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Aknowledgements: MSC - Kumera .A
Aknowledgements: MSC - Kumera .A
First and for most, thanks to the almighty God for granting me his limitless care, love and
blessing all along the way. Then I would like to forward my great thank to our department for
giving me a chance to accomplish this excitable work.
Next to that I would like to express my thanks to my advisor MSC.KUMERA .A for his
advice to accomplish the work successfully from the beginning to end without saying a tired.
My great thank extends my family and friends who had supported me directly or indirectly
throughout my project.
Finally I would like to thank all members of our physics department students.
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ABSTRACT
This project presents a review on solar cells. The aim of the project is to review the three
generations of solar cell and their working principles and to compare the efficiencies of solar
cell. Generally the first generations solar cell based on Silicon (Si) solar cell. The advantage of
first generation solar cell is broad spectral absorption range and high carrier mobility. The
disadvantage of first generation solar cell is requires expensive manufacturing technologies,
growing and sawing of ingots is a highly energy intensive process. The Second Generation Solar
cells, also called thin-film solar cells, are significantly cheaper to produce than first generation
cells but have lower efficiencies. Some advantages are illustrated below. It has high absorption
co-efficient, Lower cost in comparison of Si based solar cell and the Disadvantages are:
Environmental Contamination starts from fabrication process and Materials are hard to find.
Third generation solar cells are inherently different from the previous two generations because
they do not rely on the p-n junction design of the others. The Advantages of third generation
solar cells are : Raw materials are easy to find Easier fabrication process rather than other
two technology Cost is minimal and the Disadvantages of third generation solar cells are: Liquid
electrolyte (low temperature)and High cost dye .
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Table of Contents
AKNOWLEDGEMENTS...................................................................................................................................i
ABSTRACT....................................................................................................................................................ii
CHAPTR ONE................................................................................................................................................1
SOLAR CELL..................................................................................................................................................1
1.INTRODUCTION........................................................................................................................................1
1.1 Statement of problem solar cell........................................................................................................2
1.2 Significance or impact of solar cell.....................................................................................................3
1.3 Objective of the study........................................................................................................................3
General objective.....................................................................................................................................3
Specific objective....................................................................................................................................3
CHAPTER TWO.............................................................................................................................................4
2. Literature review.....................................................................................................................................4
2.1 Types of Solar Cells and Application..................................................................................................6
2.1.1 Amorphous Silicon Solar Cell (A-Si).............................................................................................7
2.1.2. Biohybrid Solar Cell....................................................................................................................8
2.1.3. Buried Contact Solar Cell...........................................................................................................8
2.2 ENERGY PLANNING............................................................................................................................9
CHAPTER THREE........................................................................................................................................11
3 .Methodology and material or equipment.............................................................................................11
3.1 Material or Equipment for Solar Cell...............................................................................................11
3.2 Budget break down.........................................................................................................................12
Table 1 Budget break down.......................................................................................................................13
3.3Time break down..............................................................................................................................13
Table 2 Time break down..........................................................................................................................14
CHAPTER FOUR..........................................................................................................................................14
4. CONCLUSION.........................................................................................................................................14
REFERENCES..............................................................................................................................................16
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List of tables
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CHAPTR ONE
SOLAR CELL
1. INTRODUCTION
Solar cells are a promising and potentially important technology and are the future of sustainable
energy for the human civilization. PV is world’s fastest growing power generation technology. A
solar cell, or photovoltaic cell, is an electrical device that converts the energy of light to
electricity by Photo voltaic effect, which is physical and phenomenon. Also, methods of
conversions of solar energy into electricity working principles and materials used for various
types of photovoltaic technology (Prentice-HallInc, 1982).
There are such a wide variety of applications. Solar is a cleaner, safer investment for our family
and business PV technology offers a number of significant benefits. Solar power is a renewable
resource that is available everywhere in the world. Solar PV technologies are small and Thus, PV
will continue to produce power indefinitely (as long as the sun shines). Photovoltaic are truly a
sustainable and environmentally friendly method of producing energy (Nayfeh, 1929).
Solar cells need to absorb a range of energy, which corresponds to the solar spectrum to be
efficient. The purpose of this paper is to explain different types of PV technology present today
in the world and to provide the achievements in the field of advanced photovoltaic and
photochemical conversion of solar energy into electricity and methods of selection of PV
technology according to different criteria (cost of production, the efficiency of solar energy
conversion, and others…) Rapid technological developments (Minger T .1990).
There are a wide range of PV cell technologies on the market today, using different types of
materials, and an even larger number will be available in the future. PV cell technologies are
usually classified into three generations, depending on the basic material used and the level of
commercial maturity (Aldous, Scott, 1986).
