R. K. MALIK'’S JEE (MAIN & ADV.), MEDICAL + BOARD, NDA, IX & X NEWTON CLASSES Enjoys unparalleled reputation for best results in terms of percentage selection www.newtonclasses.net JEE MAIN (ONLINE SET - 3) 2013 This test will be a 3 hours Test. This test consists of Physics, Chemistry and Mathematics questions with equal weight age of 120 Each question is of 4 marks. There are three parts in the qliestion paper consisting of Physics (Q.no.] to 30), Chemistry (Q.n0.31 to 60) and Mathematics (Q. no.61,16 90). There will be only One correct choice in the given four choices. For each question 4 marks will be awarded for corfect choice, 1 mark will be deducted for ineorrect choice.and Zero mark will be awarded forfot attempted question. Any textual, printed of written materials mobile pliones, calculator éte. is not allowed for the students appearing for the test. All caléulations / written work should be done in the rough sheetyprovided. My (k+ Hog) PHYSICS . Almass of SOgiof water in a closed vessel, with () Larger than al { surroundings ata constant temperature takes 2 minutes to cool from 30°C to 25°C. A mass of 100g ofanother liquid in an identical vessel with 4a af M identical surroundings takes the same time to G+ Abg) fol from 3066 1025, C. The Spegibc Bogie tis Which of the following circuits correctly liquid is represents thé following truth table ? (The water equivalent ofthe vessel is 30g.) (@) \2.0kealke (b) Tkcal/kg ABE (©) Akcalkg (@)_ O.Skcavkg 000 A uniform cylindér of length 'L_and mass M 0 1 1 I having cross-sectional area A is suspended, with its length vertical, from a fixed point by a massless spring, such that it is half submergedin a liquid of density o at equilibrium position, When the) cylinder is given a downwatd push and released, it starts oscillating vertically with a small amplitude, The time period T of the oscillations ofthe cylinder will be : (@) Smaller than af (k+ dog) () nf 1 0 1 Office.: 606 , 6” Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0651-2562523, 9835508812, 8507613968 NEWTONCLASSES.NETR. K. MALIK'S NEWTON CLASSES One of the two small circular coils, (none of them having any self - inductance) is suspended with a V-shaped copper wire, with plane horizontal. The other coil is placed just below the first one with plane horizontal. Both the coils are connected in series with a de supply. The coils are found to attract each other with a force. Which one of the following statements is incorrect ? (a) Both the coils carry currents in the same direction. (b) Coils will attract each other, even if the supply is an ac source. (©) Force is proportional to d~! (d)_ Force is proportional to d~ This question has Statement-1 and Statement-2. Of the four choices given after the Statements, choose the one that best describes the two Statements. Statement 1 : No work is required to be done to move a test charge between any two points on an equipotential surface. Statement 2 : Electric lines of forceat the equipotential surfaces are mutually perpendicular to each other. (a) Statement 1 is true, Statement 2 is true, Statement 2 is the correct explanation of Statement 1. (b), Statement 1 is true, Statement 2 is true, Statement 2 is not the correct explanation of Statement 1 (©) Statement | is true, Statement 2 is false. (d)_ Statement | is false, Statement 2 is true. A thin glass plate of thickness is a (A is wavelength of light used) and refractive index x= 1.5 is inserted between one ofthe slits and the screen in Young's double slit experiment. At a point on the screen equidistant from the slits, the ratio of the intensities before and after the introduction of the glass plate is, (@ 2:1 ) 14 © 4:1 @ 4:3 ‘The maximum range ofa bullet fired from a toy pistol mounted on a car at rest is Ry= 40 m. What will be the acute angle of inclination of the pistol for maximum range when the car is movingin the (©) _1.8Gauss (4) 032Ganss t °o ‘A 12.5'eV electron beam is used to bombard ‘gaseous hydrogen at room temperature. It will Bis an (@) lines in the Lyman series and | line in the Balmar series (b) 3 lines jn the Lyman series 3 (©) Llinéin the Lyman series and 2 lines in the ‘Balmar series (d)_ 3lings in the Balmér series an A mefal sample carrying a’current along X-axis with density, is subjected to a magnetic field