JEE Advanced 2016 Paper-2

®
JEE (Advanced) 2016

22-05-2016
PAPER ¼isij½- 2 CODE - 7
Time : 3 :00 Hrs. le; :3 ?kaVs Max. Marks : 186 vf/kdre vad : 186
READ THE INSTRUCTIONS CAREFULLY ( dì;k bu funsZ'kksa dks /;ku ls i<sa)

General lkekU; %
1. The sealed booklet is your Question Paper. Do not break the seal till you are instructed to do so.
;g eksgjcU/k iqfLrdk vkidk iz'ui=k gSA bldh eqgj rc rd u rksMsa tc rd bldk funsZ'k u fn;k tk;sA
2. The question paper CODE is printed on the right hand top corner of this sheet and the right hand top corner of the back cover of this
booklet.
iz'u&i=k dk dksM (CODE) bl i`"B ds Åijh nk;sa dksus vkSj bl iqfLrdk ds fiNys i`"B ds nk;sa dksus ij Nik gSA
3. Use the Optical Response Sheet (ORS) provided separately for answering the question.
iz'uksa dk mÙkj nsus ds fy, vyx ls nh x;h vkWIVhdy fjLikal 'khV ¼vks- vkj- ,l-½ (ORS) dk mi;ksx djsaA
4. The ORS CODE is printed on its left part as well as the right part of the ORS. Ensure that both these codes are identical and same
as that on the question paper booklet. If not, contact the invigilator for change of ORS.
vks- vkj- ,l- dksM blds ck;sa rFkk nk;sa Hkkx esa Nis gq, gSaA lqfuf'pr djsa fd ;g nksuksa dksM le:i gSa rFkk ;g dks M rFkk iz'ui=k
iqfLrdk ij Nik dksM leku gSA ;fn ugha] rksa fujh{kd dks lEidZ djsaA
5. Blank spaces are provided within this booklet for rough work.
dPps dk;Z ds fy, bl iqfLrdk esa [kkyh LFkku fn;s x;s gSaA
6. Write your Name and Roll Number in the space provided on the back cover of this booklet
bl iqfLrdk ds fiNys i`"B ij fn, x, LFkku esa viuk uke rFkk jksy uEcj fyf[k,A
7. After the open booklet, verify that the booklet contains all the 54 questions along with the options are legible.
bl iqfLrdk dks [kksyus ds i'pkr~] dì;k tk¡p ysa fd lHkh 54 iz'u vkSj muds mÙkj fodYi Bhd ls i<sa tk ldrs gSaA
8. You are allowed to take away the Question Paper at the end of the examination.
ijh{kkFkhZ iz'ui=k dks ijh{kk dh lekIrh ij ys tk ldrs gSA
OPTICAL RESPONSE SHEET : vkWfIVdy fjLikal 'khV %
9. The ORS (top sheet) will be provided with an attached Candidate's Sheet (bottom sheet). The Candidate's Sheet is a carbon-less
copy of the ORS.
nh xbZ vks-vkj-,l- ¼Åijh 'khV½ ds lkFk ijh{kkFkhZ dh 'khV ¼uhpyh 'khV½ layXu gSA ijh{kkFkhZ dh 'khV ORS ds
dkcZu&jfgr izfr gSA
10. Darken the appropriate bubbles on the ORS by applying sufficient pressure. This will leave an impression at the corresponding place
on the Candidate's Sheet.
ORS vuq:i cqycqyksa (BUBBLES) dks i;kZIr ncko Mkydj dkyk djsaA ;g dkcZu&jfgr fupys i`"B ds vuq:i LFkku ij
fpfUgr djsxkA
11. The ORS will be collected by the invigilator at the end of the examination.
ORS dks ijh{kk ds lekiu ij fujh{kd ds }kjk ,d=k dj fy;k tk;sxkA
12. You will be allowed to take away the Candidate's Sheet at the end of the examination.
ijh{kk ds lekiu ij vkidks dkcZu&jfgr 'khV ys tkus dh vuqefr nh tk,xhA
13. Don not tamper with or mutilate the ORS. Do not use the ORS for rough work.
vks-vkj-,l- dks gsj&Qsj@fod`fr u djsaA ORS dk dPps dke ds fy, iz;ksx u djsa A
14. Write your name, roll number and code of the examination centre and sign with pen in the space provided for this purpose on the
ORS. Do not write any of these details anywhere else on the ORS. Darken the appropriate bubble under each digit of your roll
number.
viuk uke] jksy ua- vkSj ijh{kk dsanz dk uke ewy i`"B esa fn, x, [kkuksa esa dye ls Hkjsa vkSj vius gLRkk{kj djsaA buesa ls
dksbZ Hkh tkudkjh dgha vkSj u fy[ksaA jksy uEcj ds gj vad ds uhps vuq:i cqycqys dks dkyk djsaA
Please read the last page of this booklet for the instructions. (Ñi;k funsZ'kksa ds fy;s bl iqfLrdk ds vfUre i`"B dks i<+sA)
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This solution was download from Resonance JEE ADVANCED 2016 Solution portal
| JEE ADVANCED-2016 | DATE : 22-05-2016 | PAPER-2 | CODE-7 | PHYSICS
PHYSICS (PAPER-2)
SECTION – 1 : (Maximum Marks : 18)

 This section contains SIX questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct.
 For each question, darken the bubble corresponding to the correct option in the ORS.
 For each questions, marks will be awarded in one of the following categories :
Full Marks : +3 If only the bubble corresponding to the correct option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –1 In all other cases.
[kaM 1 : (vf/kdre vad : 18)


 bl [kaM esa N% iz'u gSaA
 izR;sd iz'u esa pkj fodYi (A), (B), (C) rFkk (D) gSaA ftuesa dsoy ,d gh lgh gSA
 izR;sd iz'u ds fy, vks-vkj-,l- ij lgh mÙkj fodYi ds vuq:i cqycqys dks dkyk djsaA
 izR;sd iz'u ds fy, vad fuUufyf[kr ifjfLFkr;ksa esa ls fdlh ,d ds vuqlkj fn;s tk;saxs %
 iw.kZ vad : +3 ;fn flQZ lgh fodYi ds vuq:i cqycqys dks dkyk fd;k gSA
'kwU; vad : 0 ;fn fdlh Hkh cqycqys dks dkyk ugha fd;k gSA
_.k vad : –1 vU; lHkh ifjfLFkr;ksa esaA
1. A gas is enclosed in a cylinder with a movable frictionless piston. Its initial thermodynamic state at
pressure Pi = 105 Pa and volume Vi = 10–3 m3 changes to a final state at Pf = (1/32) × 105 Pa and
Vf = 8 × 10–3 m3 in an adiabatic quasi-static process, such that P3V5 = constant. Consider another
thermodynamic process that brings the system from the same initial state to the same final state in two
steps : an isobaric expansion at Pi followed by an isochoric (isovolumetric) process at volume Vf. The
amount of heat supplied to the system in the two-step process is approximately.
,d [kks[kys csyu] ftlesa ,d ?k"kZ.k&jfgr pyk;eku fiLVu yxk gS] esa ,d xSl can gSA fudk; dh izkjfEHkd Å"ekxfrdh
voLFkk (thermodynamic state) esa xSl dk ncko Pi = 105 Pa ,oa vk;ru Vi = 10–3 m3 gSA ,d :}ks"e LFkSfrddYi
(adiabatic quasi-static) dh izfØ;k] ftlesa P3V5 = fLFkjkad gS] ls fudk; vafre Å"ekxfrdh voLFkk Pf = (1/32) × 105 Pa ,oa
Vf = 8 × 10–3 m3 esa ifjofrZr gks tkrk gSA ,d nwljh Å"ekxfrdh izfØ;k esa ogh izkjfEHkd ,oa vafre voLFkk,a nks pj.kksa esa
iw.kZ dh tkrh gSa : igys pj.k esa Pi ij leku ncko o`f) (isobaric expansion) ds ckn nwljs pj.k esa ,d leku vk;ru
izfØ;k(isochoric /isovolumetric process) Vf vk;ru ij gksrh gSA nks pj.kksa okyh izfØ;k esa fudk; dks nh xbZ
Å"ek dh ek=kk yxHkx gSA
(A) 112 J (B) 294 J (C) 588 J (D) 813 J
Ans. (C)
Sol.

This solution was download from Resonance JEE ADVANCED 2016 Solution portal PAGE # 1
P (pascal)
5
10
1
 105
32
V(m 3)
–3 –3
10 8 × 10
5/3
PV = C   = 5/3
Q1 = nCPT
5
R PV 3 5 35
= n T = =   105 (7  103 ) =  7  102   102 J
 1  1 5  2 2
 3  1
 
 1 
  1105  8  103
nR ( P)V  32  31 8  10 2 93
Q2 = nCVT = T  = =  3 =  102 J
 1  1 5 32 2 8
1
3
 35 93  2
Q = Q1 + Q2 =    × 10
 2 8 
140  93 4700
Q2 =  100 = = 587.5 Joule
8 8
2. An accident in a nuclear laboratory resulted in deposition of a certain amount of radioactive material of

half-life 18 days inside the laboratory. Tests revealed that the radiation was 64 times more than the
permissible level required for safe operation of the laboratory. What is the minimum number of days
after which the laboratory can be considered safe for use ?
,d ukfHkdh; iz;ksx'kkyk esa nq?kZVuk dh otg ls jsfM;ks,fDVo inkFkZ dh dqN ek=kk tek gks x;h] ftldh v/kkZ;q 18
fnuksa dh gSA ijh{k.k ls irk pyk fd iz;ksx'kkyk esa fofdj.k dk Lrj lqjf{kr Lrj ls 64 xq.kk T;knk FkkA U;wure
fdrus fnuksa ds ckn iz;ksx'kkyk dke djus ds fy, lqjf{kr gksxh \
(A) 64 (B) 90 (C) 108 (D) 120
Ans. (C)
 t / TH
Sol. A  A0 2
A0 t / T t
  A0 2 H  6=  t = 6TH = 108 days
64 TH

3. There are two Vernier calipers both of which have 1 cm divided into 10 equal divisions on the main
scale. The Vernier scale of one of the calipers (C1) has 10 equal divisions that correspond to 9 main
scale divisions. The Vernier scale of the other caliper (C2) has 10 equal divisions that correspond to 11
main scale divisions. The readings of the two calipers are shown in the figure. The measured values (in
cm) by calipers C1 and C2, respectively, are
nks ofuZ;j dSfyilZ bl rjg ls gSa fd muds eq[; iSekus dk 1 cm, 10 leHkkxksa esa foHkkftr gSA ,d dSfyij (C1) ds
ofuZ;j iSekus ij 10 cjkcj Hkkx gSa tks fd eq[; iSekus ds 9 Hkkxksa ds cjkcj gSA nwljs dSfyij (C2) ds ofuZ;j iSekus
ij Hkh 10 cjkcj Hkkx gSa tks fd eq[; iSekus ds 11 Hkkxksa ds cjkcj gSaA nksuksa dSfyilZ ds iBuksa dks fp=k esa n'kkZ;k x;k
gSA C1 rFkk C2 n~okjk ekis x, lgh eku (cm esa) Øe'k% gSa
2 3 4
C1
0 5 10
2 3 4
C2
0 5 10
(A) 2.87 and 2.87 (B) 2.87 and 2.86 (C) 2.87 and 2.83 (D) 2.85 and 2.82
(A) 2.87 ,oa 2.87 (B) 2.87 ,oa 2.86 (C) 2.87 ,oa 2.83 (D) 2.85 ,oa 2.82
Ans. (C)
Sol. For vernier C1
10 VSD = 9 MSD = 9 mm
1 VSD = 0.9 mm
 LC = 1MSD – 1VSD = 1mm – 0.9 mm = 0.1 mm
 Reading of C1 = MSR + (VSR)(L.C.) = 28mm + (7)(0.1)
Reaing of C1 = 28.7 mm = 2.87 cm
For vernier C2 : the vernier C2 is abnormal,
So we have to find the reading from basics.
The point where both of the marks are matching :
distance measured from main scale = distance measured from vernier scale
28mm + (1mm)(8) = (28 mm + x) + (1.1 mm) (7)
solving x = 0.3 mm
So reading of C2 = 28 mm + 0.3 mm = 2.83 cm

ofuZ;j C1 ds fy;s 10 VSD = 9 MSD = 9 mm
1 VSD = 0.9 mm
 LC = 1MSD – 1VSD = 1mm – 0.9 mm = 0.1 mm
 C1 dk ikB~;kad = MSR + (VSR)(L.C.) = 28mm + (7)(0.1)
C1 dk ikB~;kad = 28.7 mm = 2.87 cm
ofuZ;j C2 ds fy;s : ofuZ;j C2 vlkekU; gS

blfy;s bldk ikB~;kad fuEu ds vk/kkj ij Kkr djrs gSa
og fcUnq tgk¡ nksuksa fpUg lqesfyr gksrs gS:a
eq[; iSekus ls ekih x;h nwjh = ofuZ;j iSekus ls ekih x;h nwjh
28mm + (1mm)(8) = (28 mm + x) + (1.1 mm) (7)
gy djus ij x = 0.3 mm
vr% C2 dk ikB~;kad = 28 mm + 0.3 mm = 2.83 cm
4. A smaller object is placed 50 cm to the left of a thin convex lens of focal length 30 cm. A convex
spherical mirror of radius of curvature 100 cm is placed to the right of the lens at a distance of 50 cm.
The mirror is tilted such that the axis of the mirror is at an angle  = 30º to the axis of the lens, as
shown in the figure.
,d NksVh oLrq dks 30 cm Qksdl nwjh (focal length) okys ,d irys mÙky (convex) ysal dh ckbZa vksj 50 cm dh nwjh
ij j[kk x;k gSA 100 cm dh oØrk f=kT;k okys ,d mÙky xksykdkj niZ.k dks ysal dh nkbZa vksj 50 cm dh nwjh ij j[kk
x;k gSA niZ.k dks bl rjg ls >qdk;k x;k gS fd niZ.k dk v{k ysal ds v{k ls  = 30º dk dks.k cukrk gS] tSlk fp=k esa
n'kkZ;k x;k gSA
f = 30 cm

x
(–50, 0) (0, 0)
R = 100 cm
50 cm
(50  50 3, 50)
If the origin of the coordinate system is taken to be at the centre of the lens, the coordinates (in cm) of
the point (x, y) at which the image is formed are
;fn funsZ'kkad i)fr dk ewy fcUnq ysal ds e/; esa gks rks tgk¡ izfrfcac cuk gS ml fcUnq dk funsZ'kkad (x, y), lsaVhehVj esa]
D;k gksaxak\
(A) (125/3, 25 / 3 ) (B) (25, 25 3 ) (C) (50  25 3, 25) (D) (0, 0)
Ans. (B)

Sol.
I2
y
30° I1
30°
o 50–x 25
x
For I1  u = –50 f = +30 v = +75cm

final image is I2
vafre izfrfcEc I2 gSA
y
= tan 60 = 3 y = 50 3 – 3x
50 – x
y+ 3 x = 50 3
A and B both option satisfy this, nksuksa fodYi A rFkk B bldks larq"V djrs gS,a
size of image > size of object

izfrfcEc dk vkdkj > oLrq dk vkdkj
2
y2   50 – x  sin30° > 25 sin30°
y2 + (50 – x)2 > 625

