Organic Chemistry - Naming: Chapter - 14

Brilliant STUDY CENTRE REPEATERS CHEMISTRY -2021 (ONLINE CLASS NOTES)
CHAPTER - 14
ORGANIC CHEMISTRY - NAMING
The word organic signifies life - ie, compounds directly or indirectly derived from living beings.
Berzelius - Vital force theory

Organic compounds are produced only under the influence of some mysterious force existing in living
beings, such a force cannot be created artificially in laboratories.
In 1828 - Wohler discovered urea by heating an inorganic compound.
NH4CNO 

NH2  CO  NH2
Later Kolbe synthesis acetic acid
Berthelot synthesised methane and acetylene
Thus vital force theory was rejected and it was shown that organic compounds should be synthesised
from inorganic source.
Organic chemistry
It is the study about carbon and its compounds or hydrocarbons and their derivatives.
Hydrocarbon classsification
On the basis of nature of carbon skelton
1. Acyclic or open chain compounds
2. Cyclic or closed chain compounds
I. Acyclic or open chain compounds
Compounds containing open chains of carbon atom in their molecule. It may be straight or
branched. These are also known as aliphatic compounds. Further divided into
 Saturated hydrocarbon or alkanes or paraffins
Compounds containing carbon carbon single bond (C–C)
 Unsaturated hydrocarbon
 Alkenes or Olefins - Containing C = C
 Alkynes or Acetylene - Containing C  C
1
II. Cyclic or closed chain compounds
Compounds containing one or more closed chains or rings of atom
Further divided into
a. Homocyclic :
Rings which are made up of only one kind of atom. Mainly C atom- known as carbocyclic.
i. Alicyclic compounds.
Rings containing 3 or more carbon atom
CH2 CH2 CH2
CH2 CH2 CH2 CH2
ii. Aromatic compounds.

From the greek word Aroma - Fragrant smell
a. Benzenoid aromatic compounds
Aromatic compounds containing one or more fused or isolated benzene rings.
OH CH3
Benzene
Phenol Toluene
Fused Isolated
Naphthalene Biphenyl
Anthracene Ter-phenyl
2
b. Non-benzenoid aromatic compound
Compounds that does not contain benzene ring but contain other highly unsaturated rings.
O O
OH
Tropone Tropolone
Heterocyclic compounds
Cyclic compounds containing one or more hetero atom in their rings.
a. Alicyclic heterocyclic
Aliphatic cyclic compounds containing one or more hetero atom
O N
Oxirane Tetra hydro furan H
Tetra hydro pyrrole
b. Aromatic heterocyclic
Aromatic cyclic compounds containing one or more hetero atom.
O N S N
Furan Thiophene Pyridine
H
Pyrrole
3
Hydrocarbon
Acyclic Cyclic
Saturated Unsaturated Homocyclic Heterocyclic
Alicyclic Aromatic
Alkene Alkyne
Benzenoid Non-benzenoid
Fused Isolated
Alicyclic
Aromatic
Nomenclature
System of naming
 Trivial system
 IUPAC system
TRIVIAL SYSTEM
Also known as common names.
For representing saturated hydrocarbon mainly 3 prefixes are used.
1. n
n - stands for normal or straight chain
CH 3 CH 2 CH 2 CH 3 CH3 CH2 CH2 CH2 CH3

n-butane n-pentane
4
2. Iso
The second carbon containing one methyl group
CH3 CH3
CH3 CH CH3 CH3 CH CH2 CH3

Iso-butane Iso-pentane
3. Neo
Second carbon atom containing 2 methyl group
CH3 CH3
CH3 C CH3 CH3 C CH2 CH3
CH3 CH3
Neo-pentane Neo-hexane
Saturated hydrocarbon contains 4 types of carbon atoms.
CH3 CH3
CH3 C CH CH2 CH3
CH3
Quarternary
30 20 10
Alkane 
H
 Alkyl
CH 
4
H
 CH3 - Methyl
methane
CH3  CH3 