B, (alongz-axis), The electric field E, developed along ¥-axisis directly proportional fo J, as well as B;-The constant of proportionality has SI unit. Office.: 606 , 6" Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0651-2562523, 9835508812, 8507613968 NEWTONCLASSES.NETR. K. MALIK'S NEWTON CLASSES A printed page is pressed by a glass of water. The refractive index of the glass and water is 1.5, and 1.33, respectively. If the thickness of the bottom of glass is 1 cm and depth of water is Sem, how much the page will appear to be shifted if viewed from the top ? (@) 1.033em (b) 3.581cm © 13533em @ 19cm Ina transverse wave the distance between a crest and neighbouring trough at the same instant is 4.0 cm and the distance between a crest and trough at the same place is 1.0 cm.The next crest appears at the same place after a time interyalOf 0.4s. The maximumy’speed of the vibrating particles in the medium is : ) ems 2 & Bay (dy 2nemis Which of thelfollowing/modulated signal has the best noise+tolerance ? (@) Léng-waye (6) Short-wave! (© Medium-wave (@) Amplitude-modulated When resonance is produced in a series LCR citcuit, then which of the followingiis not correct ? (a), Current in the circuit is in phase with the applied voltage. (6) \Inductive and capacitive reactances are equal. (©) IfRis reduced, the voltage across capacitor will increase, (@)_ Impedance of the circuit is maximum. Inan experiment, a small steel bal! falls through a liquid at a constant speed of{10,¢ms. If the steel ball is pulled upward with a force equal to) twice its effective weight, haw fast will it moye upward ? @) Sem/s (b) Zero (©) 10cmis @ ems A parallel plate capacitor having a separation between the plates d, plate area A and material with dielectric constant K has capacitance Co, Now one-third of the material is replaced by another material with dielectric constant 2K, so that effectively there are two capacitors one with I atea 5 A, dielectric constant 2K and another with 2 area 5 A and dielectric constant K. If the capacitance of this new capacitor is C then io. a @ 1 ) 2 OA «@ A series LR cifeuit is e@nnected to an ac source of frequency (and the inductive reactance is equal t8.2R. A GApacitance of capacitive reactance equal to R is added in series with L and R. The ratio of the new power factor to the ald one is: @ 2 & 5 3 5 © 3 @) £ In anjexperiment on photoelectric effect, a student plot® stopping potential, V,, against reciprocal of the fvavelength 2 of the incident light for two different metalsA and By These are shown in the figure. Looking at the graphs, you can most appropriately say that: (a) Work function of metal B is greater than that of metal A Office.: 606 , 6" Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.; 0651-2562523, 9835508812, 8507613968 NEWTONCLASSES.NETJEE MAIN (ONLINE SET ~ 3) 2013 (b) For light of certain wavelength falling on both metal, maximum kinetic energy of electrons emitted from A will be greater than those emitted from B. (©) Work function of metal A is greater than that of metal B (@)_ Students data is not correct ‘The source that illuminates the double - slit in ‘double - slit interference experiment’ emits two distinct monochromatic waves of wavelength 500 nm and 600 nm, each of them producing its own: pattern on the screen. At the central point of the pattern when path differencé is zero, maxittia Of both the patterns coificide and the resulting interference pattert is most distinct at the region ‘of zero path difference, But as one moves out of this central fegions the.tWo fringe systems are ‘gradually Out of stepistich that maximum due to ‘on wavelength coincides with the minimum due to the/other and the combinied fringe system becorhes cotfipletely indistinct. This may happen when path difference in nim is: (@)/ 2000) (b) 3000 (©) 1000 (@ 1500 ‘This question has Statement-1 and Statements- 2. Of the four choices given after the Statements, choose the one that best describes the two Statements. Statemefif-1 {)Out\ of radio waves and microwayes, the radio\waves undergo more diffraction. Statement-2 : Radio,waves have greater frequeney compared to microwaves. (a) Statements true, Statement-2'is:true and Statement-2 isthe correct explanation Of Statement ) (©) Statement-1is trie, Statements false. (@)_ Statement-1 is true, Statement-2 is true but Statement-2 is not the correct explanation of Statement-1 Aring of mass M and radius R is rotating about its axis with angular velocity «. Two identical bodies each of mass m are now gently attached at the two ends of a diameter of the ring. Because of this, the kinetic energy loss will be : a mM +2 gt Mm (292 (M +m) Mm 292 © Gram? ® (M+m)M. 2 92 tM OR @ “(ts2m ° ‘A.wind-powered generator converts wind energy into€lectrical energy. Assume that the generator converts a fixed fraction of the wind energy intereepted by its blades into electrical energy. For wind speed.