FIITJEE INTERNAL TEST–1

IIT–JEE, 2023
CLASS–XI(XI-N-3)
[IIT-JEE(Advance)]
Time :- 3 Hours Date : 01-08-21 Maximum Marks : 306.

A. General:
1. This Question Paper contains 57 questions.
2. The question paper consists of 3 parts (Physics, Chemistry and Mathematics). Each part consists of
three Sections.
B. Question paper format and Marking scheme:
3. The question paper consists of 3 parts (Physics, Chemistry and Mathematics). Each part consists of
three Sections.
4. For each question in Section I, you will be awarded 4 marks if you darken only the bubble corresponding
to the correct answer and zero mark if no bubbles are darkened. In all other cases minus one (1) mark
will be awarded.
5. Section II,
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
 For each question, marks will be awarded in one of the following categories :
Full Marks : +5If only the bubble(s) corresponding to all the correct
option(s) is(are) darkened
Partial Marks : +1 For darkening a bubble corresponding to each correct
option, provided NO incorrect option is darkened
Zero marks :0 If none of the bubbles is darkened
Negative Marks : –1 In all others cases
 For example, If [A], [C] and [D] are all the correct options for a question, darkening all these three
will get +4 marks; darkening only [A] and [D] will get +2 marks; and darkening [A] and [B] will get
–1 marks, as a wrong option is also darkened
6. For each question in Section III, each question in this section carries a maximum of 8 marks. Thus, you
will be awarded 2 marks for each row in which your darkened the bubbles(s) corresponding to the correct
answer. There is no negative marks awarded for incorrect answer(s) in this Section.
7. For each question in Section IV, you will be awarded 6 marks if you darken only the bubble
corresponding to the correct answer and zero mark if no bubbles are darkened. There is no negative
marks awarded for incorrect answer(s) in this Section.

Enrolment No. :

Name : . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Batch : . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
 XI-Adv P1 – [XI (XI-Adv-1)]–2020

Useful Data
1 amu = 1.66 × 10–27 kg R = 0.082 L-atm K–1 mol–1
h = 6.626 × 10–34 J s NA = 6.022 × 1023

me = 9.1 × 10–31 kg e = 1.6 × 10–19 C

c = 3.0 × 108 m s–1 F = 96500 C mol–1

2.18 × 10–18 J 1.00 × 10–10 C2 N m
–1 –1
RH = 40 =

Atomic No. : H=1, He=2, Li=3, Be=4, B=5, C=6, N=7, O=8, F=9, Na=11, Mg=12, Al = 13, Si = 14,
P = 15, S = 16, Cl = 17, Ar =18, K=19, Ca=20,Cr=24, Mn=25, Fe=26, Co=27, Ni=28,
Cu=29, Zn=30, As=33, Br = 35, Ag = 47, Si = 21, Sn = 50, Ti = 22,I = 53, Xe = 54, Ba = 56,
Pb = 82, U = 92, V = 50.
Atomic masses: H =1, He=4, Li=7, Be=9, B=11, C=12, N=14, O=16, F=19, Na=23, Mg=24, Al=27, Si=28,
P=31, S=32, Cl=35.5, K=39, Ca=40, Cr=52, Mn=55, Fe=56, Co=59, Ni=58.7, Cu=63.5,
Zn = 65.4, As = 75, Br = 80, Ag = 108, Sn = 118.7, I = 127, Xe = 131, Ba = 137, Pb = 207,
U = 238.

2 FIITJEE
 XI-N1( Paper1) Adv.–2021

P
PAAR
RTT –– II :: P
PHHY
YSSIIC
CSS
SECTION–I (Single Correct Choice Type)

This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.
 
1. If a  3 ˆi  4 ˆj , find a unit vector in the direction of a .
1 ˆ 1 ˆ 1 ˆ 1 ˆ
(A)
5

3 i  4 ˆj  (B)
5

3 i  4 ˆj  (C)
5

3 i  2 ˆj  (D)
5

3 i  2 ˆj 
sin x dy
2. If y = , then equals :
sin x  cos x dx
sin x  cos x 1 cos x
(A) 2
(B) (C) (D) none of these
( sin x  cos x) ( sin x  cos x)2 (sin x  cos x)2

x dx
3. If y = , then equals :
x5 dy
(A) 5(1 – y)–2 (B) 5(1 + y)–2 (C) (1 – y)–2 (D) none of these

   
4. If A and B are two mutually perpendicular vectors, where A  5 ˆi  7 ˆj  3kˆ and B  2 ˆi  2 ˆj  akˆ , then the
value of a is
(A) –2 (B) 8 (C) –7 (D) –8

SECTION – II (Multiple Correct Answers Type)

This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE OR MORE may be correct.
 
