Safety Data Sheet

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OHYOUNG GHS Safety Data Sheet
According to Regulations (EC) No 1907 / 2006 , (EC) No 1272 / 2008 (CLP)
Version : 2-1
Revision : 01/05/2013
Product : Sunfix Blue SPR

1. Identification of the Substance/Preparation and Company

1.1 Product identifier

Trade name : Sunfix Blue SPR

1.2 Relevant identified uses of the substances or mixture and uses advised against
Relevant identified uses : This is a dyestuff which will be applied to yarn or fabric
manufactured from Cellulose fibres.

1.3 Details of the supplier of safety data sheet

Company name : OHYOUNG Industrial Co., Ltd.
Adress : 6th Floor SEMTOP-Building 448-16, Singil 5-dong, Yeongdeungpo-gu,
Seoul, Korea
Tel : +82-2-834-5050
Fax : +82-2-836-5101
E-mail : ohyoung@ohyoung.net.

1.4 Emergency telephone number

Emergency Aid : ohyoung@ohyoung.net.
Emergency Tel : +82-2-834-5050

2. Hazards identification

2.1 GHS Classification :

Eye Irritation Category 2B
Skin Corrosion/Irritation Category 3

2.2 Hazard Identification

Warning

H316 Causes mild skin irritation

H320 Causes eye irritation
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OHYOUNG GHS Safety Data Sheet
Version : 2-1
Revision : 01/05/2013
Product : Sunfix Blue SPR
2.3 Precautionary Statements:
(1) Prevention
P264 Wash ... thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
(2) Response
P305+P351+P338 If in eyes , Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rising
P332+P313 If skin irritation occurs: Get medical advice/ attention.
P337+P313 If eye irritation persists: Get medical advice/attention.

(3) Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.

(4) Disposal
P501 Dispose of contents/container should be according to local regulations and
Laws.
2.4 Risk phrase
R42/43 : May cause sensitisation by inhalation and skin contact.

3. Composition / Information on Ingredients

Chemical name CAS No. %

Azo Reactive dyestuffs Blue Trade secret 60-70
Sodium Sulfate 7757-82-6 30-40

4. First aid Measures

4.1 Swallowed
(1) Immediately give a glass of water.
(2) First aid is not generally required. If in doubt, contact a Poisons Information Center
or a doctor.
4.2 Eye
(1) If this product comes in contact with eyes:
- Wash out immediately with water.
- If irritation continues, seek medical attention.
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OHYOUNG GHS Safety Data Sheet
Version : 2-1
Revision : 01/05/2013
Product : Sunfix Blue SPR

4.3 Skin
(1) If skin or hair contact occurs:
- Flush skin and hair with running water (and soap if available).
- Seek medical attention in event of irritation.
4.4 Inhaled
(1) If fumes or combustion products are inhaled remove from contaminated area.
(2) Other measures are usually unnecessary.

4.5 Notes to physician

(1) Treat symptomatically.
Periodic medical surveillance should be carried out on persons in occupations
exposed to the manufacture or bulk handling of the product and this should include
hepatic function tests and urinalysis examination.

5. Fire-fighting Measures

5.1 Extinguishing media

(1) There is no restriction on the type of extinguisher which may be used.
(2) Use extinguishing media suitable for surrounding area.
5.2 Fire fighting
(1) Alert Emergency Responders and tell them location and nature of hazard.
(2) Wear breathing apparatus plus protective gloves for fire only.
5.3 Fire /explosion hazard
(1) Non combustible.
(2) Not considered to be a significant fire risk, however containers may burn.
May emit poisonous fumes.
5.4 Fire incompatibility
(1) None known.
5.5 Personal Protective Equipment
(1) Gas tight chemical resistant suit.
(2) Limit exposure duration to 1 BA set 30 mins.

6. Accidental Release Measures

6.1 Minor spills

(1) Clean up all spills immediately.
(2) Avoid breathing dust and contact with skin and eyes.
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OHYOUNG GHS Safety Data Sheet
Version : 2-1
Revision : 01/05/2013
Product : Sunfix Blue SPR

6.2 Major spills

(1) Moderate hazard.
-Caution : Advise personnel in area.
-Alert Emergency Responders and tell them location and nature of hazard.
-Personal Protective Equipment advice is contained in Section 8 of the MSDS.

7. Handling and Storage

7.1 Prpcedure for handling

(1) Avoid all personal contact, including inhalation.
(2) Wear protective clothing when risk of exposure occurs.

