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7 Concrete: 7.1 Cement
7 Concrete: 7.1 Cement
7 Concrete
Concrete is a mixture of cement and water forming a paste that binds
aggregates together, to which admixtures may have been added.
7.1 Cement
Several cements are available, each displaying different properties.
1 Portland cements
These are made by burning together limestone and clay or similar materials
to form a clinker which is rich in calcium silicates. The clinker is ground to a
fine powder with a small amount of gypsum to control the rate of setting.
Concrete made with HAC develops very high early strength, allowing it to be
brought into early use. For this reason it was previously used in structural
concrete.
The 1985 Building Regulations allow the use of HAC only at high
temperatures in refractory concrete or mortars. Used with crushed fire brick
aggregate, it resists temperatures of 1,300ºC and, with refractory white
cement, 1,800ºC.
3 Supersulphated cement
Supersulphated cement is composed essentially of granulated blast furnace
slag, calcium sulphate and a small percentage of Portland cement or lime. Its
main advantage is its resistance to chemical attack by sulphate-bearing
waters and weak acids, but unlike HAC it is not subject to chemical
conversion.
Setting time
Initial setting time is determined by a Vicat apparatus (Figure 7):
z the initial setting time is the time taken from adding the mixing water
until the needle stops not less than 5 mm from the bottom of the
mould;
z the initial setting time should not be less than 45 minutes for ordinary
and rapid-hardening Portland cements.
z the test is made by repeatedly bringing the needle gently to the surface
of the block and releasing it;
z the final set is said to have occurred when the needle makes an
impression but the annular cutting edge does not;
z the final setting time is the time taken from adding the water until the
final set is observed;
z the final setting time must be not more than 10 hours for ordinary and
rapid-hardening Portland cements.
The practical significance of this test is that it ensures that the material
incorporating the cement will provide a working surface within a reasonable
length of time.
Materials Paper 1400 Page 43
Soundness
z A standard split brass cylinder about 25 mm diameter with needle
points attached to it is filled with wet neat cement (Figure 8).
z The mould is submerged in water for 24 hours and the distance
between the pointers measured.
z The mould is then submerged in boiling water for one hour and the
distance measured again.
z The difference represents the expansion of the cement and should not
be more than 10 mm.
1 Workability aids
These enable less water to be used during mixing:
2 Accelerators
These can increase the rate of setting and strength development. However:
4 Retarders
These are designed to retard the setting of concrete without affecting its
workability or strength. They are used in the production of large quantities of
concrete, where delays in the laying or placing of the concrete may occur.
Retarding admixtures are generally based on sugars, starches, zinc oxide, etc.
5 Polymers
Various types of polymer admixture are available, which are designed
specifically to strengthen or reduce permeability or increase the durability of
the final concrete element.
7.4 Aggregates
‘Aggregates’ are the gravels, sands, crushed rocks etc. which are mixed with
the cement and water to make concrete. Aggregates make up the bulk of the
concrete mix, and their selection is therefore most important to the
performance of the concrete.
z For reinforced concrete, the maximum aggregate size must allow the
concrete to be easily placed between the reinforcement. A nominal
size of 20 mm is usually specified for this type of work.
z In foundations and mass concrete work, a maximum of 40 mm can
often be used.
z For highly reinforced or narrow sections, a 10 mm maximum size may
be necessary.
Materials Paper 1400 Page 45
Quality of aggregates
Aggregates should be clean and free from organic impurities, and the
quantity of fine material (i.e. less than 300 mm) should be limited to less than
10% by volume. The aggregates should be hard and durable, free from
materials which may decay or decompose, and not frost susceptible. Grading
(i.e. the proportions of different sizes of particles which make up the
aggregate) should allow a dense, well-compacted concrete to be achieved.
7.5 Water
Water for concrete must be equal in quality to a good drinking water. Peat,
moorland or sea water must not be used in ordinary circumstances without a
laboratory test. If circumstances do require the use of these difficult types of
water, seek special advice.
Water:cement ratio
The strength of concrete is affected greatly by the ratio of water to cement in
the mix. Excess water evaporates after the setting of the cement, leaving
pores in the concrete, and weakening the material. The amount of water in
concrete should therefore be strictly controlled.
The usual practice is to keep the water content as low as possible consistent
with workability – that is, ease of placing and compaction. The final use for
the material is also taken into account. No great strength or density is
required for concrete over-site, and a wet concrete is permissible. However,
high strength is required for reinforced concrete and no more than sufficient
water to enable adequate placing and compaction must be used.
1. designated concrete
2. designed concrete
3. prescribed concrete
4. standardised prescribed concrete
5. proprietary concrete.
The volumes relate to ‘dry’ materials and must be adjusted for bulking if the
materials are damp. It is more accurate to batch materials by weight, as the
difference in weight for a given water content will not be so great as the
difference in volume.
The properties of the concrete in both the fresh and the hardened state must
be considered (Table 5).
The water:cement ratio is the most important factor for medium strength
concretes.
z The first step is to choose a ratio which will give the required strength.
Figure 9 illustrates the effect on strength of different ratios.
z Next it is necessary to select the proportions of fine and coarse
aggregates and the richness of the mix to give the required workability
and cohesiveness for the conditions of mixing and placing.
z Cubes are made from trial mixes and tested for crushing strength. The
proportions are adjusted until a satisfactory mix is obtained.