625 625
for option (A)  < 625
3 9
625 625
fodYi (A) ds fy;s  < 625
3 9
for option (B) 625(3) + 625 > 625
so B is correct.
fodYi (B) ds fy;s 625(3) + 625 > 625 vr% B lgh gSA
5. The electrostatic energy of Z protons uniformly distributed throughout a spherical nucleus of radius R is
given by
3 Z( Z – 1)e 2
E
5 4 0R
The measured masses of the neutron, 11H , 15
7 N, and 15
8 O are 1.008665 u, 1.007825 u, 15.000109 u
15 15
and 15.003065 u, respectively. Given that the radii of both the 7 N and 8 O nuclei are same,
1 u = 931.5 MeV/c2 (c is the speed of light) and e 2 / 4 0  =1.44 MeV fm. Assuming that the difference
15 15
between the binding energies of 7 N and 8 O is purely due to the electrostatic energy, the radius of
–15
either of the nuclei is (1 fm = 10 m)

f=kT;k R okys ,d xksykdkj ukfHkd (nucleus) esa Z izksVksu leku:i ls forfjr gSA ,sls ukfHkd dh fLFkj fon~;qr~
ÅtkZ uhps lehdj.k esa nh xbZ gS
3 Z( Z – 1)e 2
E
5 4 0R
U;wVªkWu] 11H , 15
7 N ,oa 15
8 O ukfHkdksa (nuclei) ds ekis x;s nzO;eku Øe'k% 1.008665 u, 1.007825 u, 15.000109 u
,oa 15.003065 u gSA 15
7 N vkSj 15
8 O ukfHkdksa dh f=kT;k;sa leku nh xbZ gSA 1 u = 931.5 MeV/c2 (tgka ij c
izdk'k dh xfr gS) vkSj e 2 /4 0  = 1.44 MeV fmA ;fn 15 15
7 N vkSj 8 O dh ca/kd ÅtkZvksa dk varj flQZ fLFkj
fon~;qr~ ÅtkZ ds dkj.k gS] rks nksuksa esa ls fdlh Hkh ukfHkd dh f=kT;k D;k gksxh \(1 fm = 10–15 m)
(A) 2.85 fm (B) 3.03 fm (C) 3.42 fm (D) 3.80 fm
Ans. (C)
3 Z(Z  1)e2
Sol. E=
5 40R
n  158 O  157 N  11H

Q = Mn  MO15  mN15  MH1 C
8 7 1
 2
= 0.003796 × 931.5
= 3.5359 MeV
3 e2 1
E =   (8  7  7  6)
5 40 R
3 1
=  (1.44 MeV fm)   14 = 3.5359 MeV
5 R
R = 3.42 fm
6. The ends Q and R of two thin wires, PQ and RS, are soldered (joined) together. Initially each of the
wires has a length of 1m at 10 °C. Now the end P is maintained at 10 °C, while the end S is heated and
maintained at 400 °C. The system is thermally insulated from its surroundings. If the thermal
conductivity of wire PQ is twice that of the wire RS and the coefficient of linear thermal expansion of PQ
is 1.2 × 10–5 K–1, the change in length of the wire PQ is.
,d irys rkj PQ ds Nksj Q dks vU; irys rkj RS ds Nksj R ij Vkadk yxkdj (soldered) tksM+k x;k gSA
10 °C ij nksuksa rkjksa dh yEckbZ 1m gSA vc bl fudk; ds Nksj P rFkk Nksj S dks Øe'k% 10 °C rFkk 400 °C ij
fLFkj j[kk tkrk gSA ;g fudk; pkjksa vksj ls Å"ekjks/kh gSA ;fn rkj PQ dh Å"e pkydrk rkj RS dh Å"e
pkydrk ls nqxuh gS rFkk rkj PQ dk js[kh; Åf"er o`f) xq.kkad (coefficient of linear thermal expansion)
1.2 × 10–5 K–1 gS] rc rkj PQ dh yEckbZ esa ifjorZu dk eku gS
(A) 0.78 mm (B) 0.90 mm (C) 1.56 mm (D) 2.34 mm

Ans. (A)

Sol.
P 1m Q,R 1m S
10°C 140°C 400°C

2k, 1 k, 2
d = dx1 ( – 10)
  – 10  130
 =  d    1   = 10 + 130x
 x 
1
x2
 =  130x  1dx
0
 = 130 1
2
1
 = 130 × 1.2 × 10–5 × = 78 × 10–5 = 0.78mm Ans. (A)
2
 This section contains EIGHT questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four
option(s) is(are) correct.
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS.
 For each question, marks will be awarded in one of the following categories :
Full Marks : +4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened.
Partial Marks : +1 For darkening a bubble corresponding to each correct option, provided NO
incorrect option is darkened.
 For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will
result in +4 marks ; darkening only (A) and (D) will result in +2 marks and darkening (A) and (B) will
result in –2 marks, as a wrong option is also darkened.
 bl [kaM esa vkB ç'u gSaA
 izR;sd iz'u esa pkj mÙkj fodYi (A), (B), (C) rFkk (D) gSaA ftuesa ls ,d ;k ,d ls vf/kd fodYi lgh gSA
 izR;sd iz'u ds fy, vks-vkj-,l- ij lkjs lgh mÙkj ¼mÙkjksa½ ds vuq:i cqycqys ¼cqycqyksa½ dks dkyk djssaA
 iw.kZ vad : +4 ;fn flQZ lgh fodYi ¼fodYiksa½ ds vuq:i cqycqys ¼cqycqyksa½ dks dkyk fd;k gSA
vkaf'kd vad : +1 çR;sd lgh fodYi ds vuq:i cqycqys dks dkyk djus ij] ;fn dksbZ xyr fodYi dkyk
ugha fd;k gSA
'kwU; vad : 0 ;fn fdlh Hkh cqycqys dks dkyk ugha fd;k gSA
_.k vad : –2 vU; lHkh ifjfLFkfr;ksa esa
 mnkgkj.k % ;fn ,d ç'u ds lkjs lgh mÙkj fodYi (A), (C) rFkk (D) gSa] rc bu rhuksa ds vuq:i cqycqyksa dks dkys
djus ij +4 vad feysaxs flQZ (A) vkSj (D) ds vuq:i cqycqyksa dks dkys djus ij +2 vad feysaxs rFkk (A) vkSj (B)
ds vuq:i cqycqyksa dks dkys djus ij –2 vad feysaxs D;ksafd ,d xyr fodYi ds vuq:i cqycqys dks Hkh dkyk fd;k
x;k gSA

7. Light of wavelength ph falls on a cathode plate inside a vacuum tube as shown in the figure., The work
function of the cathode surface is  and the anode is a wire mesh of conducting material kept at a
distance d from the cathode. A potential difference V is maintained between the electrodes. If the
minimum de Broglie wavelength of the electrons passing through the anode is e, which of the following
statement(s) is (are) true ?
ph rjaxnS/;Z dk izdk'k fuokZr uyhdk (vacuum tube ) ds vanj ,d dSFkksM ij fxjrk gS] tSlk fp=k esa n'kkZ;k
x;k gSA dSFkksM dh lrg dk dk;ZQyu  gS ,oa ,uksM] tks dh ,d pkydh; inkFkZ ds rkjksa dh tkyh gS] dSFkksM ls
d nwjh ij fLFkr gSA ,ysDVªksM+ksa ds chp dk foHkokUrj V fLFkj gSA ;fn ,uksM dks ikj djus okys bysDVªkWuksa dh
U;wure " n czksXyh" (de Broglie) rjaxnS/;Z e gS , fuEufyf[kr esa ls dkSulk@ dkSuls dFku lR; gS@gSa \
Light
Electrons
V
– +
(A) e increases at the same rate as ph for ph < hc/.
(B) For large potential difference (V >> /e), e is approximately halved if V is made four times.
(C) e is approximately halved , if d is doubled
(D) e decreases with increase in  and ph.
(A) vxj ph < hc/ gS rks ph ds lkFk e,d leku nj ls c<+sxkA
(B) mPp foHkokUrj (V >> /e) ij vxj V dks pkj xquk c<+k;k tk, rks e yxHkx vk/kk gks tk,xkA
(C) d dks nqxuk djus ij e yxHkx vk/kk gks tk,xkA
(D)  vkSj ph dks c<+kus ij e de gksxkA
Ans. (B)
Sol. e = Min. de broglie wave length U;wure fM&czksXyh rjaxnS/;Z
hc hc
=+ + eV
ph e
 –1   1 
hc  2 dpn  = hc  – 2 d e 
 pn    
   e 
2
dph ph
 2 (A wrong vlR; gS)
d e e

V >>
e
Energy of electron bysDVªkWu dh ÅtkZ = eV
P2 h 1
=E = 
2m p 2mE
P= 2mE Ans. (B)

8. Two thin circular discs of mass m and 4m, having radii of a and 2a, respectively , are rigidly fixed by a
massless, rigid rod of length l  24a through their centers. This assembly is laid on a firm and flat
surface, and set rolling without slipping on the surface so that the angular speed about the axis of the

rod is . The angular momentum of the entire assembly about the point 'O' is L (see the figure). Which
of the following statement (s) is (are) true ?
m rFkk 4m nzO;eku okyh nks iryh o`rkdkj pf=kdk,¡ (discs), ftudh f=kT;k;sa Øe'k% a rFkk 2a gSa] ds dsUnzksa dks
l  24a yEckbZ dh nzO;eku&jfgr nz<+ (rigid) MaMh ls tksM+k x;k gSA bl lewg dks ,d etcwr lery lrg ij
fyVk;k x;k gS vkSj fQlyk;s fcuk bl rjg ls ?kqek;k x;k gS fd bl dks.kh; xfr MaMh ds v{k ds fxnZ  gSA iwjs

lewg dk fcUnq 'O' ds fxnZ dks.kh; laosx L gS (fp=k nsf[k;s)a A fuEufyf[kr esa ls dkSulk@dkSuls dFku lR; gS@gSaA
4m
z m 
l
2a
l
O a

(A) The magnitude of the z-component of L is 55 ma2 .

(B) The magnitude of angular momentum of the assembly about its centre of mass is 17 ma2 .
2
(C)The magnitude of angular momentum of centre of mass of the assembly about the point O is 81ma2 

(D) The centre of mass of the assembly rotates about the z-axis with an angular speed of .
5
 2
(A) L ds z-?kVd dk ifjek.k 55 ma  gS

(B) iwjs lewg dk mlds lagfr&dsUnz ds fxnZ dks.kh; laosx dk ifjek.k 17 ma2 gS
2
(C) iwjs lewg dk lagfr&dsUnz dk fcUnq O ds fxnZ dks.kh; laosx dk ifjek.k 81ma2  gS

(D) iwjs lewg ds lagfr&dsUnz z-v{k ds fxnZ dks.kh; osx ls ?kwe jgk gS
5
Ans. (BD)
4m 
z
Sol.   24
m cos  = 
CM 2 2 5
 a
 P
 a 4/5

 O


(D) Velocity of point P : a =  then fcUnw P dk osx : a =  rks 
a
= = Angular velocity of C.M. w.r.t point O.

a
= = nzO;eku dsUnz dk fcUnq O ds lkis{k dks.kh; osx

Angular velocity of C.M. w.r.t z axis =  cos 
nzO;eku dsUnz dks z v{k ds lkis{k dks.kh; osx =  cos 
a 24 a 24
C.M. – z = 
 5 24a 5

CM – z =
5
ma 2 4m(2a)2 17ma 2 
(B) LD – CM =  
2 2 2
 9  9 81m  2  81m  2 a
(C) LCM – O = (5m)      
5  5 5 5 
81m a 81 24a 2m 
LCM – O = 
5 5
(A) LZ = LCM–0 cos – LD–CM sin
81 24 2 24 17ma2  1 81 24ma2  17ma2 
= a m    = 
5 5 2 24 25 2 24
9. In the circuit shown below, the key is pressed at time t = 0. Which of the following statement(s) is (are)
true?
uhps fn[kk;s x, ifjiFk esa le; t = 0 ij cVu (key) dks nck;k x;k gSA fuEufyf[kr esa ls dkSulk@dkSuls dFku
lR; gS@gSa\
40F 25k
–
V
+
50k 20F
A
+ –
key 5V
(A) The voltmeter displays –5 V as soon as the key is pressed, and displays +5 V after a long time
(B) The voltmeter will display 0 V at time t = n 2 seconds
(C) The current in the ammeter becomes 1/e of the initial value after 1 second
(D) The current in the ammeter becomes zero after a long time
(A) cVu dks nckrs gh oksYVehVj –5 V fn[kkrk gS tcfd yEcs le; ds ckn oks +5 V fn[kkrk gS
(B) le; t = n 2 seconds ij oksYVehVj 'kwU; oksYV fn[kkrk gS
(C) 1 second ds ckn vehVj esa /kkjk izkjfEHkd /kkjk dk 1/e xq.kk gksrh gS
(D) yacs le; ds ckn vehVj esa /kkjk 'kwU; gks tkrh gS

Ans. (ABCD)
Q1
25k
  –
V
 +
50k Q2
A
+ –
Sol. key 5V
 t t
–   – 
q1 = (200 × 10–3) 1– e 1  ; q2 = (100 × 10–3) 1– e 1 
   
q1 3 dq
= (50 × 10 ) 2
C dt
 200  10 1– e 
–3 –t
= (50 × 103)(100 × 10–3)[e–t]

40  10 –6
106
(1 – e–t) = 50 × 103(e–t)
20
1
= e–t
2
t = n2
I = I1+ I2 = (200 × 10–3)(e–t) + (100 × 10–3)e–t
= 100 × 10–3[2e–t + e–t]
= (300 × 10–3) e–t
 300  10 –3 
=  
 e
 
At t =  ij I=0
10. In an experiment to determine the acceleration due to gravity g, the formula used for the time period of
7(R – r)
a period of a periodic motion is T  2 . The values of R and r are measured to be (60  1)
5g
mm and 10  1 mm respectively. In five successive measurements, the time period is found to be
0.52 s, 0.56 s, 0.57 s, 0.54 s and 0.59 s. The least count of the watch used for the measurement of time
period is 0.01 s. Which of the following statement(s) is (are) true?
(A) The error in the measurement of r is 10%
(B) The error in the measurement of T is 3.57%
(C) The error in the measurement of T is 2%
(D) The error in the determined value of g is 11%

7(R – r)
xq:Roh; Roj.k g ds fu/kkZj.k ds ,d iz;ksx esa iz;qDr vkorhZ&xfr dk le;dky dk lw=k T  2 gSA R
5g
rFkk r dk ekik x;k eku Øe'k% (60  1) mm, rFkk (10  1) mm gSaA yxkrkj ik¡p ekiu esa ekik x;k le;dky
0.52 s, 0.56 s, 0.57 s, 0.54 s rFkk 0.59 s gSaA le;dky ds ekiu ds fy, iz;ksx esa yk;h x;h ?kM+h dk vYiRekad
0.01 s gSA fuEufyf[kr esa ls dkSulk@dkSuls dFku lR; gS@gSa\
(A) r ds ekiu esa =kqfV 10% gS
(B) T ds ekiu esa =kqfV 3.57% gS
(C) T ds ekiu esa =kqfV 2% gS
(D) g ds fudkys x;s eku esa =kqfV 11% gS
Ans. (ABD)
Sol.
S. No. T absolute error = |T – Tmean|

(1) 0.52 0.04
(2) 0.56 0.00
(3) 0.57 0.01
(4) 0.54 0.02
(5) 0.59 0.03
2.78 (T)mean = 0.02
Tmean =
5
Tmean = 0.56
0.02
% error in T (T esa izfr'kr =kqfV ) = ×100 = 3.57%
0.56
According to the question iz'u ds vuqlkj
T2
g
R–r
dg dT dR  dr
2 
g t R–r
dg 1 1
= 2(3.57%) + ×100%
g 60 – 10
dg
= 11% Ans. (A,B,D)
g
11. A rigid wire loop of square shape having side of length L and resistance R is moving along the x-axis
with a constant velocity v 0 in the plane of the paper. At t = 0, the right edge of the loop enters a region
of length 3L where there is a uniform magnetic field B0 into the plane of the paper; as shown in the
figure. For sufficiently large v0, the loop eventually crosses the region. Let x be the location of the right
edge of the loop. Let v(x), (x) and F(x) represent the velocity of the loop, current in the loop, and force
on the loop, respectively, as a function of x. Counter-clockwise current is taken as positive.

