MAINCOTE™ HG-31

Waterborne Acrylic Resin for Water and Corrosion-Resistant Industrial Coatings

Description

MAINCOTE HG-31 is a waterborne acrylic resin which can be formulated into water-resistant industrial coatings for
masonry and steel substrates. It displays excellent performance in primers and direct-to-metal (DTM) finishes for
metal substrates, with excellent corrosion resistance and adhesion to steel and other metals. It is also useful in
coatings for cementitious surfaces where water barrier properties are important. MAINCOTE HG-31 also provides
excellent water whitening resistance in clear coatings.

Typical Physical Properties

These properties are typical but do not constitute specifications.

Appearance Milky-white liquid

Solids (% by weight) 45.0
pH 7.5
Viscosity (Brookfield, cP) <1000
Density (lbs/gal) 8.64
Tg (°C) 35

Potential Applications

z Industrial Maintenance Finishes

e.g., steel and concrete structures, bridges, storage tanks
z Transportation Finishes
e.g., railcars, shipping containers
z Commercial Architectural Finishes for Metal and Concrete
e.g., metal buildings, beams, ceilings, walls
z DIY Metal and Masonry Coatings

Key Features and Benefits

MAINCOTE HG-31 provides formulators with a versatile waterborne acrylic binder that can be formulated into
pigmented and clear coatings for metal and masonry surfaces.

z Hydrophobic binder with excellent resistance to early water contact

z Excellent water whitening (blushing) resistance in clear coatings
z Excellent corrosion resistance

Performance Data

The typical performance demonstrated by MAINCOTE HG-31 resin in a white DTM finish, such as formulation G-31-
1, is shown in the tables below. Table 1 demonstrates the excellent corrosion resistance and water resistance of
coatings based on MAINCOTE HG-31. Figure 1 compares salt spray exposure of MAINCOTE HG-31 and a
commercial styrene-acrylic binder in the same DTM formula (G-31-1), and demonstrates the excellent
performance of MAINCOTE HG-31, especially considering that the formula contains no corrosion-inhibiting
pigments. Figure 2 shows the water whitening resistance of MAINCOTE HG-31 compared to a commercially
available acrylic binder known to have good blushing resistance. Both binders were formulated into a clear coating
according to formulation C-31-1. Coatings were cast onto glass, dried for several hours and then immersed in
water overnight. MAINCOTE HG-31 showed no whitening, compared to a slight whitening of the commercial acrylic
binder.
Table 1: Film Properties of MAINCOTE HG-31 in an 18 PVC Gloss White DTM Finish
Property Result
pH (initial/equil) 9.1/9.0
Viscosity (KU, initial/equil) 86/88

Heat age stability (10 days @ 140°F)

delta pH -0.4
delta KU +5

Salt Spray Exposure (3 mil DFT on blasted steel) blister / rust / undercut
72 none / none / none
192 none / 10% slight / 3mm
408 9F / 10% slight / 3mm
576 5-7F / 30% medium / 10mm

Cleveland condensation cabinet (blistering on Bonderite™ 1000)

300 hr none
Testing Notes:
1) Salt spray resistance tested according to ASTM B-117 on hot rolled steel.
2) Blister resistance measured on Bonderite 1000 cold rolled steel @ 2 mil DFT.
3) Coating was dried at 75°F and 50% RH for 1 week prior to testing.

Table 2: Film Properties of MAINCOTE HG-31 in an 18 PVC Gloss White DTM Finish
Property Result
Gloss (20°/60°) 36/75

Gloss Retention (UV-A exposure)

190 hr 13/58
410 hr 15/58
575 hr 24/69
700 hr 29/75
980 hr 57/89
1240 hr 49/85

Hardness
Pencil 3B
Konig (sec) 17

Adhesion (ASTM D3359 rating, % removed)

Cold rolled steel
1 day 5B (0%)
7 day 5B (0%)
7 day wet 4B (5%)
Galvanized steel
1 day 2B (19%)
7 day 5B (0%)
7 day wet 3B (10%)
Testing Notes:
1) Gloss, hardness and gloss retention measured on Bonderite 1000 cold rolled steel @ 2 mil DFT.
2) Adhesion tested on G70 galvanized steel from ACT Laboratories and untreated cold rolled steel (Type R) from Q-
Panel.
3) Coating was dried at 75°F and 50% RH for 1 week prior to testing.
4) QUV A cycle was 8 hr light @ 60°C, 4 hr condensation at 40°C.
Figure 1: Comparison of MAINCOTE HG-31 and a commercially available styrene-acrylic binder after 408 hours
salt spray exposure in an 18 PVC gloss white DTM formulation (G-31-1). Coatings were applied at 3 mil dry to
blasted hot rolled steel (SSPC-SP 5) and dried for 1 week prior to testing.