H
 CH3  CH2 - Ethyl
CH3  CH2  CH3 

H
 CH3  CH2  CH2 - Propyl
CH3  CH2  CH3 

H
 CH3 CH CH3 - Iso-propyl
CH3 CH3
CH3 CH CH3 

H
 CH3 CH CH2 - Iso-butyl
CH3 CH3
CH3 CH CH3 

H
 CH3 C CH3 - Tert-butyl
5
IUPAC SYSTEM
In 1892 an International Chemical Congress was held at Geneva, they started a new naming
system for organic compounds known as Geneva system of Nomenclature. This system was further
modified as IUPAC nomenclature.
Rules
Each systematic name contain
 Word root;  Suffix;  Prefix
Word root :
It denote no.of carbon atoms in the parent chain.
Primary suffix
It shows saturation or unsaturation in a chain
Nature of C-chain 1° suffix 2° suffix
C–C –ane Alkane
C=C –ene Alkene
CC –yne Alkyne
2C = C –adiene Alkadiene
2C  C –adiyne Alkadiyne
Secondary suffix
It indicates the presence of a particular group (functional group)
Functional group 2° suffix
Alcohol –ol
Aldehyde –al
Ketone –one
Primary prefix
It is used to distinguish cyclic from acyclic compound. In case of carbocyclic compound, 1°
prefix cyclo is used.
Secondary prefix
It denote the presence of substitutent or side chain on the parent chain.
–X halo
–NO2 Nitro
–R Alkyl
–OR Alkoxy
The complete IUPAC name of compound contain:
2° prefix + 1° prefix + word root + 1° suffix + 2° suffix
Eg : 2-methyl butanoic acid  Methyl  2° prefix : but - word root : an  1° suffix : oic acid-2° suffix
6
NAMING OF COMPLEX COMPOUNDS
 Longest chain rule
Select the longest continuous chain of carbon atom in the molecule. The continuous chain of carbon
atom is called parent chain or main chain. Carbon atom which are not included in the parent chain are
considered as substituent or side chain.
CH3
Derivative of pentane
CH3 CH2 CH CH2 CH3
 Two or more carbon chains of equal length, then the selected chain should contain maximum no.of
side chain or substituent.
CH3
CH3
CH3 C CH3
H3C C CH3
CH3 CH2 CH CH2 CH3 CH3 CH2 CH CH2 CH3
1- side chain 3- side chain (correct way)
CH3
CH3 CH CH2
CH CH CH3
CH3 CH CH3
CH3
Derivative of heptane
 Numbering of carbon chain

The carbon atoms of longest continuous chains are numbered. The no that indicate the position
of substituent is known as Locants.
The carbon atom carrying first substituent get the lowest possible locants.
1 2 3 4 5
CH3 CH CH2 CH2 CH3 2-Methylpentane (correct); 4-methyl pentane (wrong)

3 2 1
5 4
CH3
7
Two or more similar substituent is attached to the parent chain, lowest set of locant is preferred. The
lowest set is determined by first point of difference rule. The rule says “when two or more different
set of locants containing same no.of term is possible, then the set of locants is compared term by
term with other set, each set in order of increasing magnitude. The set of locant is preferred which
has a lower no.at the first point of difference”.
6 5 4 3 2 1
1 2 3 4 5 6
CH CH2 CH CH CH3 CH3 CH CH2 CH CH CH3
CH3
CH3 CH3 CH3 CH3 CH3 CH3

(2, 3, 5) lowest set
(2, 4, 5) 2,3,5-Trimethyl hexane
 If there are different alkyl substituents attached to the parent chain, their names are written in
alphabetical order.
1 2 3 4 5
CH3 CH CH CH2 CH3 - 3-Ethyl-2-methyl pentane
CH3 CH2 CH3
 If there are different alkyl substituent at equivalent positions the numbering is done in such a way that
the substituent which comes first in alphabetical order get lowest possible number.
1 2 3 4 5 6
CH CH2 CH CH CH
2 2
CH3 3-Ethyl-4-methylhexane
6 3 5 4 3 1
CH3 CH2 CH3
Naming of complex alkyl substituents

