SUPERVISED ADVANCE

TEST - 38
Time: 3 Hours Maximum Marks : 180
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.

QUESTION PAPER FORMAT AND MARKING SCHEME :

NSTRUCTED TO DO SO BY THE INVIGILATOR

7. The question paper has three parts: Mathematics, Physics and Chemistry. Each part has two sections.
8. Each section as detailed in the following table :

Category-wise Marks for Each Question Maximum

Number of
Section Question Type Marks of the
Questions Negative
Full Marks Partial Marks Zero Marks Section
Marks
+3
0 –1
Single digit Integer If only the bubbles
1 11 – if not In all other 33
(0-9) corresponding to the correct
attempted cases
answer is darkened
+3 0
–1
Comprehension If only the bubbles If none of
2 9 – In all other 27
(SCQ) corresponding to the correct the bubbles
cases
answer is darkened is darkened

AL WITHOUT BEING I
 MATHEMATICS
PART : I MATHEMATICS
SECTION – 1 : (Maximum Marks : 33)

 This section contains ELEVEN questions

 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
 For each question, darken the bubble corresponding to the correct integer in the ORS
 Marking scheme :
+3 If the bubble corresponding to the answer is darkened
0 If none of the bubbles is darkened
–1 In all other cases

a b c 
  2 2 2 2 2 2 2
1. Let A = p q r  and B = A . If (a – b) + (p – q) = 25, (b – c) + (q – r) = 36, (c – a) + (r – p) = 49
 1 1 1

|B|
then find the value of .
144

sin x  5cos x  cos3 x  

2. If f(x) = 2 ln2   dx and
 (2 – sin x) (3  cos2 x) 
f   = e 3 , then find the value of f(0)
2
 

3. Let a, b and c are complex numbers and the roots of the equation z3  a z2  bz  c  0 are

unimodular then the value of c a  b is ..... 

2 x
cos x ex 2x cos2  
2  /2

sin x  x 3 then find the value of  (x 1)(f(x)  f "(x)) dx

2
4. If f(x) = x 2 sec x

1 2 x  tan x –
2

z –1 ei
5. If the imaginary part of the expression + is zero, then locus of z is a circle with centre
ei z –1

(a, b) and radius (r). Find a + b + r

2 2
6. If the system of equations ax + hy + g = 0, hx + by + f = 0, ax + 2hxy + by + 2gx + 2fy + c + t = 0

abc  2fgh – af 2 – bg2 – ch2

has a unique solution and = 8, then find t.
h2 – ab

Area enclosed by curve 4  x  y  2(| x |  | y |) is (in square units)

2 2
7.
 1
8. A continuous real function of x satisfies f(2x) = 3f(x),  x  R. If  f(x) dx = 1, then the value of
0

2
definite integral  f(x) dx is
1

9. Let C be a curve which has the property that length of the perpendicular from origin upon any of its

tangent is equal to the abscissa of the point of tangency. If the curves passes through (2, – 2) and

the area enclosed by the curve above the x-axis is k, then find the value of k.

x2  y2 z2 z2
10. If x, y, z are cube roots of unity and D = x2 y 2  z2 x 2 then the real part of D is
y2 y2 z  x2
2

2 y
11. Let y = y(t) be a solution to the differential equation y + 2ty = t , then find the value of 16 lim .
t t

(where y is the first derivative of y with respect to t)

SECTION – 2 : (Maximum Marks : 27)

 This section contains THREE paragraphs
 Based on each paragraph, there will be THREE questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is
correct
 For each question, darken the bubble corresponding to the correct option in the ORS
 Marking scheme :
+3 If only the bubble corresponding to the correct option is darkened
0 If none of the bubble is darkened
–1 In all other cases
Paragraph for Question Nos. 12 to 14
a 
sin nx
Consider n =  dx , where a  R and n, µ,  N.
+

0
sin x


12. If a  ,   2,   1 , then n + 1 – n is equal to
2
1 1 1
(A) (B) (C) (D) none of these
2n  1 2(n  1) n 1


13. If a  ,   2,   2 , then n + 1 + n – 1 – 2n is equal to
2
(A) 0 (B) 1 (C) 2 (D) none of these


14. If a ,   1,   1 and n is an even number, then n + 2 – n is equal to
2
n n n
( 1) 2 ( 1) 2 ( 1) 2
(A) 2 (B) (C) 2 (D) none of these
n 1 n 1 n 1
 Paragraph for Question Nos. 15 to 17

A(Z1), B(Z2), C(Z3) are the vertices of a triangle taken in anticlockwise direction. ABC is inscribed

in the circle |Z| = 2. Internal angle bisector of the angle A meets the circumcircle again at D(Z4).