,d oxhZ; vkd`fr okyk rkj dk nz<+ Qank] ftlds Hkqtk dh yackbZ L ,oa izfrjks/k R gS] x-v{k dh fn'kk esa ,d fLFkj
xfr v 0 ls bl dkxt ds Iysu ij (plane of the paper) xfreku gSA le; t = 0 ij Qans dk nkfguk fdukjk 3L
yackbZ ds fLFkj pqacdh; {ks=k B0 esa izos'k djrk gSA pqacdh; js[kkvksa dh fn'kk dkxt ds Iysu ds yacor~ vanj dh vksj
gS ¼tSlk fp=k esa n'kkZ;k x;k gS½A v0 dk eku i;kZIr gksus ij varrksxRok Qank pqacdh; {ks=k dks ikj djrk gSA eku
fyft, dh Qans dh nkfguh Hkqtk LFkku x ij gSA Qans dh xfr] Qans esa /kkjk ,oa Qans ij cy dh x ij fuHkZjrk dks
Øe'k% v(x), (x) ,oa F(x) ls fu:fir fd;k x;k gSA okeorZ /kkjk dks iksftfVo ysaA
xxxxxxxxxxxxxxxxxxxxx
R xxxxxxxxxxxxxxxxxxxxx
L xxxxxxxxxxxxxxxxxxxxx
v0 xxxxxxxxxxxxxxxxxxxxx
x
0 L 2L 3L 4L
Which of the following schematic plot(s) is(are correct? (Ignore gravity)
fuEufyf[kr esa ls dkSulk@dkSuls O;oLFkk fp=k lgh gS@ gSa \ ¼xq:Rokd"kZ.k ux.; ekus½
F(x)
(x)
x
0 L 2L 3L 4L
x
0 L 2L 3L 4L
(A) (B)
(x)
v(x)
3L 4L
x
0 L 2L
x
(C) (D) 0 L 2L 3L 4L
Ans. (CD)
Sol. while entering izos'k djrs le; i.e. x<L
i
i = vB vB i
r
f

B 2 2 v
F = iB =
R
f B 2 2 v vdv
a2 = = Kv = 
m mR dx
v x
 dv  K  dx  v = v0 – kx
v0 0
2 2
B 
f= ( V0  kx )    x
R
B
i = (v 0  kx) = i0 – x
R
for 3 L > x > L ds fy;s f = 0 i=0 v = constant. fu;r
4L > × > 3 L
vB R
i = vB f
r
B 2 2 v
f = iB =
R
B2  2 vdv
a= v = kv = 
mR dx
v = v '0  kx
f =  '  '.x
i = i0'   ' x
f
I
L 3L 4L
o
L 3L 4L
L 3L 4L

12. A block with mass M is connected by a massless spring with stiffness constant k to a rigid wall
and moves without friction on a horizontal surface. The block oscillates with small amplitude A
about an equilibrium position x 0. Consider two cases : (i) when the block is at x 0 ; and (ii) when
the block is at x = x 0 + A. In both the cases, a particle with mass m (< M) is softly placed on the
block after which they stick to each other. Which of the following statement(s) is(are) true about
the motion after the mass m is placed on the mass M ?
M
(A) The amplitude of oscillation in the first case changes by a factor of , whereas in the second
mM
case it remains unchanged
(B) The final time period of oscillation in both the cases is same
(C) The total energy decreases in both the cases
(D) The instantaneous speed at x0 of the combined masses decreases in both the cases
,d nzO;eku&jfgr fLiazx] ftldk nz<+rk xq.kkad (stiffness constant) k gS] ds ,d Nksj ij M nzO;eku dk ,d
xqVdk tqM+k gS] rFkk nwljs Nksj dks nz<+ nhokj ls tksM+k x;k gSA ;g xqVdk ,d lery ?k"kZ.k&jfgr lrg ij ,d
larqfyr fLFkfr x0 ds fxnZ NksVs vk;ke A ls nksyu djrk gSA ;gk¡ nks ifjfLFkfr;ka ekfu, % (i) tc xqVdk x0 ij gS
vkSj (ii) tc xqVdk x = x0 + A ij gSA nksuksa ifjfLFkfr;ksa esa nzO;eku m (< M) ds ,d d.k dks xqVds ij /khjs ls bl
izdkj j[kk tkrk gS dh og rqjar xqVds ls fpid tkrk gSA d.k dks xqVds ds Åij j[kus ds ckn xfr ds ckjs esa
fuEufyf[kr esa ls dkSulk@dkSuls dFku lR; gS@gSa \
M
(A) igyh ifjfLFkfr esa nksyu dk vk;ke HkkT; (factor) ls ifjofrZr gksrk gS] tcfd nwljh ifjfLFkfr esa
mM
;g vifjofrZr jgrk gSA
(B) nksuksa ifjfLFkfr;ksa esa nksyu dk vafre le;dky leku gSA
(C) nksuksa ifjfLFkfr;ksa esa lEiw.kZ ÅtkZ de gks tkrh gSA
(D) lfEefyr nzO;ekuksa dh x0 ij rkR{kf.kd xfr nksuksa ifjfLFkfr;ksa esa de gks tkrh gSA
Ans. (ABD)
Sol. Case-1
Just before m is placed Just after m is placed
m
V1 V2
M M
X0 X0
Case-2
Just before m is placed
Just after m is placed

M m
M
X0+A
Case-I

m dksj [ kusdsBhd i gy s m dksj [ kusdsBhd ckn
m
V1 V2
M M
X0 X0
Case-II
m dksj [ kusdsBhd i gy s
m dksj [ kusdsBhd ckn
M m
M
X0+A
In case-1 esa
MV1 = (M + m)V2
 M 
V2 =   V1
Mm 
k  M  k
A2 =   A1
Mm Mm  M
M
A2 = A1
Mm
In case-2 esa
A2 = A1
Mm
T = 2 in both case. nksuksa fLFkfr;ksa esa
K
Total energy decreases in first case where as remain same in 2nd case.
Instantaneous speed at x0 decreases in both case.
izFke fLFkfr esa dqy ÅtkZ ?kVrh gS tcfd f}rh; fLFkfr esa fu;r jgrh gSA
x0 ij rkR{kf.kd pky nksuksa fLFkfr;ksa esa ?kVrh gSA
13. While conducting the Young's double slit experiment, a student replaced to two slits with a large
opaque plate in the x-y plane containing two small holes that act as two coherent point sources (S1, S2)
emitting light of wavelength 600 nm. The student mistakenly placed the screen parallel to the x-z plane
(for z > 0) at a distance D = 3 m from the mid-point of S1S2, as shown schematically in the figure. The
distance between the sources d = 0.6003 mm. The origin O is at the intersection of the screen and the
line joining S1S2. Which of the following is(are) true of the intensity pattern on the screen ?

,d fon~;kFkhZ us ;ax nks fLyV okys iz;ksx (Young's double slit experiment) djrs le; nks fLyVksa dh txg ,d
cM+h lery vikjn'khZ iêh dks x-y ry ij j[k fn;kA bl iêh esa nks NksVs fNnz gSa tks 600 nm rjaxnS/;Z izdk'k
mRiUu djus okys nks dyklac) fcUnq L=kksrksa (S1, S2) ds leku gSaA fon~;kFkhZ us xyrh ls insZ (screen) dks x-z ry
(z > 0) ds lekukUrj S1S2 ds e/; fcUnq ls D = 3 m dh nwjh ij j[k fn;k] tSlk dh O;oLFkk&fp=k esa fn[kk;k x;k
gSA L=kksrksa ds chp fd nwjh d = 0.6003 mm gSA S1S2 dks tksM+us okyh js[kk tgk¡ insZ ls feyrh gS ogk¡ ij ewyfcUnq
O gSA insZ ij rhozrk izfr:i (intensity pattern) ds fy, fuEufyf[kr esa ls dkSulk@dkSuls lR; gS@gSa \
Screen
z
O
y
S1 S2
d x
D
(A) Semi circular bright and dark bands centered at point O
(B) Hyperbolic bright and dark bands with foci symmetrically placed about O in the x-direction
(C) The region very close to the point O will be dark
(D) Straight bright and dark bands parallel to the x-axis
(A) fcUnq O ij dsfUnzr v/kZo`rh; nhIr rFkk vnhIr ifê;k¡
(B) x-fn'kk esa fcUnq O ds fxnZ lefer Qksdlksa ds lkFk vfrijoyf;d (Hyperbolic) nhIr rFkk vnhIr ifê;k¡
(C) fcUnq O dk fudVre {ks=k vnhIr gksxk
(D) x-v{k ds lekukUrj nhIr rFkk vnhIr lh/kh ifê;k¡
Ans. (AC)
Sol. from theory fringes will be semi circular
d 1
and  1000 
 2

at 0 x = 1000 
2
so at 0 it will be dark
F;ksjh ds vk/kkj ij fÝUtsa v)Zo`Ùkkdkj gksaxh
d 1
rFkk  1000 
 2

0 ij x = 1000 
2
vr% 0 ij ;g dkyh gksxh

14. Consider two identical galvanometers and two identical resistors with resistance R. If the internal
resistance of the galvanometers RC < R/2, which of the following statement(s) about any one of the
galvanometers is(are) true ?
(A) The maximum voltage range is obtained when all the components are connected in series
(B) The maximum voltage range is obtained when the two resistors and one galvanometer are
connected in series, and the second galvanometer is connected in parallel to the first galvanometer
(C) The maximum current range is obtained when all the components are connected in parallel
(D) The maximum current range is obtained when the two galvanometers are connected in series, and
the combination is connected in parallel with both the resistors.
nks ,dleku xsYosuksehVj rFkk ,dleku izfrjks/k R okys nks izfrjks/kd fn;s x;s gSaA ;fn xsYosuksehVj dk vkarfjd
izfrjks/k RC < R/2 gS] rks fdlh Hkh ,d xsYosuksehVj ds ckjs esa fn;s x, fuEufyf[kr dFkuksa esa ls dkSulk@dkSuls lR;
gS@gSa \
(A) izkIr fd xbZ oksYVrk ifjlj (voltage range) vf/kdre gksxh tc lHkh ?kVd Js.kh esa tqM+s gq, gSa
(B) izkIr fd xbZ oksYVrk ifjlj vf/kdre gksxh tc nks izfrjks/kd rFkk ,d xsYosuksehVj Js.kh esa tqM+s gSa rFkk nwljk
xsYosuksehVj igys xsYosuksehVj ds lekukUrj esa tqM+k gSA

(C) izkIr fd xbZ /kkjk ifjlj (current range) vf/kdre gksxh tc lHkh ?kVd lekukUrj esa tqM+s gSa
(D) izkIr fd xbZ /kkjk ifjlj vf/kdre gksxh tc nks xsYosuksehVj Js.kh esa tqM+s gSa rFkk ;s la;kstu izfrjks/kdksa ds lkFk
lekukUrj esa tqM+k gSA

Ans. (BC)
Sol. Suppose current for full deflection (i.e., For maximum range) through galvanometer is g.
(A)
g
G G
R R
Total potential difference V1 = 2Ig(R + RC)
(B)
g
G
2g
g R R
G
R 
Total potential difference V2 = 2g  C  2R  = g (RC + 4R)
 2 
Now since 2RC < R
So V1 < 3gR
while V2 > 4Rg
So V2 > V1

(C)
g
G
1
g
G
gRC = R
RC
 = g
R
 R 
1 = 2 g 1  C 
 R 
(D)
2 g
G G

R

2gRC = R
RC
 = 2 g
R
 4R C 
2 = g  1  
 R 
We can be see 1 > 2

 This section contains TWO paragraphs.
 Based on each paragraph, there are TWO Questions.
Zero Marks : 0 In all other cases.

 bl [kaM esa nks vuqPNsn gSaA
 izR;sd vuqPNsn ij nks iz'u fn;s x;s gSaA

 izR;sd iz'u esa pkj fodYi (A), (B), (C) rFkk (D) gSaA ftuesa dsoy ,d gh lgh gSA
 izR;sd iz'u ds fy, vks-vkj-,l- ij lgh mÙkj fodYi ds vuq:i cqycqys dks dkyk djsaA
 iw.kZ vad : +3 ;fn flQZ lgh fodYi ds vuq:i cqycqys dks dkyk fd;k gSA
'kwU; vad : 0 vU; lHkh ifjfLFkr;ksa esaA
Paragraph for Question Nos. 15 to 16

iz'u 15 vkSj 16 ds fy, vuqPNsn
A frame of reference that is accelerated with respect to an inertial frame of reference is called a non-
inertial frame of reference. A coordinate system fixed on a circular disc rotating about a fixed axis with a
constant angular velocity  is an example of a non-inertial frame of reference. The relationship between
 
the force Frot experienced by a particle of mass m moving on the rotating disc and the force Fin
experienced by the particle in an inertial frame of reference is,
      
 
Frot  Fin  2m  rot    m   r   ,
 
Where rot is the velocity of the particle in the rotating frame of reference and r is the position vector of
the particle with respect to the centre of the disc.
Now consider a smooth slot along a diameter of a disc of radius R rotating counter-clockwise with a
constant angular speed  about its vertical axis through its center. We assign a coordinate system with
the origin at the center of the disc, the x-axis along the slot, the y-axis perpendicular to the slot and the

 
z-axis along the rotation axis   k̂ . A small block of mass m is gently placed in the slot at

r   R / 2  î at t = 0 and is constrained to move only along the slot.
,d funsZ'k ra=k tks ,d tM+Roh; funsZ'k ra=k dh rqyuk esa Rofjr gks] vtM+Roh; funsZ'k ra=k dgykrk gSA fLFkj dks.kh;
osx ls ?kwerh gqbZ fMLd ij c) (fixed) funsZ'k ra=k vtM+Roh; ra=k dk ,d mnkgj.k gSA m nzO;eku dk ,d d.k

?kwerh gqbZ fMLd ij xfreku gSA xfreku d.k fMLd ij c) funsZ'k ra=k ds lkis{k cy Frot rFkk ,d tM+Roh; funsZ'k
  
ra=k ds lkis{k cy Fin dks eglwl djrk gSA Frot vkSj Fin ds chp dk laca/k fuEufyf[kr lehdj.k esa fn;k x;k gS
      
 
Frot  Fin  2m  rot    m   r   ,
 
;gk¡ ij rot ?kwers gq, funsZ'k ra=k esa d.k dk osx gS rFkk r d.k dk fMLd ds e/; fcUnq ds lkis{k fLfFkfr lfn'k
(position vector) gSA
Ekfu, fd R f=kT;k dh ,d fMLd] ftlesa O;kl ds lekukUrj ,d ?k"kZ.kjfgr [kk¡pk gS] ,d fLFkj dks.kh; xfr ls
vius v{k ij okekorZ fn'kk esa ?kwe jgh gSA ,d funsZ'k ra=k ekfu, ftldk ewyfcUnw fMLd ds e/; fcUnq ij gS ,oa
x-v{k [kk¡ps ds lekukUrj gS] y-v{k [kk¡ps ds vfHkyEc ij gS ,oa z-v{k ?kweus okyh v{k ds lekukUrj gS    k̂  A

m nzO;eku okys ,d NksVs xqVds dks le; t = 0 ij r   R / 2  î fcUnq ij /khjs ls bl rjg ls j[kk tkrk gS fd oks
flQZ [kk¡ps esa gh py ldsA


m
R/2
15. The distance r of the block at time t is :