If the substituent on the parent chain is a complex, the carbon atom of this group attached to the
parent chain is given as 1.
1 2 3 4 5 6 7
CH3 CH2 CH2 CH CH2 CH2 CH3 4- (1-methyl ethyl)heptane
or
1 CH CH3 4-isopropyl heptane
2 CH3
8
1 2 3 4 5 6 7 8 9
CH3 CH2 CH2 CH2 CH CH2 CH2 CH2 CH3 5- (2-methylpropyl)nonane
or
1
CH2 5-isobutyl nonane
2 CH CH3
3 CH
3
 While deciding the alphabetical order of various substituents, the name of complex substituent is
considered to begin with first letter of complex name.
1 2 4 5 6 7 8 9 10 11
3
CH2 CH2 CH CH2 CH CH2 CH2 CH2 CH3
CH3 CH2
1 CH CH3 CH2 CH3
2 CH CH3 5-(1, 2-Dimethyl propyl)-7-ethylundecane
3 CH
3
CH3
1 2 3
H3C C CH2 CH3
1 2 4 5 6 7 8 9
3
CH3 CH2 CH2 CH2 C CH2 CH2 CH2 CH3
CH2 CH
2
CH3
1 3
CH3
5-(1, 1-Dimethyl propyl)-5- (2-methylpropyl)nonane
9
 If two complex substituents are of equal length, then the complex substituent with larger no.of alkyl
group form a part of longest carbon chain while the other one considered as complex substituents.
CH2 CH3
6 5 1 2 3
10 9 8 7 4
CH3 CH2 CH2 CH2 CH2 CH CH2 CH CH2 CH3
4 CH2
H3 C 3C
CH3
CH2 CH3
2 1
5-(2-Ethylbutyl)-3,3-dimethyldecane
 If same complex substituent occur more than once prefix such as bis(2), tris(3), tetra kis (4)..... etc
are used before the name of complex name.
CH3
CH CH3
6 5 4 2 1
3
CH3 CH2 CH2 C CH CH3
CH3
H3C CH
CH3
2-methyl-3,3-bis(1-methylethyl) hexane
Naming of unsaturated compound

 Longest chain of carbon atom is selected to included the double or triple bond, even if it is not the
actual longest chain
6 5 4 3 2 1
CH3 CH2 CH2 CH CH CH2
CH2 CH2 CH3
10
 If more than one double or triple bond is present in the molecule, the selected chain should contain
maximum number of such bonds.
7 6 5 4 3 2 1
CH3 CH CH CH2 CH CH CH2
CH2 CH2 CH3
 The parent chain is numbered in a manner to give lowest number to that carbon atom linked by a
double or triple bond.
CH3 CH3
CH3 CH CH CH CH2 CH CH3

1 2 3 4 5 6 7
4,6-Dimethyl hept-2-ene
 If a compound contains both double or triple bond, such compounds are named as Alkenynes.
5 4 3 2 1
CH3  C  C  CH  CH2 Pent-1-en-3-yne
5 4 3 2 1
CH  C  CH2  CH  CH2 Pent-1-en-4-yne
5 4 3 2 1
CH3  CH  CH C  CH Pent-3-en-1-yne
6 5 4 3 2 1
CH  C  CH  CH CH  CH2 Hexa-1,3-dien-5-yne
In some cases all the double and triple bond are not included in the parent chain, in such cases,.......
CH2   Methylene CH2  CH   vinyl/ ethenyl
CH3  CH   Ethylidene CH  C   Ethynyl

are used
CH2
1 2 3 4 5
CH2 CH C CH CH2
3-Methylene penta-1,4-diene
11
Naming of compounds containing one functional group.

 Longest chain
The selected parent chain should be the one containing functional group.
CH3 CH2 CH2 CH CH2 CH3
CH2 OH
 Numbering of carbon chain

The carbon linking to functional group get the lowest possible number.
When a chain terminating group such as –CHO, –COOH, –COOR, –CONH2, –CN are present as
functional group it must be assigned as number 1.
 The last ‘e’ of the 1° suffix is dropped and the secondary suffix corresponding functional group is
added.
 Numerical prefix like di, tri, tetra etc are attached before the suffix name if the same functional group
occur more than once.
Alkyl halide
R–X CN : Alkyl halide
IUPAC : Haloalkane
CH3  CH2  Br  Ethylbromide ; Bromoethane
CH3
CH3 CH Cl  Isopropyl chloride : 2-chloropropane

