‘ Resonance ze Educating for better tomorrow JEE (Advanced) 2013 02.06.2013 waa : 3 que Time : Hours ee Se ea Soren ee a ‘fReet INSTRUCTIONS. Code 3 ied errr] ne 4g gfe ore vena 81 FR we 9 as on oe Proerat & aR ga PE ‘® General: “This booklet is your Question Paper. Do not break the seal o this booklet before being inetructed to + Pe do 60 by the ivigator, 2 Wea Wi Hs (CODE) FH GSH BA GE | The question paper CODE is pied on the ght fy ate ge gferer w Rere ger (ge see | Mand top comer ofthis sheet and onthe back page ° (Page No. 44) of his Book. 44) 8H 3. wel wis A Wiel Ge GN GIA Une ew | Blank epaces and blank pages are provided in he gre a By ae ew Fre wre arma fear rm 4 ait wins, Raw ae (CLIP BOARD), ait ain, cagse, tegen ter, dae, ter ak eh oars Rage ToT ter 3H # Sapa TH 4 {question paper for your rough work. No additonal ‘Shes wll Be provided for rough work Blank papers, clipboards, log Tables, ide rules, caleiatrs, cameras, elluiar phones, pagers, and ‘lecrone. gadgets are NOT allowed incide the ‘examination hall 3 es fae @ fea yo wT RA Spray she a ta ac 6 ae o on aR ond aiiew oma ew i fi orm ah aT rh ten ene Te a aE am aT we A ite tte tere ate fe oh Rees a ae a ge arm vest are sie & orth | Pret ari a stay Wite you rame_and rel number i the space provided on the back cover of his booklet. ‘Anewere to the questions and personal details are to be filed on a tworpart carbonless paper, which ie provided eeparately.Theee parte ehoula ony be ‘eparated at the ond of the examination hen inatuctod by the invigiatr. The upper sheet isa machine-gratable "Objecive Response Sheet (ORS) witch vill be retained by the ivigiater. You Wil be allowed to take avay the boom sheet at the end of tne examination 7. Sah =H YS F gaye (GUBBLES) wt we aia age aH sia Bt) geN aA Te Ps Peet gebe yes Perr er omy Using a Black ballpoint pen, darken the bubbles on the upper original’ sheet. Apply sulfcient pressure so that the impression is {rested onthe bottom sheet. @. aiaiee ORS) aeafeght 7 81 = iene ‘DO_NOT TANPER WITHIMUTIATE THE ORS (OR THE BOOKLET, 9. ee gre A ae et vee Fre oe fe gai a4 ge # ote a 60 oe otk som free dhe ng or aad #1 eA a ob men BR ge PEAT wT a ‘Or breaking the seals ofthe bookt check tat t Contains 44 pages and all the 60 questions and Corresponding ansver choices are lege. Read ately the Instuctions printed athe beginning of ‘each section, Sree ee (ORS) S are aT wT eT stares @ ef ste mg am 8 ats ot Rel 11 ai & fr stamens we gfe ot ree wen etior 2 a FF ge) & oT ae Sar & tok 7% B. Filling the Right Part of the ORS ‘The ORS has CODE printed on ts lo and right pars, ‘Cheek fa the same CODE ie printed onthe ORS (@n both shoot) ithe same ae tat on tvs booklet ‘and pul your signature affming that you have Vetifed ti TF THE CODES DO NOT MATCH, ASK FOR A (CHANGE OF THE BOOKLET. Resonance Eduventures Pvt. Ltd. reer ize ‘CORPORATE OFFICE: CG Tower, A-46 & 52, IPIA, Near City Mall, dhalawar Road, Kota Rajasthan) - 324005 Tel. No.: 0744-3192222, 3012222, 3022222 | Toll Free : 1800 200 2244 | To Know more: sms RESO st $6677PART -I : PHYSICS SECTION ~1 : (One or more options correct Type) ws -1: (ga a afte wal faaed FoR) This section contains 8 multiple coice questions. Each question has four choices (A), (B), (C) and (D) out of which ONE or MORE are correct. ae ees 48 agltoes wer E | cto He A are Peet (A), ©), (ste O) 8, For @ ew aT aie EB Sol A particle of mass m is attached to one end of a mass-less spring of force constant k, lying on a frictionless horizontal plane. The other end of the spring is fixed. The particle starts moving horizontally from its equilibrium position at ime t= Owith an initial velocity u,. When the speed of the particle is 0.5 u, it colies elastically with a rigid wall. After this collision (A) the speed of the particle when it returns to its equilibrium position is u, [m (B) the time at which the particle passes through the equilibrium position for the first time is t = ra (C) the time at which the maximum compression of the spring occurs is 13] (O) the time at which the particle passes througout the equilibrium position for the second time is t = = et anor rar oe SE et Rereen oA are ees PR Ce RRB mH Hr aT GT YTB gw fein an gare fire ag 8 | oe oor oar armen 8 wer t= OW of aftr an uf afta at eer 8 | Te oo 0.5 u, BAB we CH ge MaRS HR via IH By TE alae} ae — (A) ooo ort areareen & crea & et a uz | (By 4 eh mre EA ae gor Bae aT t= | By _ 4x (©) a fir eetige ve ee B as wT t= SE IF By Sx |m (0) 3a oe aoe area Ga a GaveT ae TAT t= EN Ans. (A,D) Displacement x= Asinot oA Velocity v= Awcosa t= z ee This sottton was donnioad rom Resonance JEE ADVANCED 2013 Solution portal SoS Oe ma Page #f 2Hindi Resonance Atthe time of collision a Yo 2 2 x {mv t=2] for(©) Se for (D) - SF eoniscomen RRETTH x= Asinot oA AI v= Aocose t= (aire wr = i 5x [m si 6 2 (So it is incorrect) 2n fm, fm Osi we St NK Sx [m BK So itis correct ‘A steady current flows along an infinitely long hollow cylindrical conductor of radius R. This cylinder is placed coaxially inside an infinite solenoid of radius 2R. The solenoid has n tums per unit length and carries a steady current I. Consider a point P at a distance r from the common axis. The correct statement(s) is (are) (A) Inthe region 0 2R, the magnetic field is non-zero, ww R from ora aa eked arom dear A ares yw Ree aT ae ea a et a 2R Prom aA omrI safer ome eres wal ay & | gt unre Hn Ae florg aver 18 1 ye fre TL TLR, TS ROSA ASS AT 28 SS, RORY eng oboe Page #3PS fay ot wma 8 rat we Grr (@) aH Tate (AyocreRa, gradi da a me & @Rer<2RH, qaaha da a fer anes a Pe As (CR ARH, geass Ga apa ae Ans. (A,D) Sol. @ — For0 B40 © = Forr>2R=>B+0 Hindi, W O B+O Resonance Tris soon wos domo rm Resonance 1 ADVANCED 2019 SHON BO BasSol. Gis © PaRe fe B+0 Two vehicles, each moving with speed u on the same horizontal straight road, are approaching each other. Wind blows along the road with velocity w. One of these vehicles blows a whistle of frequency f,. An observer in the other vehicle hears the frequency ofthe whistle to bef, The speed of sound instill airis V. The correct statement(s) is (are) : (A) Ifthe wind blows from the observer to the source, f,> f, (B) Ifthe wind blows from the source to the observer, f,> f, (©) Ifthe wind blows from the observer to the source, f, H,1 (©) ae ay Sha Shaw A fan aes, Ff, | (©) af ary dares B eta BH Ae A ae 8, f,f, Resonance Tis soa wos domo rm Resoanc IE ADVANCED 2013 SMHEN BOT Bas yg‘° —w a Source Hindi, u fey = (i. Sol. aft ear aia & dere aA ote aE wee (Www) tu) (wew)-u)" > tt aS war Bera @ ae aA sire aw wal & ¢ Ww ‘Source u tae AE ((w-w)su £5 (wowyu)" = tH, Using the expression 2d sin 0 = i, one calculates the values of d by measuring the corresponding angles 0 in the range 0 to 90%, The wavelength i. is exactly knowns and the errorin 6 is constant for all values of AS 0 increases from 0° (A) the absolute errorind remains constant. (8) the absolute error in d increases. (C) the fractional error in d remains constant. (0) the fractional error in d decreases. ior 2d sin 0 = 2am aed ae ge MO BH ATT a wT AT GIFT ames # | OWT ATT Oa 90's dra HE ended wor ars ei GReparr set 8 ear a TY A APS, 0} A aT | re ATA 8 | GR 0 wT ATH OP as tn (A) a Pieter gfe Per at 8 aa Pete ge ahs (0) d4 Proto aft Ree vec 8 (0) 4a Prone ae aed 8 | Ans. (D) 2d sino 2sind dlifferntiate ~ 5 (cosect) cos ec8 cot )c8 2 Aeaorence| ‘This solution was downloed from Resonance JEE ADVANCED 2013 Solution portal eng oboe Page # 6~i.c088 a= ew 2@ 2sin? 6. 2.6088 as 0) = increases , 5+, decreases 2sin® 6 Alternate solution Sol = 2sind end =en}.-én2-en sino No) I 299 1 ccos0ro d 00 sind a0) Fractional eror |+(4)| = [C010 80] Absoulute error Ad = (doote) a0 d cost) 2sind * sind Hindi 2sind TRE BET o@ B 6 (cosech) 2(@= S(-cosecdeatoyoo ~.c080 a= ~ = a5int 0 Sent = aaey 20°88 t 3sin?9 7 Alternate solution Go 2sin0 ind= én ).—¢n2-en sind 1 €080(A0) 8 xe) frre ate [+(€)|= [cot 40] feta PE Ad = doot0) a0 Ngesonance ‘This solution was downloed from Resonance JEE ADVANCED 2013 Solution portal Page #7Sol. d__ cosé 2sind sind cos sin? ‘Two non-conducting spheres of radii , and R, and carrying uniform volume charge densities +p and -p, respectively, are placed such that they partially overlap, as shown in the figure. At all points in the overlapping region 2) arareres R, eH PRA are Al aT aR +p eT —p RATS PS Aer ATs SPAR Pe aT | ser ah rt A aie orga gat eo TS We cea eT 8 FPR ry A carte 8 | sett a wee fry p (A) the electrostatic field is zero (C) the electrostatic field is constant in magnitude (A) Ree aga da eae (©) Rew Sega 8 ar aRRAT eR | Ans. (C,D) A ¥ For electrostatic field, &, -E48, Resonance - (8) the electrostatic potential is constant (D) the electrostatic field has same direction (@) Ree Age fea oem & (D) Rew ge a af Ren ae | ‘This solution was downloed from Resonance JEE ADVANCED 2013 Solution portal Page # 8For electrostatic potential, Since electric field is non zero so it is not equipotential 2 Hindi. g Ror aga da 3 fy E, -€,+€, = Pop Dee Be 3e9 Co Ror tga fora & fre, oe Rega Sa seep 8 ore: ae THT a i ‘The figure below shows the variation of specific heat capacity (C) of a solid as a function of temperature (T). “The temperature is increased continuously from 0 to 500 K at a constant rate. Ignoring any volume change, the following statement(s) is (are) correct to a reasonable approximation. fea fret cher AFR re eRe (C) aor TET (1) oe Pekar at ee ara | ATTA #0 500K Tr re hy aA aA | a ae PR ere Racha ert 8, Pe a A a a (&) aaa aE wa? @? 100 200 300 400 500 Tk) (A) the rate at which heat is absorbed in the range 0-100 K varies linearly with temperature T. (@) heat absorbed in increasing the temperature from 0-100 Kis less than the heat required for increasing the temperature from 400-500 K. (©) there is no change in the rate of heat absorbtion in the range 400-500 K. (0) the rate of heat absorption increases in the range 200-300 K. (A) 0-100 K & ata, srashftte Ger a ax STOTT Ge Berar ampere Pearce | ‘This solution was download trom Resonance JEE ADVANCED 2012 Solution port Resonance Tit slum nes smnon tm Rennes JE ADUNCED 21 hn FO Bae y gSol. (8) 0-100 K arp araars at Aare ge sree GoM, 400-00 K as Ata aes a GON a ge A wT ey (©) sraehfiter sen a ze 400-600 K ara & ata rafal @ | (©) won srazitamr ah a 200-200 K ares & da az -~. Itis given that h is Planck constant and R is Rydberg constant. The possible wavelength(s), when the atom de-excites, is (are) ep gga Tay eels we A Poe 4.5a,8 set a, ae rom 8 | ge esas ar ae ah wit Fb fear 8 Ph sia Pacis aR Roe Pacis & | sey aT aA oe Seat AE amended a siareri & (A) oR 8) 6g or 0) oR © Ter OR OR Ans. (A, C) R,=4.5a, 3h L=mvr= 5 [asn=3, z= 2) Resonance Tis sola wos domo ram Resa 5 ADVANCED 2019 SHON PO Bay 4SECTION —2 : (Paragraph Type) wes ~2: (SGBe OR) This section contains 4 paragraphs each describing theory, experiment, data etc. Eight questions relate to four paragraphs with two questions on each paragraph. Each question of a paragraph has only one correct answer among the four choices (A), (B), (C) and (0) i ws 4 Raia, meat ote oferal ont ah eas ard 4 ange | ar one & afer one we, far ae ogee we 2 wer HR A anges A aw we aK PI (A), ©), (C)ahe(O)E, Ars a dam ew awe Paragraph for Questions 09 and 10 eH 09 sire 10 o fay ogee ‘Asmall block