(a) Mezcla kmol PRESION SATXB XT PB (Kpa)

Benceno 12.5 40 0.5 1 20

Tolueno 25 11.3
Agua 25 12.3

(b) Mezcla kmol PRESION SATXB XT PB (Kpa)

Benceno 25 40 1 0.5 40
Tolueno 12.5 11.3
Agua 25 12.3

© Mezcla kmol PRESION SATXB XT PB (Kpa)

Benceno 10 40 1 1 40
Tolueno 10 11.3
Agua 10 12.3
PT (Kpa) Ptotal (Kpa) YB YT YA
11.3 43.6 0.4587156 0.25917431 0.28211009

PT (Kpa) Ptotal (Kpa) YB YT YA

5.65 57.95 0.69025022 0.04874892 0.26100086

PT (Kpa) Ptotal (Kpa) YB YT YA

11.3 63.6 0.62893082 0.17767296 0.19339623
 log10 Pvap  =  A  -  [B / (T °C +  C)] mmHg
PRESION DE VAPOR BENCENO
PRESION DE BENCENO TOLUENO (°C) SISTEMA TB(°C) A
20 -2.6 18.4 benceno 80.1 6.89272
40 7.5 31.8 tolueno 110.6 6.95805
60 15.4 40.3 PRESION 760
100 26.1 51.9 2.5
200 42.2 69.5
400 60.6 89.5
760 80.1 110.6
1520 136

T(°C) X1 X2 PRESION 1 ^SPRESION 2^SK1 K2

110.622167 0 1 1783.55241 760.000128 2.3467794849 1.00000017
106.136845 0.1 0.9 1589.23624 667.86254 2.0911003158 0.8787665
100.23857 0.25 0.75 1358.85353 560.382014 1.7879651649 0.73734476
98.4605685 0.3 0.7 1294.71828 530.834356 1.70357668 0.69846626
95.1459483 0.4 0.6 1181.40388 479.063517 1.5544787843 0.63034673
92.1157592 0.5 0.5 1084.66424 435.333808 1.427189793 0.57280764
89.3320728 0.6 0.4 1001.31264 398.029218 1.3175166284 0.52372266
86.763244 0.7 0.3 928.891545 365.917739 1.2222257167 0.48147071
84.3828517 0.8 0.2 865.487104 338.049863 1.1387988217 0.44480245
82.1686336 0.9 0.1 809.590144 313.684181 1.0652501896 0.41274234
80.1017845 1 0 759.999642 292.235983 0.9999995289 0.38452103

𝑥1=(𝑃− 〖𝑃 2 〗 ^𝑆𝐴𝑇)/ 𝑌1=(𝑋1∗ 〖𝑃 1 〗 ^𝑆𝐴𝑇)/𝑃

( 〖𝑃 1 〗 ^𝑆𝐴𝑇−
X1 〖Y1𝑃 2 〗 ^𝑆𝐴𝑇 )
-1.2509E-07 -2.935702E-07 DIAGRAMA X-Y
0.1000001 0.2091102356 1.2
0.25000014 0.4469915332
0.30000061 0.5110740476 1
0.40000048 0.6217922653 0.8
0.5000015 0.7135970386
0.60000121 0.7905115714 0.6
Y

0.70000106 0.8555592976 0.4

0.80000065 0.9110397997
0.2
0.90000091 0.9587261421
1.00000077 1.0000002943 0
0 0.2 0.4 0.6 0.8 1
X
 0.2

0
0 0.2 0.4 0.6 0.8 1
X

composicion del vapor y liquido residual

Fx=yV+xL
Fx= 0.3225
y= 0.6775

DIAGRAMA T.X

109

104

100.01
Temperatura (°C)

99

94

89

84

79 0.21 0.360.4
0 0.1 0.2 0.3 0.5

X, Y fracciones mo
+  C)] mmHg

B C
1203.531 219.888
1346.773 219.693

Y1 Y2 SY a1 a2
0 1.00000017 1.0000001685 0 0.83333333
0.2091100316 0.79088985 0.9999998817 0.1515151515 0.78947368
0.4469912912 0.55300857 0.9999998578 0.3333333333 0.71428571
0.511073004 0.48892638 0.9999993843 0.3846153846 0.68627451
0.6217915137 0.37820804 0.9999995532 0.4761904762 0.625
0.7135948965 0.28640382 0.9999987176 0.5555555556 0.55555556
0.790509977 0.20948906 0.9999990394 0.625 0.47619048
0.8555580017 0.14444121 0.9999992146 0.6862745098 0.38461538
0.9110390573 0.08896049 0.9999995476 0.7407407407 0.27777778
0.9587251707 0.04127423 0.999999405 0.7894736842 0.15151515
0.9999995289 0 0.9999995289 0.8333333333 0

