Conrad Electronic SE, Klaus-Conrad-Str.

1, D-92240 Hirschau

Code: TC1653

Material Safety Data Sheet

1. Identification of the substance/mixture and of the company/undertaking

Product: Spray Paint
Manufacturer: Conrad Electronic SE
Address: Klaus-Conrad-Str. 1, D-92240 Hirschau
Telephone: +49 (0) 9604 / 40 - 8988
Date of issue: 13.09.2019

1.1 Product identifier

Spray Paint : TC1653
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture:
Spray Paint, low in solvents, sensitising

2. Hazards identification
2.1. Classification of the substance or mixture
Regulation (EC) No. 1272/2008
Hazard categories:
Hazard Statements:
Skin corrosion/irritation: Skin Irrit. 0
Serious eye damage/eye irritation: Eye Irrit.
Respiratory or skin sensitisation: Skin Sens.
Hazardous to the aquatic environment: Aquatic Chronic
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye irritation.

2.2. Label elements

Regulation (EC) No. 1272/2008
Hazard components for labelling
Spray Paint (number average molecular weight <= 700), reaction product: bisphenol-A-(epichlorhydrin)
Bisphenol-F-Epoxy resin
1,6-Bis(2,3-epoxypropoxy)hexane
Signal word: Warning
Pictograms:

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Hazard statements
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H411 Toxic to aquatic life with long lasting effects.
Precautionary statements
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Special labelling of certain mixtures
EUH205 Contains epoxy constituents. May produce an allergic reaction.
2.3. Other hazards
No information available.

3. Composition/information on ingredients
3.2. Mixtures
Hazardous components
CAS No. Chemical name Quantity
EC No. Index No. REACH No.
Classification according to Regulation (EC) No. 1272/2008 [CLP]
25068-38-6 Epoxy resin (number average molecular weight <= 700), reaction product: bisphenol-A-(epichlorhydrin) 50 - 100 %
500-033-5 603-074-00-8
Eye Irrit. 2, Skin Irrit. 2, Skin Sens. 1, Aquatic Chronic 2; H319 H315 H317 H411
16096-31-4 1,6-Bis(2,3-epoxypropoxy)hexane 10 -25 %
240-260-4 01-2119463471-41
Skin Irrit. 2, Eye Irrit. 2, Skin Sens. 1, Aquatic Chronic 3; H315 H319 H317 H412
28064-14-4 Phenol, polymer with formaldehyde, glycidyl ether 10 - 25 %

Skin Irrit. 2, Eye Irrit. 2, Skin Sens. 1, Aquatic Chronic 2; H315 H319 H317 H411
Full text of H and EUH statements: see section 16.

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Material Safety Data Sheet

4. First aid measures

4.1. Description of first aid measures
General information
Take off immediately all contaminated clothing.
After inhalation
Provide fresh air. If breathing is irregular or stopped, administer artificial respiration. Medical treatment necessary.
After contact with skin
After contact with skin, wash immediately with polyethylene glycol, followed by plenty of water. Take off immediately all
contaminated clothing and wash it before reuse. If skin irritation occurs.
After contact with eyes
After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time , then consult an
ophthalmologist immediately.
After ingestion
Seek medical advice immediately.
4.2. Most important symptoms and effects, both acute and delayed
No information available.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

5. Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media
Carbon dioxide (CO2), Extinguishing powder, Water spray jet.
Unsuitable extinguishing media
Full water jet
5.2. Special hazards arising from the substance or mixture
The product itself does not burn. In case of fire may be liberated: Gases/vapours, toxic.
5.3. Advice for firefighters
Wear a self-contained breathing apparatus and chemical protective clothing. Full protection suit.
Additional information
Suppress gases/vapours/mists with water spray jet. Collect contaminated fire extinguishing water separately. Do not allow
entering drains or surface water.

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6. Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Use personal protection equipment.
6.2. Environmental precautions
Do not allow to enter into surface water or drains.
Do not allow to enter the soil or subsoil.
6.3. Methods and material for containment and cleaning up
Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Treat the recovered
material as prescribed in the section on waste disposal.
6.4. Reference to other sections
Carefully cleaning scene of an accident.

7. Handling and storage

7.1. Precautions for safe handling
Advice on safe handling
The usual precautions when handling chemicals must be observed.
Advice on protection against fire and explosion
No special fire protection measures are necessary.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Keep/Store only in original container. Provide for retaining containers, eg. floor pan without outflow.
Advice on storage compatibility
Store separately from foodstuffs.
Further information on storage conditions
Keep receptacles tightly sealed.
7.3. Specific end use(s)
The product does not contain any relevant quantities of substances with workplace-related limit values to be monitored.