Alcohol
R–OH CN : Alkylalcohol
IUPAC : Alkanol
CH3 -OH  Methanol; Methylalcohol

CH3 -CH2 -CH2 -OH  Propanol; Propylalcohol
Ether
R–O–R CN : Dialkylether
IUPAC : Alkoxy alkane
CH3  O  CH3  Dimethyl ether CH3  O  C2H5  Ethyl methyl ether

Methoxy methane  Methoxy ethane
12
Carboxylic acid
–COOH
CN : Obtained from the source from which they were isolated or present in large quantity.
IUPAC : Alkanoic acid
H  COOH  Formic acid CH3COOH  Acetic acid

Methanoic acid Ethanoic acid
CH3CH2COOH  Propionic acid CH3CH2CH2COOH  Butyric acid

Propanoic acid Butanoic acid
Aldehyde
- CHO
CN : Replace the terminal -ic acid in corresponding acid by aldehyde
IUPAC : Alkanal
H – CHO  Formaldehyde ; Methanal
CH3CHO  Acetaldehyde ; Ethanal
Ketone
C
CN : Dialkylketone
IUPAC : Alkanone
CH3 – CO – CH3  Dimethyl ketone (Acetone) ; Propanone
Amine
–NH2
CN : Alkylamine
IUPAC : Alkanamine
NH2
CH3 -NH2  Methyl amine CH3 CH CH3 : Isopropylamine

Methanamine Propan-2-amine
CH3  NH  CH3  N  methylmethana min e
CH3 CH2 N CH3  N,N-Dimethyl ethanamine
CH3
13
Amide
C NH2
CN : replace -ic acid by amide

IUPAC : Alkanamide
H C NH2  Formamide : Methanamide
CH3 CH2 C NH CH3  N-Methylpropanamide
Acid halide
C X
CN : Replace -ic acid by -yl halide
IUPAC : Alkanoyl halide
H C Cl  Formyl chloride : Methanoyl chloride
O
 Acetyl chloride : Ethanoylchloride
CH3 C Cl
Acid anhydride
O O
C O C CN : Replace acid by anhydride; IUPAC : Alkanoic anhydride
O O
H C O C H  Formic anhydride : Methanoic anhydride
O O
CH3 C O C CH3  Acetic anhydride : Ethanoic anhydride
14
O O
H C O C CH3  Acetic formic anhydride : Ethanoic methanoic anhydride
Ester
C O
CN : Replace - ic acid by ate
IUPAC : Alkyl alkanoate
H C O CH3 : Methyl formate : Methylmethanoate
CH3 C O CH3 : Methylacetate : Methylethanoate
Naming of compounds containing more than one functional group

A compound containing more than one functional group or more than one multiple bond is considered
as poly functional compounds.
In such compounds one functional group is considered as principal functional group and others are
substituents. The principle functional group is mentioned by its suffix name and substituent is mentioned
by its prefix name
Rules
 Select the principal functional group
 Select the parent chain, it include principal functional group (PFG)
 Numbering the chain, PFG get lowest possible number.
Numbering preference order PFG      substituent
15
Functional group Prefix name Suffix name
COOH Carboxy -oic acid
 SO 3 H Sulpho Sulphonic acid
O O
- -oic anhydride
C O C
O
Alkoxy carbonyl -oate
C O R
O
Halocarbonyl -oyl halide
C X
O
Carbamoyl -amide
C NH 2
CN Cyano -nitrile

O
Formyl -al
C H
O
Keto/oxo -one
C
Hydroxy -ol
OH
SH Mercapto thiol
NH 2 Amino -amine
C  C  - alkene
- alkyne
C  C 
R Alkyl -
 OR Alkoxy carbonyl -
 NO 2 Nitro -
 NO Nitroso -
N  N  Diazo -
16
CH3 CH C COOH
4 3 2 1 3-Methyl-2-oxobutanoic acid
CH3
4 3 2 1
CH2 CH2 CH CONH2

