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Multiple Reactions Solved Example 1

Reactant A decomposes by three simultaneous reactions to form


three products, one that is desired, B, and two that are undesired, X
and Y. These liquid-phase reactions, along with the appropriate rate
laws, are called the Trambouze reactions (AIChE J.,5, 384).

The specific reaction rates are given at 300 K and the activation
energies for reactions (1), (2), and (3) are E1= 10,000 cal/mole, E2=
15,000 cal/mole, and E3= 20,000 cal/mole.

How, and under what conditions (e.g., reactor type(s), temperature,


concentrations), should the reaction be carried out to maximize the
selectivity of species B for an entering concentration of species A of
0.4 M and a volumetric flow rate of 2.0 dm3/s?
How could the conversion of B be increased and still keep selectivity
relatively high?

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