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8. Exposure controls/personal protection

8.1. Control parameters
-
8.2. Exposure controls

Protective and hygiene measures

Remove contaminated, saturated clothing immediately. Draw up and observe skin protection programme.
Wash hands and face before breaks and after work and take a shower if necessary . When using do not eat or drink.
Eye/face protection
Suitable eye protection: goggles.
Hand protection
When handling with chemical substances, protective gloves must be worn with the CE-label including the four control digits.
The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place
concentration and quantity of hazardous substances. For special purposes, it is recommended to check the resistance to
chemicals of the protective gloves mentioned above together with the supplier of these gloves.
Suitable material: FKM (fluoro rubber), NBR (Nitrile rubber)
Thickness of the glove material: > 0,5mm
Skin protection
Wear suitable protective clothing.
Respiratory protection
In case of inadequate ventilation wear respiratory protection. ABEK-P2

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Material Safety Data Sheet

9. Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state: Liquid
Colour: yellowish
Odour: characteristic
Test method
pH-Value: not determined
Changes in the physical state
Melting point: not determined
Initial boiling point and boiling range: 200 °C
Flash point: 150 °C
Flammability
Solid: not applicable
Gas: not applicable
Lower explosion limits: not determined
Upper explosion limits: not determined
Auto-ignition temperature
Solid: not applicable
Gas: not applicable
Decomposition temperature: not determined
Oxidizing properties
Not oxidising.
Vapour pressure: 1 hPa (at 20 °C)
Density (at 23 °C): 1,1 g/cm³ ISO 2811-2
Water solubility: The study does not need to be conducted
because the substance is known to be
insoluble in water.
Solubility in other solvents
not determined
Partition coefficient: not determined
Viscosity / dynamic (at 23 °C): 875 mPa·s ISO 3219
Vapour density: not determined
Evaporation rate: not determined
9.2. Other information
Solid content: not determined

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10. Stability and reactivity

10.1. Reactivity
No hazardous reaction when handled and stored according to provisions.
10.2. Chemical stability
no decomposition when stored and handled properly
10.3. Possibility of hazardous reactions
reaction with strong oxidising agents Alkalis (alkalis). Acids
10.4. Conditions to avoid
The product does not contain any relevant quantities of substances with workplace-related limit values to be monitored.
10.5. Incompatible materials
Keep away from oxidising agents.
10.6. Hazardous decomposition products
no decomposition when stored and handled properly
In case of fire may be liberated: toxic and caustic gases and vapours

11. Toxicological information

11.1. Information on toxicological effects
Acute toxicity

CAS No. Chemical name

Exposure route Dose Species Source
25068-38-6 Epoxy resin (number average molecular weight <= 700), reaction product: bisphenol-A-(epichlorhydrin)
oral LD50 11400 mg/kg Rat GESTIS

dermal LD50 > 22800 mg/kg Rabbit GESTIS

16096-31-4 1,6-Bis(2,3-epoxypropoxy)hexane
oral LD50 3010 mg/kg Rat OECD 401
dermal LD50 > 2000 mg/kg Rat OECD 402
28064-14-4 Phenol, polymer with formaldehyde, glycidyl ether
oral LD50 > 2000 mg/kg Rat
dermal LD50 > 2000 mg/kg Rat

Additional information on tests

The mixture is classified as hazardous according to regulation (EC) No 1272/2008 [CLP].

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12. Ecological information

12..1 Toxicity
CAS No. Chemical name
Aquatic toxicity Dose [h] | [d] Spe Species Source
25068-38-6 Epoxy resin (number average molecular weight <= 700), reaction product: bisphenol-A-(epichlorhydrin)
Acute fish toxicity LC50 4,4 mg/l 96 h Oncorhynchus mykiss (Rainbow trout) EPA-660/3-75-009
Acute algae toxicity ErC50 9,4 mg/l 72 h Scenedesmus capricornutum EPA-660/3-75-009
Acute crustacea toxicity EC50 2,8 mg/l 48 h Daphnia magna OECD 202
Acute bacteria toxicity (> 100 mg/l) 3h Activated sludge
16096-31-4 1,6-Bis(2,3-epoxypropoxy)hexane
Acute fish toxicity LC50 30 mg/l 96 h Oncorhynchus mykiss (Rainbow trout) OECD 203
Acute crustacea toxicity EC50 39 - 57 mg/l 48 h Daphnia magna OECD 202

12.2. Persistence and degradability

The product does not contain any relevant quantities of substances with workplace-related limit values to be monitored.
CAS No. Chemical name
Method Value d Source
Evaluation
25068-38-6 Epoxy resin (number average molecular weight <= 700), reaction product: bisphenol-A-(epichlorhydrin)
OECD 301F 5% 28 Manufacturer
Not readily biodegradable (according to OECD criteria)
OECD 301B 6-12% 28 Manufacturer
Not readily biodegradable (according to OECD criteria)
16096-31-4 1,6-Bis(2,3-epoxypropoxy)hexane
OECD 301D 47% 28 Manufacturer
Readily biodegradable (according to OECD criteria).