Lke; t ij xqVds dh nwjh r dk eku gS %
R R 2t R R t
(A)
2
cos 2t (B)
4
e  e2t  (C)
2
cos t (D)
4
e  et 
Ans. (D)
2
Sol. mr = ma
a = r2
v r
vdv
 r 2 ;  vdv  2  rdr
dr
0 R/2
R2
v =  r2 
4
r t
dr

R/2 2 R2

  dt
0
.....(1)
r 
4
R
Assume ekuk : r = sec 
2
R
sec  tan d t  2r
R 2 4r 2  R 2 
dr = sec  tan  d ;  
 dt ; t = n  
2 R2 R R 
2
tan  0  
4
R t
r
4
e  e t 
16. The net reaction of the disc on the block is :
xqVds ij fMLd dh usV izfrfØ;k (net reaction) gS %
(A) m 2R sin t ˆj – mgkˆ (B) m 2R cos t ˆj – mgkˆ
1 1
(C)
2
 
m2R et  et ˆj  mgkˆ (D)
2
 
m2R e2t  e2t ˆj  mgkˆ

Ans. (C)
Sol.
(k̂ )
y( ĵ )
r vr
î
 
Frot  Fin  2m(v rot î )  k̂  m(k̂  r î )  k̂

mr2 î  Fin  2mvrot ( ĵ)  m2r î

Fin  2mv r  ĵ ......(1)
R t
r
4

e  e  t 
dr R  R t  mR2 t
dt
 vr 
4
 
e t  e  t ; Fin  2m
4

e  e  t  ĵ ; Fin 
2
 
e  e  t ĵ 
Also reaction is due to disc surface then
bl izdkj pdrh dh lrg }kjk Hkh izfrfØ;k vkjksfir gks rks
 mR2 t
Freaction 
2

e  e t ĵ  mgk̂ 
Paragraph for Question Nos. 17 to 18
iz'u 17 vkSj 18 ds fy, vuqPNsn
Consider an evacuated cylindrical chamber of height h having rigid conducting plates at the ends and
an insulating curved surface as shown in the figure. A number of spherical balls made of a light weight
and soft material and coated with a conducting material are placed on the bottom plate. The balls have
a radius r << h. Now a high voltage source (HV) is connected across the conducting plates such that
the bottom plate is at +V0 and the top plate at –V0. Due to their conducting surface the balls will get
charged, will become equipotential with the plate and are repelled by it. The balls will eventually collide
with the top plate, where the coefficient of restitution can be taken to be zero due to the soft nature of
the material of the balls. The electric field in the chamber can be considered to be that of a parallel plate
capacitor. Assume that there are no collisions between the balls and the interaction between them is
negligible. (Ignore gravity)
h ÅapkbZ okys fuokZfrr (evacuated) ,d csyukdkj d{k ds nksuksa Nksjksa ij nks nz< (rigid) pkyd iV~Vhdka, gSa vkSj
mldk oØiz"V vpkyd gS] tSlk dh fp=k esa n'kkZ;k x;k gSA de Hkkj okyh eqyk;e inkFkZ ls cuh gq;h dbZ xksykdkj
xksfy;k¡] ftudh lrg ij ,d pkyd inkFkZ dh ijr p<+h gS] uhps okyh ifV~Vdk ij j[kh gqbZ gSaA bu xksfy;ksa dh

f=kT;k r << h gSA vc ,d mPp oksYVrk dk lzksr (HV) bl rjg ls tksMk tkrk gS fd uhps okyh ifV~Vdk ij +V0 ,oa
Åij okyh ifV~Vdk ij –V0 dk foHko vk tkrk gSA pkyd ijr ds dkj.k xksfy;k¡ vkosf'kr gksdj ifV~Vdk ds lkFk
lefoHko gks tkrh gSa ftlds dkj.k os ifV~Vdk ls izfrdf"kZr gksrh gSaA varrksxRok xksfy;k¡ Åijh ifV~Vdk ls Vdjkrh
gSa] tgk¡ ij xksfy;ksa ds inkFkZ dh eqyk;e izd`fr ds dkj.k izR;oLFkku xq.kkad (coefficient of restitution) dks 'kwU;
fy;k tk ldrk gSA d{k esa fon~;qr {ks=k dks lekukUrj ifV~Vdk okys la/kkfj=k ds leku ekuk tk ldrk gSA xksfy;ksa
dh ,d nwljs ls ikjLifjd fØ;k ,oa Vdjko dks ux.; ekuk tk ldrk gSA (xq:Rokd"kZ.k ux.; gSA)
A
–
HV
+
17. Which one of the following statements is correct?

(A) The balls will execute simple harmonic motion between the two plates
(B) The balls will bounce back to the bottom plate carrying the opposite charge they went up with
(C) The balls will bounce back to the bottom plate carrying the same charge they went up with
(D) The balls will stick to the top plate and remain there
fuEufyf[kr esa ls dkSulk dFku lR; gS\
(A) xksfy;k¡ nksuksa ifV~Vdkvksa ds chp ljy vkorZ xfr fu"ikn djsaxh
(B) xksfy;k¡ ftl vkos'k ds lkFk Åij tkrh gSa mlds foijhr vkos'k ds lkFk mNydj fupyh ifV~Vdk ij okil vk
tkrh gSA
(C) xksfy;k¡ ftl vkos'k ds lkFk Åij tkrh gSa mlh vkos'k ds lkFk mNydj fupyh ifV~Vdk ij okil vk tkrh gSa
(D) xksfy;k¡ Åijh ifV~Vdk ij fpiddj ogha jg tkrh gSa
Ans. (B)
18. The average current in the steady state registered by the ammeter in the circuit will be
(A) proportional to V02 (B) proportional to V01/2
(C) proportional to the potential V0 (D) zero
ifjiFk esa yxk, vehVj esa LFkk;h voLFkk esa vkSlr /kkjk
(A) V02 ds lekuqikrh gksxh (B) V01/2 ds lekuqikrh gksxh
(C) V0 ds lekuqikrh gksxh (D) dk eku 'kwU; gksxk

Ans. (A)
Sol. (17–18)

just before collision 2q just after collision
¼VDdj ds Bhd igys½ ¼VDdj ds Bhd ckn½
2q
–V0
–q
2 V0
E
h
+q
+V0
2q
Kq Vor
= Vo = q =
r K
1  qE  2
 t = h
2 m
1 V0r 2 V0 2
t =h
2 K hm
h2 mk
t2 =
V02 r
h mk
t=
V0 r
During every collision 2q charge will flow from circuit.
izR;sd VDdj ds nkSjku 2q vkos'k ifjiFk ls izokfgr gksrk gSA
2q 2V02 r r
Average current vkSlr /kkjk Iavg = =
t h mk k
Iavg V02
17. The balls will bounce back to the bottom plate carrying the opposite charge they went up with.
xksfy;k¡ ftl vkos'k ds lkFk Åij tkrh gSa mlds foijhr vkos'k ds lkFk mNydj fupyh ifV~Vdk ij okil vk
tkrh gSA
18. Iavg V02

| JEE ADVANCED-2016 | DATE : 22-05-2016 | PAPER-2 | CODE-7 | CHEMISTRY
PART : II CHEMISTRY

 This section contains SIX questions.
2+ 2+ 2+
19. The geometries of the ammonia complexes of Ni , Pt and Zn , respectively, are
(A) octahedral, square planar and tetrahedral
(B) square planar, octahedral and tetrahedral
(C) tetrahedral, square planar and octahedral
(D) octahedral, tetrahedral and square planar
Ni2+, Pt2+ rFkk Zn2+ ds veksfu;k ladqyksa dh T;kfefr;k¡ Øe'k% gSa
(A) v"VQydh;, oxZ leryh rFkk prq"Qydh;
(B) oxZ leryh] v"VQydh;, rFkk prq"Qydh;
(C) prq"Qydh;] oxZ leryh rFkk v"VQydh;
(D) v"VQydh;] prq"Qydh; rFkk oxZ leryh
Ans. (A)
Sol. Ni2+ with NH3 shows CN=6 forming [Ni(NH3)6]2+ (Octahedral)
Pt2+ with NH3 shows CN = 4 forming [Pt(NH3)4]2+ (5d series CMA, square planner)
Zn2+ with NH3 shows CN = 4 forming [Zn(NH3)4]2+ (3d10 configuration, tetrahedral)
NH3 ds lkFk Ni2+, CN=6 n'kkZrk gS rFkk [Ni(NH3)6]2+ cukrk gSSA (v"VQydh;)
NH3 ds lkFk Pt2+, CN = 4 n'kkZrk gS rFkk [Pt(NH3)4]2+ cukrk gSSA (5d Js.kh CMA, oxZ leryh)
NH3 ds lkFk Zn2+, CN = 4 n'kkZrk gS rFkk [Zn(NH3)4]2+ cukrk gSSA (3d10 foU;kl prq"Qydh;)

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PAGE # 25
20. The major product of the following reaction sequence is

O
i) HCHO (excess)/NaOH, heat
+
ii) HCHO/H (catalytic amount)
fuEufyf[kr vfHkfØ;k vfHkØe dk eq[; mRikn gS
O
i) HCHO (vf/kd ek=kk esa)/NaOH, Å"ek
+
ii) HCHO/H (mRizsjd ek=kk)(catalytic amount)
O O O O OH
(A) (B)
O O O OH
HO
(C) (D)
OH
Ans. (A)
O O OH OH

HCHO/OH OH HCHO/OH
Sol. Cross Cannizzaro + HCOOH
Cross aldol
Nucleophilic 
addition HCHO / H
O O
O O OH OH
HCHO/OH OH HCHO/OH
Sol. + HCOOH
ØkWl ,YMksy ØkWl dSfutkjks
ukfHkdLusgh ;ksx HCHO / H
O O

PAGE # 26
21. The correct order of acidity for the following compounds is

fuEufyf[kr ;kSfxdksa dh vEyrk dk lgh Øe gS
CO2H
CO2H CO2H CO2H

HO OH OH
OH
OH
I II III IV
(A) I > II > III > IV (B) III > I > II > IV
(C) III > IV > II > I (D) I > III > IV > II
Ans. (A)
Sol. Due to ortho effect, ortho substituted benzoic acid is more acidic than meta & para isomers.
vkWFkksZ izHkko ds dkj.k] vkWFkksZ izfrLFkkfi csUtksbd vEy dh vEyh;rk mlds esVk ,oa isjk leko;oh ls vf/kd gksrh gSA
or ;k
Due to strong hydrogen bond in conjugate base of ortho hydroxybenzoic acid, it is more acidic than
its meta & para isomers.
vkWFkksZ gkbMªkWDlh csUtksbd vEy ds l;qXeh {kkj esa izcy gkbMªkstu cU/k ds dkj.k vEyh;rk mlds esVk ,oa isjk
leko;oh ls vf/kd gksrh gSA
22. For the following electrochemical cell at 298 K,

Pt(s) | H2 (g, 1 bar) | H+ (aq, 1 M) || M4+(aq) | M2+(aq) | Pt(s)
M2+ aq 
 
Ecell= 0.092 V when  = 10x.
M 4   aq  
 
0 RT
Given : EM 4  / M 2  = 0.151 V; 2.303 = 0.059 V
F
The value of x is
(A) –2 (B) –1 (C) 1 (D) 2
298 K ij fuEufyf[kr oS|qr&jklk;fud lsy (electrochemical cell),
+ 4+ 2+
Pt(s) | H2 (g, 1 bar) | H (aq, 1 M) | M (aq) M (aq) | Pt(s)
M2+ aq 
 
ds fy, Ecell= 0.092 V tc = 10x.
M 4   aq  
 
RT
eku yhft, dh : EM0 4  / M 2  = 0.151 V; 2.303 = 0.059 V, rc
F
x dk eku D;k gksxk \
(A) –2 (B) –1 (C) 1 (D) 2

PAGE # 27
Ans. (D)
0.059 [M2 ][H ]2

Sol. Ecell = E°cell – log10
2 [M4  ] pH2
0.059
0.092 = 0.151 = log10 10x
2
x = 2
23. The qualitative sketches I, II and III given below show the variation of surface tension with molar
–
concentration of three different aqueous solution of KCl, CH3OH and CH3(CH2)11 OSO3 Na+ at room
temperature. The correct assignment of the sketches is
–
uhps fn;s xq.kkRed js[kkfp=k I, II rFkk III lkekU; rki ij KCl, CH3OH rFkk CH3(CH2)11 OSO3 Na+ ds rhu fHké
tyh; foy;uksa dh eksyj lkanzrk (concentration ) ds lkFk i`"B ruko (surface tension) ds ifjorZu dks n'kkZrs gSaA
js[kkfp=kksa dk lgh fufnZ"Vhdj.k D;k gS \
II III
Surface tension
Surface tension
Surface tension
I
Concentration Concentration Concentration

–
(A) I : KCl II : CH3OH III : CH3(CH2)11 OSO3 Na+
–
(B) I : CH3(CH2)11 OSO3 Na+ II : CH3OH III : KCl
– +
(C) I : KCl II : CH3(CH2)11 OSO3 Na III : CH3OH
–
(D) I : CH3OH II : KCl III : CH3(CH2)11 OSO3 Na+
Ans. (D)
Sol. Impurities affect surface tension appreciably. It is observed that impurities which tend to concentrate on
surface of liquids, compared to its bulk lower the surface tension.
Substance like detergents, soaps (CH3(CH2)11SO3–Na+) decreases the surface tension sharply.
Those like alcohol (eg. –CH3OH, C2H5OH) lower the surface tension slightly. This can also be related to
the fact that CH3OH has smaller dielectric constant. Dielectric constant is directly proportional to
surface tension. So, on adding CH3OH in water, overall dielectric constant decreases and surface
tension decreases.
Inorganic impurities present in bulk of a liquid such as KCl tend to increase the surface tenstion of
water.
gy : v'kqf);k¡ i`"V ruko ij miq;Dr izHkko Mkyrh gS ;g izsf{kr gksrk gS fd v'kqf);k¡ tks cYd dh vis{kk æoksa dh lrg ij
lkfUær gksrh gS rks i`"V ruko dks de dj nsrh gSA
inkFkZ tSls viektZd] lksi (CH3(CH2)11SO3–Na+) i`"V ruko dks rsth ls ?kVkrh gSA
,YdksgkWy (mnkgj.k –CH3OH, C2H5OH) i`"V ruko dks FkksM+k de djrh gSA bldks bl rjg Hkh dgk tk ldrk gS
CH3OH dk ijkoS|qr LFkjkad de gSA ijkoS|qr LFkjkad i`"V ruko ds lekuqikrh gksrk gSA blfy, ty esa CH3OH
feykus ij ijkoS|qr fLFkjkad ?kVrk gS rFkk i`"V ruko ?kVrk gSA
vdkcZfud v'kqf+);k¡ æo tSls KCl ds cYd esa mifLFkfr gksrh gS rks ty ds i`"V ruko dks c<+krh gSA

PAGE # 28
24. In the following reaction sequence in aqueous solution, the species X, Y and Z, respectively, are
+ +
S2O3
2– Ag Ag with time
X Y Y
Clear white black
solution precipitate precipitate
3– 5–
(A) [Ag(S2O3)2] , Ag2S2O3, Ag2S (B) [Ag(S2O3)3] , Ag2SO3,Ag2S
(C) [Ag(SO3)2]3–, Ag2S2O3, Ag (D) [Ag(SO3)3]3–, Ag2SO4,Ags
tyh; foy;u esa fuEufyf[kr vfHkfØ;k vfHkØe es] Lih'kht+ (sequence) X, Y rFkk Z, Øe'k% gSa
+ +
S2O3
2– Ag Ag l e; dsl kFk
X Y Y
l kQ l Qsn dky k
foy ; u vo{ks
i vo{ks
i
(A) [Ag(SO2O3)2]3–, Ag2S2O3, Ag2S (B) [Ag(S2O3)3]5–, Ag2SO3,Ag2S
3– 3–
(C) [Ag(SO3)2] , Ag2S2O3, Ag (D) [Ag(SO3)3] , Ag2SO4,Ags
Ans. (A)
Ag+ (with time)
Sol. Ag+ + S2 O32 
 [Ag(S2O3)2]3–  Ag2S2O3 (  )  Ag2S (  )
(X) White ppt. (Y) Black (Z)
Ag+ (l e; d sl kFk)
Ag+ + S2 O32 
 [Ag(S2O3)2]3–  Ag2S2O3 (  ) 
 Ag2S (  )
(X) 'osr vo{ksi (Y) dkyk (Z)
 This section contains EIGHT questions.