®, the electrical power output Will be most likely proportional to, @ v © v ov @v ‘A copper ball of radius 1 cm.andiWork function 4 #7eV is irradiated with ultrayiolet radiation of wayelength 2500 A\ The effectofiirradiation resultsin the emission of electrons from the ball. Further the ball will acquire charge and due to this there will be a finite value of the potential on the ball. Thehiatge acquired by the ball is : @ “55x10 8C (b) 7.5% 10-3C (45x 1RE @ 25x 0-1'c In the isothermal expansion of 10g 6f gas from volume V to 2V the work done by the gas is $75J. What is the root mean square speed of the molecules of the gas‘at that temperature? (@)-398m/s (6) 520m/s (©) 499mis (a) /532m/s GHEMISTRY The catenation tendéncy of C, Si and Ge is in the order Ge-< Si < C. The bond energies (inkJ oF ') of C- C, Si—Si and Ge ~Ge bonds. are respectively ; (a) 348,297, 260 (b) 297,348, 260 (©) 348,260,297 (A) 260,297,348 Office.: 606 , 6" Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0651-2562523, 9835508812, 8507613968 NEWTONCLASSES.NETR. K. MALIK'S NEWTON CLASSES In which of the following exothermic reactions, the heat liberated per mole is the highest ? (a) Ca0+H,0 Ca(OH), (b) SrO+H,0 — Sr(OH), (©) BaO+H,0— Ba(OH), (@ MgO +H,0 > MgO), Given (A) n=5,m, 8) n=2, ¢=1,m,=-1,m,=412 ‘The maximum number of electron(s) in an atom that can have the quantum numbers as giver ir (A) and (B) are respectively: (@) 25and1 (&) Sand (©) 2and4 @ 4andt Which one of the following cannot funetion as an oxidising égent 2 @ F (b) S(s) C10} (© NO5 (aq) @) cl NOy © (D) Giver Je (a) c)) In the above compounds eotrect order of reactivityimelectrophilic substitution reactions will be» (@)\ B>A>C>D. (bt) D>C>B>A (©) \A>B>C>D @ B>C>A>D Which one of thesfétlowing is the wrong assumption of kinetic theory of gases ? (a) Momentiim and energy always-remain conserved. (©). Pressure'is the result offelasti@Gollision of molecules with the containier’s wall (©) Molecules are separated by great distances! compared to their sizes. All the molecules move in straight line between collision and with same velocity. A radioactive isotope having a half-life period of 3 days was received after 12 days. If3g of the isotope is left in the container, what would be the initial mass of the isotope ? @ 12g (b) 36g © 48g @ 24g 38, Which of the following statement is not correct? (@) Amylopectin is a branched polymer of a glucose, (b) Cellulose isa linear polymer of B-glucose (©) Glycogen is the food reserve of plants (a) Allproteins are polymers of -amino acids. ‘The major product in the following reaction CH,OH Heat +HCI Heat, is: OH CH;OH, cl Rg, Theratio —~ forthe redetion CO(g)* 40316) = CO; (2) is: L fa) 4b) cary”? (oy RT. @ ii Copper crystallises in fee with a unit length of 361 pmgWhat istic radius of copper atom ? (@)_157pm (b) 128pm (©) 108pm @ 18pm In which of the following sets, all the given species are isostructural ? (@ CO,,NO,,CI0,,Si0, (b) PCL,,AICI,, BCI, SbCl, (© BF,,NF,,PF,.AIF, @ BEY .CCly,NH},PCI; Office.: 606 , 6" Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.; 0651-2562523, 9835508812, 8507613968 NEWTONCLASSES.NETJEE MAIN (ONLINI SET - 3) 2013 7 Given that: @ ArH? of N20 is 82kJ mot! (i) Bond energies ofN = N, N=N, O=Oand N=Oare 946, 418, 498 and 607 kJ mol! respectively, The resonance energy of N,O is : (@) -88k (b) ~66kI (©) -62k5 @ 45 What would be the pH ofa solution obtained by mixing 5g of acetic acid and 7.5g of sodium acetate and making the volumeequal to 500 mL? (K,= 1.75 « 10°, pK,=476) (a) pH=4.70 () pH<4.70 (©) pHof s6lution willbe equal to pH of acetic acid (@) 476 ~@)_ [CO(NHL,) In nucleophilic substitution reaction;-order_of. halogens as incoming (attacking) nucleophile