisible by 2n + 1 as g(0) = 2
2 2 2 2
8. a – 3b = (x1 + x2 + x3) – 3  x1x 2 = (x3 – x1) – (x3 – x2)(x2 – x1) < (x3 – x1)
2 2
Also 4(a – 3b) = 4(x3 – x1) – 4(x3 – x2)(x2 – x1)
2 2
= 3(x3 – x1) + (x3 – x1) – 4(x3 – x2)(x2 – x1)
2 2 2
= 3(x3 – x1) + ((x3 – x2) + (x2 – x1)) – 4(x3 – x2)(x2 – x1)  3(x3 – x1)
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REVIEW TEST-24-P2-PCM-JEE ADV.-2020 9

9. A, B are not true for n = 1

If we arrange the letters and envelope in a circle and draw chords like in Pn by switching the
envelopes of letters at the end point of each chord we get a case in Dn hence
Dn > Pn also clearly (2n)! > Dn

10. Let an = 0  an + 1 = an + 2 = …..  are zero

 an – 1 is zero hence all are zero
Also let bn = 0  bn – 1 = 0 also let bm be the first non-zero term
 bm – 1  0 which is not true
1 1 1
Clearly <bn> can be taken as 1, , , ..... 
2 4 8
So infinite sum exists
For an however if lim  a1  a2 ..... an  exists we can find n such that an + 1 + an + 2 …..  < 1
n

Then an  an21  an22 .....  an  an1  an 2  .....  an which is not possible

SECTION – B


1. tan 4, tan 1 > 1 also 1 is closer to  2n  1 hence tan 1 > tan 4
2
tan 1 = a1, tan 4 = a2
1 > sin 2, sin 1, cos 1, sin 3 > 0
  1
Since 1  , sin 1 > cos 1 also sin 2 > sin 1 and sin3  sin   cos1
4 6 2
Hence, sin 2 = a3, sin 1 = a4, cos 1 = a5, sin 3 = a6
Similarly, tan 2 < –1 hence tan 2 = a12 and tan 3, cos 2, cos 4, sin 4, cos 3  (–1, 0)

2. If f(2)   – 1 then ln( – f(n)) <  – f(n) – 1 as ln x < x – 1

So f(n + 1) = f(n) + ln( – f(n)) <  – 1
Also f(n + 1) – f(n) = ln( – f(n)) so ln( – f(n))  0
f(n)   – 1

SECTION – C

1. x3 – 3x2 – x + 4 = 0 has all 3 roots irrational and a, b, c  Q if one root is common

a b c 5
   
1 3 1 4

2. Put x  t to get a cubic equation

Whose roots are 2, 2, 2 then replace t by 5 – y to get y3 – 10y2 + 23y + 11 = 0

7  2 
3. z – 1 = (z – 1)  z2  2cos z  1 …..
 7 
 2     6 
1  z  z 2  .....  z6   z2  2cos z  1 z 2  2cos z  1 z 2  2cos z  1
 7  7  7 
2
Comparing coefficient of z on both side
2 4
1  3  4 cos cos
7 7

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 10 REVIEW TEST-24-P2-PCM-JEE ADV.-2020

n n 1
n 1 1 1
4. lim  2 2
 lim   2
 2
dx  tan1 1  tan1 0
n 
i 1 i  n n 
i 1 n i 0 1  x
  1
n
2n
n
Similarly lim  2 2
 tan1 2  tan1 1 and so on adding all till  gives us
i 1 i  n
n 

n2
n 
lim
n 
 i2  n2 
2
i 1

5. y3 – (x + 1)3 = x3 + 8x2 – 6x + 8 – (x3 + 3x2 + 3x + 1) = 5x2 – 9x + 7 > 0  x

y>x+1
3 3 2
Similarly, also (x + 3) – y = x + 33x + 19 > 0  x
y<x+3
All points lie on the line y = x + 2

6. Equation of normal y + tx = 2t + t3 y
2
Intersecting again at Q with parameter  t  2
P(t , 2t)
t
Area enclosed
2
x
2 2 1 2 2 2
t  2t  2t  2   t    2 t 
3 2 3 t t
2
1  2   2
  t    t 2  2  2  t    2
2
 2 
2  t   t Q   t   , 2  t   
 t  t  


7. Let line joining centeC1 and C2 intersect arc AB at P, then centre of C1(O1) lies between P and O2
(centre of C2)
 Length of arc AP = length of arc PB > 1
Also maximum arc length AB is achieved when C2 lies inside C1
Hence, a = 2, b = 2

8. Break the in integral into 1 to 2, 2 to 3, ….., [k] – 1 to [k] and [k] to k

g(x) = [x]

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