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The working principle of solar cells is based on the photovoltaic effect, i.e. the generation
potential difference at the junction of two different materials in response to electromagnetic
radiation. Solar cells are usually divided into three main categories called generations up to
recent years (http://en.wikipedia.org/wiki/Cost_of_electricity_by_source#Photovoltaics:
A solar cell, or photovoltaic cell, is an electrical device that converts the energy of light directly
into electricity by the photovoltaic effect, which is a physical and chemical phenomenon. The
word “photovoltaic” can be divided into two parts: “photo” and “voltaic”
(http://en.wikipedia.org/wiki/Air_mass_(solar_energy)
Nano-structured layers in thin film solar cells offer three important advantages. First, due to
multiple reflections, the effective optical path for absorption is much larger than the actual film
thickness. Second, light generated electrons and Current solar cells cannot convert all the
incoming light into usable energy because some of the light can escape back out of the cell into
the air (N. S. Sariciftci, L,1992).
Installing solar panels on a house is expensive and requires experienced people. These
systems used fixed solar panels since alignment systems are too expensive for the average
homeowner (see: How to determine the correct angle for solar panels). The initial investment
outlay is a significant factor in why there is a lack of support for solar power from
consumers.
Giant solar farms have been built in desert regions and have reduced the installation cost
since a larger economy-of-scale is created (parts, material & installation people are in one
location). But these large, inexpensive tracks of lands are found far from cities where the
power is needed. Expensive transmission lines are needed to bring the power to a distant
market.
Maintenance costs and time can add-up since every inch of a solar panel must be kept clean
and clear of debris for them to operate at their most efficient. Their efficiency drops
drastically even when a small portion is blocked by fallen debris or a film of dust.
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The main problem with solar power that has stifled its use is the fact that energy production only
takes place when the sun is shining. Large storage systems need to be developed to provide a
constant and reliable source of electricity when the sun isn't shining at night or when a cloud goes
overhead.
When solar panels are not producing energy, it takes longer to recoup their installation and
maintenance cost.
General objective
The general objective of the project work is to understand working principle of solar cell, Nano
structure based solar cell and compare the generation of solar cell.
Specific objective
The specific objectives of this project work are the following:
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To reduce the time for operation.
To make in minimum cost.
CHAPTER TWO
2. Literature review
They have presented an experimental investigation to study a semiconductor material used in a
PV cell and its importance in determining the efficiency of the solar cell at various parameters
such as regards to behavior with respect to temperature, weight and as well as other parameters
with which it is used and all those contribute to the deciding factor of efficiency of the PV cell
The inventor has conducted many experimental researchers to devise improvised methods and
apparatus for forming thin film layers of semiconductor materials.
The field of photovoltaics generally relates to multi-layer materials, converts sun light directly
into DC Electrical Power. The basic mechanism for this conversion is “The Photovoltaic Effect”.
Solar cells are typically configured as a co-operating sandwich of P-Type and N-Type
semiconductors, in which the N-Type semi conductor material (on one side of the sandwich)
exhibits an excess of electrons and the P-Type semiconductor material (on the other side of the
sandwich) exhibits an excess of holes each of which signifies the absence of the an electron.
[Ho; Frank. (Yorba Linda, CA) Yeh; Milton Y (Santa Monica, CA) 1995] Has worked on in
improving the efficiency of Solar Cells. They have found that the efficiency of the solar cell
varies from 15% to 22% and innovations are being carried out by changing the combination of
semiconductor material in the PV cell and find out improved efficiency. The inventor has
analyzed the properties of semiconductor material thoroughly and has come out with a
combination of cells- cascaded cell, permits achieving more than overall efficiency of 23%.
Up to the present time it has been proposed to use either Germanium or Gallium Arsenide as the
substrate for solar cell in which the principal active junction is formed of N-Type and P-Type
Gallium Arsenide. Attempts are continuing at developing solar cells that efficiently use as much
of solar spectrum as possible. In order to catch as much as possible protons, the semiconductor
used in the solar cell must be designed for a small band gap, since the semiconductor material is
otherwise transparent to radiation with proton energy less than the band gap.
[Bareis; Bernard F (Plano,TX) and Goei; E Esmond T. (Dublin, CA) 2004]
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They have investigated on the concentrating solar energy receivers. In their study they have
commented that the solar collectors can be classified into focusing type (concentrating type) and
Non – focusing type (non-concentrating type). The inventor has designed the concentrating type
solar energy receiver comprising a primary parabolic reflector having a centre and a high
reflective surface on a concave side of the reflector and having a fixed axis extending from the
concave side of the reflector and passing through a fixed point of the primary parabolic reflector
and a conversion module having a reception surface. Non concentrating type solar collecting
devices intercept parallel un-concentrated rays of the sun with an array of photovoltaic cells. The
output is the direct function of array.