is: I>Br->cr ‘The order of halogens as departing nucleophile should be (@) Br->I->Ccr (©) Cr>Br>r (b) F>Br>cr @ Cr>r>Br 50. The Gibbs energy for the decomposition of ‘Al,0, at 500 C isas follows: 2al,05 > : Al+09,4,G = +940kJ mot! The potential difference needed for the electrolytic reduction of aluminium oxide at 500°C should be at least @ 45V () 30V (©) Sov @ 25V Cannizaro’s reaction is not given by: @ «)— CHO CHO 40 CH, (© CA;CHO @ HCHO Phenol on heating with CHOWjand NaOH gives salicylaldchyde. The reaction is called (@) Reimer - Tiemann reaction, (®), Claisen reaction (©) Cannizzaro’s reaction (@)_ Hell- Volhard - Zelinsky reaction The’intérntlelear distances in O—O bonds for 03,0,,03 and 03° respectively are’: (a) 130A,1.49.4, 112A, 121A (b) 149A,12VA, LIZA 1304 (©) 1.21A,142A,1494, 130A (@)_ 1.12.4, 1.21 A130 A, 1.49 Among the following/vitaming/the one whose deficiency causes tickeis/(boné deficiency) is : @_ Vitamin A (6) Vitamin B (©) Vitamin @)_ Vitamin Which one of the following arrangements represents the e6rrect order of the proton affinity of the given species (@) - VAR CO,Et (@)_glyco/LiATH,/H,0* (®) glycol/NaH/H,O* @ LAlH, (@) NaBH, A solutionsPicopper sulphate (uSO,) is electrolysed for 10 minutes with a current of 1.5 amperes. The mass\of copper deposited at the cathode (at. mass of Cu= 63u) is (a) 03892g (db). 0.2938g (© 02398g (@) 03928, MATHEMATICS Given a sequeiice of 4 numbers, first three of, which are in GP. and the Jast three are in AP with common difference six. Iffirstand last terms: of this sequence are equal, then the last term is @ 16 ) 8 © 4 @ 2 Statement 1: The only circle havingradius JT and a diameter along line 2x + y= Sis x? + y?-@r Statement 2 :2x+y=5 isa normalto the circle P4y6r+2y Statement | is false; Statement 2 is true. Statement 1 is true; Statement 2 is true, Statement 2 is a correct explanation for Statement 1 Statement | is true; Statement 2 is false. (d) Statement | is true; Statement 2 is true; Statement 2 is not a correct explanation for Statement 1 Ifa circle of unit radius is divided into two parts by an arc of another circle subtending an angle 60° on the circumference of the first circle, then the radius of the are is: 1 OG © > @ 1 () 2 Ifthe image of point P(2, 3) ina line L is Q(4, 5), ‘hen the imageof point R(0, 0) in the same line is: @ 22) ©) aS © 64) @ aD Consider the System of equations shay az 0 andiz+ ax=0. Then theset $fall real values ofa" for which the system has a unigue solution is: @ R-{} ) R-{-)) © (1-1) @ 11,0, ‘Arcommonstangent to the conics x? = 6y and 24? = a az ap je O20, =o} Thentthe number of non-sirigular matrices in the set Sis: @ 2. () 24 © 0 (d) 20 Let¥ € (0, 1). The set of all x such that sin” le> cos, is the interval: os 0 # (4) © 1) Office.: 606 , 6" Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.; 0651-2562523, 9835508812, 8507613968 NEWTONCLASSES.NETJEE MAIN (ONLIN' SET - 3) 2013 9 Let A (-3, 2) and B (-2, 1) be the vertices of a triangle ABC. If the centroid of this triangle lies, on the line 3x + 4y +2 =0, then the vertex Clies on the line : (@) 4x+3y45 () 3x+4y+ (©) 4x+3y43 @ 3x+4y+5 Let ABC be a triangle with vertices at points A (2, 3, 5), BCA, 3, 2) and C (A, 5, 1) in three dimensional space. If the median through A is equally inclined with the axes, then (A, w) isequal to (@ (10,7) © 7,19 Ifthe integral (b)_ 55) @ 6,7), fj cos8x+1 cot 2x— tan 2x. where & is an arbitraryconstant, then Ais equal to: dy Acos8x+k, L @ /-7¢ © % L Og @ -3 ‘The equation of the curve passing through the origin and satisfying the differential equation aay 2 1+ x°)—+ 2xy = 4x° is O42) 4 day @\ (ex?) sx? 2x0 © (&x)y 23x ©) 30437 @ 30+2)y sar For 05x57, theyalue of 0s? x J sin tear J cos™ (ve)a@requals: 0 ° @) (b) 0 x 4 © 1 74, BB. Let f:[~2,3]—> [0, co )bea continuous function such that f(1-x)= f(x) for all x € [-2,3] If R, is the numerical value of the area of the region bounded by y=/(x),x=—2,x=3 and the 3 axisofxand Ry = J xf(x)dx, then: 2 (@ 3R,=2R, (© R=R, Let-a=2i + 7-246 such that (b) 2R,=3R, @|=2y2 and the angle between Tel. @xb and ¢ is 30%then |(axb)xc| equals: 1 wi @ > © > 3 @ 5 Let p and g be any two logical statements and rep® (~ p vq).