of mass 1kg is released from rest at the top of a rough track. The track is a circular arc of radius ore ssa wos donna ra Resa 5 ADVANCED 2019 SHON BO Bay 4440m. The block slides along the track without toppling and a frictional force acts on it in the direction opposite to the instantaneous velocity. The work done in overcoming the friction up to the point Q, as shown in the figure below, is 150 J, (Take the acceleration due to gravity, g= 10 ms) ee wat Te Gea fg B GH tho eT | qed wy vera S wks ore B | we ve 40m Pro a ge a 8 | eT oy er ae Fe ae ER ROT S| BT TE eH enor as oe rH feta Fee A TT 8) RIA ead organ, AZO ae oF & Ry aor a siftans ah Py 150 ani we Twa 8 | (TR BROT gar A = 10ms?aAey) ° 9. The speed of the block when it reaches the point Q is ra Jeon Pry Q we vam & ewe nfs a — (A) 5ms* (8) 10ms* (©) 10/3 ms* (0) 20ms* Ans. @) R ol Sol. Mgi)-150= SMV" 1%*10* 20 : ve 72 >V=10ms 10, The magnitude of the normal reaction that acts on the block at the point Q is fry QR qed wa ae siftera ga a oft & (A)75N (@)86N (115N (0)22.5N Ans. (A) Mg _ M10)? . n- NO =N= Sol oo - MO SN=75N ee ‘Thi solution was dovnload from Resonance JEE ADVANCED 2013 Sokiton portal Se ee SS sss Page #12"1 Sol. 12, Sol. Paragraph for Questions 11 and 12 Wer 11 sie 123 fay srqee Athermal power plant produces electric power of 600 KW at 4000 V, which is to be transported to a place 20 km away from the power plant for consumers’ usage. It can be transported either directly with a cable of large current carrying capacity or by using a combination of step-up and step-down transformers at the two ends. ‘The drawback of the direct transmission is the large energy dissipation. In the method using transformers, the dissipation is much smaller. In this method, a step-up transformers used at the plant side so that the current is reduced to a smaller value. At the consumers’ end, a step-down transformer is used to supply power to the consumers at the specified lower voltage. Itis reasonable to assume that the power cable is purely resistive and the transformers are ideal with a power factor unity, All the currents and voltages mentioned are rms values, wee aria fae eats 600 kW at erfae1 4000 VaR seanfea eee & Fl 20km a ae wR SIAR B soe | fay 3 ort on 8 | geet am ot seq are aera ae Haar S Fon oT wera sa SA fet oe eA a sera siwcitee or get ae Rea on goer B | weaeT oor ar She ae 8 fe ge Go wr ara aga ote eer 8 rah girwehic & oat } atte 4 ara aga oa dior 2] ge ad 8 ew gear ginny dia at alk oT ora 2 Foren are ore eH St oY | Sent FRE A ora leery ar aire Fe are & HRY oH ue fay aH ate oe Pega efee A on ad | ae ArT on eee 2 PH He ye wfeedfla 8 aen gently reel 8a oral Ufa gain we 8) site Ret area ares a dees wr ATG rms 8 | Ifthe direct transmission method with a cable of resistance 0.4 © km*is used, the power dissipation (in %) during transmission is aR iter or ere ver aT Fwrmr Fee 0.4 Co kent & era eT ee HY Rens Tht ar (96 H) & (20 (20 40 50 Ans. (8) P = 600 « 1000 = 4000 x 1 150A, dH at 150)? x 0.4 «20 ‘Which is 30% of 600 kW. In the method using the transformers, assume that the ratio of the number of tus in the primary to that in the ‘secondary in the step-up transformer is 1 : 10. Ifthe power to the consumers has to be supplied at 200V, the ratio of the number of turns in the primary to that in the secondary in the step-down transformer is irretie ob eit et arch fA 4, ae ar seat Cimon & orate a fr # otc a een ar arg 12108 af fea afte, coMireTsH Gr 2OOV oe SI oT & sera giety A Mert a feeb atic Bt een Hague 8 (A) 20:1 (8) 150:1 (©) 10:1 (50:4 Resonance Tsou wos domo ram Resoanc 5 ADVANCED 2019 SHON PO Bag 43Paragraph for Questions 13 and 14 Wer 13 oie 14% fey aqee Apoint charge Q is moving in a circular orbit of radius R in the x-y plane with an angular velocity «. This can be Q considered as equivalent to a loop carrying a steady current > .A. uniform magnetic field along the positive x z-axis is now switched on, which increases at a constant rate from 0 to B in one second. Assume that the radius of the orbit remains constant. The application of the magnetic field induces an emf in the orbit. The induced emf is defined as the work done by an induced electric field in moving a unit positive charge around a closed loop. Itis known that, for an orbiting charge, the magnetic dipole moment is proportional to the angular momentum with a proportionally constant y eye Po aA en a Hw ge wen RPA ve eT GTA ec SO sree ang & eo a oH aT 8 | 9a CoN Gata Sa aT aa 2-H arg aed & rT a OF BT em Shows A ewer ae Yaga Be TAMA AH ge eter wet By Prout Rew ach 8) acta da} aA a ‘wa Hw emt iter eter & | ge AR Fg drat are geo ers ree a eige G are ite gaa A Fe A re By rar aR Perey et (emt) er eM | STE AH ea Me ae eH aT GPT aT Ta eT gatha haga orept wad thot site & nga ara # frerar sgunw Rena #1 43. The magnitude of the induced electric field in the orbit at any instant of time during the time interval of the magnetic field change is gaia da & oftacts & dhe war A fret fete aor oe Ra Age at ar a BI BR BR ay o> (BR (0)28R 4 2 Ans.) «8 so. fed = E.2nR=—nR°B -BR fea Alternat E2nR Resonance isso wos dma ram Resonance JE ADVANCED 2019 SHON PO gy 4g14, The change in the magnetic dipole moment associated with the orbit, at the end of the time interval of the magnetic field change, is fre were oars A facta dra A Rahs a @, Se orareTa oa A, ote} er Gaara faa oH afte 2 2 (@)-/0R* @ Pk © ee ():80R? Ans. (B) Sol. Megneticdipole moment M = J so Alternet riz glo Qo 4g? _ GOR, eae 2 Induced electric field is oppsite, to the « so the charge is retarded, =o at QE _Q,BR _ QB = O&M, (a= . & im), mR R 2m 2m (. QB)\R? 28 am)2 esomemce Ti slutin was donload ram ResnanceJEE ADVANCED 218 Stn poral SoS oOo —m——— Page #15= QoR? BR? QoR? _ gar? 2. 