Figure 2: Water whitening resistance of MAINCOTE HG-31 and a commercial acrylic binder.

Formulating Guidelines

In addition to the resin, the other ingredients in a coating formulation and/or their level of usage can play a
significant role in the performance of the coating. The choice of ingredients can impact the protective, aesthetic
and application properties of a coating, and thus should be evaluated carefully. The following guidelines serve as a
starting point to help in maximizing the performance of coatings based on MAINCOTE HG-31 resin. Formulations
should be fully tested prior to commercialization.

Coalescents

MAINCOTE HG-31 requires approximately 15 to 20% of coalescent for proper film formation. This is particularly
important when the coating is applied under marginal conditions. Suitable slow coalescents include Texanol,
Dowanol™ DPnB and Dowanol PPh. Suitable fast coalescents include Butyl Cellosolve and Dowanol DPM.
Pigments and Colorants

A highly durable grade of titanium dioxide, such as Ti-Pure™ R-706 or Tiona™ RCL-696, is recommended for the
best durability in topcoats and direct-to-substrate finish coats. For coatings designed strictly as primers, a less
durable grade such as Ti-Pure R-900 or Tiona RCL-9 can be used. Care should be taken when selecting pre-
dispersed colorants, as many contain surfactants and glycols which can affect final film properties. Suitable pre-
dispersed colorants include the UCD E-line, industrial colorants based on dispersing resin and which do not contain
glycols.

Mar Aids

Mar resistance can be improved by inclusion of a mar aid. Suitable mar aids include Byk™ 333, Byk 337, and
TegoGlide™ 410 at levels of approximately 0.3 – 0.5% on total formulation weight.

Defoamers

Foam control is a major concern in waterborne paint formulation design. Additives are necessary to eliminate foam
during manufacture and film application. The choice of defoamer type and level will depend primarily on the
formulation and mode of application. Effectiveness of the defoamer can be screened by the shaker test, but the
best candidates should be checked by actual application. Drawdowns should be made to check for surface defects
and impact on gloss. Defoamer persistence should be checked by oven aging and retesting the defoaming
capabilities. Suitable defoamers for MAINCOTE HG-31 include Tego™ Foamex 825 and Surfynol™ DF-58.

Rheology Modifier and Thickeners

HEUR-type (hydrophobically-modified, ethoxylated urethane) associative thickeners, such as ACRYSOL™ RM-8W,

ACRYSOL RM-12W, ACRYSOL 2020NPR or ACRYSOL RM-5000 are recommended. Anionic rheology modifiers and
cellulosic thickeners should be avoided, especially in direct-to-metal finishes as they can negatively impact
corrosion resistance.

Dispersants and Surfactants

Copolymer dispersants such as TAMOL™ 165A and TAMOL 681, or the low VOC alternative TAMOL 2001, at 1 to
2% on pigment (solids/solids) are recommended as a starting point. In general, polyacrylic acid and
polymethacrylic acid dispersants are not a good choice, as they normally reduce corrosion resistance. High levels
of dispersant should also be avoided, as they can increase water sensitivity and lower corrosion resistance. A
suitable surfactant for use as wetting aid is Surfynol 104DPM.

Flash Rust Inhibitors

In waterborne paints for steel, the aqueous phase should contain flash rust inhibitors because rapid rusting (flash
rust) can occur as the paint is drying. The recommended additive is sodium nitrite, which is effective at low use
levels, such as 1 to 2 lbs (solid) per 100 gallons. Addition in a diluted form (15% aqueous solution) is
recommended to prevent stability problems and grit formation. Other inhibitors that can be used include
ammonium benzoate, as well as commercially available products such as Halox™ Flash-X 150.
Gloss White Direct-to-Metal Coating
G-31-1