[Britt; Jeffery s. (tucswon.AZ) Wiedeman; Scott (Tucson.AZ) 2009]
They have presented an experimental investigation to study a semiconductor material used in a
PV cell and its importance in determining the efficiency of the solar cell at various parameters
such as regards to behavior with respect to temperature, weight and as well as other parameters
with which it is used and all those contribute to the deciding factor of efficiency of the PV cell
The inventor has conducted many experimental researchers to devise improvised methods and
apparatus for forming thin film layers of semiconductor materials.
The field of photovoltaics generally relates to multi-layer materials converts sun light directly
into DC Electrical Power. The basic mechanism for this conversion is “The Photovoltaic Effect”.
Solar cells are typically configured as a co-operating sandwich of P-Type and N-Type
semiconductors, in which the N-Type semi conductor material (on one side of the sandwich)
exhibits an excess of electrons and the P-Type semiconductor material (on the other side of the
sandwich) exhibits an excess of holes each of which signifies the absence of an electron. They
have worked on thin film solar cells. When an incident photon excides an electron in the cell into
the conduction band, the excited electron becomes unbound from the atom of the semi conductor
creating a free electron, hole-pair. It extends a conductive path between the two sides of the cell.
Electrons will move from N-Type side to P-Type side along the external path, creating an
electric current. Such a photo voltaic structure when appropriately located electrical contacts are
included and the cell is in-cooperated into a closed electric circuit constitutes a PV Cell device.
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One particular type of solar cell that has been developed for commercial use is “Thin Film PV
Cell”. Thin Film Cells require less light absorbing semiconductor material to create a working
cell and thus can reduce processing costs.
[Zhao; Xiaofeng (Guangdong, CN) 2011]
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applications, there is a lot of research invested into these technologies as they promise to
achieve the goal of producing low-cost, high-efficient solar cells.
“First generation” panels include silicon solar cells. They are made from a single silicon
crystal (mono-crystalline), or cut from a block of silicon that is made up of many crystals (multi-
crystalline - shown at right).
“Second generation” thin-film solar cells are less expensive to produce than traditional
silicon solar cells as they require a decreased amount of materials for construction.
The thin-film PV cells are, just as the name implies, a physically thin technology that
has been applied to photovoltaics. They are only slightly less efficient than other types but do
require more surface area to generate the same amount of power.
The following are the different types of solar cells.
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silicon achieves a yield of about 18 percent, amorphous solar cells’ yield remains at around 7
percent. The efficiency rate is partly due to the Staebler-Wronski effect, which manifests
itself in the first hours when the panels are exposed to sunlight, and results in a decrease
in the energy yield of an amorphous silicon panel from 10 percent to around 7percent.The
principal advantage of amorphous silicon solar cells is their lower manufacturing costs,
which makes these cells very cost competitive.
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2.1.3. Buried Contact Solar Cell
The buried contact solar cell is a high efficiency commercial solar cell technology based
on a plated metal contact inside a laser-formed groove. The buried contact technology
overcomes many of the disadvantages associated with screen-printed contacts and this allows
buried contact solar cell to have performance up to 25% better than commercial screen-
printed solar cells.
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1) BESOM – Brookhaven energy system optimization model that attaches all costs to
energy flows and minimizes their sum over one year.
2) TESOM–Time stepped energy system optimization modelmakes consecutive BESOM
type optimizations for single year.
3) MARKAL – Market allocation model is a successor of
BESOM and is a large scale, technology oriented activity analysis model which
integrates the supply and demand side sectors of an economy.
4) MENSA – Multiple Energy systems of Australia is an improved and recognized
version of MARKAL that chooses the combination of demand side and supply side
technologies which delivers energy at a least cost, averaged over a specified time period.
5) EFOM – Energy flow optimization model provides an engineering oriented bottom up
model of a national energy system and has been developed under the approval of the
commission of the European communities. The EFOM describes the energy system as a
network of energy flows, by combining the extraction of primary fuels, through a number
of conversion and transport technologies to the demand for energy services or large
energy consuming materials.
The second method of energy planning is by planning based on analogy that
allows the simulation of the same quantity, with a time lag, in a less developed
country, through the use of leading case as a reference and the knowledge of the
time behaviour of a quantity in a more developed country.
The third and the last method emphasizes on inquiry methods like Delphi
questionnaires to expert members and evaluating their answers for an accurate
chart of the future (Cormio et al 2003).
Energy models can also classified as optimization models, resource allocation models,
models based on artificial intelligence techniques and forecasting models. In addition to
MATLAB various tools can be used to formulate and run the models in computers like
LINDO, LINGO, TORA and GAMS which are primarily optimization packages. Energy
models are broadly classified into two types as Bottom up model and top down model.