4m 2 i) Hindi, arta aa arech ame Alternet Qo 1p? _ QoR? Co nR? = . 2m 2 BR Raga a ow Aaete 8 om: oer eer eT M QE _ BR _ QB. (= OEM). = OR Ram 2m fo QB )\R? 2 om) 2 rr QoR? _Q7BR?_ QoR? BOR? Ziaaran ean a Paragraph for Questions 15 and 16 We 15 sie 16 o fay ogee The mass of a nucleus # x is ess that the sum of the masses of (A ~Z) number of neutrons and Z number of protons in the nucleus. The energy equivalent to the corresponding mass difference is known as the binding energy of the nucleus. A heavy nucleus of mass M can break into two light nuclei of masses m, and m, only if (m, + m,) < M. Also two light nuclei of masses m, and m, can undergo complete fusion and form a heavy nucleus of mass M' only if (m, + m,) > M’, The masses of some neutral aloms are given inthe table below want 4x area (A-2) 2B Gd Zafer} cor S a Bo den 8 | MEH A oS we ut ay ders ro aed & | OTT Mabe aT RD m, gem, zaI eee aa A Raker aA Resonance Tis soluion wos domo rm Resonance 5 ADVANCED 2019 SMION PO Bay 4g28, a (m,+m) < Mae m, ae m, MEE Te} zavA Ay afer | AAT jH_| 1.007825u | 7H | 2.014102u | 7H | 3.016050u | $He | 4.002603u SLi | 6.015123u | jLi | 7.016004u | %2Zn| 69.925325u | ${Se | 81.916709u | Ecd |151.919803u | 25Pb | 205.974455u | 228i | 208.980388u | 3!°Po | 209.982876u 15. The correct statement is. wel ETB) (A) The nucleus §Li can emit an alpha particle afte §Li ve tem oor seaftia ax Waa 8) (8) The nucleus 2!°P, can emit a proton sift 2°R, qo atcha acattia we wT t | (©) Deuteron and alpha particle can undergo complete fusion, ‘wages ote Rept wor ge ier art een (©) The nuclei 2zn and §Se can undergo complete fusion. afta 220 wi afta Sse wt eae oe aa B Ans. (C) Sol (A) 34 4, Het +H? Am = My —Mye Mp] = [6.01513 — 4.002603 - 3.016050] 1.003523u Am is negative so reaction is not possible. © agro 5 ga 9" AM is negative so reaction is not possible. (©) a ate" 4 gh Am is Positive so reaction is possible. (©) a0?” 349% 5 6490" Am is negative so reaction is not possible. Hindi (A) 3b" 5, Het +H? Am = My —Mye Mp] [6.01513 ~4.002603 - 3.016050} 1,003523u Am scorers @ ata: etree era at & ®) gare”, gg 417" am aeoreree ® are: ewe ara wah Resonance Tiss wos domo rm Resoranc 5 ADVANCED 2019 SHON PO ay 4716. Sol (©) a 5 ate" at mm eras ora: aeRO TT | (O) 30?” 4.345 5 aoe? Am aeororn & orc: eettareer ereera Te & The kinetic energy (in keV) ofthe alpha particle, when the nucleus 2!°P, at rest undergoes alpha decay. is: cra feraracen Hanon 20, em ert ace &, oa mt wor a atin Gra (keV) ete 8 (a) 5319 (6) 5422 (©) 5707 (0) 5818 Ans. (A) gro? gh _, got am =[M,,~M,,~M,,] = 0.008421 u (008421932 MeV = 5422 KeV ge S422KeV = 5320KeV SECTION-3: (Matching List Type) ws - 3: (qian at wae) This section contains 4 multiple choice questions. Each questions has matching lists. The codes for the lists have choices (A), (B), (C) and (0) out of which ONLY ONE is correct. BH es A agftwe me | ee sre A GTO EPH 8 | eet fre wesw frees (A), (B), (C) AED). for a daa we wet 21 17 ‘A right angled prism of refractive index u, is placed in a rectangular block of refractive index y,, which is surrounded by a medium of refractive index jas shown in the figure, A ray of ligth’e' enters the rectangular block at normal incidence. Depending upon the relationships between jj, and i, it takes one of the four possible paths ‘ef’, 'eg’, ‘eh’ or ‘ei’. We pu, roast eae foe ay organ aera wttay A wear aa B | AUT aM pores Te flea A cay organ Fa eB | sore aH fem sre ait wR aftstaa si et EH, HATH, at Paks ath af nerve fre aTe Gina Tel ‘ef ‘eg! ‘eh! aT el AG UT aH 81 Ih Hs Match the paths in List I with conditions of refractive indices in List II and select the correct answer using the codes given below the lsts PTH A we ge TA ey era aR AAfRIy ate GRA BAB BAT ats a tT ae wa ore gPT List 1) itr List 11/ qt 11 PR eof o> 2m Resonance Tsou wos donno rm Reson 5 ADVANCED 2019 SHON PO Bay 4gSol. Hindi, 18, Q eog 2 Hy > Hand Ta p> a, R. eoh 3 wy eH s. esi 4 HS, < v2 Hand’ Ta p> Codes: P Q R s A 2 3 1 4 ® 1 2 4 3 © 4 1 2 3 © 2 3 4 1 Ans. (0) For esi 45> 0, sin 45° > sino, 1 me 4,> v2up Fore->f angle of refraction is lesser than angle of incidence, so p>, and then u, > 1, Fore 9.4, = fore, 1<, < vBuy and 1> K, eid fay 45°> 0, sin 45° > sin 0, 1 we v2 7 1,> Bite este fay ra hey sae TOT A TET BA p> wy TEM TT > by est RH =H eh RG 8 Match List I with List Il and select the correct answer using the codes given below the lists List List II P. Boltzmann constant 1, (MUT-} Q Coefficient of viscosity 2 [MT] R Planck constant 3 [MLT?k-] S. Thermal conductivity 40 MLTR] eae He Gate Titty ote YP S Any A Ta ahs Hr IT Oh we TR BARA al aan Pawar Praca 1. MET Q earren eT 7 [MLU‘T) R wie Paes 3 MIT] Ss. Ser Bree 4, [MUT=K*] ee ‘Thi solution was dovnload from Resonance JEE ADVANCED 2013 Sokiton portal Page #19Sol. 19, Codes: P Qa eR os a 3 4 2 4 (6) ees eee 1 4 © 4 2 1 3 Oo 4 1 2 3 Ans. (C) up > KK => [K=ML av Mut? a @FemAR = Weyer SMUT (DE=hy = METS [mT > th}=MLeT+ dQ _ kANO Mer. a Oa a> aT MLT? (One mole of a monatomic ideal gasis taken along two cyclic processes E -> F -»G->E and E ->F -»H-» E as shown in the PV diagram. The processes involved are purely isochoric, isobaric, isothermal or adiabatic. we eo meres oral ta} gw His a, fea H auld Pvorte & ogaR a ata gw EF GE FEF HOES A orn ore 8) dala BamH Yaa: BST, ewer, waa a1 wee & | Match the paths in List with the magnitudes of the work done in List II and select the correct answer using the codes given below the lists. ead FR ell ah eh A ae ord aT er I ae she ai ANS RA Ta ws oT sear ae we a GPR | List 1/91 List 1/ qe 11 PR GoE 1. 