\lfrhdsa truth value F, then the truth values of p and g are respectively @ RF ) TT ©, TF @) ET If the events Aland B are mutually exclusive © 3 + events such hat | P(A) PB) ; then the set of possible values of xliesin the intefval ; (10, 1] ws © F359 The equation of a plane through the line of intersection of the planesx +2y=3,y—2z-+ I=0, and perpendicular to the first plane is : Office.: 606 , 6" Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0651-2562523, 9835508812, 8507613968 NEWTONCLASSES.NETR. K. MALIK'S NEWTON CLASSES If for positive integers r> 1, n> 2, the coefficients of the (37)! and (r + 2)" powers of x in the expansion of (1 +.x)** are equal, then n is equal to: (@) 2r+1 () 2 (©) 3r @ rt If p and q are non-zero real numbers and a? +B>=-p,aB=q, then a quadratic equation whose roots are @ prr—gxtp?=0 () getpx+g?=0 (©) pet+gxtp=0 @) ge-pxt A spherical balloon ig being inflated at the rate of 35cc/min. Thesfate ofincrease in the surface area (in cmh?/min. ) ofthe balloon when its diameter is 14cm, is (@) 10 (6) Ji0 (© / 100 @ 1010) Let A={@ : sin(0)=tan(@)} and B = (@:€05(6) = 1) be two sets. Then @ A=B ) AcB () BaA (@), A qBland) B-4 #6 Let x satisfy| z |= Vand 2= 1- z Statement 1 :zisa real number. Statement 2 : Pringipal argument of zis (@) Statement’ Lis true Statement-2-is true; Statement 2 i8,a correctiexplanation for Statement\l, (b) Statement 1 is false; Statement? is true (©) Statement | is true, Statement? is false. (@) Statement 1 is true; Statement 2 is trey Statement 2 is not a correct explanation for, ‘Statement 1 Consider the function : S(s)=[x] +| 1x], -15.x<3 where [x] is the {greatest integer function. Statement 1 : fis not continuous at x= 0, 1, 2 and 3. ox, -Isx<0 I-x, O 4.2 for | then the valueof| ais: @ 2 © oa @ 2wW2 The value of P + 32+ 5? + wet 257s: (a) 92925 (&) 140 (1728 @ 1436 If an equation of a tangent to the curve, y~ cost + f},—1/-15 £5 UP Rpis + 2y =k then & is equal to @t & 2 x © @ F Se ign numberSarc tobe formed using 2, 3, 5, 7, 9 without repeating thedigits.Ifp be the number of such numbers that exceed 20000 and q be the numbens6f those thatie between 30000 and 90000, then p: gis: @ 65 (b) 3:2 (4:3 (@) 5:3 Appoint on te ellipse, 4x2+ 9)? = 36, where the normal is parallel tothe line, 4 o (3) © G3) of) of Office.: 606 , 6" Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.; 0651-2562523, 9835508812, 8507613968 NEWTONCLASSES.NETJEE MAIN (ONLINE SET ~3) 2013 ANSWER KEY oO @ @ oO ol«Lop«l@l«lol @ 7 © | 6. Tw | 6. @ [76 To [86 |) @ @ 177.1 © | 87.| @ HINTS & SOLUTIONS PHYSIES (@ As the surrounding identical, vessel is identieal time takerto cool both water and liquid (fromi30°C 10 25°C) is same 2minutes, therefore (a)-(2) at dt (my Cy + WAT in Oj + WAT t t (WiSWwater, equivalent of the vessel) water liquid or, ory myCy = M/C; myCw . Specific heat SFliquia,C,= 50x .Sykcal / kg 100 a Forcircuit 1 +A 4 (@™As the force between thie two coils is attractive henée currents in'the coil must be in the same direction and the force, Foc He 2nd where 1, and I, are the @irrents\flowing through the coils. The work done is moving a charge along an equipotential surface is always zero. The (direction of electric ficld is perpendicular to the equipotential surface or lines. 2/0 Electric field intensity at the centre of the disc. o EaaS Aieiven) 29 Electric field along the axis at any distance x from the centre ofthe dise ae] Fromquestion, x = R (radius of disc) Office.: 606 , 6" Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0651-2562523, 9835508812, 8507613968 NEWTONCLASSES.NETR. K. MALIK'S NEWTON CLASSES 9. :. % reduction in the value of electric field (e795) eg) x10 a 000», - 70.7% 2mM_ (b) Tensi the =| 0 Tonite vin, T-( 228) Force/Tension ___2mM™ Area “acm Mp © _ meng Xin+2m) (= 2mgiven) SNikg and E,=12 Nkg ional. potential Gravitational field « distanee (Given: potential at the origin is zero) Vu2mo) _ Ex x12 ys x2 * Voosm EyxS | 12x8 Wotk done = Area bounded by PV graph and Volumeaxis Among the three process, bounded area by PV graph and volume axis is greatest for isobaric process, hencework done is greatest fof isobaric process. Graph (b), correctly dipicts~the acceleration-time graphofithe block. Resistance between P and Q 5 ro ry™eer tt (345) ra Resistance between Q and R ES Rigted 3s Fon = FH a 2°3 Resistance between P and R Hence, itis clear that rpg is maximum 2M rm Earth's magnetic field, B= Go (©4105) hog 