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Refrigeration and Air Conditioning - ECII - Module 4 - Jan - May - 2021
Refrigeration and Air Conditioning - ECII - Module 4 - Jan - May - 2021
Refrigeration and Air Conditioning - ECII - Module 4 - Jan - May - 2021
to
and
Unit of refrigeration--- TR
= 1TR=3.5kW, = 210kJ/min
19 May 2021 Prof. S S B. K.J.Somaiya College of Engg. Dept. of Mech. 2
How does it work?
High Temperature
Reservoir
Heat Rejected
R Work Input
Heat Absorbed
Low Temperature
Reservoir
How does it work?
Thermal energy moves from left to right through five
loops of heat transfer:
1) 2) 3) 4) 5)
Indoor air Refrigerant Condenser Cooling
loop Chilled
water loop loop water loop water loop
4
(Bureau of Energy Efficiency, 2004)
Types of refrigeration systems
As per Refrigerant (Heat Exchange media)
1. Air refrigeration
2. Vapor refrigeration
Air Refrigeration ( Rev Carnot, Rev Bryton Or Joule Or Bell Coleman Cycle)
1. Open air
2. Closed OR Dense air
Open Air
Components: compressor , condenser, expander , evaporator
Adv: Air is free. Low Cost, no health hazards
Dis. Adv: higher size of Compressor, Moisture Trapping, Freezing in lines
= Heat absorbed in
evaperaor /Work in put
= Change in enthalpy of
refrnt. Before and after
evaporation / change in
enthalpy of refrnt. Before
and after compression
19 May 2021 Prof. S S B. K.J.Somaiya College of Engg. 6
Dept. of Mech.
Vapour Compression Refrigeration
3
Condenser
High
4 Pressure
Side
Expansion
Device Compressor
1 2 Low
Pressure
Evaporator Side
Generic Refrigeration Cycle
(reversed Rankine cycle)
Cascading
improves the
COP of a
refrigeration
system.
Some systems
use three or
four stages of
cascading.
Schematic and T-s diagram for a refrigerator–freezer unit with one compressor.
Liquefaction of Gases
Many important scientific and engineering processes at cryogenic temperatures (below
about 100°C) depend on liquefied gases including the separation of oxygen and nitrogen
from air, preparation of liquid propellants for rockets, the study of material properties at low
temperatures, and the study of superconductivity.
Linde-Hampson system
for liquefying gases.
Vapor Absorption Cycle
The performance of
ammonia-water system
depends considerably
upon the performance of
analyzer and rectifier
columns.
Q3 Q Q2
+ 1 =
T3 T1 T2
C.O.P = Q1
Q3 From 1 and 2 equations
1 1
Q1 Q3 T3 T2 Where; T3>T2>T1.
1 1
This is coefficient of performance for
T2 T1
T T3 T2 T1 T T2 T1
all absorption refrigeration systems
Q3 3 Q3 3 as Q2 is total quantity of heat
T3 T2 T1 T2 T2 T1 T3
Q1 T1 T T2 discharged in Absorber and
THUS C.O.P. 3
Q3 T2 T1 T3 condenser at temperature T2.
Electrolux system of refrigeration
Also known as three fluids absorption system
Uses NH3 as a refrigerant, a water as absorbent and H2 as inert
gas for working
The basic
components of
this refrigerator
are:
•Generator
•Absorber
•Heat Exchanger
•Evaporator
•Condenser
•Separator
Advantage: It is noiseless.
Disadvantage: It cannot be used for industrial applications as the
coefficient of performance of the system is low.
Lithium Bromide Absorption Refrigeration
System
IT uses a solution of lithium
bromide in water.
Lithium bromide is a
highly hygroscopic salt
and is used as an
absorbent. Water is used
as the refrigerant.
The system is suitable for
low refrigeration
temperatures. However as
the freezing point of water is
0oC, refrigeration
temperature is kept above
0oC.
An inhibitor such as lithium
chromate is added to
prevent against the
corrosive action of lithium
bromide.
Comparison Of Lithium-Bromide System With
Ammonia-Water System
LITHIUM BROMIDE SYSTEM AQUA-AMMONIA SYSTEM
The pure water leaves the generator An analyzer and rectifier are a must
since the salt does not evaporate. for an Ammonia water system.
So the analyzer and the rectifier can
be eliminated.
The pressure difference is so small The pressure difference is much
that the pumping system can be higher and to do away with the
eliminated. The evaporator can be pumping system would require the
put an about 1 metre elevation evaporator to be at an elevation of
compared to the generator. about 90 metres. So a pump less
ammonia system is practically too
complex.