160P,V,In2 Q Go>H 2 36P,V, Ro FoH 3, 24P.V, 8 Fae 4 31PV, sonsnce Ts soluion wos donna rm Resoranc 5 ADVANCED 2019 SHON PO Baw 9gCodes: P Qa eR os w 4 302 1 (6) era ee 1 2 © 3 1 2 4 oO 1 30 2 4 Ans. (A) Pp 32P, sol P, | H isobaric vy (32Vp) InF-s6 work done in sotnermal procesisnRT In| "| = 32P, In | "ye = 22P,V, In2°= 160P, VjIn2 InG->E,AW=P, AV=P, G1 V) =31 PV, In GH work done is less than 31 P,V, Le. 24 PV, InF > H work done is 36 P,V, Hindi. . . (v) (32Vp ) FoG a aoa spn rt ward = TIN [] =82P, Vy In y| =32P,V, In2°= 160 P, V,In2 sonsnce ssa wos donna ra Reson EE ADVANCED 2019 SHON BO Bay 94Sol. G +E 4, W=P, AV=P, 1 V)=31P,V, GHA, fom ma ori 31 PV, 8 oH B sia 24 PAV, 81 FH, fou mn ord 36P,V, 21 Match List of the nuclear processes wit List I containing parent nucleus and one ofthe end products of each process and then select the correct answer using the codes given below the lists aah 1 ge saa atten St mg 8 | GALA go ais} ora sae a ee sift Ra aes Re Aye afta & a fa ay ahs a1 he ad WA SR APE List ue 1 List 1/@f 1 P. Alpha decay 1 Boot SNe tema Q prdecay 2 Bu+B Ths pera R.Fission 3. Beis Pos frst S. Proton emission 4 BeusHP Las Codes: Pease Reena (A) 4 2 1 3 ® 1 3 2 4 © 2 1 4 3 © 4 3 2 4 Ans. (C) (p) In a decay mass number decreses by 4 and atomic number decreases by 2. (@) In decay mass number remains unchanged while atomic number decreases by 1 (0) In Fission, parent nucleus breaks into allmost two equal fragments. (s) In proton emission both mass number and atomic number decreases by 1 Hindi. (p) cera 4 cerry stom 48 ae sean HIN, ww 28 HEMT (@ pr ara A womans sie raRaha veh & wal HIM wae 1 Ge TAT | (9 Reaves 4 age ante 2 am ae aT A Ze OTT e| (9) stds Seas gop chem gen TE wai 1 Te TAT 1 Resonance Tisai wos donmtond ra Resonance 5 ADVANCED 2019 SHON BO Bay 9PART - Il: CHEMISTRY SECTION ~1 : (One or more options correct Type) This section contains 8 multiple coice questions. Each question has four choices (A), (B), (C) and (O) out of which ONE or MORE are correct. i ave 48 agtaoen wea E | uote Hes a Ret (A), ©), (C) she 0), Revi 8 ww a aif wae) 21. TheK,, of Ag,CrO, is 7.1 » 10- at 298 K. The solubility in molL) of Ag,CrO, in a 0.1 MAGNO, solution is K,, (Ag,CrO,) HIF 208 K 51.1 x 10- 210.1 MAGNO, & FAcraF Ag, Cro, Facraan Ata/Aex A (A) 1.1% 107 (B) 1.1. «107 (C) 1.1 «10-7 Ans. (B) Sol, Ag,CrO, = 2Ag'+ C102 s o1+25 s = 04 14x10 = (0.1)'s s=1.1« 10 22. _Inthe following reaction, the product(s) formed is(are) Prefettad ftir & eure /searet at ary OH CHCl OH cH, “oO 8 H.C CHCl, H.C CHCl, P Q R (A) P (major) (8) Q (minor) (©)R imino, Ngesonance () 1.4 «10° oH cHO CH, 8 (©) 8 (major) ‘This solution was downloed from Resonance JEE ADVANCED 2013 Solution portal Page # 23CHEMISTRY (A) PA) acim (Rem) )S (R=) Ans. (B,D) OH Fr 9° ° 9° 9° éa, CHCl, “QO=O020". 0-0-0 cH, cH, cH, ch, Sel, CH, CHC! = CH, on? ° iw R CHO . oy . _aaea 2 ch, Ho, ies cH, {H, CHCL, 23. ‘The major product(s) of the following reaction is (are) OH aqueous Br, (3.0 equivalents) _Bqueous Br, (3.0 equivalents) , SO.H on oH OH OH Br Br Be Br Br Br Br ‘Br Br Br SOH er Br SoH P a R s (ay @a OR os restr cif wr (@) HEI sare & @) oH Ata Br, (8.0 ge) Sie eae ? SO.H OH OH OH OH Br : Br Br Br oy Br ‘Br Br Br SO.H Br Br SO,H Pp Q R s wp @a OR os Ans.) ee is ett at domtnd tom Resnain J ADANGED 209 SOWEN P as y 24Sol. Sol CHEMISTRY OH SOH After completion of the reactions (| and Il), the organic compound(s) in the reaction mixtures is (are) aenraPas iAH LACM) B GR eV a ae va Parr A era eAAep (PT) a) we | ° Reaction: AA _Battomay april: HG, | SCH aqueous ars NaOH ° Reactont sation aA HC gmt CH.COOH g ° He” “cir Hc cer, B.c~ cer, Br cH.er H,c~ ~ONa CHBr, P Q R s T u (A) Reaction |: P and Reaction Il: P- (B) Reaction | : U, acetone and Reaction Il : Q, acetone (C) Reaction 1: T, U, acetone and Reaction Il: P (D) Reaction 1: R, acetone and Reaction II: S, acetone (A) siaRraT Pi PARP AL: (8) sfRrEMT U, wee att fA, wee (©) aiPafbrar dT, U, walter atte sera N:P (0) afRfirart celica ifirar 8, este (c) oO Be Br, (1.0 mol) az Be(L0me) _ cH.coona + cHen+ Ke H, Reaction |: fy py, Na‘OHP H, CH, 4.0 mol (Unreacted) (in basic medium complete haloform reaction takes place since the rate of reaction increases with each ‘o-halogenation) sonsnce Tiss wos domo rm Resoranc 5 ADVANCED 2019 SHON PO Bay ogSol. CHEMISTRY Br, (1.0 mol) Reaction Il: GH, tH, CH;COOH &, CHer 1.0 mol (In acidic medium monohalogenation takes place with 1-mol of halogen) fo aoe or ————> CH.COONa + CHBr, + ea: Gy, Na°OH? Hy 4.0 mol (ora) (arte arene Rete sean yo wa S was eth By cen wets a-Relo te oe shia BH ax age & |) 9° ° DAR Br, (1.0 mol) a sififraril: GA, OH, CH;COOH fH, tHe 1.0 mol (orstta Frere 41 mol citar & arr aectorftare eta z |) The correct statement(s) about O, is (are) (A) O-O bond lengths are equal. (B) Thermal decomposition of O, is endothermic. (©) 0, is diamagnetic in nature (©) 0, has a bent structure, 0, & eee #8 ara 8 @) (A) 0-0 amit ft ard were (8) 0, a are fore semen & (©) 0, aftjactra & (0) 0, a8 aie fra eet {A,C,D) A s288 JX Allelectrons are paired so diamagnetic (at gata aftre & ve sftrgeacta é 30, —> 20, AH=+ 142 kJ/mol. Inthe nuclear transmutation Spe+Xx —> $Be+¥ (X, Y) is (are) @Cr.n) @@.0) (mo) Op) free ase arr gpe+x —+$B0+¥ ROME (Cr) ® 0,0) (©(,0) ©.) (AB) Be? + X—> Be? + If Xis 7° then Y is. aR x, of Baa Y, PbCI, (white ppt) soluble in hot water Pbi-+ 2ck —s Poel, (za stata) a oar 4 fata “The coloured solution S contains ()Fe(S0), (@)Cuso, (©)zns0, (O)Nacro, im fae Si waftert 8 (@) FeSO), (@)cuso, (©)znso, O)Na,cro, © povror Hl, ppc, + crcl, ) @) White ppt Filtate (Dissolve in (HS / mineral Hot water) acid) Green ppt. (R) CrOH). | (H.S [ammonical No effect, medium) Na,Cro, yellow solution (s) Ree eeenee Tsou wos dont rm Resonance 5 ADVANCED 2019 SHON BO ay ogHCl CHEMISTRY sol. pptycr HO, pec, + crc, ) Q) win sade Poee (rf aa ¥ faa) (H,S | erst sr) Ba ora (R) Cr(OH), ag He siete Ta sam) Na,CrO, aa fear (8) Paragraph for Question 31 and 32 wer 31d 923 fra owe P and @ are isomers of dicarboxylic acid C,H,0,. Both decolorize Br./H,O. On heating, P forms the cyclic anhydnde. Upon treatment with dilute alkaline KMnO,, P as well as Q could produce one or more than one from ‘S, Tand U. 00H 00H 00H H—ton bon Ho tH H. ‘OH HO- H H. ‘OH GooH cooH COOH s T u Poi Q ym srgordfftaiern ora C,H,0,% ao aarard @ | a Br/H,071 eres aed € i we RP TA (regs Tare & ay ata KMINO, grat P te Q rats sia We TH seTAT Cw B sil zh" S, T serar Uwe aA 00H 00H 00H H—ton = fon Hof H: ‘OH HO- H H. ‘OH COOH COOH COOH s T u 31. Compounds formed form P and Q are, respectively (A) Optically active $ and optically active pair (T, U) (8) Optically inactive S and optically inactive pair (T, U) (C) Optically active pair (T, U) and optically active S (©) Optically inactive pair (T, U) and optically inactive S ssonsnce ‘This solution was downloed from Resonance JEE ADVANCED 2013 Solution portal Page # 29Pen Q gre at chiar are & (4) gam ep S we gam yi ye (TU) (©) geen tes rH (T, U) ea Gert yk S CHEMISTRY (© gee fern Sw qaer Fat eH (T, U) (©) ger Fara ye (T, U) qa Fewer ans.) 32. Inthe following reaction sequences V and W are respectively Froese, V tk WW ae: Qty 9 HOH Lp anavate of anarste( SO) CHOH vo wo a w 0 HOH.C. © pana) © aioe TL CHOH wy OHO v yo w ans. (a) Sol, (31832) COOH Coldak HL HOO 6. ¢cCOH cotta x} on H H KMnO, H—— OH (smn adation) PCs) COOH Meso (S) ‘COOH COOH Hy geget00t cold HL on | Hot Hooc~~ SH KMnO, (OH: H Hi ‘OH i (Syn addition) 12 rans) cooH cooH T u (Racemic Mixture) 9 Hooc-cH=cH-coon —L, ‘0 o~ 4 / : ° v Resonance —— Mt soir nr ne ton Rss EADWED 29 Sten ay 9CHEMISTRY 2 OH OH TL Anhydrous AIC, 2n-Hg a aed ° HCI ° ° v Sol. (31 & 32) ay erga, oe eso OOOH KMnO, H—— OH H H (fram) HOH (Cis) COOH ra (8) aq eta COOH COOH Hoe C00H __ Kino, H OH, HO H Hooc~~ SH OH: H H ‘OH (i) '' (trans) COOH COOH T u afer Fem ° HOOC-CH=CH-COOH aa O CH= a a 3° v °o . oH oH A Psa arc, Zn-Hg 7 e oO HCI O° ° v Paragraph for Questions 33 to 34 wea 33d 343 fa ogee ACS ‘A fixed mass 'm' of a gas is subjected to transormation of states from K to to Mto N and back to Kas shown, éochesin This solution was download from Resonance JEE ADVANCED 2013 Solution portal Page #31CHEMISTRY we fe & fated germ ‘mat saeen afta K 8 LY MS Neem ares KH fea ere fread ag @ Prossure a Volume sac 33. The succeeding operations that enable this transformation of states are (A) Heating, cooling, heating, cooling (8) Cooling, heating, cooling, heating (C) Heating, cooling, cooling, heating (0) Cooling, heating, heating, cooling softies oftarars oi 3 oraver afta A wer &, ae 8 (A) mi, de, mi, dar 7 we @) sai, dar wi as we (4, a1, da, are we (0) a1, 7, 1 dat we Ans. (C) Sol. Pressure Volume K>L=V 1 at constant P Hence T 7 (Heating) LoM-= P J atconstant V Hence T | (Cooling) M>N-= V J atconstant P Hence T | (Cooling) N+K= P ¢ atconstant V Hence T (Heating) sonsnce Tsou wos donna rm Resoranc 5 ADVANCED 2019 SHON PO Bay 5Sol. Ans. Sol. CHEMISTRY KL Prem Pa Vt, ome Tt Ore LoM= Pram var P for T | =) MoN= Prod Pa VY, om TY et NK Prat Vag Pt, ier Tt (re) The pair of isochoric processes among the transormation of states is (A) Kto Land LtoM (B) Lto Mand NtoK (C)Lto Mand MtoN (0) Mto Nand NtoK crater aRac=h 3 Reafeal A aieaPtas wa aH KS LaLa @LAMaN aK (C)La Mote MBN (Ma Note NA K (6) Lom Mok Both are having constant volume therefore these processes are isochoric. Si sar Pram greet we ete € oe: ae oaH THT aH e Paragraph for Questions 35 to 36 we 350d 363 fa age The reactions of Cl, gas with cold-dilute and hot-concentrated NaOH in water give sodium salts to two (differ- ent) oxoacids of chlorine, P and Q, respectively. The Cl, gas reacis with SO. gas, in presence of charcoal, to give a product R. R reacts with white phosphours to give a compound S. On hydrolysis, S gives an oxoacid of phosphours T. Cl, fa ag oie ae NaOH & ota Fares are weer: SB ote wel ore A PEAT ae ey FR) Te + sifait—orrs & ehReaH sam, P otk 8A | Cl,(g) anata BH saRY H SO, (9) 8 siMifraT ae seATE RAT Rube ROR ERI PHA ge Ms S Ba 81S aA seam Ha BEAT a UH STERTGAG T Sa \ P and Q, respectively, are the sodium salts of (A) hypochlorus and chioric acids () hypochlorus and chiorus acids (C) chloric and perchloric acids (D) chloric and hypochlorus acids Posie Qamaan ga sian cra (A) arsasteat site aif ort (8) entacies sty zee os (0) ait ste uate are (0) we sie ergthaahen oa (a) R, $ and T, respectively, are (A) SO,CI,, PCI, and H.PO, (8)SO,CI,, PCI, and H,PO, (©) SOCI,, PCI, and H,PO, (0) SOCI,, PCI, and H.PO, sonsnce Tis soa wos domo rm Resa 5 ADVANCED 2019 SHON PO Bay 33CHEMISTRY R, Salle Taper: & (A)80,C1, PCI, st H.PO, (C) SOCI,, PCI, sit HPO, (0) SOCI,, PCI, 3% H.PO, Ans. (A) Sol. (35 & 36) Cl, + cold dil. NtOH —> NaOCl + NaCl Cl, + hot conc. NaOH ——> NaClO, + NaCl NaOCl is salt of hypochlorous acid = P. NaOCl, is salt of chloric acid = Q. Cl, + $0, ==> §0,C1, (R) (NCERT, Pg. No. -188) $0,Cl, + P, —> PCI, (6) +80, (NCERT, Pg. No.-177) PCI, + H,O —> H,PO, (1) +HCI Sol. Cl, + SRI 4 NaOH —> NaOCl + NaCl cl, +-7 ay NaQH —> Nacio, + NaCl NaOCl atgthacteer ors ot Sat NaOCl, wife sie a TAM =a. cl, + So, —2RFIF_, soci, (R) (NCERT, Pg. No. - 188) S0,Cl, + P, —> PCI, (S) + SO, (NCERT, Pg. No.