 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four
option(s) is(are) correct.
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS.
 For each question, marks will be awarded in one of the following categories :
Full Marks : +4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened.
Partial Marks : +1 For darkening a bubble corresponding to each correct option, provided NO
incorrect option is darkened.
 For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will
result in +4 marks ; darkening only (A) and (D) will result in +2 marks and darkening (A) and (B) will
result in –2 marks, as a wrong option is also darkened.
25. Extraction of copper from copper pyrite (CuFeS2) involves

(A) crushing followed by concentration of the ore by froth-flotation
(B) removal of iron as slag
(C) self-reduction step to produce 'blistercopper' following evolution of SO2
(D) refining of 'blister copper' by carbon reduction

PAGE # 29
dkWij ikbjkbV (CuFeS2) ls dkWij ¼rk¡ck½ ds fu"d"kZ.k esa D;k lafyIr gS ¼gSa½ \
(A) nyu rFkk Qsu&Iyou froth-flotation }kjk v;Ld dk lkanz.k
(B) yksgs dk /kkrqey ds :i esa fu"dklu
(C) SO2 fudkl ds i'pkr QQksysnkj rk¡csa (blistercopper) ds mRikn ds fy; Lo%&vip;u dk ix
(D) dkcZu vip;u }kjk 'QQksysnkj rk¡csa ' dk 'kks/ku
Ans. (ABCD)
Sol. Extraction of Copper :
CuFeS2 Crushing of Ore Conc. By

(Ore) Concentrated Ore
froth flotation
Roasting with O2
SO2 + Cu + FeSiO3 O2 blast

Blister Slag Cu2S + FeS
copper + SiO2 Copper matte
Refining by poling
Add coal & stirred with green pole.
Further refining
Pitch copper Pure copper
By Electrolysis
dkWij dk fu"d"kZ.k %
CuFeS2 v; Ld dk nyu Qsu&Iyou
(Ore) l kfUær v; Ld
} kj k l kUæ.k
O2 dsl kFk
SO2 + Cu + FeSiO3 O2 blast

QQksy snkj èkkr q
ey Cu2S + FeS
r k¡ck
+ SiO2 dkW
i j esV
i kW
fyx } kj k ’ kksèku
dksy dksfeykr sgSr Fkk gj h NM+dsl kFk fgykr sgS
A
oS
|q
r vi ?kVu } kj k
fi a
p dkW
ij ’ kq
) dkW
ij
iq
u%’ kksèku

PAGE # 30
26. According to Molecular orbital Theory,

(A) C22– is expected to be diamagnetic
2+
(B) O2 is expected to have a longer bond length than O2
+ –
(C) N2 and N2 have the same bond order
+
(D) He2 has the same energy as two isolated He atoms
v.kq d{kd fl}kUr (Molecular orbital Theory) ds vuqlkj
(A) C22– izR;kf'kr :i ls izfrpqEcdh; (diamagnetic) gS
(B) O22+ dh vkca/k yEckbZ (bond length) izR;kf'kr :i ls O2 dh vkca/k yEckbZ ls yEch gS
(C) N2+ rFkk N2– dh vkca/k dksfV (bond length) leku gS
(D) He2+ dh ÅtkZ nks ,dy (isolated) He ijek.kqvksa dh ÅtkZ ds leku gS
Ans. (AC)
Sol. (A) C22  Total no. of electrons = 14 so it is diamagnetic
(B) O 22 Bond order = 3; O 2 Bond order = 2
 Bond length in O 22 is less than bond length in O2.
(C ) Bond order of N2 = 2.5
Bond order of He2 = 1/2
 Some energy is released during the formation of He2 from two isolated He atoms.
Sol. (A) C22  bysDVªkWuksa dh dqy la[;k = 14 blfy, ;g izfrpqEcdh; gSA
(B) O 22 ca/k Øe = 3; O 2 ca/k Øe = 2
 O 22 esa ca/k yEckbZ O2 dh rqyuk esa de gksrh gSA
(C ) N2 dk cU/k Øe = 2.5
He2 dk cU/k Øe = 1/2
 nks He ijek.kqvksa ls He2 ds fuekZ.k ds nkSjku dqN ÅtkZ eqDr gksrh gSA
27. Mixture(s) showing positive deviation from Raoult's law at 35ºCis(are)

(A) carbon tetrachloride + methanol (B) carbon disulphide + acetone
(C) benzene + toluene (D) phenol + aniline
feJ.k tks 35ºC ij jkmYV fu;e (Raoult's law) ls /kukRed fopyu iznf'kZr djrk gS ¼djrs gS½
(A) dkcZu VsVªkDyksjkbM + esFksukWy (B) dkcZu MkblYQkbM + ,lhVksu
(C) csUthu + VkWYohu (D) QhukWy + ,fuyhu
Ans. (AB)
Sol. (A) CCl4 + CH3OH  Positive deviation from Raoult’s law

O
(B) CS2 +  Positive deviation from Raoult’s law

C
CH3 CH3
(C) C6H6 + C7H8  Ideal solution

OH NH2
(D) +  Negative deviation from Raoult’s law.

PAGE # 31
Sol. (A) CCl4 + CH3OH  jkÅYV fu;e ls /kukRed fopyu
(B) CS2 +  jkÅYV fu;e ls /kukRed fopyu

C
CH3 CH3
(C) C6H6 + C7H8  vkn'kZ foy;u

OH NH2
(D) +  jkÅYV fu;e ls _.kkRed fopyu
28. For 'invert sugar', the correct statement(s) is(are)

(Given : specific rotations of (+)-sucrose, (+)-maltose, L-(–)-glucose and L-(+)-fructose in aqueous
solution are +66º, +140º, –52º and +92º, respectively)
(A) 'invert sugar' is prepared by acid catalyzed hydrolysis of maltose
(B) 'invert sugar' is an equimolar mixture of D-(+)-glucose and D-(–)-fructose
(C) specific rotation of 'invert sugar' is –20º
(D) on reaction with Br2 water, 'invert sugar' forms saccharic acid as one of the products
'vio`r 'kdZjk' ('invert sugar') ds fy;s lgh dFku gS@gSa
(fn;k gS% (+)-lwØkst (sucrose), (+)-ekWYVkst (maltose), L-(–)-Xywdkst (glucose) rFkk L-(+)-ÝqDVkst (fructose) dk
tyh; foy;u esa fof'k"V /kzqo.k ?kw.kZu (specific rotation) Øe'k% +66º, +140º, –52º rFkk +92º gS½
(A) 'vio`r 'kdZjk' ekWYVkst ds vEy&mRizsfjr (acid catalyzed) ty&vi?kVu (hydrolysis) ls cuk;k tkrk gSS
(B) 'vio`r 'kdZjk' D-(+)-Xywdkst rFkk D-(–)-ÝqDVkst dk lev.kqd (equimolar) feJ.k gS
(C) 'vio`r 'kdZjk' dk fof'k"V /kzqo.k ?kw.kZu–20º gS
(D) Br2 ty ls vfHkfØ;k djus ij 'vio`r 'kdZjk' mRiknksa esa ls ,d mRikn ds :i esa] lSdsfjd vEy (saccharic
acid) cukrh gS
Ans. (BC)
Hydrolysis
Sol. Sucrose    D(+)-glucose + D(–) fructose
[] = +52° [] = –92°
[]mix = 0.5 × (+52°) + 0.5 × (–92°)
= –20°
Hydrolysis
gy lwØksl    D(+)-Xywdksl + D(–) ÝDVksl
[] = +52° [] = –92°

[]mix = 0.5 × (+52°) + 0.5 × (–92°)
= –20°

PAGE # 32
29. The CORRECT statement(s) for cubic close packed (ccp) three dimensional structure is(are)
(A) The number of the neighbours of an atom present in the topmost layer is 12
(B) The efficiency of atom packing is 74%
(C) The number of octahedral and tetrahedral voids per atom are 1 and 2, respectively
(D) The unit cell edge length is 2 2 times the radius of the atom
?kuh; fufoM ladqfyr (cubic close packed) (ccp) f=kfoeh; lajpuk ds fy;s lgh dFku gS@gSa
(A) ,d ijek.kq tks lokZsPp ijr (topmost layer) esa mifLFkr gS mlds fudVre izfrosf'k;ksa ¼iM+ksfl;ksa½ dh la[;k 12 gSA
(B) ijek.kq dh ladqyu {kerk 74% gS
(C) v"VQydh; rFkk prq"Qydh; fjfä;ksa dh la[;k izfr ijek.kq Øe'k% 1 rFkk 2 gSa
(D) ,d dksf"Bdk ds dksj (unit cell edge) dh yEckbZ ijek.kq dh f=kT;k dk 2 2 xquk gSA
Ans. (BCD)
Sol. (A) For any atom in top most layer, coordination number is not 12 since there is no layer above top
most layer
(B) Fact
(C) Fact
(D) 2 a = 4R
So a=2 2 R
(A) fdlh Hkh ijek.kq ds fy, lcls Åijh ijr esa] lgla;kstd la[;k 12 ugha gks ldrh D;ksfd Åijh dksbZ ijr ugha
gksrh gS
(B) rF;
(C) rF;
(D) 2 a = 4R
blfy, a = 2 2 R
30. Among the following, reaction(s) which gives(give) tert-butyl benzene as the major product is(are)
fuEufyf[kr esa VVZ&C;wfVy csUthu (tert-butyl benzene) eq[; mRikn ds :i esa nsaus okyh vfHkfØ;k ¼;sa½ gS ¼gSa½
Br
Cl
(A) (B)
NaOC2H5 AlCl3
OH
(C) (D)
H2SO4 BF3OEt2
Ans. (B,C,D)

PAGE # 33
Cl
Sol.
H2SO4
OH
BF3OEt2
31. Reagent(s) which can be used to bring about the following transformation is(are)
O O O O
C O C
H OH
O O
COOH COOH
(A) LiAlH4 in (C2H5)2O (B) BH3 in THF
(C) NaBH4 in C2H5OH (D) Raney Ni/H2 in THF
fuEufyf[kr :ikUrj.k ds fy;s fdu vfHkdkjd ¼vfHkdkjdksa½ (Reagent(s)) dk mi;ksx fd;k tk ldrk gS ¼gSa½\
O O O O
C O C
H H
O O
COOH COOH
(A) (C2H5)2O esa LiAlH4 (B) THF esa BH3
(C) C2H5OH esa NaBH4 (D) THF esa jkus (Raney) Ni/H2
Ans. (C,D)
Sol. NaBH4/C2H5OH & Raney Ni/H2 in T.H.F do not reduce acid (–COOH), ester (–COOR) & epoxide
.
O
gy NaBH4/C2H5OH ,oa jSus Ni/H2 ,T.H.F vEy (–COOH), ,LVj (–COOR) & bikWDlkbM dks vipf;r ugh
O
djrs gSA

PAGE # 34
32. The nitrogen containing compound produced in the reaction of HNO3 with P4O10
(A) can also be prepared by reaction of P4 and HNO3
(B) is diamagnetic
(C) contains one N-N bond
(D) react with Na metal producing a brown gas
HNO3 dh P4O10 ds lkFk vfHkfØ;k esa mRikfnr ukbVªkstu vUrfoZ"V ;kSfxd
(A) P4 rFkk HNO3 dh vfHkfØ;k ls Hkh cuk;k tk ldrk gSA
(B) izfrpqEcdh; (diamagnetic) gS
(C) esa ,d N–N cU/k vUrfoZ"V gS
(D) Na /kkrq ls vfHkfØ;k dj ,d Hkwjh (brown) xSl mRikfnr djrk gSA
Ans. (B,D)
Sol. 4HNO3 + P4O10 2N2O5 + 4HPO3
So, nitrogen containing compound is N2O5
(A) P4 + 20HNO3 4H3PO4 + 20NO2 + 4H2O
N2O5 Can't be prepared by reaction of P4 & HNO3.
(B) N2O5 is diamagnetic.
(C) Structure of N2O5 is:
O O
N N
O O
O
(It does not contain N–N bond)
(D) N2O5 + Na NaNO3 + NO2 
gy. 4HNO3 + P4O10 2N2O5 + 4HPO3
blfy, ukbVªkstu ;qDr ;kSfxd N2O5 gS

(A) P4 + 20HNO3 4H3PO4 + 20NO2 + 4H2O
N2O5 dks P4 & HNO3 dh vfHkfØ;k }kjk ugh cuk;k tk ldrkA
(B) N2O5 izfrpqEcdh; gSA
(C) N2O5 dh lajpuk gS&
O O
N N
O O
O
blesa N–N cU/k vuqifLFkr gSA
(D) N2O5 + Na NaNO3 + NO2 

PAGE # 35

 This section contains TWO paragraphs.
 Based on each paragraph, there are TWO Questions.
Zero Marks : 0 In all other cases.
Paragraph 1
Thermal decomposition of gaseous X2 to gaseous X at 298 K takes place according to the following
equation :
X2(g) 2X(g)
The standard reaction Gibbs energy, rGº, of this reaction is positive. At the start of the reaction, there
is one mole of X2 and no X. As the reaction proceeds, the number of moles of X formed is given by .
Thus. equilibrium is the number of moles of X formed at equilibrium. The reaction is carried out at a
constant total pressure of 2 bar. Consider the gases to behave ideally.
(Given : R = 0.083 L bar K–1 mol–1)
vuqPNsn 1
298 K ij xSlh; (gaseous) X2 dk xSlh; X esa Å"ek&vi?kVu (thermal decomposition) fuEufyf[kr lehdj.k
X2(g) 2X(g)
ds vuqlkj gksrk gSA bl vfHkfØ;k dh ekud vfHkfØ;k fxCl ÅtkZ (standard reaction Gibbs energy), rGº,
/kukRed gSA vfHkfØ;k ds izkjEHk esa X2 dk 1 eksy gS rFkk X ugha gSA tSls&tSls ;g vfHkfØ;k c<+rh gS] fufeZr X ds
eksyksa dh la[;k }kjk nh tkrh gSA bl izdkj] lkE;okLFkk ij fufeZr X ds eksyksa dh la[;k equilibrium gSA vfHkfØ;k 2
bar ds fLFkj dqy nkc ij dh tkrh gSA eku ysa fd xSlsa vkn'kZ O;ogkj djrh gSA
(fn;k x;k gS : R = 0.083 L bar K–1 mol–1)
33. The equilibrium constant Kp for this reaction at 298 K, in terms of equilibrium , is
298 K ij bl vfHkfØ;k dk equilibrium ds in esa lkE;oLFkk fLFkjkad (equilibrium constant) Kp D;k gksxk\
82equilibrium 82equilibrium 42equilibrium 42equilibrium

(A) (B) 2
(C) (D)
2  equilibrium 4 equilibrium 2  equilibrium 4  2equilibrium
Ans. (B)

PAGE # 36
Sol. Paragraph-1
X2 (g) 2 X (g)
Initial mole 1 0
t = teq. (1–) 2
Given 2 = equilibrium
equilibrium
So  =
2
  eq 
Total mole at equilibrium = (1 + ) = (1+  
 2 
  eq. 
1 
=  2 P  =  2  eq P  =  2  eq P 
Px eq. total total total
2 1    2  eq   2  eq 
 2 

 
  eq   2eq 
PX(g) =  Ptotal  =   PTotal
 eq   2   eq 
 1  
2
2
 2eq. 
2   Ptotal 
Px   2   eq. 
So KP = = 
Px 2   2
eq.