(where O is the centre of |Z| = 2)

15. Complex number representing point D is given by

1 1 Z 2  Z3 Z 2 Z3
(A) Z4 =  (B) (C) (D) Z 2 Z3
Z 2 Z3 Z1 Z1

 Z4 
16. Arg   is equal to
 (Z 2 – Z3 ) 

   2
(A) (B) (C) (D)
4 3 2 3

Z1 sin2A  Z3 sin2C
17. Evaluate
Z 2 sin2B

(A) 0 (B) 1 (C) –1 (D) 2

Paragraph for Question Nos. 18 to 20

2 2 2
A Pythagorean triplet is triplet of positive integers (a,b,c) such that a + b = c .
Matrices P, Q and R are defined as

1 2 3 1 2 2  –1 –2 –2
P = 2 1 2 , Q =  –2 –1 –2 , R =
 
2 1 2
 
2 2 3   2 2 3   2 2 3 

a 
18. Which of the following matrix product is a Pythagorean triplet of the form b  ?
c 

3  3  3 
(A) Q  4  (B) P  4  (C) R  4  (D) none of these
5  5  5 

19. Which one of the following does not hold good ?

–1 –1
(A) P = adj(P) (B) (PQ) = adj(PQ)
 adj(PQR)
–1 –1
(C) (QR) = adj(QR) (D) (PQR)

T
20. Tr (P + Q + 2R) equals
(A) 17 (B) 15 (C) 14 (D) 18
 PHYSICS
PART - II : PHYSICS

PHYSICS
SECTION – 1 : (Maximum Marks : 33)
 This section contains ELEVEN questions
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
 For each question, darken the bubble corresponding to the correct integer in the ORS
 Marking scheme :
+3 If the bubble corresponding to the answer is darkened
0 If none of the bubbles is darkened
–1 In all other cases

21. A square loop of side ‘a’ is placed in x – y plane as shown in figure. In this region there is

non-uniform time dependent magnetic field B  (cy 3 t 2 )k̂ [where t is time and c is constant]. The
Ca5 t
magnitude of emf induced in loop is . Find the value of P.
P
y (j)

(0,a) (a,a)

O x (i)
(a,0)

22. Solid uniform conducting sphere of mass ‘m’ and charge Q, rotates about its axis of symmetry
with constant angular velocity ‘’ then the ratio of magnetic moment to the moment of inertia of the
xQ.
sphere is then x is : ( Neglect induced charges due to centrifugal force)
6m

23. An infinite uniform current carrying wire is kept along z-axis , carrying current I0 in the direction of
the positive z -axis. OABCDEFG represents a circle (where all the points are equally spaced)
   l
whose centre at point (4m, 0 m) and radius 4m as shown in the figure.
k
B.d   0 0 in S.I unit,
DEF

then the value of k is :

y F
G E

x
O
(4m, 0m) D

A C
B

24. Two circular coils X and Y having equal number of turns and carry equal currents in the same
sense and subtend same solid angle at point O. If the smaller coil X is midway be between O and
Y, then if we represent the magnetic induction due to bigger coil Y at O as By and that due to
2B x
smaller coil X at O as Bx, then find the value of .
By
Y

d X d O
25. In the figure shown capacitors A and B of capacitance C are in steady state. A dielectric slab of
dielectric constant K = 2 and dimensions equal to the inner dimensions of the capacitor is inserted
in the space between the plates of the capacitor B. In the process of inserting the dielectric, energy
NCE2
in the capacitor A increases by an amount of . Find the value of N.
72

26. A capacitor is uncharged at t = 0. It is charged through a variable current .

 C

Figure shows variation of  with time and corresponding change in potential difference across
capacitor with time. Find the capacitance (in farad) of capacitor used in the circuit
 V