2-Fluoro-4-hydroxy butanamide
OH F
3 2 1
NC CH2 CH2 COOH 3-Cyano propanoic acid
O NH 2
CH3 C CH CH COOH
5 4 3 2 1 2-Amino-3-hydroxy-4-oxopentanoic acid
OH
Poly functional compounds containing more than two like functional group
If an unbranched carbon chain is directly linked to more than two like functional group, the
compound is named as the derivative of parent alkane, the carbon atoms of like functional group do
not include in the numbering, in such case suffix like Tricarboxylic acid (3COOH), Tricarbaldehyde
(3CHO), Tricarbonitrile (3CN) etc are used.
COOH CHO
3 2 1
CH2 CH CH2 CH2 CH2 CH CH2
1
4 3 2
COOH COOH CHO CHO
Propane-1,2,3-tricarboxylic acid Butane-1,2,4-tricarbaldehyde
COOH OH COOH
CH2 C2 CH2
3 1
COOH
2-Hydroxy propane-1,2,3-tricarboxylic acid
If more than 2 like functional group is not directly linked to the carbon chain, then the carbon
atoms of functional group directly attached to the parent chain is included in numbering, the other one
is considered as substituent group.
17
4 3 2 1
CH2 CH CH2 COOH
COOH CH2 COOH

5
3-(carboxymethyl)-pentane-1,5-dioic acid
1
7
CHO CHO
5 4 3 2
6
CH2 CH2 CH CH2 CH2
CH2 CHO
4-(Formylmethyl)heptane-1,7-dial
4-(2-oxoethyl)heptane-1,7-dial
Naming of alicyclic compound

 Cycloalkane
Names obtained by adding the prefix ‘cyclo’ before the name of a corresponding alkane.
Cyclopropane Cyclohexane
Alkyl substituted cycloalkane are known as “alkylcycloalkane”.

If same substituents are more than one is present numerical prefix di, tri, tetra, etc are used.
If different substituents are present their names are written in alphabetical order. Numbering is done in
such a way that substituent which comes first in alphabetical order get lowest possible number.
Numbering does not violate lowest set of locant rule.
CH3
CH2 CH3
1
2
3
CH3
Ethylcyclopentane 1,3-Dimethyl cyclohexane
18
CH3
3 1
2 2
1 3
CH2 CH3
1-Ethyl-3-methyl cyclopentane 3-Ethyl-1,1-dimethyl cyclopentane
CH3
1
C2H5
2
3
4
CH3
2-Ethyl-1,4-dimethyl cyclohexane
The ring containing more or equal number of carbon atom than alkyl group, then the compound is
named as derivatives of ring.
CH2 CH2 CH3

CH2 CH2 CH3
Propyl cyclobutane Propyl cyclopropane
If the side chain contains more no.of carbon atom than the ring, compound is derivative of side chain.
1
CH3
1 2 3 4 5
CH3 CH CH2 CH2 CH3 2
CH CH2 CH3
3 4
2-Cyclobutyl pentane
2-Cyclopropyl butane
19
If more than one alicyclic ring is directly attached to the parent chain, compound is derivative of parent
chain.
CH2
2
Dicyclopropylmethane
1,2-Dicyclohexyl ethane
Cycloalkene and cycloalkyne

Adding the prefix cyclo before the name of the corresponding alkene or alkyne.
Cyclopentene Cyclohexyne
In case of substituted cycloalkene and cycloalkyne the number of double and triple bond get lowest
possible number 1 and 2 and the substituent get lowest possible no at first point of difference rule.
CH3
3 Cl
2 3
1 1 2
3-Chlorocyclopentyne
3-Methylcyclohexene
Alicyclic compounds containing functional group

