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Class 6 - Module 1 - Schroedinger Wave Equations - DR - Ajitha - PHY1701
Class 6 - Module 1 - Schroedinger Wave Equations - DR - Ajitha - PHY1701
(PHY1701)
Dr. B. Ajitha
Assistant Professor
Division of Physics
VIT University
Chennai, India
ajitha.b@vit.ac.in
PHY1701
Module-1: Introduction to Modern Physics Dr. Ajitha
Contents
• Planck’s concept (hypothesis) (AB 66-67)
• Compton Effect (AB 80-86),
• Particle properties of wave: Matter Waves (AB 104-114),
• Davisson Germer Experiment (AB 115-117),
• Heisenberg Uncertainty Principle (AB 119-128),
• Wave function (AB 182-184 & 190-195), &
• Schrödinger equation (time dependent & independent)
(AB 187 -190 & 195-197).
Ψ = Ψ0 e−iωt −−− −2
Eqn 2, is the general solution of the wave equation, which is eqn 1.
If we include electron’s (or particle’s) parameters such as wavelength,
mass, momentum, total energy, potential energy etc., in the general
wave equation then we can call it as the wave equation of electron (or
of any particle).
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PHY1701
Time independent Wave Equation Dr. Ajitha
𝜕Ψ
= Ψ0 e−iωt × −iω
𝜕t
= −iωΨ
𝜕2Ψ 2
2
= −ω Ψ
𝜕𝑡
Now we will have (particle’s) ω2 also in the general wave equation.
Substituting these value in Equation 1 we get,
𝜕2Ψ 𝜕2Ψ 𝜕2Ψ 1 2
2
+ 2
+ 2
= 2
−ω Ψ
𝜕𝑥 𝜕𝑦 𝜕𝑧 𝑣
2 2 2
𝜕 𝜕 𝜕
Since, 𝛻 2 = + 2 + 2 (𝐿𝑎𝑝𝑙𝑎𝑐𝑖𝑎𝑛 𝑜𝑝𝑒𝑟𝑎𝑡𝑜𝑟ቇ
𝜕𝑥 2 𝜕𝑦 𝜕𝑧
2
ω
𝛻 2Ψ = − 2 Ψ
𝑣
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PHY1701
Time independent Wave Equation Dr. Ajitha
2 4π2 m2 v2
𝛻 Ψ+ 2 Ψ = 0--------- eq. 3
h
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PHY1701
Time independent Wave Equation Dr. Ajitha
h 2m
∵ђ= 𝛻2Ψ + 2
E − V Ψ = 0; −−−−−−−− eq. 5
2π ђ
For a free particle, V=0, thus,
2mE
𝛻 2Ψ
+ 2 Ψ=0
ђ
(Shroedinger’s time independent equation for free particle)
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Time independent Wave Equation PHY1701
Dr. Ajitha
ђ2 2
𝛻 Ψ − V Ψ = EΨ
2𝑚
ђ2 2
− 𝛻 Ψ+ V Ψ = EΨ
2𝑚
ђ2 2
[− 𝛻 + V]Ψ = EΨ
2𝑚
ĤΨ=𝐄Ψ
ђ2 2
Here, Ĥ = − 𝛻 + V is known as Hamiltonian Operator
2m
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Schroedinger’s Time dependent Wave Equation PHY1701
Dr. Ajitha
2
2m 𝜕Ψ
𝛻 Ψ + 2 iђ − VΨ = 0
ђ 𝜕t
2
2m 𝜕Ψ
𝛻 Ψ = − 2 iђ − VΨ
ђ 𝜕t
ђ2 2 𝜕Ψ
− 𝛻 Ψ + VΨ = iђ
2m 𝜕t
ђ2 2 𝜕Ψ
− 𝛻 + V Ψ = iђ ------- eq. 3
2m 𝜕t
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PHY1701
Dr. Ajitha
ĤΨ=𝐄Ψ
ђ2 2
Here, Ĥ = − 𝛻 + V is known as Hamiltonian Operator
2m
https://slideplayer.com/slide/4897587/
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