UNIVERSIDAD NACIONAL DEL CENTRO DEL PERÚ

FACULTAD DE INGENIERÍA QUÍMICA

Departamento Académico de Ingeniería Química

EP INGENIERÍA QUÍMICA
EP INGENIERÍA QUÍMICA INDUSTRIAL
EP INGENIERÍA QUÍMICA AMBIENTAL
EP INGENIERÍA QUÍMICA DEL GAS NATURAL Y ENERGÍA

PRUEBA OBJETIVA 3 (PO3)

ASIGNATURA: ANÁLISIS INSTRUMENTAL CÓDIGO: .................

SEMESTRE: ……… SECCIÓN: ……. FECHA: …… / Agosto / 2021

Apellidos y Nombres: .......................................................................

Código:...............................................Duración: 30 minutos.

INSTRUCCIONES: Lee detenidamente las siguientes preguntas y resuelve en forma ordenada.

1. Chromatography is a physical method that is used to separate and analyse

a) Simple mixtures
b) Complex mixtures
c) Viscous mixtures
d) Metals

2. In which type of chromatography, the stationary phase held in a

narrow tube and the mobile phase is forced through it under pressure?

a) Column chromatography
b) Planar chromatography
c) Liquid chromatography
d) Gas chromatography

3. In chromatography, the stationary phase can be supported

on a solid.

a) Solid or liquid
b) Liquid or gas
c) Solid only
d) Liquid only

4. In chromatography, which of the following can the mobile phase be

made of?
a) Solid or liquid
b) Liquid or gas
c) Gas only
d) Liquid only

5. Which of the following cannot be used as adsorbent in Column

adsorption chromatography?

a) Magnesium oxide
b) Silica gel
c) Activated alumina
d) Potassium permanganate

6. Which of the following types of chromatography involves the

separation of substances in a mixture over a 0.2mm thick layer of an
adsorbent?

a) Gas liquid
b) Column
c) Thin layer
d) Paper

7. Chromatography cannot be used to purify volatile substances.

a) True
b) False

8. In Column chromatography, the stationary phase is made of _

and the mobile phase is made of

a) Solid, liquid
b) Liquid, liquid
c) Liquid, gas
d) Solid, gas

9. Chromatography cannot be used to separate delicate products.

a) True
b) False

10. In Thin layer chromatography, the stationary phase is made of

_ and the mobile phase is made of _

a) Solid, liquid
b) Liquid, liquid
c) Liquid, gas
d) Solid, gas

11. In which of the following type of paper, chromatography does the mobile
phase move horizontally over a circular sheet of paper?
a) Ascending paper chromatography
b) Descending paper chromatography
c) Radial paper chromatography
d) Ascending – descending chromatography

12. Liquid chromatography can be performed in which of the following

ways?

a) Only in columns
b) Only on plane surfaces
c) Either in columns or on plane surfaces
d) Neither in columns nor on plane surfaces

13. Gas chromatography can be performed in which of the following ways?

a) Only in columns
b) Only on plane surfaces
c) Either in columns or on plane surfaces
d) Neither in columns nor on plane surfaces

14. In Gas-liquid phase chromatography, the stationary phase is

composed of and the mobile phase is made of

a) Solid, liquid
b) Liquid, liquid
c) Liquid, gas
d) Solid, gas

15. Which of the following types of chromatography involves the process,

where mobile phase moves through the stationary phase by the influence
of gravity or capillary action?

a) Column Chromatography
b) High Pressure Liquid Chromatography
c) Gas Chromatography
d) Planar Chromatography

(20 PUNTOS)
DATOS: T = I/Io = 10-abC; AT = A1 + A2 + A3 + ...... + An; A = –log(T) = abC;
Cx = Ax (CP/AP); A = b + mVs; Cx = (bCS/mVX); E = h; C = ; ppm = mg/L.
Creal = (Cleída )( fd); h = 6,63x10-34 Js; k = 1,38x10-23 N j Pj E
 e( );
J/K;

S  mC  Sbl No Po kT
 
2(t )  (t )  m Sm  Sbl  kSbl
_ 2 2
SS S m2S
YYXX
RB RA
X); N2
RS  ; SXX  ( Xi SYY  (Yi  Y ) ; Sr  ;
wA  wB
S R t  2
S r ; S  S  Xi 2 
;dX
X ; N  16   ; s  d 2 ;
m b r i i i
SXX
NX2  ( X )2 w N 1
i i
L (R ) s (t ) (R )2 Exx
H  ; S nuevo
 Nnuevo ; RSD  ; R nuevo S nuevo 2 ; a t
N (RS )viejo X (tR )viejo (RS viejo
)
 t 2 Nviejo
X tt (t )  t K
N  5,54  R  ; X  ;  i
K´ ( R N
)  ; A
 B, A  R B M ;
 w1/ 2  N ; (tR )A  tM KB
tM
y  a  b  c; S  2 2 Sa
S;  S 2  S ;y  a x Sy  Sa  log a; S  0,434 ;
 
y a b
x ; y 10 y
c y  a a

y  antilog a; Sy Sy
 2,303S ; y  a x b   S 2  S 2  S 2 ;
10 a
; ab  c
y c y  a  b  c 
SS  t  2
S
Cm  m ; N  16 w ; Sm 
R
bl
1 J  6,1018 eV ; y  a  bx ;
m   ; N
3S 10Sb z
LOD  b ; LOQ  ; LC para   x  z ; LC para   x  ;
b b N

N1  N2  Nnt 
 i
(x1 2 x )(x j2 x ) 2  ..... (x
j 1
 x pnt
)2 S
S ponderada 
p1
i1
; CV   x 100% ;
N1  N 2  nt x

S
 x 
2
i
(x i )2/ N
;
N1

Nivel de z Nivel de z
Confianza (%) Confianza (%)
50 0,67 96 2,00
68 1,00 99 2,58
80 1,29 99,7 3,00
90 1,64 99,9 3,29
95 1,96