5. A vector A has magnitude A and  is unit vector in the direction of A , then which of the following are
correct
 
 A   A
ˆ
(A) A. A  A (B) Â  (C) A .A  A 2
(D) A 
A Â

6. Which of the following expression is equal to zero.

        
(A) A  A (B) A.A  B 
(C) B   A  A  B 
   
(D) ˆi  ˆj  kˆ 
   
7.  
If v1  v 2 is perpendicular to v 1 
– v 2 , then
 
(A) v1 is perpendicular to v2
 
(B) v1  v 2

(C) v1 is null vector
 
(D) the angle between v1 and v2 can have any value

    
8. A  B  C Vectors A and B if rotated by  in the same sense to form A' and B ' , then
           
(A) A   B  C (B) A   B  C (C) A.B  A   B (D) A   B  C

FIITJEE 3
 XI-Adv P1 – [XI (XI-Adv-1)]–2020

9. If f (x) = x3 – x2
(A) f (x) possess local maximum at x = 0 (B) f (x) possess local maximum at x = 2/3
(C) f (x) posses local minima at x = 0 (D)f (x) possess local minima at x = 2/3

10. Following are four different relations. Which of the following are always true :
   
 1    ( r – r1 )    ( v – v1 )
(A) vav  (v1 v 2 ) (B) v av  2 (C)  r   v (t)dt (D) aav  2
2 t 2 – t1 t 2 – t1

3 2
11. y = 2x – 9x + 12x + 5 :
(A) at x = 2 minima is occur (B) at x = 1 maxima is occur
(C) minimum value of function is 9 (D) maximum value of function is 9

12. The function y = f (x) is given as shown in the figure :

(A) function is increasing in interval (0, 4)
(B) function is increasing in interval (0, 2)
(C) function is constant in interval (4, 6)
(D) function is decreasing in interval (6, 8)

SECTION–III (Matrix Type)

This section contains 2 questions. Each question has four statements (A, B, C and D) given in Column I and
five statements (p, q, r, s and t) in Column II. Any given statement in Column I can have correct matching with
one or more statement(s) in Column II. For example, if for a given question, statement B matches with the
statements given in q and r, then for that particular question, against statement B, darken the bubbles
corresponding to q and r in the ORS.

13. Match the column.

   
Column – A (Operation of vector A and B ) Column – B (Angle between A and B )
   
(A) AB  A. B (P) 0

   
(B) AB  B A (Q) 
2
   
(C) AB  A B (R) 
4
  
(D) A  B  C and A  B  C (S) 3
  4
A and B are not zero v ectors

(T) 

4 FIITJEE
 XI-N1( Paper1) Adv.–2021


14. 
For component of A  3iˆ  4ˆj  5kˆ 
Column – A Column – B
(A) along y-axis (P) 5 unit
(B) (Q) 4 unit

along 2iˆ  ˆj  2kˆ 
(C) (R) 3 unit

Along 6iˆ  8jˆ  10kˆ 
(D) (S) zero

Along 3iˆ  4 ˆj  5kˆ 
(T) none

SECTION–IV (Integer Type)

This section contains 5 questions. The answer to each question is a single-digit integer, ranging from 0 to 9. The
correct digit below the question number in the ORS is to be bubbled.

 
  r F
15.    
Considering two vectors F  4 ˆi  10 ˆj N and r  5 ˆi  3 ˆj m, compute
31
.

n
16. The slope on the graph of y = 2x2 – 3x + 1 will be zero at n, then find the value of .
4

1 1
17. If the minimum value of y = 4x + is at x  , then what is the value of n.
x n

18. The maximum value of the function y = x3 – 12x is 2n, find the value of n.

19. The minimum value of the function y = 2x3 – 9x2 + 12x is n, what is the value of n.

FIITJEE 5
 XI-Adv P1 – [XI (XI-Adv-1)]–2020

P
PAAR
RTT––IIII :: C
CHHE
EMMIIS
STTR
RYY
SECTION–I (Single Correct Choice Type)

This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.

1. The velocity of an electron in the first Bohr orbit of a hydrogen atom is 2.19 × 106 ms–1. Its velocity in the
second orbit would be
(A) 1.10 × 106 ms–1 (B) 4.38 × 106 ms–1 (C) 5.5 × 105 ms–1 (D) 8.76 × 106 ms–1

2. An electron is accelerated through V volt its de Broglie wavelength is :


h 12.27  150  2
(A) (B) Å (C)   Å (D) All of these
2 m.e.V V  V 

3. Which one among the following represents schematically the radial probability function 4r²R²(r) for a 2p
orbital?

(A) (B)

(C) (D)

4. According to Modern periodic Law, the chemical properties of elements are the periodic function of their :
(A) Density (B) Atomic number (C) Atomic mass (D) Atomic volume

SECTION – II (Multiple Correct Answers Type)

This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE OR MORE may be correct.