-177) PCI, +H,0 —> H,PO, (T) +HCI SECTION 3: (Matching List Type) ws — 3: (ert GH aR) ‘This section contains 4 multiple choice questions. Each questions has matching lists. The codes for the lists have choices (A), (B), (C) and (D) out of which ONLY ONE is correct. i ears Hg ghar wea H | cts eT Bat BN 81 yes fry ats} PReeH (A), (@), ©) she (O)¥. fcr a das ww we | 37. ‘The unbalanced chemical reactions given in List | show missing reagent or condition (?) which are provided in List I Match List | with List I! and select the correct answer using the code given below the lists agi fitra seightta sPifier 4 omeitie attara sagen eh A Svs S| eH ah EEA Gaiera sHE wen afta 3 fa fey 1a ats or war aed wal oa gia List 1 31 List iv ys I P. PbO, + H,S0, —7-» PbSO, +0, + other producvar=t see 4.NO Q. Na,S,0, + H,O—*-> NaHSO, + other productis™ sere 21, R. NH, —2-> N+ other product /am sear 3. Warmy ai 8. XeF, —2-> Xe+ other products sere 4.Cl, Codes Pp oa@oRoos M® 4 2 3 4 ® 3 2 1 4 ge eee sonsnce Tis soaion ws domo rm Resonance 5 ADVANCED 2019 SHON PO gy 3gSol. 39, CHEMISTRY (ead ee 1 ©) (P)2Pb0, + H,S0, —"™™)_, appso, + 0, + 3H.0 0,+H.0 —°2> NaHsO, + HCI (R)NH, 2 NaHSO, + HCI (S) XeF, "> xe +NOF Hence, Answer is (0) Se: FR (OD)? Match the chemical conversions in List | with the appropriate reagents in List I! and select the correct answer using the code given below the lists eh 1 PRA eA Ow A Pe oR aaa er BAT AE ear BPR ANA Req a ats a wie web A oR BPA List 1/1 List i / af P. >a —_—_—_ = 1.) Ha(OAo), ; (ii) NaBH, —_ eee So 2. NaOEt ae(y — —" 3. eter s. e 4. (0 BH, ; (i) HO.JNaOH Codes @) ® © oO (A) e cy Nae 2 EtBr Q. ONa Sy Et @ Ha(OAC), R | —_ ‘OH (Markovnikov addition) (areiftaite aim (i) NaBH, (BH, a Ss. ! (ii) HO,NaOH Oneny ReNeo RaaaaD ASANO 1», Antimarkovnikov addition) (¢Pesretrarie am) “oH ‘An aqueous solution ox X is added slowly to an aqueous solution of ¥ as shown in list |. The variation in conductivity of these reactions is given in List Il. Match List| with List Il and select the correct answer using the code given below the lists ‘This solution was downloed from Resonance JEE ADVANCED 2013 Solution portal SOnEMc] Ts solute nee oor om sarees TEE ANCES 209 Soon pore! page # 35Sol. CHEMISTRY List! List I P. (CH).N+CH.COOH 1, Conductivity decreases and then x Y increases Q.—_KI(0.1M) +AgNO,0.01M) 2, Conductivity decreases and then x Y does not change much R. CH,COOH+KOH 3. Conductivity increases and then x Y does not change much S. NaOH + HI 4, Conductivity does not change much x Y and then increases Xo ores erat spre Y wer ota Rae ARAN sre oe 8, GRY 1 Remar ae By gaffe 3 sear arena a Aran a) A aE B | eM aT AUS Ala Ary sear Ge B NS WA ats ah aa P. (CH).N+CH,COOH 1. arama ech & ote cera aah & x Y @.—_KI(@.1M)+AgNO,0.01M) 2, arermen wel & othe career stra x Y star Eh ere | R. CH,COOH + KOH 3. areren aaah & ohe aervee sie x Y vf seh 8. NaOH + HI 4, eae sa GfRafhia eh atc 8 site Bo Y arearq aah 8 Codes P oa@oR os ® 3 4 2 4 ® 4 3 2 4 © 2 3 4 4 ® 1 4 3 2 (a x y (P) (C,H,),N_ + CH,COOH —> CH,COO- (aq) + (C,H,),NH" (aq) ‘AS CH.COOH is a weak acid, its conductivity is already less. On addition of weak base, acid-base reaction takes place and new ions are created So conductivity increases. (Q) KI(0.1 M) + AgNO, (0.01 M)—» Agl 4 (ppt) + KNO, (aq) As the only reaction taking place is precipitation of AgI and in place of Ag’, K' is coming in the solution, conductivity remain nearly constant and then increases. (R) CH,COOH + KOH —> CH,COOK (aq) +H,0 OH: (aq) is getting replaced by CH,COO-, which has poorer conductivity So conductivity dereases and then after the end point, due to common ion effect, no further creation of ions take place. So, conductivity remain nearly same. (S)NaOH + HI —> Nal (aq) + H,0 ‘ASH’ is getting replaced by Na* conductivity dereases and after end point, due to OH, it increases, So answer of 39s : (P) ~ (3) ; (Q)— (4) :(R) - @) : (S) = (1). Answers (0) x y (P) (C.H,)N_ + CH,COOH > CH,COO- (aq) + (C,H)),NH" (aa) CH,COOH we gd ore @ free araaar aH 2) gyda ae fer oR ara ane APART aT FERRY = ara wr Fear er wd TeeTeN aN ‘This solution was download trom Resonance JEE ADVANCED 2012 Solution port SON EMC] Te slate nee oor om Resaranee SEE ANCES 209 Soon pore! page #36Sol. CHEMISTRY (Q) KI (0.1 M) + AgNO, (0.01 M)—> Agl + (ppt) + KNO, (aq). Bae et sifhfaren 4 Agi ar siaetrer et eer & cen Ag’ } ears we K: Pee 3 orn, atesren center Frat wet fhe we (R)CH,COOH + KOH —> CH,COOK (aq) + H,0 OH: (aq), CH,COO- arer afteenfta wer & if aH aera wea 8 | sasteat wed & cen cin fey ocean ama Ta BR ST wT ‘rf sr&h Bre Forerey areranen Tantra Fa wee | (S)NaOH + HI —> Nal (aq) + H,0 Nat, Hat afteentte aear 8, wereawH ureter wed Ben safer Rey S years OH: ere ateraraT ah | Sie 391 GA: (P)—@);Q)—(4)}(R)-@)_ 5 (8)-(1) eT The standard reduction potential data at 25°C is given below. rep sige Para 25°C we PEAR E | E° (Fe”.Fe) O77V E° (Fe Fe) 0.44V; E° (Cu*.Cu) = +0.34V; E° (Cur.Cu) 0.52V; E® (O,(g) + 4H'+ 4e- > 2H,0) =+1.23V; E (0,(g) + 2H,0 + de > 40H) = +0.40V E°(Cr.C) =-0.74V; E*(Cr-C) =-0.81V Match E° ofthe rebox pairin List | withthe values given in List Il and select the correct answer using the code given betow the lists ea 1 A ara ya wy GN BAA svar Fora a Bee AE ae GPR SAB RAT ats ar ain aS WA Ga GPA List aft List rapt P. E* (Fe Fe) 1 -0.18V Q. E° (4H,O ===4H"+ 40H) 2 0.4V R. E* (Cu + Cu 2Cu") 3. 