CHEE2001 PROCESS PRINCIPLES

1. HEATS OF FORMATION
2. STEAM TABLES
3. ENTHALPIES OF SELECTED GASES
4. ENTHAPIES OF COMBUSTION GASES

The School of Chemical Engineering, UQ

 CHEE2001 Resources, UQ School of Chemical Engineering

1. HEATS of FORMATION
Standard enthalpies of formation of 1 gmol of compound from elements in their standard states, at 25C and 1 atm.
Compound Formula Mol Wt State hF (J/gmol)
acetaldehyde CH3CHO 40.05 gas -166400
acetone C3H6O 58.08 gas -216690
acetylene C2H2 26.04 gas 226750
ammonia NH3 17.03 liquid -67200
gas -46190
benzene C6H6 78.11 liquid 48660
gas 82927
n-butane C4H10 58.12 liquid -147600
gas -124730
isobutane C4H10 58.12 liquid -158500
gas -134500
carbon C 12.01 graphite 0
carbon dioxide CO2 44.01 gas -393510
liquid -412920
carbon monoxide CO 28.01 gas -110520
carbon tetrachloride CCl4 153.84 liquid -139500
gas -106690
cyclohexane C6H12 84.16 gas -123100
cyclopentane C5H10 70.13 liquid -105800
gas -77230
ethane C2H6 30.07 gas -84667
ethyl acetate CH3CO2C2H5 88.10 liquid -442920
ethanol C2H5OH 46.07 liquid -277630
gas -235310
ethyl chloride C2H5Cl 64.52 gas -105000
ethylene C2H4 28.05 gas 52283
ethylene chloride C2H5Cl 62.50 gas 31380
formaldehyde HCHO 30.03 gas -108600
n-hexane C6H14 86.17 liquid -198800
gas -167200
hydrogen chloride HCl 36.46 gas -92311
hydrogen cyanide HCN 27.03 gas 130540
hydrogen sulfide H2S 34.08 gas -20150
methane CH4 16.04 gas -74840
methanol CH3OH 32.04 liquid -238640
gas -201250
methyl chloride CH3Cl 50.49 gas -81923
nitric oxide NO 30.01 gas 90374
nitrogen dioxide NO2 46.01 gas 33850
n-pentane C5H12 72.15 liquid -173100
gas -146400
propane C3H8 44.09 liquid -119840
gas -103850
propene C3H6 42.08 gas 20410
n-propyl alcohol C3H8O 60.09 gas -255000
sulfur S 32.07 rhombic 0
water H2O 18.02 liquid -285840
gas -241826
m-xylene C6H4(CH3)2 106.16 liquid -25420
gas 17240
o-xylene liquid -24440
gas 19000
m-xylene liquid -24430
gas 17950

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 CHEE2001 Resources, UQ School of Chemical Engineering

2.STEAM TABLES

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 CHEE2001 Resources, UQ School of Chemical Engineering

Source: Felder, R. and Rousseau R., Elementary Principles of Chemical Processes, 4th Edition.

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 CHEE2001 Resources, UQ School of Chemical Engineering

Source: Felder, R. and Rousseau R., Elementary Principles of Chemical Processes, 4th Edition.

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 CHEE2001 Resources, UQ School of Chemical Engineering

3.ENTHALPIES of SELECTED GASES

Source: Felder, R. and Rousseau R., Elementary Principles of Chemical Processes, 4th Edition.

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 CHEE2001 Resources, UQ School of Chemical Engineering

4. ENTHALPIES of COMBUSTION GASES

Enthalpies of combustion gases at 1 atm (J/gmol)

T(K) N2 O2 Air H2 CO CO2 H2O T(K)

273 0 0 0 0 0 0 0 273
291 524 527 523 516 525 655 603 291
298 728 732 726 718 728 912 837 298
300 786 790 784 763 786 986 905 300
400 3695 3752 3696 3655 3699 4903 4284 400
500 6644 6811 6660 6589 6652 9204 7752 500
600 9627 9970 9673 9518 9665 13807 11326 600
700 12652 13225 12736 12459 12748 18656 15016 700
800 15756 16564 15878 15413 15899 23710 18823 800
900 18961 19970 19116 18384 19125 28936 22760 900
1000 22171 23434 22367 21388 22413 34308 26823 1000
1100 25472 26940 25698 24426 25760 39802 31011 1100
1200 28819 30492 29078 27509 29154 45404 35312 1200
1300 32216 34078 32501 30626 32593 51090 39722 1300
1400 35639 37693 35953 33789 36070 56860 44237 1400
1500 39145 41337 39463 36994 39576 62676 48848 1500
1750 47940 50555 48325 45275 48459 77445 60751 1750
2000 56902 59914 57320 53680 57488 92466 73136 2000
2250 65981 69454 66441 62341 66567 107738 85855 2250
2500 75060 79119 75646 71211 75772 123176 98867 2500
2750 84265 88910 84935 80290 85018 138699 112089 2750
3000 93512 98826 94265 89453 94265 154347 125520 3000
3500 112131 119034 113135 108030 112968 185895 152799 3500
4000 130875 141410 132172 127528 131796 217777 180414 4000
Source: Kobe, K.A. et al. (1958). Thermochemistry of Petrochemicals, Reprint No. 44 from the Petroleum Refiner, Gulf
Publishing Co., Houston, Texas. p.30