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The former model is an “engineering type model” that typically includes description of
given energy related tasks which are to be accomplished at minimum costs given by a
given menu of technologies and also finds out the reasons about how emission reduction
task be accomplished at minimum costs. On the contrary the top down model considers
energy demand in the form of functions that depends upon sectoral economic product and
on energy prices (Leo 2005).
CHAPTER THREE
A typical silicon solar cell consists of a photoactive p/n junction formed on the surface, a front
ohmic contact stripe and fingers, a back ohmic contact that covers the entire back surface, and an
antireflection coating on the front surface.
For silicon solar cell production either poly-crystalline or mono-crystalline material is used.
Poly-crystalline silicon for photo-voltaic applications is normally produced by casting methods
while mono-crystalline silicon is prepared in a Czochralski growing process.
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Manufacturing of solar cells can be divided in 4 sections:
Manufacturing of pure silicon, starting from reduction of quartz sand with carbon,
cleaning of the raw silicon by transfer to trichlorosilane and distillation of it and finally
deposition of poly-silicon under hydrogen atmosphere.
Manufacturing of mono or poly-crystalline crystals or blocks and cutting it to silicon
wafers.
Manufacturing of the solar cells.
Manufacturing of solar modules from the solar cells.
Birr Cents
2 Notebook Piece 1 30 30 00
3 Pen Piece 4 6 24 00
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7 Secretary expense Piece 90 10 900 00
Start End
20 25
2 Introduction and literature review part writing April April 2 days Chapter 1$2
24 26
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26 28
5 Proposal defense 1
CHAPTER FOUR
4. CONCLUSION
Photovoltaic (PV) is the field of technology and research related to the application of solar cells
for energy by converting sun energy (sunlight, including sun ultra violet radiation) directly into
electricity. Solar PV is one of the very few low-carbon energy technologies with very high
potential to grow to very large scale. Many solar cell technologies exist for the direct conversion
of light into electricity, each with its own advantages and disadvantages. Solar technologies use
the sun to provide heat, light, electricity, etc for domestic and industrial applications. The term
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“photo” comes from the Greek word for light. A “volt” is a unit of measure for electric current.
Thus “photovoltaic” literally means “electricity from light.” And that’s exactly what the word
describes: capturing solar energy in the form of light and transforming it into electricity.
Solar cells can be classified into three such as; First generation cells, Second generation cells and
third generation solar cell. The advantage of first generation solar cell is broad spectral
absorption range and high carrier motilities. The disadvantage of first generation solar cell is
requires expensive manufacturing technologies.
The Second Generation Second generation cells, also called thin-film solar cells. The advantage
of the second generation of solar cell is lower manufacturing costs, lower cost per watt can be
achieved and reduced mass. The disadvantage of the second generation of solar cell is increased
toxicity.
Third generation solar cells are the cutting edge of solar technology. The Advantages of Third
Generation Solar Cells is low Energy and Low material cost. The disadvantage of the Third
Generation Solar Cells is efficiency is lower compared to silicon (wafer-based) solar cell.
all proposed nanostructures for solar cell applications using the following five fundamental
physics-based criterions.(1) Interactions between charge carriers (electrons and holes) and
phonon cannot be neglected.(2) For all the known semiconductors, hot carriers (due to ultra-short
value of thermalization time) generated in one layer of the solar cell cannot be transported to the
other side of the solar cell and collected at the other electrode.(3) The phenomenon of
photoluminescence has no direct relationship with solar cell operation(4) Intermediate band gap
recombination center will reduce solar cell performance.(5) For nanostructures, the thermal
conductivity is lower than the bulk values. For practical applications of nanostructures, the
material must have high thermal conductivity to transport heat from the device.
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REFERENCES
[1]T. Key, "Solar photovoltaic Expanding electric generation options,"2007.
[6]http://cnx.org/content/m41217/latest/
[8]http://www.altenergy.org/renewables/solar.html
[9] M. A. Green, "Third generation photovoltaic: solar cells for 2020 and beyond," vol. 14, pp.
65-70, 2002.
[10]http://gunam.metu.edu.tr/index.php/solar-technology/pv-celltypes
[11] V. V. Kislyuk and O. P. Dimitriev, “Nano rods and nanotubes for solar cells, “Journal of
Nano science and Nanotechnology, vol.8, no. 1, pp. 131–148, 2008.
[13] R. Singh, N. Gupta, and K. F. Poole, “Global energy conversionrevolution in the 21st
century through solid state devices,” in Proceedings of the 26th International Conference on
Microelectronics (ICM ’08), vol. 1, pp. 45–54, IEEE, Nis, Serbia, May 2008
[16] W. Shockley and H. J. Queisser, “Detailed balance limit of efficiency of p-n junction solar
cells,” Journal of Applied Physics,vol. 32, no. 3, pp. 510–519, 1961.
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