6.621074 x3x108 12.5x16x1079 = 993.0 a ny? ny? (where Rydberg donstant , R= 1.097} 10°) Total numberof spectral lines ‘Twolines int Lyman series form, 7 1,n,=2 and n, >, n, = 3.and one in Balmer series ‘According to question E, chBy Constant of proportionality Fy Cm BzJ, J, As I =C (speed of light) and J ==] Office.: 606 , 6" Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.; 0651-2562523, 9835508812, 8507613968 NEWTONCLASSES.NETJEE MAIN (ONLINE SET ~3) 2013 17. (©) Realdepth= Scm+lem=6cm Short-wave has the'best noise tolerance. Impedance (Z) of the series LCR circuit is Zz fra, Xe AveéSonance, X¥_ = X¢ TherefOrVZ,inigun=R T (upthrust) (viscous of force) WOweight) Weight of the body “a WAmg=gFr pg 4 -F nog and F = 6nnvr ‘When the body attains terminal velocity net force acting on the body i8 zero. i.c., W-T-F=0 And terminal velocity V = Asin case of upward motion upward force istwice its effective weight, therefore, itwill move with same speed 10 cm/s kegA d Keo 2, 2key A 3d 3d 2 (bh) Co= 4keg A 3 B—(@)—Power factor (ys R R R ¥R?+x,? SYR?+@R)? VSR Power factorggi Old power factor New power fictor’ Ee ei For metal A For metal B OK nee BI he he A lb As.thevalue of + (increasing and decreasing) is not specified hence we cannot~Say that which metal has comparatively greater or lesser work function (6). Wavelength of radio waves is greater than microwaves hence frequency of radio waves is less than microwaves. The degree of difltaction is greater whose wavelength is greater. Office.: 606 , 6” Floor, Hariom Tower, Circular Road, Ranchi , Ph.: 0651-2562523, 9835508812, 8507613968 NEWTONCLASSES.NETR. K. MALIK'S NEWTON CLASSES (©) Kinetic energy ieexinay Ky re Kinetic enerBy graiaiony Kr = 5 MV (v=Ra) 2; Weigat =O 3 iit MA Coeu U eystesn) = MR? +2mR? . __Mo Contemp 2m Solving we get loss in K.E. CHEMISTRY Thelinking of identical atoms with each other to form long chains is,called catenidtion. Hdwever, this property decreases from carbon to lead. Decrease of this property is associated with M-M bond energy which decreases from carbon to lead. (@ n=5 means !/=0,1,2,3,4 sineem=1 hence total no. ofelectrons will be =0 (from s) ¥2 (fromp) +2 (from d) +2 (from +2 (from g) +242+249=8 21s 1,m,=<1/2 represent 2p orbital with one electron Ifan electronegative element is in its lowest possible oxidation state in 2 eGmpound or in free states.It can furletion.as a powerfull reducing agent: eg. —Cl and—CH, groups are oand p directing They are electron releasing due to E-and. + M effects. Further since such groups increase electron density in the nucleus, they facilitate further electrophilic substitution and hence known as activating ‘group. The activating effect of these groups is in order of ~ CH, > -X but chlorine exceptionally deactive the ring due to strong —I effect. Hence, it is difficult to carry out substitution in chlorobenzene than in benzene. Further — NO, is a deactivating group hence deactivates the benzene nucleus, i.e. hinder the further substitution. Thus nitrobenzene undergo electrophilic substitution with a great difficulty hence the correct order will be a NO, (A) © o Molecules move very fast in all directions iiva straight line byeolliding with each other but with different velocity. Given t, 953 Total time Ts 12 No. of half lives (n)= 2 py py Bh No i6 aN No cc No Ny =48g Glycogen is called animal statch and is found in all animal-cells. It constitutes the Teserve food material Kp Ke (RT For the reaction. 1 CO(a)+5 02(8) => CO,e) ( Office.: 606 , 6" Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.; 0651-2562523, 9835508812, 8507613968 NEWTONCLASSES.NETJEE MAIN (ONLINE SET ~ 3) 2013 <= 0.35354 we given a=361 pm r= 0.3535 «361 = 128 pm 42. (d) Allhave tetrahedral structure. 1 43. @_Nalg)+ 702 >N20(8) N=N(@g) +Ho-0 A)N = N=60y AH,° = [Energy required for breaking of borids ] —[Energy released for forming of bonds} = (yen +Hatigg ~ (AHy.n + AHN-0) (946 4.4 x498)— (4184607) =170 kJ mol ResOnangeenergy = 170482 =88kJ mol! = [salt] @) pl=pK, + tog S41 @) pHapky + tog [cid] 1s =4.76+ log 500. 7+ log 1.5 =4.87 ‘500 Hence correct answer i§ 4,76 Phenol’ Formaldehyde OH ‘OH one ou ou Baiclite cH, (@) AT=Kym where m= molality 213-268= 186% 7 52 1.86% 5" $x32x10 1.86 = 860.2 ~ 868.06 g Crystal field splitting depends upon the nature of ligand. The nature of ligand A decreases as shown below €,0,- Br >Ch Inthe reaction w 2a05 Ataito, For the oxidationhalf-reaction APY 436° Sl no. ofelectron transfered (f) =3 AG?