  Ptotal 
 
 2  eq.  

2 2
 8 eq 
4 eq.
KP = × PTotal =  
2 2
 4 –  eq 
4 – eq.  
So Ans. is = B
gy vuqPNsn-1
X2 (g) 2 X (g)
izkjfEHkd eksy 1 0
t = teq. (1–) 2
fn;k gS : 2 = lkE;
 l kE;
vr%  =
2

PAGE # 37
 eq 
lkE; ij dqy eksy = (1 + ) = (1+  
 2 
  eq. 
1 
=  2 P  =  2  eq P  =  2  eq P 
Px eq. total total total
2 1    2  eq   2  eq 
 2 
 
  eq   2eq 
PX(g) =  Ptotal  =   PTotal
 eq   2   eq 

 1  2 
2
2
 2eq. 
Px  
2  
 Pdq
y
vr% KP = =  eq. 
Px 2   2 
eq.
  Pdqy 
 
 2  eq.  

2 2
 8 eq 
4 eq.
KP = × PTotal =   vr% Ans. is = B
2 2
 4 –  eq 
4 – eq.  
34. The INCORRECT statement among the following, for this reaction, is
(A) Decrease in the total pressure will result in formation of more moles of gaseous X
(B) At the start of the reaction, dissociation of gaseous X2 takes place spontaneously
(C) equilibrium = 0.7
(D) KC < 1
bl vfHkfØ;k ds fy;s fueu esa lsa vlR; dFku gS
(A) dqy nkc ds ?kVus ds ifj.kke Lo:i xSlh; X ds vf/kd eksy cusaxs
(B) vfHkfØ;k ds izkjEHk esa xSlh; X2 dk fo;kstu Lor% izofrZr (spontaneously) gksrk gS
(C) equilibrium = 0.7

(D) KC < 1
Ans. (C)
Sol. (A) Correct statement.
As on decrease in pressure reaction move indirection where no. of gaseous molecules increase.
(B) Correct statement
At the start of reaction QP < KP so dissociation of X2 take place spontaneousely.
2 2
8 eq 8x  0.7 
(C) Incorrect statement as KP = 2
= 2
4  eq 4   0.7 
> 1, but

PAGE # 38
(D) Correct statement.

0
As G > 0 & G0 = –RTlnKP
0
G > 1, So KP should be less than 1.
So K<1
KP - KC(RT)ng. (RT > 1)

KP
KC =
RT
KC < KP So KC < 1
Sol. (A) lgh dFku % tSls&tSls nkc de gksrk tkrk gS vfHkfØ;k xSlh; v.kqvksa dh la[;k esa o`f) dh rjQ c<rh gS
(B) lgh dFku % vfHkfØ;k dh 'kq:vkr esa QP < KP vr% X2 dk fo;kstu Lor% izofrZr gksrk gSA
2 2
8 eq 8x  0.7 
(C) xyr dFku D;ksafd KP = 2
= 2
> 1,
4  eq 4   0.7 
(D) lgh dFku %
0
bl rjg G > 0 & G0 = –RTlnKP
G0 > 1, vr% KP dk eku 1 ls de gksuk pkfg,A
vr% K<1
KP - KC(RT)ng. (RT > 1)

KP
KC =
RT
KC < KP So KC < 1

PAGE # 39
Paragraph 2
+
Treatment of compound O with KMnO4/H gave P, which on heating with ammonia gave Q. The
compound Q on treatment with Br2/NaOH produced R. On strong heating, Q gave S, which on further
treatment with ethyl 2-bromopropanoate in the presence of KOH followed by acidification, gave a
compound T.
vuqPNsn 2
;kSfxd O dh KMnO4/H+ ls fØ;k us P fn;k] ftlus veksfu;k ds lkFk xeZ djus Q fn;kA ;kSfxd Q us Br2/NaOH
ds lkFk fØ;k djus ij R mRikfnr fd;kA izcy :i ls xeZ djus ij Q us S fn;k ftlus ,fFky 2-czkseksizksisuksvksV
(ethyl 2-bromopropanoate) ds lkFk dh KOH mifLFkfr esa vkxs fØ;k dh ftlds i'pkr vEyhdj.k us ;kSfxd T
fn;kA
(O)
35. The compound R is
;kSfxd R gS
O O
O
NH2 Br NHBr
(A) (B) (C) (D) NBr
Br NHBr
NH2
O O O
Ans. (A)
36. The compound T is

(A) glycine (B) alanine (C) valine (D) serine
;kSfxd T gS
(A) Xykblhu (glycine) (B) ,ykuhu (alanine)
(C) oSyhu (valine) (D) lsjhu (serine)
Ans. (B)

PAGE # 40
O
COOH C–NH2 NH2
KMnO4/H NH3/ Br2/NaOH
Sol.
COOH C–NH2 NH2
(O) (P) (Q) (R)
O

O CH3 Br O O
CH3–CH–C–OC2H5
N–CH–C–OC2H5 NH
KOH
O
O (S) O
H3O
CH3–CH–COOH Alanine
NH2
(T)
O
COOH C–NH2 NH2
KMnO4/H NH3/ Br2/NaOH
Sol.
COOH C–NH2 NH2
(O) (P) (Q) (R)
O

O
CH3 Br O O
CH3–CH–C–OC2H5
N–CH–C–OC2H5 NH
KOH
O
O (S) O
H3 O 
CH3–CH–COOH , sy suhu
NH2
(T)

PAGE # 41
| JEE ADVANCED-2016 | DATE : 22-05-2016 | PAPER-2 | CODE-7 | MATHEMATICS
MATHEMATICS

2
x 2 cos x
37. The value of  1 e x dx is equal to (Definite integration) XII
–
2

2
x 2 cos x
 1 e x dx dk eku gS&
–
2
2 2 2 2
(A) –2 (B) 2 (C)  – e/2 (D)  + e/2
4 4
Ans. (A)
/ 2 /2
x 2 cos x  x 2 cos x x2 cos x 
Sol. =  dx  =   x
  dx
x
–  / 2 (1  e ) 0  1 e 1  e– x 
/2
 2  2
 =  x 2 cos xdx  (x 2 sin x – 2x(– cos x)  (2)(– sin x))0 / 2 =  – 2  – (0)  –2
0  4  4
38. Let bi > 1 for i = 1,2,….,101. Suppose logeb1,logeb2,…,logeb101 are in Arithmetic progression (A.P.) with
the common difference loge 2. Suppose a1, a2,…,a101 are in A.P. such that a1 = b1 and a51= b51. If
t = b1 + b2 + …. + b51 and s = a1 + a2 + … + a51, then (Sequence & Sereis) XI
(A) s > t and a101 > b101 (B) s > t and a101 < b101
(C) s < t and a101 > b101 (D) s < t and a101 < b101
ekukfd i = 1,2,….,101 ds fy, bi > 1 gSA eku yhft, fd logeb1,logeb2,…,logeb101 lkoZvarj (common
difference) loge 2 okyh lekarj Js.kh (A.P.) esa gSaA eku yhft;s fd a1, a2,…,a101 lekarj Js.kh esa bl izdkj gSa fd
a1 = b1 rFkk a51= b51 ;fn t = b1 + b2 + …. + b51 rFkk s = a1 + a2 + … + a51 gSa, rc
(A) s > t vkSj a101 > b101 (B) s > t vkSj a101 < b101
(C) s < t vkSj a101 > b101 (D) s < t vkSj a101 < b101
Ans. (B)
Sol. loge b1, logeb2, logeb3, ...... logeb101 are in A.P. lekUrj Js.kh esa gS
b1, b2, b3, ..........., b101 are in G.P. xq.kksÙkj Js.kh esa gS
b2
Given fn;k x;k gS : loge(b2) – loge(b1) = loge(2)  = 2 = r (common ratio of G.P. xq.kksÙkj Js.kh dk lkoZ
b1
vuqikr)

a1, a2, a3, ......... a101 are in A.P. lekUrj Js.kh esa gS
a1 = b1 = a
b1 + b2 + b3 + ........ b51 = t ,
S = a1 +a2 + ...... + a51
(r 51 – 1) a(251 – 1)
t = sum of 51 terms of G.P.(t = xq.kksÙkj Js.kh ds 51 inks dk ;ksx) = b1 = = a(251 –1)
r –1 2–1
51 51
s = sum of 51 terms of A.P. (s = lekUrj Js.kh ds 51 inks dk ;ksx.) = [2a1 + (n–1)d] = (2a + 50d)
2 2
Given fn;k x;k gS a51 = b51
a + 50d = a(2)50
50d = a(250 – 1)
51 50  51 
Hence vr% s = a [2 + 1]  s = a  51 .249  
2  2
 51   53 
s = 2  4.249  47.249    s = a  (251 – 1)  47.249  
 2  2 
 53 
s – t = a  47 . 249 + 
 2 
Clearly Li"Vr % s > t
a101 = a1 + 100d = a + 2a.250 – 2a = a (251 – 1)

b101 = b1 r 100 = a.2100 Hence vr% b101 > a101
 1 0 0
39.
 
Let P = 4 1 0 and  be the identity matrix of order 3. If Q = [qij] is a matrix such that P50 – Q= ,
 
16 4 1
q31  q32
then equals (Matrix & Det.) XII
q21
 1 0 0
ekuk fd P =  4 1 0 vkSj  rhu dksfV (order 3) dk rRled vkO;wg (identity matrix) gSA ;fn Q = [qij] ,d
16 4 1
q31  q32
vkO;wg bl izdkj gS fd P50 – Q = gS, rc dk eku gS&
q21
(A) 52 (B) 103 (C) 201 (D) 205
Ans. (B)

 1 0 0  1 0 0  1 0 0
Sol. P =  4 1 0   2 
P =  8 1 0  
3
,P =  12 1 0 
16 4 1 16(1  2) 8 1 16(1  2  3) 12 1
 1 0 0  1 0 0
 
0   1 0 
50 50 50
P =  4  50 1 P =  200 P –Q=
2
16(1  2  ...  50) 4  50 1  20400 200 1
 1 0 0   q11 q12 q13   1 0 0

 
  200 1 0  –  q21 q22 q23  = 0 1 0 
  200 – q21 = 0  q21 = 200
 20400 200 1  q31 q32 q33  0 0 1
20400 – q31 = 0  q31 = 20400 and vkSj 200 – q32 = 0  q32 = 200
q31  q32 20400  200
 = = 103
q21 200
13
1
40. The value of    (k  1) 
k  1 sin
  k 
is equal to (Trigonometry) XI
  sin  
4 6  4 6 
13
1
 
k  1 sin
 (k  1)   k 
dk eku gS&
  sin  
4 6  4 6 
(A) 3  3 
(B) 2 3  3  
(C) 2 3  1  
(D) 2 2  3 
Ans. (C)
   k     
13
sin    –   (k – 1)   13
 4 6   4 6       k  
= 2  cot   (k – 1)  – cot  
Sol. 
k 1     k        k 1   4 6 

 4 6 
sin  sin   sin
   (k – 1) 
6  4 6   4 6 
    13     29     5  
= 2  cot – cot     = 2  1– cot    = 2  1– cot    = 2 (1–(2– 3 )) =2 (–1 + 3 )
 4 4 6    12     12  
= 2 ( 3 –1)
41. Let P be the image of the point (3, 1, 7) with respect to the plane x – y + z = 3. Then the equation of the
x y z
plane passing through P and containing the straight line   is (Vector-3D) XII
1 2 1
ekuk fd fcUnq (3, 1, 7) dk] lery x – y + z = 3 ds lkis{k (with respect to), izfrfcEc (image) P gSA rc fcUnq P
x y z
ls xqtjus okys vkSj ljy js[kk   dks /kkj.k djus okys lery dk lehdj.k gS&
1 2 1
(A) x + y – 3z = 0 (B) 3x + z = 0 (C) x – 4y + 7z = 0 (D) 2x – y = 0
Ans. (C)

Q (3,1,7)
• x–y+z=3
Sol.
P (–1,5,3)
x–3 y –1 z–7 –2(6)

= = =  –4
1 –1 1 3
x =– 1, y = 5, z = 3 P (–1, 5, 3)
a(x + 1) + b(y – 5) + c (z – 3) = 0
a + 2b + c = 0 ...................(i)
a – 5b – 3c = 0
a b c
= =
–1 4 –7
–(x + 1) + 4 (y – 5) – 7 (z – 3) = 0
–x + 4y – 7z = 0
x – 4y + 7z = 0
42. 
Area of the region ( x, y )  R 2 : y  
x  3 , 5 y  x  9  15 is equal to (Definite Integration) XII
 
{ks=k (region) ( x, y )  R 2 : y  x  3 , 5 y  x  9  15 dk {ks=kQy (area) gS&
1 4 3 5
(A) (B) (C) (D)
6 3 2 3
Ans. (C)
y2 = x + 3
2
y = –x – 3
E(–4, 1)
D(1, 2)
(–4, 0)A B(–3, 0) C(1, 0)

5y = x + 9
x=6
3
2
Area ABE (under parabola) = 
4
 x  3 dx =
3

1
16
Area BCD (under parabola) =
3
 x  3 dx =
3
1 15
Area of trapezium ACDE = (1 + 2)5 = 
2 2
15 16 2 3
 Required area =   
2 3 3 2
y2 = x + 3
2
y = –x – 3
E(–4, 1)
D(1, 2)
Hindi
(–4, 0)A B(–3, 0) C(1, 0)

5y = x + 9
x=6
3
2
ABE dk {ks=kQy (ijoy; ds vUnj) = 
4
 x  3 dx =
3
1
16
BCD dk {ks=kQy (ijoy; ds vUnj) = 
3
x  3 dx =
3
1 15
leyEc prqHkZqt ACDE dk {ks=kQy = (1 + 2)5 =
2 2
15 16 2 3
vHkh"V {ks=kQy =   
2 3 3 2
 1   1  2
43. Let f :  , 2  R and g :  2 , 2  R be functions defined by f(x) = [x – 3] and
 2   
g(x) = |x| f(x) + |4x – 7| f(x), where [y] denotes the greatest integer less than or equal to y for y  R. Then
 1 
(A) f is discontinuous exactly at three points in  , 2 (LCD) XII
 2 
 1 
(B) f is discontinuous exactly at four point in  , 2
 2 
 1 
(C) g is NOT differentiable exactly at four points in   , 2 
 2 
 1 
(D) g is NOT differentiable exactly at five points in   , 2  .
 2 