X-Y

0.8 1 1.2
 0.8 1 1.2

DIAGRAMA T.X.Y

3
0.360.4 0.5 0.6 0.7 0.8 0.9 1

X, Y fracciones molares
 EQUILIBERIO VAPOR LIQUIDO PARA ISOPROPANOL Y AGUA
95
T-X-Y
T, °C x y X1 Y1
93 1.18 21.95 0.0118 0.2195
90
89.75 3.22 32.41 0.0322 0.3241

TEMPERATURA (°C)
84.02 8.41 46.2 0.0841 0.462 85
83.85 9.1 47.06 0.091 0.4706
82.12 19.78 52.42 0.1978 0.5242 80
81.64 28.68 53.44 0.2868 0.5344
81.25 34.96 55.16 0.3496 0.5516 75
80.62 45.25 59.26 0.4525 0.5926
82.32 60.3 64.22 0.603 0.6422 70
0 0.1 0.2 0.3 0.4 0.
80.16 67.94 68.21 0.6794 0.6821
80.21 68.1 68.26 0.681 0.6826 X,Y FRACCION DE
80.28 76.93 74.21 0.7693 0.7421
80.66 85.67 82.7 0.8567 0.827
81.51 94.42 91.6 0.9442 0.916

log10 Pvap  =  A  -  [B / (T °C +  C)] mmHg

SISTEMA TB(°C) A B C
ISOPROPANO 82.5 7.74021 1359.517 197.527
AGUA 100 7.96681 1668.21 228
PRESION 760

T(°C) X1 X2 PRESION 1 ^SPRESION 2^SK1 K2

100.000608 0 1 1481.93445 759.999536 1.94991375 0.99999939
97.4746139 0.1 0.9 1354.26299 693.9707 1.78192498 0.91311934
95.1876881 0.2 0.8 1246.51525 638.370088 1.64015164 0.83996064
93.1024204 0.3 0.7 1154.44486 590.951373 1.51900639 0.7775676
91.1890606 0.4 0.6 1074.91109 550.058753 1.4143567 0.72376152
89.4237019 0.5 0.5 1005.5488 514.449014 1.32309053 0.6769066
87.7869977 0.6 0.4 944.549489 483.174027 1.24282827 0.6357553
86.2629071 0.7 0.3 890.501009 455.495273 1.17171185 0.59933589
84.8381548 0.8 0.2 842.29113 430.832319 1.1082778 0.56688463
83.5015732 0.9 0.1 799.030065 408.721738 1.05135535 0.53779176
82.2437423 1 0 759.999626 388.790141 0.99999951 0.51156598

Composicion de vapor-liquido como productos

DIAGRAMA DE T
110
Fx=Yv+Xl
Fx=
y= 0.46475
105

100
C)
 110

105
0.53525

100

TEMPERATURA (°C)
95

90

85

80
0 0.1 0.2 0.3 0.35 0.4 0.5
9
X-Y FRACCION
95
T-X-Y X-Y
1
90 0.9
0.8
85 0.7
0.6
80 0.5

Y
0.4
0.3
75
0.2
0.1
70
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
X,Y FRACCION DE ISOPROPANOL
X

Y1 Y2 SY
0 0.99999939 0.99999939
0.1781925 0.82180741 0.99999991
0.32803033 0.67196851 0.99999884
0.45570192 0.54429732 0.99999923
0.56574268 0.43425691 0.99999959
0.66154527 0.3384533 0.99999856
0.74569696 0.25430212 0.99999908
0.8201983 0.17980077 0.99999906
0.88662224 0.11337693 0.99999917
0.94621981 0.05377918 0.99999899
0.99999951 0 0.99999951

DIAGRAMA DE TX-Y
0.3 0.35 0.4 0.5 0.579
0.6 0.7 0.8 0.9 1
9
X-Y FRACCION
 X-Y

0.4 0.5 0.6 0.7 0.8 0.9 1

X