The system is free from bursting, These problems are experienced in
toxicity, leakage, foundation noise the aqua-ammonia system.
and vibration. Maintenance costs
are negligible.
It does not cool below 2oC and has a It can cool below 2oC effectively and
large volume flow. volume flow is not a problem.
REFRIGERANTS
A refrigerant is any body or REFRIGERANTS
substance which acts as a Primary refrigerants Secondary
cooling agent by absorbing refrigerants
heat from another body or Halo-carbon Brines like
substance through expansion
Refrigerants calcium chloride,
or vaporization. These are
classified into two groups.
sodium chloride
and glycols like
Primary refrigerants,
which directly take part in propylene glycol,
the refrigeration systems. ethylene glycol
Secondary refrigerants,
etc.
which are first cooled by Azeotrope refrigerants
primary refrigerant and Inorganic refrigerants
then used for cooling
purposes. Hydro-carbon
refrigerants
Halo-Carbon Refrigerants Azeotrope Refrigerants
Refrigeran Chemical Chemical Refrig Azeotropic Chemical
t No. Name Formula erant Mixing Formula
No. Refrigerant
R-11 Trichloro mono CCl3 F R-500 73.8 % R12 CCl2F/CH3
fluoro methane and 26.2 % R CHF2
R-12 Dichloro difluoro CCl2 F2 152
metane
R502 48.8 % R22 CHCiF2 / CClF2
R –13 Monochlorot CClF3 and 51.2 % R CF3
rifluro
115
methane
R – 14 Carbontetra CF4 R503 40.1 % R12 CHF3 / CClF3
fluoride and
59.9 % R13
R – 21 Dichloro CHCl2F
Monofluoro R504 48.2 R32 and CH2 F2 / CClF2
methane 51.8 % R15 CF3
The term ‘azeotrope’ refers to a stable mixture of refrigerants whose vapour and
liquid phases retain identical compositions over a wide range of temperatures.
However, these mixtures usually have properties that differ from either of their
components.
Inorganic Refrigerants Hydro-Carbon Refrigerants
Refrigerant Azeotropic Chemical
No. Mixing Formula Refrigerant Chemical Chemical
Refrigerant No. name formula
R- 717 Ammonia NH3
R – 729 Air R – 170 Ethane C2 H6
R – 744 Carbon CO2 R – 290 Propane C3 H8
dioxide
R – 764 dioxide SO2 R – 600 Butane C4 H10
R – 118 Water H2O R – 1150 Ethylene C2 H4
They posses satisfactory thermodynamic
properties but are highly flammable and
explosive.
Designation System For Refrigerants
The general chemical formula for the refrigerant, is given by Cm Hn Clp Fq
In which n + p + q = 2m + 2
Where “m” = no. of carbon atoms
“n" = no. of hydrogen atoms
‘P” = no. of chlorine atoms
‘q “= no. of fluorine atoms
Refrigerants are internationally designated as ‘R’ followed by certain numbers
such as R-11,R-12,R-114 etc. The number given to the refrigerant has a
special meaning.
If ’R’ is followed by a two digit number it indicates that the number is derived
from methane base.
If ‘R’ is followed by a three digit number it represents an ethane base.
The first digit on the right is the number of fluorine atoms i.e. q
The second digit from the right is one more than the number of hydrogen
atoms present i.e. n+1.
The third digit from the right is one less than the number of carbon atoms (if
zero then it is omitted) i.e. m-1.
Therefore number given to the refrigerant is given by R(m-1) (n-1) (q)
19 May 2021 36
Prof. S S B. K.J.Somaiya College of Engg. Dept. of Mech.
Designation System For Refrigerants
Inorganic refrigerants are indicated by adding 700 to the molecular mass of
the compound.
e.g. molecular mass of NH3=17; Therefore designation is R-717 (i.e.700+17)
To Find Refrigerant Number For:
1. Dichloro-tetrafluoro-ethane
Hence,
No. of chlorine atoms, p=2
No. of fluorine atoms, q=4
No. of hydrogen atoms, n=0
We know that n+p+q = 2m+2
0+2+4 = 2m+2
therefore, m=2
i.e. Number of carbon atoms =2
Thus the refrigerant no. becomes R(2-1) (0+1) (4) or R-114.
The digit ‘2’ represents the no. of fluorine atoms since it is the first digits
from the right.
The no. of hydrogen atoms – 1-1 = 0.To balance the methane, mono-
atoms are required therefore no. of chlorine atoms will be 4-2=2.