Alicyclic alcohol, amines, ketones ....... are named as corresponding aliphatic compounds by
prefixing the word cyclo.
OH
NH2
O
Cyclohexanamine Cyclopentanone
Cyclopentanol
If an alicyclic ring is directly attached to a carbon containing functional group, the carbon atom of the
functional group is not included in the parent chain. In such cases following suffix and prefix are used
20
Functional group Prefix Suffix
–COOH Carboxy Carboxylic acid
–CHO Formyl Carbaldehyde
–COX Halocarbonyl Carbonylhalide
–CN Cyano Carbonitrile
–CONH2 Carbamoyl Carboxamide
–COOR Alkoxy carbonyl Alkylcycloalkane carboxylate
COOH
CHO
CONH2
Cyclohexane carboxylic acid Cyclopentane carboxamide Cyclobutane carbaldehyde
If a ring containing a multiple bond and the side chain containing functional group, then the
compound is derivative of side chain.
3 2 1
CH3 CH CH2 OH
1
2
3
2-(Cyclopent-3-enyl) propanol
If the ring and side chain contains functional group then the compound is named as derivatives
of ring or side chain which will contain principle functional group.
4 3 2 1
4
HO CH2 CH2 CH2 COOH
1
3 2
4-(4-Hydroxycyclohex-2-enyl)butanoic acid
If the ring and side chain contains some functional group, the compound is named as a derivative
of side chain or the ring, which containmore number of carbon atom.
OH
7 6 1
OH 2
CH2 CH3 OHe 3 1 CH2 CH2 CHO
1
2 CH2 CH 3 4
5
1 2
7-(3-Formylcyclopentyl)heptanal
2-(2-Hydroxybutyl)cyclohexanol
21
Nomenclature of Aromatic compound
Compounds are derivatives of benzene. The names are obtained by “substituent name + benzene”.
Most of the compounds have typical names.
CH3 OH
Methylbenzene (Toluene) Hydroxybenzene (phenol)
NH2 Cl
Aminobenzene (Aniline) Chlorobenzene
NO2
Nitrobenzene Cyclopropyl benzene
Special case
CHO
COOH
Benzene carboxylic acid

Benzene carbaldehyde
(Benzoic acid)
(Benzaldehyde)
CONH2 COX
Benzene carboxamide Benzene carbonyl halide

(Benzamide) (Benzoylhalide)
22
 If more than one substituents are present names are written in alphabetical order
 If any of the substituent give a special name to the compound, then compound is derivative of that
special name.
 Numbering does not violate lowest set of locant rule.
Cl
1
2
1-Chloro-3-nitrobenzene
3
NO2
Br
3
2
1 3-bromo toluene, (m-bromotoluene)
CH3
(The position number is indicated in IUPAC system but position name is indicated in common system)
NH2 CH3
4 2
OH
3 4-Amino phenol 1 2-Methyl phenol
1
2 p-Amino phenol o-methyl phenol
OH
OH
COOH
2-Hydroxybenzoic acid
o-hydroxy benzoic acid (salicylic acid)
If benzene ring is attached to an aliphatic chain containing a multiple bond or functional group or
substituent, benzene ring is considered as a substituent group known by phenyl.
3 2 1
CH2 CH CH2
3-Phenyl prop-1-ene
23
5
CH3
2 1
4 3
CH CH CH2 COOH
OH
3-Hydroxy-4-phenylpentanoic acid
Naming of bicyclo compound

Two rings having two common carbon atoms are called bicyclo compound. The common carbon
atom is known as bridge head carbon, the carbon chains connecting each bridge head carbon is
known as bridges.
Bridge head carbon (BHC)
Bridges BHC
Numbering of carbon atom

i. Start with one of the BHC (given 1)
ii. Proceed along longest chain to 2nd BHC
iii. No. the 2nd BHC and proceed to 1st BHC through next longest chain
iv. Pass over 1st BHC and proceed along the shortest chain to 2nd BHC
The name start with prefixing the word ‘Bicyclo’.
The carbon atoms in each bridge is indicated in arabic numberals in descending order, enclosed in a
square bracket. Separated one another by using dots, before the name of parent alkane.
2 8
7
Bicyclo [3.2.1]octane
6
3 5
2 7
6
Bicyclo [3.1.1]heptane
3 5
4
24
2 6
Bicyclo [2.2.0] hexane
3 5
2 10
1
3 9
Bicyclo [4.4.0] decane
4 8
6
5 7
1 9
3
8
CH3 8-Methylbicyclo[4.3.0]nonane
4
6 7
5
2
OH
4
5 8 Bicyclo [2.2.2] octan-2-ol