=—nFE° 94933296500 x E> 94010 J 3%96500 24=3V Only those aldehydes which do not have ‘-H atom undergo Cannizaro’s reaction Hence CH,CHO will not undergo Cannizaro’sreaction as it has 3 a H atoms. Office.: 606 , 6" Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0651-2562523, 9835508812, 8507613968 NEWTONCLASSES.NETR. K. MALIK'S NEWTON CLASSES cue, ae iq MOH, STC Phenol OH OH CHO From molarity equation HO, M,Vp+M,V,= MY, Salicyatidehyde_. pahyélfoxy (chief product) “benzaldehyde rainor) 53. (d)_ The bond lengthifollows the order ora) 03 £0, 403.4033 > (PaCl,}> isheisp? yb planarin shape. Aécording to thisthe possible values are 1.12A,1.21A, 1.30A, 149A Deficieiiey of vitamin D causes rickets The. species with the greatest) proton Ho affinity,yill be the strongest base, and its OCs ve conjugate acid will be the weakest acid. The [re ‘weakest acid will have the smallest value of an K, Since HI isa stronger acid than HF which gu, a is a stronger acid than HS, apartial order iKsS' 44,0 of protomafinity is et tere Elgercch dela) Singe NH, is'a very weak acid, NH,- must hee Sako ye bea very strong base) Therefore the correct Eq. wt. of opper = s S315 order of proton affinity is -XF- RNC#3KCI+3H,0 Mechanisin on CHCl, ——3™—_¢¢h, «.elimination Dichlofbearbene H Cle g, — 31.5 96500, 3hs =zit= <5 10x 60 = 0.2938; Wadit= 606) ie MATHEMATICS Loti, b, e:d be four numbers of the sequente. Now, according to the question 6 c—b=6anda—c=6 Also, given Office.: 606 , 6" Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.; 0651-2562523, 9835508812, 8507613968 NEWTONCLASSES.NETA. o @ JEE MAIN (ONLINE SET ~ 3) 2013 = @-26+ab=0 Now, c—b=6anda—c=6, 2 =>b=a-12 a? 2b? + ab=0 => @—2a- 12)? + a(a—12)=0 => @— 2g? 288+ 48a+ a2—12a=0 = 36a=288 => a=8 Hence, last terms. . Circle: x?+y?-6x+2y=0 0) Line: 2x+y=5 Ai) Centre=G,-1) Now, 2x 3—1=5,hénce centreties'@n the given line. Thefefore line passes through the centre, The given line is normal to the circle Thus sfatemeftt? istrue, but statement-L is not ffue as there fe infinite circle according tothe given conditions. Givem information is incomplete inthe question. Mid-point of PQ, 3) and Q(4, 5)=(3, 4) Slope of PQ= 1 Slope of the line L Mid-point (3, 4) lies on the line Ly Exqhation offine L., y74=- 1083) S x+y-7=0 Let image of point R(O, 0) be S(x,,.¥,) AL Mid-point of RS = ( 2) liesonltheLine (i) id) Mid-point ( y Slope of RS = => x Since RS line L 6, From (ii) and (ii), Ha =7 Hence the image of R: Given system of equations is homogeneous which is Now?| A|=[Ta(-@?)]=1 +a +0 So, system has only trivial solution. Now, |A|=0@illy when a =~ 1 So, systerfi of equatidns has infinitely many ‘solutions Whichis not possible because it is given that system has a unique solution. Hence setof all real values of ‘a’ is Consider the line, xy ‘On solving’\(i) and (iii), we get only 3 Hence (x3) is the point of/contact of coni¢(i), and line (iii) ‘On solving (ii) and (iii), we’get only x =3, p. 3} 48 also the point of contact of conic (ii) and line (ii). Hence line (iii) is the common tangent to both the given conics. (@)_Thematrices in the form a 42 je 22 Jaye 101.2}. 057-aga00 Office.: 606 , 6" Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0651-2562523, 9835508812, 8507613968 NEWTONCLASSES.NETR. K. MALIK'S NEWTON CLASSES 0 o/1/2 f 1 O/1/2 2 O/1/2 o/2 0 PLO/1/2 1 }or/2 2 At any place, 0/1/2 means 0, 1 or2 will be the element at that place, Hence thereare total 27=3 x 3+3 x3+3 3) matrices of the above form. Out of which the matrices which are singular are 0 O/1/2 Oo oljfi 1] [2 2 [007 bfire obi th 3] Hence there are total 7(= 3 + 24144) singular matrices. Therefore number of all.nonssingular ‘matrices in the’given form=27.—7= 20 Given sin-x> cos! x where x (0,11) C4 = sit! x sin“! x 2, g, Bs sif'x> A 2sintx> DS si x>% 2 4 z 1 = xo umd => 4 : Fim, Maximumivalue of sin“ x is > So, maximum value of x is 1. So, “Ce ©. (b) Lt@=ley,) AGC3, 2) Centroid, E -( oo 24) Since centroid lies on the line 3x+4y+2=0 252) -(0s }+2=0 => 3x,+4y,43=0 Hence vertex (r,,,) lies on the line Bx+4y+3=0 70. (c) Since AD is the median AQ,3,5) ic 5.0) Reig +2) p= ( Bans? 2 ) Now, dR’S of AD is =9h=7 and W10 T @ Leg=f eH Got 2x —tan2x cos2x_sin2x Now, D’=cot 2x—tan 2x= sin2x cos2x cos? 2x-sin? 2x _ 2.