1 1
ekuk fd Qyu f :  , 2  R vkSj g :  , 2  R, f(x) = [x2 – 3] vkSj g(x) = |x| f(x) + |4x – 7| f(x) ls
 2   2 
ifjHkkf"kr gSa] tgk¡ y  R ds fy, y ls de ;k y ds cjkcj ds egÙke iw.kkZad (greatest integer less than or equal to
y) dks [y] n~okjk n'kkZ;k x;k gSA rc
 1 
(A)  , 2 esa f Bhd rhu (exactly three) fcUnqvksa ij vlarr (discontinuous) gSA
 2 
 1 
(B)  , 2 esa f Bhd pkj (exactly four) fcUnqvksa ij vlarr gSA
 2 
 1 
(C)   , 2  esa g Bhd pkj (exactly four) fcUnqvksa ij vodyuh; (differentiable) ugha gSA
 2 
 1 
(D)   , 2  esa g Bhd ik¡p (exactly five) fcUnqvksa ij vodyuh; (differentiable) ugha gSA
 2 
Ans. (B,C)
 1
 –3 –
2
 x 1

 –2 1 x  2
Sol. f(x) = [x2 – 3] = [x2] – 3 = 
 –1 2x 3

0 3x2
 1 x2
g(x) = |x| f(x) + |4x–7| f(x)

 1
 (–x – 4x – 7)(–3) –
2
x0

(x – (4x – 7))(–3) 0  x 1

(x – (4x – 7))(–2) 1 x  2
= (|x| + |4x – 7|) [x2 – 3] = 
(x – (4x – 7))(–1) 2x 3

 ((x – (4x – 7))(0) 3  x  7/4

 (x  (4x – 7))(0) 7/4  x  2
 (x  (4x – 7))(1) x2

 1
15x  21 –
2
x0

 9x – 21 0  x 1

=  6x – 14 1 x  2
 3x – 7 2x 3

 0 3x2

 5x – 7 x2

Now graph of given function is vc fn;s x;s Qyu dk xzkQ
21
27/2
3
1 1 2 3 2
–1/2 1 2 3 2 3 3 7
–1/2 3 2 7
f(x) g(x) 6 2  14
–1
–8
–2
–12
–3
–21
Clearly F is not discontinuous at exactly 4 point in [–1/2, 2] and g is not differentiable at 4 points in
(–1/2, 2) Hence Ans. is BC
Li"Vr;% F [–1/2, 2] esa Bhd pkj fcUnqvksa ij vlrr~ rFkk g (–1/2, 2) esa Bhd pkj fcUnqvksa ij vodyuh; ugh gS

44. Let û  u1î  u2 ˆj  u3 kˆ be a unit vector in R3 and ŵ 
6

1 ˆ ˆ

i  j  2kˆ . Given that there exists a vector 
 
in R3 such that û    1 and w. ˆ uˆ   1. Which of the following statements(s) is (are) correct?

(A) There is exactly one choice for  (Vector-3D) XII

(B) There are infinitely many choices for such 
(C) If û lies in the xy-plane then u1  u2
(D) If û lies in the xz-plane then 2 u1  u3
Ekkuk fd R3 esa û  u1î  u2 ˆj  u3 kˆ ,d ek=kd lfn’'k (unit vector) gS vkSj ŵ 

6

1 ˆ ˆ

i  j  2kˆ gSA fn;k gqvk gS
  
ˆ uˆ   1 gSA fuEufyf[kr esa ls dkSu lk ¼ls½
fd R3 esa lfn’'k  dk vfLrRo bl izdkj gS fd û    1 vkSj w.
dFku lgh gS ¼gSa½\

(A) bl izdkj ds  ds fy, Bhd ,d (exactly one) p;u laHko gSA

(B) bl izdkj ds  ds fy, vUkUr (infinitely) p;u laHko gSA
(C) ;fn û xy- lery ij gS rc u1  u2 gSA
(D) ;fn û xz-lery ij gS rc 2 u1  u3 gSA
Ans. (B,C)


Sol. | uˆ  v | 1
 
|v| sin  = 1  is angle between û & v (, û & v ds e/; dks.k gSA)

Also rFkk, ˆ ˆ  v)  1
w.(u
  
ˆ | | uˆ | | v | sin  cos  = 1
|w  is angle between ŵ & (uˆ  v) ( ŵ vkSj (uˆ  v) ds e/; dks.k gSA)

1.1(1) cos  = 1    0   uˆ  v  w
ˆ where tgk¡  > 0
î ˆj kˆ
 
u1 u2 u3 =
6
 î  ˆj  2kˆ  (u2v z – u3vy) î + (u3v x – u1v z) ĵ + (u1vy – u2v x) k̂ =
6
 î  ˆj  2kˆ 
vx vy vz
 
(B) v is a vector such that (uˆ  v) is parallel to ŵ .
 
(B) v bl izdkj gS fd (uˆ  v) , ŵ ds lekUrj gSA
 
(C) u3 = 0  u2vz = & –u1vz =  | u2 |  | u1 |
6 6
(D) |u1| = 2|u3| (  u2 = 0)
45. Let P be the point on the parabola y2 = 4x which is at the shortest distance from the center S of the
circle x2 + y2 – 4x –16y +64 = 0. Let Q be the point on the circle dividing the line segment SP internally.
Then (Parabola) XI
(A) SP = 2 5
(B) SQ : QP =  
5 1 : 2
(C) the x-intercept of the normal to the parabola at P is 6

1
(D) the slope of the tangent to the circle at Q is
2
Ekkuk fd ijoy; (parabola) y2 = 4x ij P ,d ,slk fcUnq gS tks o`Ùk x2 + y2 – 4x –16y +64 = 0 ds dsUnz fcUnq S
ls U;wure nwjh ij gSA ekuk fd o`Ùk ij fcUnq Q ,slk gS fd og js[kk[kaM SP dks vkarfjd foHkkftr djrk gSA rc
(A) SP = 2 5
(B) SQ : QP =  
5 1 : 2
(C) ijoy; ds fcaUnq P ij vfHkyEc (normal) dk x-var%[k.M 6 gSA
1
(D) o`Ùk ds fcUnq Q ij Li’'kZjs[kk dh <ky (slope) gSA
2
Ans. (A,C,D)

2
y = 4x
2
Sol. P(t , 2t)
S Q
(2, 8)
let any point P(t2, 2t) on parabola.

As we know shortest distance between two curves lies along their common normal.
The common normal will pass through centre of circle.
2 2t  8
Slope of normal to the parabola y = 4x at P = –t, =–t
t2  2
 t3 = 8  t=2  P(4, 4)
(i) equation of normal at P(4, 4)  y = –2x + 12  x-intercept = 6
1
(ii) slope of tangent at Q = slope of tangent at P =
2
SQ 2 1 5 1
(iii)   
QP 2 5  2 5 1 4
2
y = 4x
2
Hindi. P(t , 2t)
S Q
(2, 8)
ekuk ijoy; ij fcUnq P(t2, 2t) gSA

ge tkurs gS fd nks oØks ds e/; U;wure nwjh buds mHk;fu"B vfHkyEc ds laxr gksrh gSA
mHk;fu"B vfHkyEc o`Ùk ds dsUnz ls xqtjsxk
2t  8
ijoy; y2 = 4x ds vfHkyEc dh P = –t ij izo.krk =–t
t2  2
3
 t =8  t=2  P(4, 4)
(i) P(4, 4) ij vfHkyEc dk lehdj.k  y = –2x + 12  x-vUr%[k.M= 6
1
(ii) Q ij Li'kZ js[kk dh izo.krk = P ij Li'kZ js[kk dh izo.krk =
2
SQ 2 1 5 1
(iii)   
QP 2 5  2 5 1 4

3 3
46. Let a, b  R and f : R  R be defined by f(x) = a cos (|x –x|) + b|x| sin(|x +x|). Then f is
(A) differentiable at x = 0 if a = 0 and b = 1 (LCD) XII
(B) differentiable at x = 1 if a = 1 and b = 0
(C) NOT differentiable at x = 0 if a = 1 and b = 0
(D) NOT differentiable at x = 1 if a = 1 and b = 1
ekuk fd a, b  R vkSj f : R  R, f(x) = a cos (|x3 –x|) + b|x| sin(|x3 +x|) ls ifjHkkf"kr gSA rc f
(A) x = 0 ij vodyuh; (differentiable) gS ;fn a = 0 vkSj b = 1
(B) x = 1 ij vodyuh; gS ;fn a = 1 vkSj b = 0
(C) x = 0 ij vodyuh; ugha gS ;fn a = 1 vkSj b = 0
(D) x = 1 ij vodyuh; ugha gS ;fn a = 1 vkSj b = 1
Ans. (A,B)
3
Sol. at x = 0, x = 0 is repeated root of g(x) = |x| sin|x + x|
hence f(x) is differentiable
& at x = 1  a cos|x3 – x| = acos(x3 – x)
as cos(–) = cos()  f(x) is differentiable
Hindi. x = 0 ij x = 0, g(x) = |x| sin|x3 + x| dk iqujko`Ùk ewy gSA
vr% f(x) vodyuh; gSA

x = 1 ij
 a cos|x3 – x| = acos(x3 – x)
pwafd cos(–) = cos()  f(x) vodyuh; gSA
x
 n
 nn ( x  n) x  n ..... x  n  
  2  n 
47. Let f(x) = lim , for all x > 0. Then (Definite Integration) XII
2 2 
 n! ( x 2  n2 ) x 2  n ..... x 2  n  
n 
  4   n2  
 
x
  n
 nn ( x  n) x  n ..... x  n  
  2  n 
ekuk fd lHkh x > 0 ds fy, f(x) = lim 2 2 
gSA rc
n   n  
 n! ( x  n ) x  ..... x   
2 2 2 2 n 
  4   n2  
 
 1  1  2 f (3) f (2)
(A) f    f (1) (B) f    f  (C) f(2)  0 (D) 
2 3 3 f ( 3 ) f ( 2)
Ans. (B,C)

x/n
 
x  x 1   x 1
 n2n   1   .......    
  n  n 2  n n 
Sol. f(x) = lim  
2 2  x2
2n  x  x 1  
n 1

 n! n   1   .......  2  2  
 n2  n2 22 
    n n 
x  n  x 1
n
 rx2 1   x 
n
 rx 
n
 r 2 x2  
nf(x) = lim
n n 
 n   
 r 1  n r 

r 1  r   n n  r 1  
 n  2    = lim   n  1   
n  n 
r 1
 n 1  2

 n
 
 
1 1
2 2
n(f(x)) = x  n (1 + xy)dy – x  n (1 + x y )dy
 
0 0
Let xy = t
x x
2
n(f(x)) =   n (1 + t)dt –   n (1 + t )dt
0 0
f '(x)  1 x 
= n 
f(x)  1  x2 
f '(2) 3
= n  < 0  f'(2) < 0
f(2) 5
f '(3)  4  2 f '(2) f '(3)

= n  = n   
f(3) 10
  5 f(2) f(3)
f '(x) f '(x)
Now > 0 in (0, 1) and < 0 in (1 , )
f(x) f(x)
f '(x) f '(x)
vc (0, 1) esa > 0 rFkk (1 , ) esa <0
f(x) f(x)
0 1
f(x) is increasing in (0, 1) & decreasing in [1, ) (as f(x) is positive)
f(x), (0, 1) esa o)Zeku rFkk [1, ) esa ákleku (D;ksfd f(x) /kukRed gSA)
 1  1 2
hence vr% f(1)  f   and rFkk f    f  
2
  3
  3

48. Let f : R  (0, ) and g : R  R be twice differentiable functions such that f " and g" are continuous
f ( x )g( x )
functions on R. Suppose f '(2) = g(2) = 0, f "(2)  0 and g'(2)  0, If lim = 1, then
x 2 f ' ( x )g' ( x )
(A) f has a local minimum at x = 2 (B) f has a local maximum at x = 2 (AOD) XII
(C) f "(2) > f(2) (D) f(x) – f "(x) = 0 for at least one x  R
Ekkuk fd f : R  (0, ) vkSj g : R  R ,sls nks ckj vodyuh; (twice differentiable) Qyu gSa fd R ij f " vkSj
g" lrr~ (continuous) Qyu gSaA eku yhft;s fd f'(2) = g(2) = 0, f "(2)  0 vkSj g'(2)  0 gSaA ;fn
f ( x )g( x )
lim =1 gS] rc
x 2 f ' ( x )g' ( x )
(A) x = 2 ij f LFkkuh; fuEure (local minimum) gSA
(B) x = 2 ij f dk LFkkuh; mPpre (local maximum) gSA
(C) f "(2) > f(2)

(D) de ls de ,d x  R ds fy, f(x) – f "(x) = 0 gSA
Ans. (A,D)
f(x) g(x)
Sol. lim 1
x 2 f '(x) g'(x)
f(x) g(x) 0

 lim  0  Indeterminant form as f'(2) = 0, g(2) = 0  Using L.H.
x 2 f '(x) g'(x)  
f '(x) g(x)  g'(x)f(x) f '(2) g(2)  g'(2)f(2) g'(2)f(2)

lim = = 1  f"(2) = f(2)
x 2 f "(x) g'(x)  g"(x)f '(x) f "(2) g'(2)  g"(2)f '(2) f "(2)g'(2)
and f'(2) = 0 & range of f(x)  (0, )

so f"(2) = f(2) = +ve so f(x) has point of minima at x = 2
and f(2) = f"(2) so f(x) = f"(x) have atleast one solution in x  R
f(x) g(x)
Hindi. lim 1
x 2 f '(x) g'(x)
f(x) g(x) 0

 lim 0 vfu/kkZj~; :i D;ksfda f'(2) = 0, g(2) = 0  L.H. ds mi;ksx ls
x 2 f '(x) g'(x)  
f '(x) g(x)  g'(x)f(x) f '(2) g(2)  g'(2)f(2) g'(2)f(2)

lim = = 1
x 2 f "(x) g'(x)  g"(x)f '(x) f "(2) g'(2)  g"(2)f '(2) f "(2)g'(2)
 f"(2) = f(2) rFkk f'(2) = 0 & f(x) dk ifjlj  (0, ) vr% f"(2) = f(2) = +ve
vr% f(x) dk x = 2 ij fufEu"B fcUnq gSA
rFkk f(2) = f"(2) vr% f(x) = f"(x) dk x  R esa de ls de ,d gy gSA

49. Let a, ,  R. Consider the system of linear equations (Matrix & Det) XII
ax + 2y = 
   3x – 2y = 
 Which of the following statement(s) is(are) correct ?
(A) if a = – 3, then the system has infinitely many solutions for all values of  and 
(B) If a  –3, then the system has a a unique solution for all values of  and 
(C) If  +  = 0, the the system has infinitely many solutions for a = –3
(D) If  + 0, then the system has no solution for a = –3
Ekkuk fd a, ,  R gSaA bu jSf[kd lehdj.kksa ds fudk; (system of linear equations) ij fopkj dhft,
ax + 2y = 
   3x – 2y = 
 fuEufyf[kr esa ls dkSu lk ¼ls½ dFku lgh gS ¼gSa½ ?
(A) ;fn a = – 3, rc rFkk ds lHkh ekuksa ds fy, fudk; ds vuUr (infinitely many) gy gSaA
(B) ;fn a  –3, rc rFkk  ds lHkh ekuksa ds fy, fudk; dk vf}rh; (unique) gy gSaA
(C) ;fn  +  = 0, rc a = –3 ds fy, fudk; ds vuUr gy gSaA
(D) ;fn  + 0, rc a = –3 ds fy, fudk; dk dksbZ gy ugha gSaA
Ans. (B,C,D)
Sol. ax + 2y = 
3x – 2y = 
(A) a = – 3 gives fn;k x;k gS
 = –
or ;k +=0 not for all , (lHkh ,ds fy, ugha gS
a 2
(B) a  –3   0 where tgk¡  = = –2a – 6
3 2
 (B) is correct lgh gS
(C) correct lgh
(D) if ;fn  0
 –3x + 2y =  ........(1)
& rFkk 3x – 2y =  ........(2)
inconsistent vlaxr  (D) correct lgh