5. Which of the following configurations violate Aufbau’s principle :

(A) (B)

(C) (D)

6. Quantum numbers have been matched with their characteristics. Select correct matching (s).
Quantum Numbers Characteristics
(A) l shape of orbital
(B) n orientation of orbital
(C) m size of orbital
(D) ms orientation of spin of electron

6 FIITJEE
 XI-N1( Paper1) Adv.–2021

7. IE1 of an element is lower than that of IE2 because

(A) it is difficult to remove an electron from cation compared to from the same element
(B) the ionisation process is endothermic
(C) the size of cation is smaller than its atom
(D) Ionization enthalpy of an atom is equal to electron gain enthalpy of cation

8. Select the incorrect statement(s)/order(s)

(A) d-orbital can accomodate 10 electrons
IE1 IE2 IE3
(B) Na   Na   Na2   Na3 
2 6
2s , 2p , 3s1 2
2s , 2p 6 2
2s , 2p5 2s2 , 2p4
Order of successive IE is IE1 < IE2 > IE3
(C) No. of unpaired electrons in CO2+ > CO3+
(D) IE1 of Pt > Pd

9. Consider the following values of IE (eV) for elements W and X

Element IE1 IE2 IE3 IE4
W 10.5 15.5 24.9 79.8
X 8 14.8 78.9 105.8
Other two elements Y and Z have outer electronic configuration ns2 np3 and ns2 np5 respectively.
Then according to given information which of the following compound(s) is/are not possible
(A) W 2Y3 (B) X2Y3 (C) WZ2 (D) XZ2

10. Which among the following is/are correct about chromium ?

(A) Its electronic configuration is 3d5 4s1
(B) Total spin of chromium = 3
(C) Spin multiplicity of 3d-subshell of chromium = 6
(D) Magnetic moment of chromium = 48

11. Select the correct statements for hydrogen like atoms or ions :
(A) Radius of an orbit is inversely proportional to Z
(B) Radius of an orbit is directly proportional to Z2
(C) Energy of the electron in an orbit is inversely proportional to Z
(D) Energy of the electron in an orbit is directly proportional to Z2

12. When high speed electron strikes a metal surface, which of the following are possible ?
(A) The entire energy of the electron may be converted into X-ray photon
(B) Fraction of energy of electron may be converted into X-ray photon
(C) The entire energy of electron may be converted into heat
(D) The electron may undergo elastic collision with metal surface

SECTION–III (Matrix Type)

This section contains 2 questions. Each question has four statements (A, B, C and D) given in Column I and
five statements (p, q, r, s and t) in Column II. Any given statement in Column I can have correct matching with
one or more statement(s) in Column II. For example, if for a given question, statement B matches with the
statements given in q and r, then for that particular question, against statement B, darken the bubbles
corresponding to q and r in the ORS.

13. Match the Column

Column I (Species) Column II (Characterstics)
3+
(A) Co (P) Total number of fully filled orbital is nine
3+
(B) Sc (Q) The value of magnetic moment is greater
than or equal to 3.87 BM
3+
(C) Cr (R) No. of electrons with (n +  = 3) is eight
2+
(D) Ni (S) No. of electrons with (m = 0) may he either
11 or 12
(T) no unpaired electron

FIITJEE 7
 XI-Adv P1 – [XI (XI-Adv-1)]–2020

14. Match the Column-I with Column-II.

Column-I Column-II
(A) Electrons cannot exist in the nucleus (p) de Broglie wave
(B) Microscopic particles in motion are associated (q) Electromagnetic wave
with
(C) No medium is required for propagation (r) Uncertainty principle
(D) Concept of orbit was replaced by orbital (s) Transverse wave

SECTION–IV (Integer Type)

This section contains 5 questions. The answer to each question is a single-digit integer, ranging from 0 to 9. The
correct digit below the question number in the ORS is to be bubbled.

15. The ratio of potential energy and total energy of an electron in a Bohr orbit of a hydrogen-like species is :

16. In an atom two electrons move around the nucleus in circular orbits of radii R and 4R. The ratio of the time
taken by them to complete one revolution is 1:x . Find x.