12.3. Bioaccumulative potential

The product does not contain any relevant quantities of substances with workplace-related limit values to be monitored.
Partition coefficient n-octanol/water
CAS No. Chemical name Log Pow
25068-38-6 Epoxy resin (number average molecular weight <= 700), reaction product: bisphenol-A-(epichlorhydrin) 3,24

BCF
CAS No. Chemical name BCF Species Source
Epoxy resin (number average molecular weight <= 700),
25068-38-6 31 Quantitative structure-activity relationship (QSAR)
reaction product: bisphenol-A-(epichlorhydrin)
16096-31-4 1,6-Bis(2,3-epoxypropoxy)hexane 3,57

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12.4. Mobility in soil

The product does not contain any relevant quantities of substances with workplace-related limit values to be monitored.
12.5. Results of PBT and vPvB assessment
not applicable
12.6. Other adverse effects
No information available.
Further information
Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil.

13. Disposal considerations

13.1. Waste treatment methods
Advice on disposal
Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil. Dispose of waste according to
applicable legislation.
Waste disposal number of waste from residues/unused products
080299 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS
(PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS;
wastes from MFSU of other coatings (including ceramic materials); wastes not otherwise specified
Waste disposal number of used product
080299 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS
(PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS;
wastes from MFSU of other coatings (including ceramic materials); wastes not otherwise specified
Contaminated packaging
Non-contaminated packages may be recycled. Handle contaminated packages in the same way as the substance itself.
Dispose of waste according to applicable legislation.

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14. Transport information

Land transport (ADR/RID)
14.1. UN number: UN 3082
14.2. UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(Epoxydharz)
14.3. Transport hazard class(es): 9
14.4. Packing group: III
Hazard label: 9
Classification code: M6
Special Provisions: 274 335 601
Limited quantity: 5L
Transport category: 3
Hazard No: 90
Tunnel restriction code: E
Other applicable information (land transport)
E1

Inland waterways transport (ADN)

14.1. UN number: UN 3082
14.2. UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(Epoxydharz)
14.3. Transport hazard class(es): 9
14.4. Packing group: III
Hazard label: 9
Classification code: M6
Special Provisions: 274 335 601
Limited quantity: 5L
Other applicable information (inland waterways transport)
E1

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Marine transport (IMDG)

14.1. UN number: UN 3082
14.2. UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(epoxy resin)
14.3. Transport hazard class(es): 9
14.4. Packing group: III
Hazard label: 9
Marine pollutant: Yes
Special Provisions: 274, 335
Limited quantity: 5L
EmS: F-A, S-F
Other applicable information (marine transport)
E1

Air transport (ICAO-TI/IATA-DGR)

14.1. UN number: UN 3082
14.2. UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(epoxy resin)
14.3. Transport hazard class(es): 9
14.4. Packing group: III
Hazard label: 9
Special Provisions: A97 A158
Limited quantity Passenger: 30 kg G
IATA-packing instructions-Passenger: 964
IATA-max. quantity - Passenger: 450 L
IATA-packing instructions - Cargo: 964
IATA-max. quantity – Cargo: 450 L
Other applicable information (air transport)
E1
Passenger-LQ: Y964
14.5. Environmental hazards
ENVIRONMENTALLY HAZARDOUS: yes
Danger releasing substance: Epoxy resin (number average molecular weight <= 700), reaction product:
bisphenol-A-(epichlorhydrin)
14.6. Special precautions for user
No information available.
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
not applicable

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15. Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulatory information
Employment restrictions:
Observe restrictions to employment for juvenils according to the 'juvenile work protection guideline' (94/33/EC).
Water contaminating class (D):
2 - clearly water contaminating
15.2. Chemical safety assessment
Chemical safety assessments for substances in this mixture were not carried out.

16. Other information

Abbreviations and acronyms
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road )
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service
LC50: Lethal concentration, 50%
LD50: Lethal dose, 50%
Relevant H and EUH statements (number and full text)
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
EUH205 Contains epoxy constituents. May produce an allergic reaction.
Further Information
The above information describes exclusively the safety requirements of the product and is based on our present-day
knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data
sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of
mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily
valid for the new made-up material.
(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data
sheet.)

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