TABLA DE REFRACCIONES ATÓMICAS

1N. Bauer, K. Fajans. and S Lewin, in A. Wcissbcrger. cd . Physical Methods of Organic Chemistry, 3d cd., Wilcv lntersciencc,
, -
New York. I 960, Vol. 1, Pi. 11. Chap. 28.

TABLE 17.1 Atomic and Group Refractions

Group Mr „ Group ,Mr„
H 1.100 N ( primary aliphatic amine ) 2.322
C 2.418 N (sec-aliphatic amine ) 2.499
Double bond ( C=C) 1.733 N (tert-aliphatic amine) 2.840
Triple bond ( C^C ) 2.398 N ( primar)' aromatic amine ) 3.21
Phenyl (C6H5) 25.463 N (sec-aromatic amine) 3.59
,
Naphthyl (C 0H7) 43.00 N ( tert-aromatic amine ) 4.36
0 (carbonylXC=0) 2.211 N ( primar)' amide ) 2.65
0 (hydroxylXO H) —— —
0 (ether. esterXC 0 )
1.525
1.643
N (sec-amide)
N ( /ert-amidel
2.27
2.71
F (one fluoride) 0.95 N (imidine) 3.776
F ( polyfluorides) 1.1 N ( oximido) 3.901
( 'I
. 5.967 N (carbimido) 4.10
Br 8.865 N (hydrazone ) 3.46
I 13.900 N (hydroxylamine ) 2.48

—— — ——
S ( thiocarbonvlMC O)
S ( thioXS H)
S ( dithiaX S S )
7.97
7.69
8.11
N (hydrazine)
N ( aliphatic cyanide )(C= N)
N ( aromatic cyanide )
2.47
3.05
3.79
Se (alkyl selenides ) 11.17 N ( aliphatic oxime) 3.93
Three-membered ring 0.71 NO ( nitroso ) 5.91
Four-membered ring 0.48 NO ( nitrosoamine) 4.37
,
NO (alkyl nitrate) 7.59
NOj ( alkyl nitrite ) 7.44
NO, ( aliphatic nitro) 6.72
NO, ( aromatic nitro ) 7.30
NO, ( nitramine ) 7.51