1
7
6
Bicyclo [3.2.1] octane-8-carboxylic acid

COOH
Naming of spiro compounds

2 rings have 1 common carbon atom
i. Numbering starts with carbon atom adjacent to common carbon, proceed 1st along shortest chain
then to longest chain through common carbon.
 Name start with prefixing the word spriro.
25
 Number of carbon atom in each ring enclosed in a square bracket in ascending order, separate one
another by using dots, before the name of corresponding alkane
5 4
3 Spiro [2.3] hexane
6 1
9
10
8
1
5 Spiro [4.5] decane
7 2
6
4
3
Cl
2 1
3
6
1-Chloro spiro [4.4] nonane
4 5 7
9
8
Naming of epoxide
 These are cyclic ether
1. CH2 CH2
O Epoxy
1,2-Epoxy ethane (Oxirane)
3 2 1
2. CH3 CH CH2
O
1,2-Epoxy propane (Methyloxirane)
2 3
3.
1 4
O
1,4-epoxy butane
26

Organic Chemistry - Naming: Chapter - 14

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Brilliant STUDY CENTRE REPEATERS CHEMISTRY -2021 (ONLINE CLASS NOTES)

Berzelius - Vital force theory

CH2 CH2 CH2

CH2 CH2 CH2 CH2

ii. Aromatic compounds.

Saturated Unsaturated Homocyclic Heterocyclic

CH 3 CH 2 CH 2 CH 3 CH3 CH2 CH2 CH2 CH3

CH3 CH CH3 CH3 CH CH2 CH3

CH3 C CH3 CH3 C CH2 CH3

Saturated hydrocarbon contains 4 types of carbon atoms.

CH3 C CH CH2 CH3

CH3  CH3 

CH3  CH2  CH3 

CH3  CH2  CH3 

CH3 CH CH3 

CH3 CH CH3 

CH3 CH2 CH CH2 CH3 CH3 CH2 CH CH2 CH3

1- side chain 3- side chain (correct way)

 Numbering of carbon chain

CH3 CH CH2 CH2 CH3 2-Methylpentane (correct); 4-methyl pentane (wrong)

CH3 CH3 CH3 CH3 CH3 CH3

CH3 CH2 CH3

CH3 CH2 CH3

Naming of complex alkyl substituents

2 CH CH3 5-(1, 2-Dimethyl propyl)-7-ethylundecane

Naming of unsaturated compound

CH3 CH2 CH2 CH CH CH2

CH2 CH2 CH3

CH2 CH2 CH3

CH3 CH CH CH CH2 CH CH3

CH2   Methylene CH2  CH   vinyl/ ethenyl

CH3  CH   Ethylidene CH  C   Ethynyl

Naming of compounds containing one functional group.

CH3 CH2 CH2 CH CH2 CH3

 Numbering of carbon chain

CH3  CH2  Br  Ethylbromide ; Bromoethane

CH3 CH Cl  Isopropyl chloride : 2-chloropropane

CH3 -OH  Methanol; Methylalcohol

CH3  O  CH3  Dimethyl ether CH3  O  C2H5  Ethyl methyl ether

H  COOH  Formic acid CH3COOH  Acetic acid

CH3CH2COOH  Propionic acid CH3CH2CH2COOH  Butyric acid

CH3 -NH2  Methyl amine CH3 CH CH3 : Isopropylamine

CH3  NH  CH3  N  methylmethana min e

CH3 CH2 N CH3  N,N-Dimethyl ethanamine

CN : replace -ic acid by amide

H C NH2  Formamide : Methanamide

CH3 CH2 C NH CH3  N-Methylpropanamide

H C Cl  Formyl chloride : Methanoyl chloride

C O C CN : Replace acid by anhydride; IUPAC : Alkanoic anhydride

H C O C H  Formic anhydride : Methanoic anhydride

CH3 C O C CH3  Acetic anhydride : Ethanoic anhydride

H C O C CH3  Acetic formic anhydride : Ethanoic methanoic anhydride

H C O CH3 : Methyl formate : Methylmethanoate

CH3 C O CH3 : Methylacetate : Methylethanoate

Naming of compounds containing more than one functional group

Numbering preference order PFG      substituent

Functional group Prefix name Suffix name

COOH Carboxy -oic acid

 SO 3 H Sulpho Sulphonic acid

CN Cyano -nitrile

SH Mercapto thiol

NH 2 Amino -amine