0.04 S. ENC, Cr) 4 083V Codes P Q R Ss ® 4 1 2 3 (Gi aaeoianed ements © 1 2 3 4 ® 3 4 +1 2 ©) ®) = 1K O77 +2 (-0.44)=3 xx = ony 0.04 Vv. sxe Sty. @ — 4H,O 4H +40H- Ree eeenee Ts solaion wos domo rm Resoranc 5 ADVANCED 2019 SHON PO Bay 37CHEMISTRY 2H,0 —> 0, + 4H + 4e 123 + 0, + 2H,0+ 4e- —> 40H +04 4H,0 <= 4H" + 40H =083V R Eoareor eso) ou" > cu 2% cu +0.34V, n=2 x1 +052 *1=0.34*2 x= 0.16 V, = cu +e —> cu o16v + cu —> cuter -0.52V cut + Cu —> 20u" - 0.36 V However, in the given option, — 0.18 Vis printed, RA a Bg (Option) —0.18 V Rea gs & | CP 9 or Bs cy (9) Bae oy =O7av, n=3 x142« (0.91) =3x (0.74) x = 1.8: 2.22 > x=-04V Hence, most appropriate is (0) ie: BR SEAR IE (O) 8 | )=@);(Q)~ 4); R)=(1) ;(S)-2. PART - Ill MATHEMATICS SECTION ~1 : (One or more options correct Type) ws -1: (tH a afte aA ftaed Her) This section contains 8 multiple coice questions. Each question has four choices (A), (B), (C) and (D) out of which ONE or MORE are correct. a es 48 agian wea E | sicko He Aare Perot (A), ©), (©) ste (O) 8, For A yw aT ale EB mn. Sol (942° +..+n?) 4 7 e-t, tim = = Fora « R (the set of all eal numbers), a%—1, IM sas) «(na va)+..0(narm) 60° ENA (P42? +t) 1 ae Rw areata Gensit wr aye), ae —1 & fee lim nar) +(na+2)+.4 army 60% one as -15 -17 (as @7 oy o> (8,0) 2 eye ee is etn an domtnd tom Resonanin J ADVNGED 209 SOWEN Pa 3g42. Sol. Sol. MATHEMATICS 20) Gr tiny' aca afreax 2a+t — @asHar) 60 120= (2a+1)(a+1) a=7,-17/2 Circle(s) touching x-axis at a distance 3 from the origin and having an intercept of length 2,/7 on y-axisiis (are) xr a apfing & 3g we eel wearer (IR) AMT y-I 9/7 aTENS wT aT (ard) THe (A) x2 + 86x + By +9=0 (B) e+ y'-6x+ 7y+9=0 (C) x¢+ y°—6x— By + 9=0 (0) e+ y-6x-7y+9=0 (acy Let ari x’ + y?+ 2ox + 2fy+c=0 g-c=0 gee 0} WP -¢ =207 Poo Ai) 9+0+6g+0+C=0 9+6g+g'=0 @+3y= 3 6 feed 1 e+ ye Ox t By +9=0 Twolines L,:x=5, 3* >= > andl, :x=«, 27> 57 are coplanar. Then a can take value(s) z aang ice 5, a= 2 gem xe a, = 52> mata 8) 0a a a HTB Oe @2 @s os (AD) Seat yaa 0 3-a -2 0-1 2-a (5a) (B=) (@-a)-2)=0 (2 -5u+6-2)=0 (= 5)(08 = 5a 4 o=1,45 0 : Resonance a at Fr eee IE ONIN 2018 Sotto Por page # 394, Sol. Sol. MATHEMATICS Ina triangle POR, P is the largest angle and cosF ; Further the incircle of the triangle touches the sides PQ, QR and RP aN, L and M respectively, such thatthe lengths of PN, QL and RM are consecutive even integers. Then possible length(s) of the side(s) of the triangle is (are) Prop POR, P ec ator & ae cosP= 2 | eb ae as a org APF PO, AR ae RPA ae NL Mover ae ere aT & FPN, QL cen RM A el woe OE eo oa Po aT (goal a ener ara (wea) & ae @ 18 (2 2 (8,0) P _ 2n+2) +(an+4F-(2n+6F 1 ano YN \ one coer 2en+2)\en=4) 3 a ene a2 4 or = 2ne)"3 =2n+2 1 where C is the set of all complex numbers. If z, « PH, z, ¢ PH, and O represents the origin, then 02,5 3B See oth zeC:Rez>3} gon arate w= Som den P= {wen = 12,3...) gad oftat H, {zee Re 2<-3} ei Cas toms mr aeTa 81a 2, cP OH, 26 POH, we O RES Rez> 1/2 Resonance Tiss wos donna rm Resonance 5 ADVANCED 2019 SHON PO Ba 4pSol. 47. Sol. MATHEMATICS 22,022 5508 Wa*= 4", then x= aR Oe a1 a x= 2log, 2 2 1 2log,3 2log, 2-1 ®) 2109.3 © 410g,3 ©) 2i0g, 3 (A,B,C) yeae (x-1) 09,4 x(1 = 2log,2) = —2l0g,2 2logs 2 2log,2—1 ‘Ans. (A) Again xlog,3= (x-1)-2 x (og,3-2) Ans.(B) 1 1 —_- ‘Ans.(C) 1—11og,3, 110043 2 Let © be a complex cube root of unity with o # 1 and P = [p,J be a n x n matrix with p, =o! *!. Then 0, when n= wed or we afis oT o aifey, vel o 41 Ta P= [p] TH nx noma afte, wet p, =o!) ae P20, 08 (A) 57 (8) 55 (0) 56 (B,C, D) n=4 P= lo} 3 o? 1 fo? 1 ©] [0 0 Oo] 2 2 pe|1 © o|/1 © o*/=|0 00 o o 1]/o o 1] [0 0 0} Similarly P? * 0 when nis not multiple of 3. Aeaorence| ‘This solution was download from Resonance JEE ADVANCED 2013 Solution portal eg eee SS SSS Page # 44MATHEMATICS A FR P20 ra n, 3a UT EB 48. The function f(x) = 2[x| + x + 2|—|[x + 2|—2[x|| has.a local minimum or a local maximum at x= WAT AH) = px] + x 2] = |x + 2] —2pxl] wr GH ePaper safes fore a I Te a, we e (A)-2 8 > (2 0) 2 “- OF © 5 Sol. (A,B) (x) = 2px] + [x + 2|—| x +2] -2 xf] -2x-4 xs-2 2x+4 -22 Graph of y = f(x) is minima at x=-2,0; maxima at x=-2/3 y= f(a) or site & ow Pitts 213 1 sPeas SECTION ~2 : (Paragraph Type) AUS ~ 2: (9IGeIE TOR) This section contains 4 paragraphs each describing theory, experiment, data etc. Eight questions relate to ‘four paragraphs with two questions on each paragraph. Each question of a paragraph has only one correct answer among the four choices (A), (B), (C) and (0). ge avs 4 fgicl, wart ote stil onfe ah eat are 4 argede 2 | ani srjedel 8 ddfta ome wea 2, fore Ae apee wea we 81 RAN MN ages Ha es aK Aa A), B), CaO), fri F daa w awit Paragraph for Question Nos. 49 to 50 Wer 49.8 506 fare aged Let f:[0, 1] > R (the set of all real numbers) be a function. Suppose the function f is twice differentiable, (0) = (1) = O and satisfies £"(x) ~ 2°) + 10) =e, x € [0, 1] ara £20, 1] +R QnA anata eens wr ayer) ww we Bl aT Ay wert Fal ane sree B, (0) = (1) = 02H F(x) — 2F(W) + £0) > e%, xe [0,1] BY tige aa B 49. Which of the following is true for 0 10), 00,x = (14,1) > e* FO) -e*f09) <0, x = (0, 1/4) F(X) <100), O 0. I Rh PQ Waray? = dax Vw aM hat B | Ryall P ae Q wR Nara eae La we fg BR Pec 3 oh fH ar y= xt, a> 0% Red 2) Length of chord PQ is star PQ a arg & (A) 7a (8) Sa (C) 2a (0) 3a (8) Ries ony =2x+a Ry=2x+ ater w Rem & Ree eeenee Ts soa wos domo rm Resa 5 ADVANCED 2019 SHON BO Bay 452. Sol. 53. Sol. MATHEMATICS a-aae-3] If chord PQ subtends an angle 0 at the vertex of y= 4ax, then tan 0 = cafe iia PQ, y¥@= dax & ein w atm 0 siafta wah # aa tan = 2» wit (0) UW) _ 25 Paragraph for Question Nos. 53 to 54 wer 53.8 54% fay ages Let $= S,9 S,-S,, where { z-1+y3i]_ 9] zec lal <4)8,= [eC uf a J>°| 8,:{ZeC:Rez>0} at fF $= 8,4 8,08, eH i z-1+v3i]_ 4 = eC: 2] <4), 8,5 Fee mete of — 8,:(@eC:Rez>0} Area of S Sw dame 10% 20n 16x 32m ws oF o® o% 6) S18 + F< 16 Zot VB CD Ky HN Aeaorence| Tis soaion wos domo ram Resonance 5 ADVANCED 2019 SHON PO a 4g