6A 12V
24
t (in s)
12 12 24 t (in s)
–6A

27. Two cells of emf 1 and 2 (2 < 1) are joined as shown in figure :

When a potentiometer is connected between X and Y it balances for 300 cm length against 1. On

connecting the same potentiometer between X and Z it balances for 100 cm length against 1 and

32
2. Find integer value of .
1

28. In the circuit shown, current through the resistance 2  is i and current through the resistance 30
1

i1
is i2. Find the ratio .
i2
 29. A long straight wire is carrying current I1 = 2/5 A in +z direction. The x - y plane contains a closed

circular loop carrying current I2 = 5/2 A and not encircling the straight wire, then the force

(in newton) on the loop will be ? (radius of the circular loop R = 3/4m).

30. A square non- conducting loop of 20 cm side is placed in a magnetic field The centre of side AB

coincides with the centre of magnetic field The magnetic field is increasing at the rate of 0.2T/s.

Find the magnitude of line integral of induced electric field (in mV) along path BC.

A B

D C

31. A series RLC, AC circuit operates at half its resonant frequency and at a power factor of 0.8. Then

XC
write the ratio of :
R

SECTION – 2 : (Maximum Marks : 27)

 This section contains THREE paragraphs
 Based on each paragraph, there will be THREE questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is
correct
 For each question, darken the bubble corresponding to the correct option in the ORS
 Marking scheme :
+3 If only the bubble corresponding to the correct option is darkened
0 If none of the bubble is darkened
–1 In all other cases

Space
Paragraph for RoughNos.
for Question Work32 to 34
A certain transmission line (very long) is constructed from two thin metal plates (parallel to each
other) of width b, which are separated by a very small distance ‘h’ < < ‘b’ . The current travels
down one strip and back along the other, and it is distributed uniformly over the surface of the
plates as shown in figure. Neglect fringing field at ends of plates.
y

b
x
h

z
32. Capacitance per unit length of this combination is
0h2 0b 2 0b
(A) Infinite (B) (C) 2
(D)
b h h

33. Magnetic field between the space of two plates is

I  Ib I  0Ih
(A) 0 (k̂) (B) 0 2 (k̂) (C) 0 ( k̂) (D) ( k̂)
2h 2h b b2

34. Self inductance per unit length ofSpace for Rough

combination is (c isWork
speed of light)
2
b c b h c 2b
(A) (B) (C) (D)
0c h
2  0b 0c 2b 0h
 Paragraph for Question Nos. 35 to 37

A fan operates at 200 volt (DC) consuming 1000 W when running at full speed. It's internal wiring
has resistance 1 . When the fan runs at full speed, its speed becomes constant. This is because
the torque due to magnetic field inside the fan is balanced by the torque due to air resistance on
the blades of the fan and torque due to friction between the fixed part and the shaft of the fan. The
electrical power going into the fan is spent (i) in the internal resistance as heat, call it P1 (ii) in

doing work against internal friction and air resistance producing heat, sound etc., call it P2. When

the coil of fan rotates, an emf is also induced in the coil. This opposes the external emf applied to
send the current into the fan. This emf is called back-emf, call it 'e'.
Answer the following questions when the fan is running at full speed.

35. The current flowing into the fan and the value of back emf 'e' is :
(A) 200 A, 5 volt (B) 5 A, 200 volt (C) 5 A, 195 volt (D) 1 A , 0 volt

36. The value of power 'P1' is

(A) 1000 W (B) 975 W (C) 25 W (D) 200 W

37. The value of power 'P2 is

(A) 10000 W (B) 975 W (C) 25 W (D) 200 W

Paragraph for Question Nos. 38 to 40

Consider a given series LCR circuit as shown in figure. There are 10 switches. Answer the
following questions.

