SOLUTIONS

OBJECTIVE TYPE QUESTIONS

MULTIPLE CHOICE QUESTIONS:-

1. Which of the following liquid pairs will exhibit a positive deviation from Raoult’s
law ?
a) n-hexane & n-heptane b) Ethanol & chloroform
c) Phenol & aniline d) Chloroform & acetone

2. Camphor is often used in molecular mass

determination because : a)it is readily
available
b) it has high cryoscopic constant
c)it is volatile
d)it is solvent for organic substances .

3. The relative lowering of vapour pressure of an aqueous solution containing

non volatile solute is 0.0125. The molality of the solution is :
(a)0.70 b)0.50
(c)0.60 d)0.80

4. An aqueous solution of methanol in water has vapour pressure

(a) Equal to that of water
(b) Equal to that of methanol
(c) More than that of water
(d) Less than that of water.

ASSERTION AND REASON TYPE:-

Directions; In each of the following questions a statement of Assertion (A) is given

followed by a corresponding statement of Reason (R) just below it..Of the statements,
mark the correct answer as
(a) If both assertion and reason are true,reason is the best explanation of the assertion
(b) If both assertion and reason are true,reason is not the best explanation of the
assertion
(c) If assertionis true but reason are false
(d) If both assertion and reason are false

6. Assertion: Any concentration of NaCl solution can be injected intravenously as NaCl,

being a common table salt , is a harmless chemical.
 Reason: 0.9% ( mass/volume) NaCl solution is isotonic with the fluid inside the blood
cells.

Directions; Each question contains STATEMENTS-1(Assersion) and STATEMENTS-2

(Reason) Each question has four choices (a), (b), (c), (d),out of which ONLY ONE is
correct.Choose the correction option is under ;
a) statement-1 is true, statement-2 is true, statement-1 is the
correct explanation of statement-1
b) statement-1 is true, statement-2 is true, statement-1 is not the
correct explanation of statement-1
c) statement-1 is true, statement-2 is false
d) statement-1 is false, statement-2 is true

5. Statement-1:-
Statement-2:-

6. Statement-1:-If on mixing the two liquids , the solution become hot ,it implies
that it shows negative deviations from Raoult’ s law .
Statement-2:-Solutions which shows negetive deviations are accompanied by decrease in
volume.

Q9. Assertion; The sum of mole fractions of all the components of a solution is unity.
Reason ; Mole fraction is a temp dependent mode of concentration

Q10. Assertion; Increasing pressure on pure water decrease its freezing point
Reason ;Density of water is maximum at 273 K

Answers:- 1b,2a,3b, 4a,5c, 6c,7d,8b,9c, 10

Directions; Each question contains STATEMENTS-1(Assersion) and STATEMENTS-2

(Reason) Each question has four choices (a), (b), (c), (d),out of which ONLY ONE is
correct.Choose the correction option is under ;
e) statement-1 is true, statement-2 is true, statement-1 is the
correct explanation of statement-1
f) statement-1 is true, statement-2 is true, statement-1 is not the
correct explanation of statement-1
g) statement-1 is true, statement-2 is false
h) statement-1 is false, statement-2 is true

7. Statement-1:-Any concentration of NaCl solution can be injected

intravenously as NaCl, being a common table salt , is a harmless chemical.
Statement-2:-0.9% ( mass/volume) NaCl solution is isotonic with the fluid inside the
blood cells

8. Statement-1:-If on mixing the two liquids , the solution become hot ,it implies
that it shows negative deviations from Raoult’ s law .
Statement-2:-Solutions which shows negetive deviations are accompanied by decrease in
volume.