Materials Paper 1400 Page 47
The standard deviation of the cube crushing strength from the Codes
measures the variability of strength of all the concrete produced in a given
period. The standard deviation is affected by the method of batching and the
quality of supervision – the better the supervision, the lower the standard
deviation. As a general rule, the average strength of the test cubes should
equal the minimum strength specified plus twice the standard deviation.
7.7 Tests
The usual tests for measuring the workability of concrete are:
z A vertical metal cone 300 mm high, 200 mm diameter at the base and
102 mm diameter at the top, and open at both ends, is put vertically on
a flat metal surface and filled in four equal layers with the concrete to
be tested.
z Each layer is compacted with a standard rammer.
z When the cone is filled to its top, it is removed from the concrete,
which then slumps downwards.
z The amount of vertical displacement of the top surface of the concrete
is known as the slump. A dry mix gives a slump of less than 25 mm
while a wet mix may give a slump of 75 mm or more.
z Cover the bottom cylinder and close the two hopper traps.
z Fill hopper A level with concrete and open hopper A trapdoor – the
concrete falls into hopper B.
Materials Paper 1400 Page 49
This is the weight of fully compacted concrete. The compacting factor can
now be calculated:
z First, do a slump test to form a cone of concrete inside the drum. Use
the hopper head to ensure that no concrete spills into the drum outside
the slump cone.
z With the concrete cone formed (usually giving a very small slump),
carefully lower the transparent plate on top of the concrete.
z Switch on the vibrator. Under the weight of the transparent plate, the
concrete reforms from a cone into a cylinder, the top of which is
completely in contact with the transparent plate.
z Use a stopwatch to record the time taken from switching on the
vibrator until the concrete is seen to be completely in contact with the
transparent plate. This time, in seconds, is known as Vebe degrees. It
is a measure of the workability of the concrete: the longer the time
required to reform the concrete, the lower the workability.
Materials
If freshly mixed concrete is dropped from a height of more than 1.50 m, or
subjected to long hauls to or across the site, care must be taken to prevent
segregation. This is the separation of the concrete mix into its constituent
materials. Premixed concrete is now available and delivered to sites in
special lorries which are able to mix the concrete during transport, producing
on arrival a quality controlled and properly mixed concrete.
If such precautions are not taken during cold weather, so the mixture does
not fall below 5°C disastrous failures can arise, because the water used for
mixing freezes before the hydration of the cement can take place. Even after
the cement has set – if indeed it does set – the water in its minute pore spaces
can freeze, expand and burst the material.
Adding calcium chloride to the concrete speeds its hardening and probably
slightly improves its strength. It should not be used in quantities greater than
2% of the cement, otherwise the concrete sets too quickly and there is a
danger of corroding the reinforcement.
Attack by chemicals
Portland cement concrete may be attacked by:
Where these kinds of attack are anticipated, it is the practice to use the
proprietary sulphate-resisting Portland cement with a dense aggregate in
place of Portland cement. High alumina cement can often be used. It is
considerably more expensive than ordinary or rapid-hardening Portland
cement, but it is chemically very inert. It also resists high temperatures,
which Portland cement will not do.
Materials Paper 1400 Page 52
High alumina cement concrete requires special care in its curing because the
material emits considerable heat during its hydration. Unless it is kept damp
and at a temperature below about 25ºC during its setting and hardening,
serious damage to the concrete may result. For this reason it is inadvisable to
use high alumina cement in tropical climates except on the advice of the
manufacturers.
Lightweight aggregate
This is a form of concrete with low strength but high heat-insulating
properties. It is much used in flooring and roofing screeds and non-load-
bearing partition walls. Its use has increased greatly in recent years.
z lightness in weight;
z good thermal insulation;
z sound absorption (but not sound insulation);
z key for plaster;
z high moisture movement and drying shrinkage;
z low strength.
Aerated concrete
Bubbles of gas are produced in the wet mix by adding powdered aluminium
or a foaming agent, or by using excess water which leaves voids by
evaporation. Densities may vary between 400 and 1,440 kg/m³, with
compressive strengths of 0.7–3.5 N/mm².
Materials Paper 1400 Page 53
No-fines concrete
As the name implies, fine aggregate or sand is excluded from the mix.
Usually all the aggregate should pass a 19 mm mesh, with not more than 5%
passing a 4.76 mm mesh sieve. This form of concrete is discussed in
Building Research Digest No. 237.
Waterproofing
Concrete is normally a porous material, and various patent additives to
decrease its porosity have been marketed. So far, however, no preparation
has been found to be efficient. External waterproofers such as paraffin wax
have been tried but are open to objections.
8 Fibre-reinforced composites
Just as steel reinforcement can be used to carry the tensile stresses in
concrete, so short lengths (usually about 25 mm long) of fibre can be used to
reinforce materials such as cement pastes and plastics. The advantage of the
technique is that very thin sections with good structural properties can be
produced.
The reinforcing fibres are added to the material either while it is being mixed
or as an incorporated matting.
It is likely that future developments will include the use of carbon fibres or
other reinforcements either to supplement or replace glass fibres.