¢0s 4x sin2xeos2x sin 4x Office.: 606 , 6" Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.; 0651-2562523, 9835508812, 8507613968 NEWTONCLASSES.NETJEE MAIN (ONLINE SET ~3) 2013 20s? 4x.sin 4x 4, Now, we find f(a) at 2 v2 = f sin” are fear "Vi de 7 ai +cos! Vi) dt Now, ~7r.c0s 8r-+k = A cos 8x +k ant 16 72. (d) Given differential equation is (42) 24a ea? de 2x jp Required’ ® —S 2» Required integration = = Yae \iee P1 7 4 ‘This iSlinear diff. equation # @ Wehave a 3 4 ina Joes) 148 R= fx sede = [dea Fn) de Solution is 2 14x? 5 * y+x)= | Saree? ee sig [ (0) de =[ f(a +b- 9) de => +e) aie 4 3 2= Jd-») flyer > Required curve is 7A 3+) =48) (7 C0), (4P)=/0 —¥ on [-2,3) 73. (@) Consider ; 5 sin? c Rat Rae fx Spades (0-9 fo ax J sin! el dt v cos "(yr) de = = Let =/(x) after integrating and putting the = J f@ae=R, limits. S#'@)= sin" Vein? x (2 sin x €08 x)-0 +0087! feos? x (-2 cos xsin x)—0 © £@)=0 = f@)=C (constant) Office.: 606 , 6" Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0651-2562523, 9835508812, 8507613968 NEWTONCLASSES.NETR. K. MALIK'S NEWTON CLASSES ao fii and axb=|2 1 11 +3 jaxb|=Vaeas1=3 Now, | ¢ —a|=2V2 => |e -aP =8 +29 4 =>|e-a|.(c -a)=8 +, 4% => |cP+|aP 2c.a=8 =| of +942] el] =8 (je |? =05 |e >, -— 1 M(Qx 1) € | =)axb | 6 (sin 30° = 31 16. (©) p> © pq) has truth value F. Itmeans p> (+p v q)is false. It means p is trae and ~p v q is false. => pistrueand both ~ pandg are false, = pisiitieand gis false Sirige events andB are mutually exclusive *. P(A)+P(B)=1 3x+1 3 => 12kt 443 3x= 12 => 9x=5 pis “ [$5] Equation of a plane through the line of intersection of the planes x+2y=3,y-22+ 1=0is (x+2y-3)+2.(y-22+1)=0 S>xt(2+Qy-2AG)-3 +2=0 @ Sux=8 9 80, ©) Now, plane (i) is L tox +2y=3 Their dot product is zero 1+22+2)=0 => Thus, required plane is Expansion of (1 +X)?" is 1 +°C,x+"C,x? Me ne + PC TREC NG sare + AC IH As giveni@#C,,. =21C,, nyt Qn)! = (FFD! Qn-r-2)! Gr) \(2n-3! Gr)! 2n—-370S+ 2)! 2n -r-2)! (1) Now, put value of fromthe given choices. Choice (a) put n= 2r+ 1 in (1) LHS: Gr) ! 4r-#2—37) !=(3r) (#2)! RUS 273) 1(3/)! Let sae be the root of required quadratic oqiation. Hence, required quadratic equation is 2 (2 )sea=0 = P42 xtq=0 > getpxtg=0 q Office.: 606 , 6" Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.; 0651-2562523, 9835508812, 8507613968 NEWTONCLASSES.NETJEE MAIN (ONLINE 4 81. (@) Volume of sphere V aie 2 dr 35 = 40? iw? or Surface area of sphere = S= 4x7? ds So gnxrrx ase & dt a de a) dt Now, diameter #14 om, r=7 ds, a 82 (b)_LetA={0:sin0=tan0} and B= {80s 071} (Byusing (1) 10 _ sin 8 Now, Reafpsino cos 0. = {0: sin 0(c030—1)=0} = 0, 276, Hern} For B:cos 0=1\ => 0 = 2m, 4m Thisshowslthat A isnot contained in Bhi.e. AGB. butBeA. (b) \Let2= x +iy, Now, tan 0= Bot 22 (4ve since only principal argument) ” (Gis the argument) SET — 3) 2013, fi = tan“! V3 == ai Hence, zis not a real number So, statement-1 is false and 2 is true. Let (x) =[x]+| 1x], —1 x3 where [x] = greatest integer functi ‘Fis not continuous atx =0, 1,2,3 But in statement-2 f(x) is continuous at Hence, Statement-1 is true and 2 is false. Given f(1)=—2and f"(x)2 4.2 for 1< x<6 LPS) h SL + ELSI"). 4.2h So, fet h)27)+(4.2)h put.x= 1 and h = 5, we get, S(6)2f(1) + 5(4.2E> F(G)> 19 Hence f(6) liesin [19, <0) Clearly mean 40 Consider ((@)= D(x+ A)? Now, standard deviation 6 = in a =lal Henee, |a|2 Gotisider 12 + 3745? + n sera, = (2n—%, +252 13 xB Now,$;= > Ty =) (2n-1)? mln BoB 42+ PY 1-)) an =4) 413-4> 0 Office.: 606 , 6" Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0651-2562523, 9835508812, 8507613968 NEWTONCLASSES.NETR. K. MALIK'S NEWTON CLASSES = o{aeet cee) yg ne Put n= 13, we get S,=26% 149+ 13-26% 14 = 3276+ 13-364 =2925. Let y= cos (x+y) a —sin (x+y) [142 sin (x of *) Now, given equation of tangent is x+2y=k Total no, of ways = 5! = 120 Since all numbers are> 20,000 all numbers 2, 3, 5, 7,9 can come at first Total no. of ways =3 4! =72 (c: 2.and9 can not be put at first place) So.P:q=120272=5:3 Given ellipse is4x? P9y?=36 2 SOF Normal at the point is parallel to the line 4x—2y-3%0 Slope ofnormial=2 Slope of tangent = Office.: 606 , 6" Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.; 0651-2562523, 9835508812, 8507613968 NEWTONCLASSES.NET