7.2 Suitable container

(1) Polyethylene or polypropylene container.
(2) Check all containers are clearly labelled and free from leaks.

7.3 Storage requirements

(1) Observe manufacturer's storing and handling recommendations.

8. Exposure controls and personal protection

8.1 Engineering Controls

(1) Local exhaust ventilation usually required. If risk of overexposure exists, wear
an approved respirator.

8.2 Personal Protection Respiratory Protection : Dust mask or respirator required.

(1) Hand Protection : Impervious gloves, for example, PVC.
(2) Eye Protection : Safety glasses and chemical goggles with side protections shield
(3) Body Protection : Wear protective clothing
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OHYOUNG GHS Safety Data Sheet
Version : 2-1
Revision : 01/05/2013
Product : Sunfix Blue SPR

9. Physical and chemical properties

Appearance : Powder / Blue

Odor : Odourless
Odor threshold : No data available
pH : Approx. 6.0 - 7.0 (0.5g/l)
Melting point No data available
Initial Boiling Point/Boiling Ranges : No data available
Flash point : No data available
Evapourating Rate : No data available
Flammability(solid, gas) No data available
Upper/Lower Flammability or explosive limits No data available
Vapour pressure : No data available
Solubility : 200g/l (25'C)
Vapour density(Air=1) : No data available
Specify gravity: No data available
Partition coefficient of n-octanol/water : No data available
Autoignition Temperature No data available
Decomposition Temperature : No data available
Viscosity : No data available
Molecular weight : No data available

10. Chemical Stability

10.1 Chemical Stability : Stable under normal temperatures and pressures.

10.2 Conditions to avoid : Heat, moisture.
10.3 Substances to avoid : Strong acid, strong bases and strong oxidizing agents.
10.4 Hazardous reactions : Product is considered stable and hazardous polymerization will
not occur.
10.5 Hazardous decomposition products : Thermal decomposition products may include
NOx, COx

11. Toxicological information

 Safety Data Sheet
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OHYOUNG GHS Safety Data Sheet

Version : 2-1
Revision : 01/05/2013
Product : Sunfix Blue SPR

Acute oral toxicity LD50 > 2,000mg/kg(rat) / OECD 401

Skin Irritation(Rabbit) non-irritant (rabbit) / OECD 404
Eye irritation(Rabbit) non-irritant (rabbit eye) / OECD 405

Sensitization (Skin) No data available

Remark : Test results of similarly composed product.

12. Ecological information

Fish toxicity
LC50 > 100mg/l (96h, Brachydaniorerio OECD 203)
Daphnia toxicity
No data available
Algae toxicity
No data available
Biodegradability
<20% (OECD 302 B)

Remark : Test results of similarly composed product.

COD(Mn)
650mg/l
BOD5
<30mg/l
Aquatic toxicity against
>1 >100mg/l (OECD 209 / IC50 / 3h)
bacteria
No data available
Biological accumulation
No data available
Water/Soil
No data available
Persistence:Air

Results of PBT and vPvB assessment : No data available

This product contains approx 3.5% copper complex in the chromophor.

13. Disposal considerations

(1) Recycle where possible Otherwise ensure that:

(2) licenced contractors dispose of the product and its container.
(3) disposal occurs at a licenced facility.
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OHYOUNG GHS Safety Data Sheet
Version : 2-1
Revision : 01/05/2013
Product : Sunfix Blue SPR

14. Transport information

(1) UN number : No data available

(2) UN Proper shipping name : No data available
(3) Transport Hazard class : No data available
(4) Packing group : No data available
(5) Marine pollutant : No data available
(6) Special precautions for user related to transport or transportation measures :
- EmS FIRE SCHEDULE : Not applicable
- EmS SPILLAGE SCHEDULE : Not applicable
(7) Not regulated for transport of dangerous goods : DOT, IATA, IMDG

15. Statutory Regulation

15.1 Regulation
H316 Causes mild skin irritation
H320 Causes eye irritation
R42/43 : May cause sensitisation by inhalation and skin contact.

15.2 Poison schedule : None

16. Other information

* A list of reference resources used to assist the committee may be found at :

( www.chemwatch.net/references)

※ Warranty
The information contained herein is based upon data believed to be correct. However, no
guarantee or warranty of any kind, expressed or implied, is made with respect to such data or
information. The user is responsible for determining whether the product is suitable for its
intended conditions of use.

OHYOUNG INDUSTRIAL CO., LTD. is a member of The Ecological and

Toxicological Association of the Dyestuffs Manufacturing Industry(ETAD)