Ingredients Pounds Gallons

Grind
Water 50.00 5.99
TAMOL 681 9.43 1.03
Surfynol 104DPM 4.00 0.48
Tego Foamex 825 1.00 0.12
Ammonia (28%) 2.00 0.27
Ti-Pure R-706 220.00 6.59
Grind Sub-total 286.43 14.48
Letdown
MAINCOTE HG-31 600.00 68.98
Water 48.40 5.80
Ammonia (15%) 5.00 0.64
Add grind from above
Texanol 48.60 6.13
Dowanol DPM 16.20 2.04
Sodium Nitrite (15%) 9.00 0.99
Ammonia (15%) 2.00 0.25
ACRYSOL RM-8W 6.00 0.69
Total 1021.62 100.00

Formulation Constants
Volume Solids (%) 36.8
Weight Solids (%) 48.7
Density (lb/gal) 10.2
PVC (%) 17.9
pH 9.0
Viscosity (KU) 88
VOC (g/L) 181

Water-Resistant Clear Coating

C-31-1

Ingredients Pounds Gallons

MAINCOTE HG-31 686.16 78.89
Water 102.92 12.33
Surfynol 104DPM 0.34 0.04
Surfynol DF-58 0.69 0.08
Butyl Cellosolve 61.75 8.22
Ammonia (15%) 3.43 0.44
Total 855.30 100.00

Formulation Constants
Volume Solids (%) 33.8
Weight Solids (%) 36.2
Density (lb/gal) 8.6
pH 8.53
Viscosity (KU) 50
VOC (g/L) 176
Sources of Recommended Raw Materials

Ingredients Function Supplier

ACRYSOL RM-8W Rheology modifier Rohm and Haas Company
100 Independence Mall West
Philadelphia, PA 19106
(215) 592-3000
Butyl Cellosolve Coalescent The Dow Chemical Company
Dowanol DPM 2030 Dow Center
Midland, MI 48674
(989) 636-1000
Surfynol 104DPM Wetting aid surfactant Air Products
7201 Hamilton Boulevard
Allentown, PA 18195-1501
(610) 481-4911
Surfynol DF-58 Defoamer Air Products
TAMOL 681 Dispersant Rohm and Haas Company
Tego Foamex 825 Defoamer Degussa Goldschmidt
710 South 6th Avenue
P.O. Box 1111
Hopewell, VA 23860-1111
(800) 446-1809
Texanol Coalescent Eastman Chemical Products
P.O. Box 431
Kingsport, TN 37662
(423) 229-2000
Ti-Pure R-706 Titanium dioxide pigment DuPont Company
DuPont Titanium Technologies
Chestnut Run Plaza 728/1229
P.O. Box 80728
Wilmington, DE 19880-0728
(800) 441-9485

Material Safety Data Sheets

Rohm and Haas Material Safety Data Sheets (MSDS) contain pertinent information that you may need to protect
your employees and customers against any known health or safety hazards associated with our products.

Under the OSHA Hazard Communication Standard, workers must have access to and understand MSDS on all
hazardous substances to which they are exposed. Thus, it is important that you provide appropriate training and
information to your employees and make sure they have available to them MSDS on any hazardous products in
their workplace.

Rohm and Haas Company sends MSDS for all its products, whether or not they are considered OSHA-hazardous, to
both the "bill to" and/or "ship to" locations of all its customers upon initial shipment, including samples. If you do
not have access to one of these MSDS, please contact your local Rohm and Haas representative for an additional
copy.

Updated MSDS are sent upon revision to all customers of record. In addition, MSDS are sent annually to all
customers receiving products deemed hazardous under the Superfund Amendments and Reauthorization Act.

MSDS should be obtained from your suppliers of other materials recommended in this bulletin.

Rohm and Haas Company is a member of the American Chemistry Council (ACC) and is committed to ACC’s
Responsible Care® Program.
ACRYSOL, MAINCOTE and TAMOL are trademarks of Rohm and Haas Company or of its subsidiaries or affiliates.

These suggestions and data are based on information we believe to be reliable. They are offered in good faith, but without guarantee, as
conditions and methods of use of our products are beyond our control. We recommend that the prospective user determine the suitability of
our materials and suggestions before adopting them on a commercial scale.

Suggestions for uses of our products or the inclusion of descriptive material from patents and the citation of specific patents in this
publication should not be understood as recommending the use of our products in violation of any patent or as permission or license to use
any patents of Rohm and Haas Company.

©Rohm and Haas, 2008 All rights reserved. October 2007