 1 
50. Let a, b Rand a2 + b2 0. Suppose S = z  R : z  ,t  R,t  0  , where i = –1 .
 a  ibt 
If z = x + iy and z S then (x, y) lies on (Complex number) XII
1  1 
(A) the circle with radius and centre  ,0  for a > 0 , b  0
2a  2a 
1  1 
(B) the circle with radius – and centre  – 2a ,0  for a < 0, b  0
2a  
(C) the x-axis for a 0, b = 0
(D) the y-axis for a = 0, b  0
1
ekuk fd a, b R vkSj a2 + b2 0 gSA eku yhft, fd S = z  R : z  
,t  R,t  0  , tgk¡ i = –1 .
 a  ibt 
;fn z = x + iy vkSj z S gS rc (x, y) 

1 1
(A) ml o`Ùk ij gS ftldh f=kT;k vkSj dsanz fcUnq  ,0  gS tc a > 0 , b  0
2a  2a 
1  1 
(B) ml o`Ùk ij gS ftldh f=kT;k  vkSj dsanz fcUnq   ,0 gS tc a < 0 , b  0
2a  2a 
(C) x- v{k ij gS tc a 0, b = 0
(D) y- v{k ij gS tc a = 0, b  0
Ans. (A,C,D)
a – ibt
Sol. x + iy =
a2  b2 t 2
a – bt
x= 2 2 2
.........(1) ; y= .........(2)
a b t a  b2 t 2
2
If ;fn a = 0, b  0, x = 0  (D)  If ;fn a  0, b = 0, y = 0  (C)
a bt a bt ay

a2 + b2t2 = & a2 + b2t2 =  =  t= ........(3)
x y x y bx
Putting (3) in (1) ((3) ls (1) esa j[kus ij)
 a2 y 2   a2 y 2  2 2 2 1
x  a2  b2  2 2   a ; x  a2  2   a a (x + y ) = ax  x 2 + y2 – x=0
 b x  x a
   
2
 1   1  2 1
circle with centre  , 0  dsUnz okyk o`Ùk ; radius f=kT;k =   0 0 =
 2a   2a  2a

Paragraph # 1
Football teams T1 and T2 have to play two games against each other. It is assumed that the outcomes
of the two games are independent. The probabilities of T1 winning, drawing and losing a game against
1 1 1
T2 are , and , respectively. Each team gets 3 points for a win, 1 point for a draw and 0 point for a
2 6 3
loss in a game. Let X and Y denote the total points scored by teams T1 and T2, respectively, after two
games. (Probability) XI
QqVckWy nyksa T1 rFkk T2 dks ,d nwljs ds fo:) nks [ksy (games) [ksyus gSA ;g eku fy;k x;k gS fd nksuksa [ksyksa
ds ifj.kke ,d nwljs ij fuHkZj ugha djrsA ny T1 ds ny T2 ds fo:) ,d [ksy esa thrus] cjkcj gksus vkSj gkjus dh
1 1 1
izkf;drk Øe’’”'k% , vkSj gSaA izR;sd ny thrus ij 3 vad] cjkcjh ij 1 vad vkSj gkjus ij 0 vad vftZr
2 6 3
djrk gSA ekuk fd nks [ksyksa ds i’’'pkr ny T1 vkSj ny T2 ds }kjk vftZr dqy vad Øe’'k% X vkSj Y gSaA
51. P (X > Y) is
P (X > Y) dk eku gS&
1 5 1 7
(A) (B) (C) (D)
4 12 2 12
Ans. (B)
Sol. P(X > Y) = T1T1 + DT1 + T1D (Where T1 represents wins and D represents draw)
1 1 1 1 1 1 5
= .  .  . =  (B) is correct
2 2 6 2 2 6 12
Hindi. P(X > Y) = T1T1 + DT1 + T1D (tgk¡ T1 thr rFkk D cjkcjh dks n'kkZrk gSA)
1 1 1 1 1 1 5
= .  .  . =  (B) lgh gSA
2 2 6 2 2 6 12
52. P (X = Y) is
P (X = Y) dk eku gS&
11 1 13 1
(A) (B) (C) (D)
36 3 36 2
Ans. (C)
1 1 1 1 1 1 1 1 39 13
Sol. P(X = Y) = DD + T1T2 + T2T1 = .  .  . =  = =  (C) is correct lgh gSA
6 6 2 3 3 2 36 3 36  3 36

Paragraph-2
x2 y2
Let F1(x1, 0) and F2(x2, 0), for x1 < 0 and x2 > 0, be the foci of the ellipse + = 1. Suppose a
9 8
parabola having vertex at the origin and focus at F2 intersects the ellipse at point M in the first quadrant
and at point N in the fourth quadrant. (Tangent Normal & Its application) XII
x2 y2
ekuk fd F1(x1, 0) vkSj F2(x2, 0) (ftlesa x1 < 0, x2 > 0) nh?kZo`Ùk (ellipse) + = 1 dh ukfHk;k¡ (Foci) gSA
9 8
ekuk fd ,d ijoy; (parabola) ftldk ‘'kh”"kZ (vertex) ewyfcUnq (origin) ij vkSj ukfHk (focus) F2 ij gS] nh”?kZo`Ùk
dks çFke prqFkkZa'k (first quadrant) esa M ij vkSj prqFkZ prqFkkZa'k (fourth quadrant) esa N ij çfrPNsfnr djrk gSA
53. The orthocentre of the triangle F1MN is

f=kHkqt F1MN dk yEcdsUæ (orthocentre) gS&
 9  2   9  2 
(A)  – , 0 (B)  , 0  (C)  , 0  (D)  , 6 
 10  3   10  3 
Ans. (A)
x 2 y2
Sol. Ellipse :  1 ………..(1)
9 8
foci of ellipse are (±1, 0)
Equation of parabola having vertex (0, 0) and focus (1, 0) is y2 = 4x …………….(2)
y
2
y = 4x
M
x
F1(–1,0) R
F2(1,0)
N
x 2 4x 2 3
from equation (1) & (2)  1  2x + 9x – 18 = 0  x= , –6 (rejected)
9 8 2
3  3 
 M  , 6  and N  ,  6 
 2   2 
3  5  3
Equation of altitude from vertex M  , 6  is y  6 =
2  2 6
  x  2 
 
12 3 9  9 
put y = 0 we get   x x =  orthocenter of F1 MN is  ,0 
5 2 10  10 

x 2 y2
Hindi. nh?kZo`Ùk:  1 ………..(1)
9 8
nh?kZo`Ùk dh ukfHk;k¡ (±1, 0) gSaA
2
(0, 0) 'khZ"kZ rFkk (1, 0) ukfHk okys ijoy; dk lehdj.k y = 4x …………….(2)
y
2
y = 4x
M
x
F1(–1,0) R
F2(1,0)
N
x 2 4x 3
lehdj.k (1) rFkk (2) ls  1  2x2 + 9x – 18 = 0  x= , –6 (vLohdk;Z)
9 8 2
3  3 
 M  , 6  rFkk N  ,  6 
2  2 
3  5  3
M  , 6  ls 'kh"kZyEc dk lehdj.k y  6 =
2  2 6
  x  2 
 
y = 0 j[kus ij
12 3 9
  x x =
5 2 10
 9 
F1 MN dk yEcdsUnz  ,0  gSA
 10 
Ans. (A)
54. If the tangents to the ellipse at M and N meet at R and the normal to the parabola at M meets the x-axis
at Q, then the ratio of area of the triangle MQR to area of the quadrilateral MF1NF2 is
;fn nh?kZo`Ùk ds fcUnqvksa M vkSj N ij Li’'kZ js[kk,a (tangents) R ij feyrh gS vkSj ijoy; ds fcUnq M ij vfHkyEc
x-v{k dks Q ij feyrk gS] rc f=kHkqt MQR ds {ks=kQy vkSj prqHkZqt (quadrilateral) MF1NF2 ds {ks=kQy dk
vuqikr (ratio) gS&

(A) 3 : 4 (B) 4 : 5 (C) 5 : 8 (D) 2 : 3
Ans. (C)

3  x(3 / 2) y 6
Sol. Equation of tangent at point M  , 6  to the ellipse is  1
2  9 8
put y = 0  R is (6, 0)
3  6  3
Equation of normal to the parabola at point M  , 6  is y  6 = 
2 
2
 x  2 
 
7 
put y = 0  Q is  ,0 
2 
1 5
. . 6
Area of MQR 5
Now = 2 2  Ans. (C)
Area of quadrilateral MF1NF2 1
.2.2 6 8
2
3  x(3 / 2) y 6
Hindi. nh?kZo`Ùk ds fcUnq M  , 6  ij Li'kZ js[kk dk lehdj.k  1
2  9 8
y = 0 j[kus ij  R, (6, 0) gSA
3  6  3
M  , 6  ij ijoy; ds vfHkyEc dk lehdj.k y  6 = 
2  2
  x  2 
 
gSA
7 
y = 0 j[kus ij  Q  ,0  gSA
2 
1 5
. . 6
MQR dk {k=
skQy 2 2 5
vc =  Ans. (C)
pr q
HkZ
t MF1NF2 dk {k=
q skQy 1
.2.2 6 8
2

DARKENING THE BUBBLES ON THE ORS : (ORS ij cqycqyksa dks dkyk djus dh fof/k) CODE - 7
15. Use a BLACK BALL POINT to darken the bubbles on the ORS. ORS ds cqycqyksa dks BLACK BALL POINT isu ls dkyk djsaA
16. Darken the bubble COMPLETELY. cqycqys dks iw.kZ :i ls dkyk djsaA
17. The correct way of darkening a bubble is as: cqycqys dks dkyk djus dk mi;qDr rjhdk gS :
18. The ORS is machine-gradable. Ensure that the bubbles are darkened in the correct way.
ORS e'khu&tkaP; gSA lqfuf'pr djsa dh cqycqys lgh fof/k ls dkys fd;s x;sa gSaA
19. Darken the bubbles ONLY IF you are sure of the answer. There is NO WAY to erase or "un-darken" a darkened bubble.
cqycqys dks rHkh dkyk djsa tc vki mÙkj ds ckjsa esa fuf'pr gksA dksys fd, gq, cqycqys dks feVkus vFkok lkQ djus dk
dksbZ rjhdk ugha gSA
QUESTION PAPER FORMAT AND MARKING SCHEME :
20. The questions paper has three parts : Physics, Chemistry and Mathematics.
bl iz'u&i=k esa rhu Hkkx gSa% HkkSfrd foKku] jlk;u foKku vkSj xf.kr] A
21. Each part has three sections as detailed in the following table :
gj Hkkx esa rhu [kaM gSaA iz'u i=k dk izk:i vkSj vadu ;kstuk %
Category-wise Marks for Each Ques. Maximum
No. of
Ques. Type oxkZu ql kj izR ;sd i z' u d s vad Marks of
Ques.
Section iz' u dk the Section
iz' uksa
[kaM i zd kj Negative [kaM esa
dh Full Marks Partial Marks Zero Marks
Marks vf/kd re
la[ ;k iw. kZ vad vkaf 'kd vad ' kwU ; vad
_.k vad vad
.+3
0
If only the bubbles
If none of –1
Single corresponding to the
the bubbles In all other
Correct correct option is
is darkened cases
Option darkened
1 6 – (;fn fdlh Hkh (vU; lHkh 18
(,dy lgh (;fn flQZ lkjs lgh
cqycqys dks ifjfLFkfr;ksa
fodYi) fodYi ds vuq: i
dkyk ugha es)a
cqycqys dks dkyk fd;k
fd;k g S)
gS)
.+1
.+4
For darkening a bubble 0
One or If only the bubble(s)
corresponding to each If none of –2
More corresponding to all
correct option, provided NO the bubbles In all other
Correct the correct option(s)
incorrect option is is darkened cases
Option(s) is(are) darkened
2 8 darkened (;fn fdlh Hkh (vU; lHkh 32
(,dy ;k ,d (;fn flQZ lg h
(izR;sd lgh fodYi ds vuq: i cqycqys dks
fodYi@fodYiksa ds ifjfLFkfr;ksa
ls vf/kd lg h cqycqys dks dkyk djus ij] ;fn
vuq:i cqycqys@cqycqyksa
dkyk ugha es)a
fodYi) dksbZ xyr fodYi dkyk ugha fd;k g S)
dks dkyk fd;k gS)
fd;k gS)
.+3
If only the bubbles 0
corresponding to the In all other
Comprehen correct answer is cases
3 sion 4 darkened – (vU; lHkh – 12
(vuqPNsn) (;fn flQZ lg h mÙkj ifjfLFkfr;ksa
ds vuq: i cqycqys dks es)a
dkyk fd;k gS)

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JEE (Advanced) 2016

READ THE INSTRUCTIONS CAREFULLY ( d`i;k bu funsZ'kksa dks /;ku ls i<sa)

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SECTION – 1 : (Maximum Marks : 18)

[kaM 1 : (vf/kdre vad : 18)

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2. An accident in a nuclear laboratory resulted in deposition of a certain amount of radioactive material of

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C1 dk ikB~;kad = 28.7 mm = 2.87 cm

ofuZ;j C2 ds fy;s : ofuZ;j C2 vlkekU; gS

vr% C2 dk ikB~;kad = 28 mm + 0.3 mm = 2.83 cm

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For I1  u = –50 f = +30 v = +75cm

size of image > size of object

y2 + (50 – x)2 > 625

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n  158 O  157 N  11H

(A) 0.78 mm (B) 0.90 mm (C) 1.56 mm (D) 2.34 mm

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10°C 140°C 400°C

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= (50 × 103)(100 × 10–3)[e–t]

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S. No. T absolute error = |T – Tmean|

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Just after m is placed

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(C) fcUnq O dk fudVre {ks=k vnhIr gksxk

(D) x-v{k ds lekukUrj nhIr rFkk vnhIr lh/kh ifê;k¡

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xsYosuksehVj igys xsYosuksehVj ds lekukUrj esa tqM+k gSA

lekukUrj esa tqM+k gSA

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SECTION – 3 : (Maximum Marks : 12)

[kaM 3 : (vf/kdre vad : 12)

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Paragraph for Question Nos. 15 to 16

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15. The distance r of the block at time t is :

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17. Which one of the following statements is correct?

(D) xksfy;k¡ Åijh ifV~Vdk ij fpiddj ogha jg tkrh gSa

(C) V0 ds lekuqikrh gksxh (D) dk eku 'kwU; gksxk

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18. Iavg V02

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SECTION – 1 : (Maximum Marks : 18)

(A) v"VQydh;, oxZ leryh rFkk prq"Qydh;

(B) oxZ leryh] v"VQydh;, rFkk prq"Qydh;

(C) prq"Qydh;] oxZ leryh rFkk v"VQydh;

(D) v"VQydh;] prq"Qydh; rFkk oxZ leryh

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20. The major product of the following reaction sequence is

ukfHkdLusgh ;ksx HCHO / H

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