Constituent Pure Liquid - Capacity

Pressure Relief Valve PSV

Relief Scenario Fire Case
Temperature (°C) 127.4
Pressure in vessel (kPag) 5066
Molecular Weight, M 92.14
Mass Flowrate, W (kg/h) 9214
Relief Mass Flowrate, Wrelief (kg/h) 9214
Volumertic flowrate, Q (litres/mins) 176.5
Relief Volumetric Flowrate, Qrelief (litres/mins) 176.5
Set Pressure, Pset (kPag) 5572.60
Maximum Allowable Working Pressure, MAWP (kPag) 5572.60
Relieving Pressure, P1 (kPag) 6742.85
Back Pressure, P2 (kPag) 546.20
Specific Gravity, G 0.797
Liquid Correction factor due to back pressure, K w 1.00
Correction factor due to viscocity, Kv 1.00
Vapor Capacity Correlation factor due to back pressure, K b -
Both Rated Coefficient of discharge, K d 0.65
Combination correction factor for installation, K c 1.00

Orifice Area of PSV, AR (mm2) 36.28

Adjustment on liquid viscocity

Assuming an orifice rating of D from API 526 Std
Effective Orifice Area, mm2
Viscocity, (CP) 0.2
Reynold's Number 6868324.18577951
Correction factor due to viscocity, Kv 1.005
Orifice Area of PSV, A (mm2) 36.08
Pure Liquid - Capacity Certified (Pure Toluene)
PSV 102
Blocked Discharge Thermal Expansion Control System Failure
127.4 127.4 127.4
5066 5066 5066
92.14 92.14 92.14
9214 9214 9214
8753.3 7831.9 6910.5
176.5 176.5 176.5
167.675 150.025 132.375
5572.60 5572.60 5572.60
5572.60 5572.60 5572.60
6129.86 6129.86 6129.86
546.20 546.20 546.20 0.081004 0.089105 0.089105 0.089105
0.797 0.797 0.797
1.00 1.00 1.00
1.00 1.00 1.00
- - -
0.65 0.65 0.65
1.00 1.00 1.00

36.31 32.49 28.66

71
0.2599
6524907.97649053 5838075.55791259 5151243.13933463
1.005 1.005 1.005
36.11 32.31 28.51
(LARGEST AREA)
 Constituent Pure Vapour (Tolu
Pressure Relief Valve PSV
Relief Scenario Fire Case
Temperature (K) 898
Pressure in vessel (kPag) 5066
Molecular Weight, M 20.04
Heat capacity ratio, k 1.131
Coefficient due to Heat capacity Ratio, C (Table 8) 330
Z factor 1.012
Mass Flowrate, W (kg/h) 10020
Relief Mass Flowrate, Wrelief (kg/h) 10020
Volumertic flowrate, Q (litres/mins) 368.83
Relief Volumetric Flowrate, Qrelief (litres/mins) 368.83
Set Pressure, Pset (kPag) 5572.60
Maximum Allowable Working Pressure, MAWP (kPag) 5572.60
Relieving Pressure, P1 (kPa) 6844.17
Back Pressure, P2 (kPa) 647.53
Critical Pressure, Pcf 3957.63
Specific Gravity, G 0.014
Correction factor due to back pressure, K w -
Liquid
Correction factor due to viscocity, Kv -
Vapor Capacity Correlation factor due to back pressure, K b 1.00
Rated Coefficient of discharge, K d 0.975
Both
Combination correction factor for installation, K c 1.00

Orifice Area of PSV, AR (mm2) 403.24

 Pure Vapour (Toluene and Hydrogen)
PSV 104
Blocked Discharge Thermal Expansion Control System Failure
898 898 898
5066 5066 5066
20.04 20.04 20.04
1.131 1.131 1.131
330 330 330
1.012 1.012 1.012
10020 10020 10020
9519 8517 7515
368.83 368.83 368.83
350.39 313.51 276.63
5572.60 5572.60 5572.60
5572.60 5572.60 5572.60
6231.19 6231.19 6231.19
647.53 647.53 647.53
3603.18 3603.18 3603.18 Since Pcf > P2, the flow is critical
0.014 0.014 0.014
- - -
- - -
1.00 1.00 1.00
0.975 0.975 0.975
1.00 1.00 1.00

420.76 376.47 332.18

(LARGEST AREA)
 Constituent Pure Liquid - Capacity Certified (H
Pressure Relief Valve PSV
Relief Scenario Fire Case
Temperature (°C) 30
Pressure in vessel (kPag) 1013
Molecular Weight, M 80.84
Mass Flowrate, W (kg/h) 7942
Relief Mass Flowrate, Wrelief (kg/h) 7942
Volumertic flowrate, Q (litres/mins) 150.58
Relief Volumetric Flowrate, Qrelief (litres/mins) 150.58
Set Pressure, Pset (kPag) 1219.82
Maximum Allowable Working Pressure, MAWP (kPag) 1219.82
Relieving Pressure, P1 (kPag) 1475.98
Back Pressure, P2 (kPag) 203.10
Specific Gravity, G 0.894
Liquid Correction factor due to back pressure, K w 1.00
Correction factor due to viscocity, Kv 1.00
Vapor Capacity Correlation factor due to back pressure, K b -
Both Rated Coefficient of discharge, K d 0.65
Combination correction factor for installation, K c 1.00

Orifice Area of PSV, AR (mm2) 72.34

Adjustment on liquid viscocity

Assuming an orifice rating of D from API 526 Std
Effective Orifice Area, mm2 71
Viscocity, (CP) 0.7885
Reynold's Number 1931468.20937099
Correction factor due to viscocity, Kv 1.004
Orifice Area of PSV, A (mm2) 72.02
Pure Liquid - Capacity Certified (High %Benzene and other Minorities)
PSV 107
Blocked Discharge Thermal Expansion Control System Failure
30 30 30
1013 1013 1013
80.84 80.84 80.84
7942 7942 7942
7544.9 6750.7 5956.5
150.58 150.58 150.58
143.05 128.00 112.94
1219.82 1219.82 1219.82 *Note Max is P + 30 psi (1.1 P < P + 30psi)
1219.82 1219.82 1219.82
1341.80 1341.80 1341.80
203.10 203.10 203.10
0.894 0.894 0.894
1.00 1.00 1.00
1.00 1.00 1.00
- - -
0.65 0.65 0.65
1.00 1.00 1.00

72.66 65.01 57.36

1834894.79890244 1641747.97796534 1448601.15702824

1.004 1.004 1.004
72.34 64.73 57.13
(LARGEST AREA)