S1 S2 S3 S4

XL = R R XC

S5 S6 S7
E1 E2
S8 S9 S10

E1 = E0 sint E2 = E0 sin(t + )

38. It is observed that effective current in the circuit in case if either S8, S6 and S7 or if S5 S6 S9 S10 or if
S8, S9 and S10 are closed (Rest open) remains same. Value of  is :
 2 3
(A) (B) (C) (D) zero
2 3 4

39. Switch S8, S9 & S10 are closed. Now it's observed if rest switches are opened or switches
S3, S4 are closed (rest opened) effective value of current in the circuit is same. The value of Xc is
R R
(A) R (B) 2R (C) (D)
2 3

40. Switch S8, S6, S7 are closed. Now effective current if S 1, S2 closed (Rest opened) is I1 and if
2
 
S3S4 closed (Rest Opened) is I2 value of  1  is
 2 
3 2 1 2
(A) (B) (C) (D)
5 3 3 5
 PART : III CHEMISTRY
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]

SECTION – 1 : (Maximum Marks : 33)

 This section contains ELEVEN questions

 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
 For each question, darken the bubble corresponding to the correct integer in the ORS
 Marking scheme :
+3 If the bubble corresponding to the answer is darkened
0 If none of the bubbles is darkened
–1 In all other cases

41. A certain saturated hydrocarbon effuses 2 times slower as compared to N2 gas under identical
conditions. The number of carbon in one molecule of hydrocarbon is "p" and index of hydrogen
deficiency is "q". Give the value of " p × q".

42. How many of the following statement(s) is/are not correct ?

(1) Extensive properties are non-additive properties.
(2) For irreversible cyclic process Ssurr = 0
(3) The entropy of an isolated system can never decrease.
(4) In adiabatic free expansion, heat involved is zero and therefore entropy change will be zero.
(5) The heat absorbed during isothermal expansion of an ideal gas against vaccum is zero.
(6) A process occurs in such a direction as to cause an increase in the entropy of the universe.
(7) If the isoentropic process for an ideal gas is reversible, it must be adiabatic.

43. For the just coagulation of 500 mL of Fe(OH)3 sol in two hours, 1 mL of 1M Na2SO4 electrolyte is
required. What is the coagulating value of Na2SO4 electrolyte ?

+ -
44. The two ions A and B have radii 88 and 200 pm respectively. In the close packed crystal of
+
compound AB, predict the coordination number of A .

45. How many of the following statement(s) is/are true regarding a real gas?
 dZ 
(i) Boyle temperature is the temperature at which slope   of the curve between
 dP 
compressibility factor v/s P is same as that for an ideal gas in low pressure region.
(ii) Critical temperature is highest temperature at which liquid and vapour co-exist.
(iii) At low pressure attractive force in the real gas dominates and the gas is more compressible at
temperature lower than Boyle's temperature.
(iv) At critical state the compressibility factor is 3/8.
(v) Z approaches 1 at very large inter-molecular separations and real gas behaves almost like an
ideal gas.
(vi) Z < 1 implies attractive forces dominate, gas occupies a smaller volume than an ideal gas, at
same temperature and pressure.
(vii) Z > 1 implies repulsive forces dominate, gas occupies a larger volume than an ideal gas, at
same temperature and pressure.
(viii) Z < 1 at very small inter-molecular separations.
 1
46. Consider the following graph of Z v/s drawn at low pressure and inversion temperature
Vm

CHEMISTRY
a
(T = ), using the virial form of vanderwaal's equation :
Rb

 a  1 b2 b3
Z = 1 + b  + + + ................
 RT  Vm Vm2 Vm3

1.02

Z 1.01

0.001 0.011
1 (/cm3)
Vm

3
Find critical molar volume (VC) in cm ?

47. The volume of nitrogen gas (at STP) required to cover a sample of silica gel with a monomolecular
3 –1 2
layer is 112 cm g of gel. Calculate the surface area per gram (in m ) of the gel if each nitrogen
–22 2
molecule occupies 16.0 × 10 m . Give your answer to the nearest single digit integer.
23
{NA = 6 ×10 }

48. The number of compounds which can show geometrical isomerism is :

(I) N2H4 (II) H2N2 (III) HN3 (IV) CH2N2

(V) (CH3)2N2 (VI) (NH2)2N2 (VII) HN=N–N=NH (VIII) NH2–CH=N–NH2

(IX) NH2–CH=NH (X) CH2=N–NH2 (XI) Cl–CH=C=C=C=CH–Cl

49. How many statements are correct.

S1 : The reductive ozonolysis of m–xylene and p-xylene give the same products.
S2 : The reductive ozonolysis of o-xylene gives glyoxal + methyl glyoxal + dimethyl glyoxal.
S3 : The reductive ozonolysis of benzene gives only one product.