17. Maximum number of electrons in any given element with atomic number 20. Which can have l = 2 and spin
1
 is ……….:
2

18. The number of groups which constitute p-block element is/are

19. How many of the following elements are s-block elements?

Rb, Al, B, K, S, Cd, Zn, Th, Sr

8 FIITJEE
 XI-N1( Paper1) Adv.–2021

P
PAAR
RTT––IIIIII :: M
MAAT
THHE
EMMA
ATTIIC
CSS
SECTION–I (Single Correct Choice Type)

This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.

1. If log (x + 3) + log (x – 3) = log 27, then the value of x is :

(A) 2 (B) 3 (C) 4 (D) 6

2. If | x – 1 |  4, then the complete set of values of x :

(A) (–, –3]  [5, ) (B) (3, 5) (C) (5, ) (D) (–, 3)

sec ( )cos(90   )tan(180  )

3. The value of is equal to :
sec (360  )sin(180  )cot (90  )
1
(A) 2 (B) 1 (C) 3 (D)
2

4. The exact value of cosec 10º – 4 sin 70º =

(A) 1 (B) 5 (C) 2 (D) 3

SECTION – II (Multiple Correct Answers Type)

This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE OR MORE may be correct.

x y
5. If sin x  sin y  p; cos x  cos y  q and tan .tan  r   1 then which of the following may be correct ?
2 2
2 2
p q 2 q2  p2
(A) cos  x  y   (B) cos  x  y   2
2 p  q2
1  r p2  q2 
(C)  (D) x  y  if p  q
1 r 2q 2

3
6. The values of x satisfying the inequality | x  1| 1 x belong to
(a) (, 1] (b) [0, 1] (c) [1, ) (d) (, )

7. Which one of the following is irrational :

(A) log5 7 (B) log2 32 (C) sin 60° (D) tan 405°

8. If (log2 x)2 – log2 x3 + 2 = 0, then the value of x is :

(A) 2 (B) 3 (C) 4 (D) 6

 8 
9. If log8  2   3(log8 x )2 , then the value of x is / are :
x 
1
(A) 2 (B) 1/8 (C) 8 (D)
2

10. The inequation (x – 1)(x – 2)2 (x – 3)3 (x – 4)4  0 has

(A) Infinite positive integral solution (B) Infinite negative integral solution
(C) Zero positive integral solution (D) Zero negative integral solution

FIITJEE 9
 XI-Adv P1 – [XI (XI-Adv-1)]–2020

11. The value of : x  2 x –1  x – 2 x –1 

(A) 2 x – 1 , if x > 2 (B) 2, if 1 x 2 (C) 2 x – 1 , if 1 x 2 (D) 2 if x > 2

12. Which of the following is/are false ?

2
(A) The complete solution set to x > 25 is (5, )
x–2
(B) The inequality < 2 can be solved by multiplying both sides by x + 3, resulting in the equivalent
x3
inequality x – 2 < 2(x + 3)
x 3
(C) (x + 3) (x – 1)  0 and  0 have the same solution set
x –1
x
(D) = 1 for all x  R
x

SECTION–III (Matrix Type)

This section contains 2 questions. Each question has four statements (A, B, C and D) given in Column I and
five statements (p, q, r, s and t) in Column II. Any given statement in Column I can have correct matching with
one or more statement(s) in Column II. For example, if for a given question, statement B matches with the
statements given in q and r, then for that particular question, against statement B, darken the bubbles
corresponding to q and r in the ORS.

13. Match the following column:

Column-I Column-II

(A) 3log3 ( x 2)  log 6 (216) (P) 5

(B) 2 (Q) 8
xlog x ( x 3)  36

(C) 2log5 x  16 (R) 3

(D) log 2 2 x  4 (S) 625

14. Match the following column:

Column-I Column-II
(Solution of inequality)

(A) (x – 1)200 (x – 3)101 > 0 (P) x  (–, –1]  [2, )

(B) ( x  2) (Q) x  (3, )
0
x 5

(C) (x – 4)205 · (x – 2)20 > 0 (R) x  (–, 2]  (5, )

(D) ( x  1) ( x  2) (S) x  (4, )
2
0
x 2

10 FIITJEE
 XI-N1( Paper1) Adv.–2021

SECTION–IV (Integer Type)

This section contains 5 questions. The answer to each question is a single-digit integer, ranging from 0 to 9. The
correct digit below the question number in the ORS is to be bubbled.

1 35a
15.  log 64 256  (a  R) then find a ____ .
log 3
81 24

16. If A= log2 log2 log4256+ 2log 2

2 then value of A is :

17. If x= logba, y = logcb, z = logac, then xyz is

18. The value of log34 log45 log56 log67 log78 log89 is

19. If log9  log 6 ( a  a  12)   0 , (a > 0) then find the value of a _____ .

FIITJEE 11