2
S4 : Positive charge is present in phenyl cation ( ) in sp orbital

S5 : Negative charge is present in benzyl anion ( ) in p-orbital

S6 : Three 2º amines are possible for molecular formula C4H11N.

50. How many substituted phenol are possible by the molecular formula C 8H10O.
51. Number of meso compounds from the following is :

(i) (ii) (iii)

CH3

(iv) (v) OH OH (vi)

H H

CH3

Me
D CH3
(vii) (viii)
D CH3
Me

SECTION – 2 : (Maximum Marks : 27)

 This section contains THREE paragraphs

 Based on each paragraph, there will be THREE questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is correct
 For each question, darken the bubble corresponding to the correct option in the ORS
 Marking scheme :
+3 If only the bubble corresponding to the correct option is darkened
0 If none of the bubble is darkened
–1 In all other cases

Paragraph for Question Nos. 52 to 54

A gaseous mixture of propane, acetylene and CO2 is burnt in excess of air. Total 4800 kJ heat is

evolved. The volume of CO2 formed during combustion is 224 liters at STP.

The total evolved heat is used to perform two separate process:

(i) Vapourising 87.5% of water (liquid) (by mole) obtained in the process of burning the original
mixture.
(ii) Forming 3808 liters ethylene measured at STP from its elements.
 HºHH = 435 kJ/mol  HºCH = 416 kJ/mol  HºCC = 347 kJ/mol

 HºCC = 615 kJ/mol,  HºCC = 812 kJ/mol Hº sub lim ation of (C,s) = 718 kJ/mol

Hºf (CO2, g) = – 394 kJ/mol Hºf (H2O, ) = – 286 kJ/mol. Hºf (H2O, g) = – 246 kJ/mol.
52. Sum of enthalpies of combustion of C3H8(g) and C2H2(g) is :
(A) –2198 kJ (B) – 3499 kJ (C) –2798 kJ (D) –3099 kJ

CHEMISTRY
53. Select the correct option for the given information :
(A) Hºf of C3H8 (g) : (-154 kJ / mol.)

(B) Hºf of C2H2(g) : (200 kJ/mol.)

(C) Hºf of C2H4(g) : (27 kJ/mol.)

(D) None of these

54. Total moles of gases taken in the initial mixture of propane, acetylene and CO2 is
(A) 5 (B) 4 (C) 2 (D) 6

Paragraph for Question Nos. 55 to 57

In a unit cell of a hypothetical solid, atoms (A) are present at all corners, (B) are present at
alternate face centres and all edge centers. Atoms (C) are present at remaining face centers and
1 th
one at each body diagonal, at distance of of body diagonal length from corner.
4

55. Formula of the given solid is :

(A) AB6C7 (B) AB4C6 (C) A2B9C11 (D) None of thesea

56. A tetrad axis is passed from the given unit cell and all the atoms touching the axis are removed.

The possible formula of the compound left is :

(A) AB3C6 (B) AB4C5 (C) A3B6C7 (D) (A) or (B)

57. Fraction of number of total voids (TV + OV) occupied is :

(A) 0.58 (B) 0.25 (C) 0.48 (D) None of these

Paragraph for Question Nos. 58 to 60

An aromatic compound C11H12 (P), which gives dicarbonyl compound (Q) on reductive ozonolysis.

(Q) gives positive iodoform test and also give red precipitate with fehling solution. Hydrogenation
of (P) results benzenoid compound (S). Compound (S) gives three monochloro products (only

structural) on monochlorination.

P Q R + CHI3

S
58. The structure of the aromatic compound P is :

(A) (B) (C) (D)

59. The structure of the product R is :

(A) (B)

(C) (D)

60. Choose the incorrect statement :

(A) Compound S show geometrical isomerism.
(B) Compound P show optical isomerism.
(C) Compound R gives CO2 gas with NaHCO3
(D) Compound P gives one mole H2 gas with Na metal.